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Use of waste glass in alkali activated cement mortar

Article  in  Construction and Building Materials · January 2018

DOI: 10.1016/j.conbuildmat.2017.11.080

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Original citation:
J.X. Lu, C.S. Poon, Use of waste glass in alkali activated cement mortar, Construction and Building
Materials 160 (2018) 399–407.

https://doi.org/10.1016/j.conbuildmat.2017.11.080

First author: [email protected]; [email protected]

Use of waste glass in alkali activated cement mortar

Jian-Xin Lu, Chi Sun Poon*
Department of Civil and Environmental Engineering,
The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong

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Abstract:
This paper presents a study on alkali activated cement (AAC) mortar produced with waste soda-lime-silica

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glass. The waste glass was used simultaneously as a precursor and fine aggregates in the alkali activated fly
ash-slag mortar. The influences of waste glass in cullet and powder forms on workability, compressive and
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flexural strengths, fire resistance of AAC mortar were investigated. The experimental results showed that the
workability was gradually increased as the replacement level of natural sand by glass cullet increased, and it
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significantly improved with decreasing aggregates-to-binder ratios. The mechanical properties data indicated
that the compressive strength was reduced as the glass cullet content increased. However, for the flexural
strength, the optimum percentage of glass cullet replacement was 50. Due to the low reactivity, a reduction in
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strength was observed when the glass powder was used to replace the fly ash and slag. Nevertheless, in terms
of fire resistance, the incorporation of glass cullet could improve the resistance of the AAC to high temperature
exposure (800 oC). In particular, the AAC mortar prepared with the use of glass powder as a precursor
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exhibited remarkable high temperature resistance. The use of waste glass in AAC material was feasible from
mechanical properties and fire resistance points of view.
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Keywords: Alkali activated cement (AAC); Waste glass; Glass powder; Strength; Fire resistance

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1. Introduction

1.1. AAC material

It is generally known that the Portland cement industry produces 5 to 8% of the anthropogenic CO2 [1]
emission, which contribute significantly to the increase in greenhouse gas. It is therefore a need to develop
alternate concrete binders other than Portland cement. According to previous studies [2,3], the properties of
alkali activated cement (AAC) are comparable or even superior to Portland cement. A number of studies have
demonstrated that the AAC exhibits high compressive strength [4,5], excellent sulphate and seawater
resistance [6,7], good performance in the environment of acid corrosion [8,9], good resistance to chloride

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penetration [10], and freeze–thaw cycles [11,12]. These advantages are attributed to the special nature of the
hydration products and the lower porosity and permeability of the AAC. Due to its high strength and excellent
durability properties, the AAC mortar/concrete has potential applications in a range of applications. In

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Australia, pre-mixed alkali-activated concrete has been commercialized for the construction of a bridge
upgrade project [13]. Also, using AAC precast footpath panel segments produced from blends of fly ash, slag

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and alkaline activators has been successfully demonstrated in the industrial application [14]. In Ukraine, alkali
activated blast furnace slag cement has been used in the construction of apartment buildings, road sections,
pipes, drainage and irrigation channels, flooring for dairy farms, precast slabs and blocks [15]. Another known
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application for AAC was in the production of railway sleepers. Spain led the development of pre-stressed
steam-cured sleepers based on alkali activated fly ash [16]. Basically, this AAC material can be produced
through the alkaline activation of aluminosilicate materials such as coal fly ash (FA) and ground granulated
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blast furnace slag (GGBS). But in Hong Kong, there is no any steel plants for producing GGBS and almost
all FA has already been used up by the construction industry.
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1.2 Waste glass

Waste glass bottle (soda-lime silicate glass) is a significant solid waste type in the municipal solid waste (MSW)
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stream in Hong Kong. Due to the lack of a glass manufacturing industry, the current recycling rate of waste
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glass bottles is low (less than 10%) [17]. By contrast, based on the European Container Glass Federation [18],
11.6 million tons of waste glass bottles were collected in 2014 and the glass recycling rate has reached 74%
in Europe.

The HK SAR government plans to promote the recycling of waste glass beverage bottles in Hong Kong by
introducing a producers’ responsibility legislation to be implemented in late 2017. It has been estimated about
50 kilotons/annum of waste glass beverage bottles will be collected after the scheme is implemented. There is
an urgent need to find practical outlets for the collected waste glass.

Previously, Poon and co-workers in the Hong Kong PolyU have paid much effort on developing practical
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methods for recycling waste glass cullet as fine aggregates in concrete blocks or mortar production [19-29].
The results indicated that the incorporation of glass cullet as natural fine aggregates could reduce the drying
shrinkage [19,20] and water absorption due to the non-absorbent nature of glass [20]. The replacement of river
sand by glass cullet enhanced the fresh properties of concrete since the glass particles had a smooth surface
and low water absorption [21]. Also, the addition of glass cullet could improve the resistance to acid attack
[22] and high temperature exposure [23]. Furthermore, the use of glass cullet as aggregates could reinforce
photocatalytic activities because of its light transmittance property [24]. Based on our past research, it was
demonstrated that it was feasible to use the glass cullet as partial substitution of fine aggregates in producing
cement based building materials. And several practical and potential applications have been developed such

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as eco-glass concrete paving blocks [25], glass-based self-compacting concrete [26] and architectural mortars
[27,28]. In particular, the eco-glass concrete paving block technology developed has been commercially
transferred to the local block manufactures and the blocks have already been put into successful uses at various

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different sites in Hong Kong [29].

Additionally, after the further grinding to the glass cullet, the produced waste glass powder (WGP) with proper
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particle size can be used as a Portland cement replacement since it has been proven in many studies [30-34]
that the WGP has pozzolanic activities. Therefore, efforts have been made in the concrete industry to use WGP
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as a supplementary cementitious material [33-35] due to large quantities of amorphous silica and calcium in
glass. Also, attempts have been made to use WGP as an alkali-silica-reaction suppressor although it has a high
alkali content [36-38]. Recently, more studies have also pointed out that the finer glass powder showed
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significantly improved ability to enhance durability characteristics of concrete products [39,40].

During the past few years, there has also been increasing research efforts [41-50] directed to recycle WGP
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into AAC taking advantage of its chemical instability in alkaline environments and high content of silica-rich
glassy phase. These WGPs include waste cathode ray tubes glass [41], post-consumer window glass [42,43],
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waste solar panel glass [44], spent linear fluorescent lamps [45] and waste LCD glass [46]. However, there is
a lack of information on the alkali activation of soda-lime silicate glass [47-50]. It is expected that the high
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alkali and silicon contents of soda-lime silicate glass would facilitate the alkali-activation reaction [48,51]
making it an attractive material for partial replacement of FA or GGBS in the production of AAC. Furthermore,
it is also believed that using waste soda-lime silicate glass cullet to partially replace natural aggregates in the
AAC is feasible.

1.3 Research significance

This research will contribute to the environmental improvement and conservation of Hong Kong by recycling
waste glass and make a contribution to develop new technologies on waste glass recycling. Waste glass was
reused in two forms: (1) using waste glass powder to replace FA and GGBS in AAC mortar, (2) using the

3
waste glass cullet to replace natural aggregates for producing AAC mortar. Therefore, this study focused on
developing a novel way to maximize the re-utilization of waste soda-lime silicate glass both as a precursor
and aggregates for producing AAC materials. It is anticipated that recycled glass would constitute above 60%
by mass of the novel construction product developed. One intended use of the products can be precast partition
wall blocks with enhanced fire rating performance.

2 Experimental work

2.1 Materials

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The materials used to fabricate the AAC mortar were natural fine aggregates (river sand), recycled soda-lime
silicate glass, FA, GGBS and an alkaline activator. Natural fine aggregates (NFA) and recycled waste glass
were sourced from aggregate suppliers and waste recycling facilities in Hong Kong, respectively. The soda-

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lime silicate glass was crushed by the glass bottle recycler in Hong Kong to obtain suitable particle sizes for
use as fine aggregates. The collected waste glass cullet (WGC) was washed to remove the contaminant in the
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waste glass. The gradation and appearance of the NFA and WGC are presented in Fig. 1a. From the gradation
curves of NFA and WGC, it can be found that the WGC has a lower fineness than the NFA. The alkaline
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activator used in this study was a commercially available sodium hydroxide (NaOH).

(a) (b)
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Fig. 1 Gradation curve (a) and appearance (b) of NFA and WGC

For the glass powder, the WGC was furthered ground with a specified milling time (2h) by a laboratory ball
mill. Two types of commonly used mineral admixtures, i.e. FA and GGBS, were used in this study. FA was
produced as a by-product during the generation of electricity from coal fired power plants. GGBS (supplied
from China, a byproduct of steel production) was sourced from a commercial source. The particle size

4
distributions of the FA, GGBS and WGP were determined by a laser scattering technique, see Fig. 2d. The
chemical compositions of the FA, GGBS and WGP are shown in Table 1. Scanning electron microscopy (SEM)
was employed to observe the morphologies of FA, GGBS and WGP (Fig. 2). The micrographs show that the
FA consisted of many spherical particles in micrometer range, GGBS and WGP made up of vitreous structure
with a smooth surface texture, irregular shape with sharp edges.

(a) (b)

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(c) er (d)
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Fig. 2 Morphologies of FA (a), GGBS (b), WGP (c) and their particle size distributions (d)
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Table 1
Chemical compositions of FA, GGBS and WGP (ms %).
FA GGBS WGP
SiO2 45.70 34.78 73.5
Al2O3 19.55 14.22 0.73
Fe2O3 11.72 0.27 0.38
CaO 12.27 38.38 10.48
MgO 4.10 7.32 1.25
K2O 1.71 0.77 0.69
Na2O 1.36 - 12.74
TiO2 1.09 0.71 0.087

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SO3 1.82 3.12 -
SiO2 + Al2O3 + Fe2O3 76.97 49.36 74.61

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2.2 Mixture proportions

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As a benchmark, 30% FA and 70% GGBS by mass were used as precursors in the control alkali-activated
binder due to their high calcium and aluminum contents. The NFA in the AAC mortar was replaced by the
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WGC at 0, 25%, 50%, 75%, 100% to investigate the effects of various levels of WGC replacements on the
properties of AAC mortar. In the case of AAC mortar containing 100% WGC as aggregates, 30% of WGP
was further used as a replacement for FA or GGBS in the production of AAC mortar to amplify the use of
waste glass.
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It took two steps to prepare the AAC mortar. First, the pure sodium hydroxide was mixed with water to prepare
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a NaOH solution (10 M). Then, the cooled NaOH solution was introduced to the dry mixture of the precursors-
aggregates until a homogeneous mixture was formed. The water-to-binder (w/b) ratio was set to 0.4. Three
aggregate-to-binder (a/b) ratios (2.0, 2.5, 3.0) were taken to assess the effect of a/b on the workability, strength
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and fire resistance properties of AAC mortar. The procedure of fabricating the AAC mortar is shown in Fig.3.
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The mix proportions of AAC mortar are listed in Table 2. A range of mixes were prepared and named based
on variations of the compositions as follows:

·M0G: NFA only used as the fine aggregates.

·M25G: 25% of NFA was replaced by the WGC.
·M50G: 50% of NFA was replaced by the WGC.
·M75G: 75% of NFA was replaced by the WGC.
·M100G: 100% of NFA was replaced by the WGC (total fine aggregates are WGC).
·M2.5: The a/b in the mix was set to 2.5 (total fine aggregates are WGC).
·M2.0: The a/b in the mix was set to 2.0 (total fine aggregates are WGC).
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·MGF: The WGP was used to fully replace the 30% FA by mass (total fine aggregates are WGC).
·MGG: The WGP was used to partially replace the 30% GGBS by mass (total fine aggregates are WGC).

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Fig. 3 Procedure of producing AAC mortar

Table 2 Mix proportions of AAC mortar

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Precursors (g) Aggregates (g) Alkaline activator (g)
Mix a/b w/b
FA GGBS WGP NFA WGC NaOH solution
M0G 480 1120 0 4800 0 896 3.0 0.4
M25G 480 1120 0 3600 1200 896 3.0 0.4
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M50G 480 1120 0 2400 2400 896 3.0 0.4

M75G 480 1120 0 1200 3600 896 3.0 0.4
M100G 480 1120 0 0 4800 896 3.0 0.4
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M2.5 480 1120 0 0 4000 896 2.5 0.4

M2.0 480 1120 0 0 3200 896 2.0 0.4
MGF 0 1120 480 0 3200 896 2.0 0.4
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MGG 480 640 480 0 3200 896 2.0 0.4

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2.3 Test methods

2.3.1 Workability

The workability of the AAC mortar was determined according to BS EN1015 [52]. Table 2 shows the mix
proportions of different AAC mortars prepared. The workability value was measured by using a mini-slump
flow cone with a 100 mm internal diameter on a 250 mm flow table disc. Firstly, the mold was filled with the
fresh mortar, then raised vertically to spread out the mortar on the table by vibrating the disc 15 times at a
constant frequency. The spread diameters of the mortar after vibration were recorded.

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2.3.2 Mechanical properties

The mix proportions of the AAC mortar for the compressive strength tests are given in Table 2. All the well
mixed composites were poured into cube molds with the size of 50 × 50 × 50 mm. Each mold was put on a
vibrating table for 15s for compaction. After 24h, specimens were demolded and kept in laboratory conditions
of 25 ± 2 oC and 50 ± 5% relative humidity. After 1, 4, 7, 14, 28 and 60 days of air curing, three cubes were
tested for the compressive strength by a hydraulic compression machine with a loading rate of 0.3 MPa/s. For
the three-point flexural test, specimens of 40 mm ×40 mm ×160 mm size were prepared. The mixtures (M0G,
M25G, M50G, M75G and M100G) were mixed thoroughly before the fresh mortars were cast into steel molds.
After 60 days of air curing, three specimens were tested for flexural strength in conformity with ASTM C348

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[53].

2.3.3 Fire resistance

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For the high temperature exposure test, after 60 days of curing for each mix (Table 2), three cube specimens
were transferred to the oven at 105 oC for 24h to remove moisture. Then, the specimens were heated in an

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electric high temperature furnace at a rate of 5 oC/min from room temperature to 800 oC. After a 2h holding
period, the furnace was switched off and the specimens were allowed to be cooled down in the furnace before
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the residual compressive strength were tested. Based on the compressive strength values of AAC mortar with
and without exposure to 800 oC, the residual strength index (RSI) was calculated by the following equation:

RSI = Sr / Si × 100% (1)

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Where Sr is the residual compressive strength of AAC mortar after heating at 800 oC; Si is the initial
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compressive strength of AAC mortar after 60 days of curing (without exposure to 800 oC).

The RSI was employed in this study in order to evaluate the fire resistance of AAC mortar. A higher RSI
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value means a higher resistance to high temperature exposure, and vice versa.
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3 Results and discussion

3.1 Workability

Fig. 4 shows the effect of waste glass including WGC and WGP on the workability of AAC mortar. Obviously,
it was found that the increasing replacement level of NFA by WGC improved the workability of AAC mortar
(blue arrow). This behavior was also observed by Wang et al. [54] and Terro [55] in the cases of ordinary
Portland cement (OPC) concrete. They attributed the enhancement of workability to the inherent smooth
surface and negligible water absorption of glass. Another reason may be resulted from the larger particle size
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of WGC compared to the NFA (see Fig. 1a). Less amount of cement paste was needed to coat the WGC which
resulted in more available cement paste necessary for the fluidity. However, the increase magnitude in the
flow value due to the replacement of NFA by WGC was not significant. And, no bleeding nor segregation
occurred when 100% NFA were replaced by WGC. Conversely, there were severe bleeding and segregation
happening in OPC concrete when 100% fine aggregates were replaced by the recycled glass aggregates [56].
This difference is because the alkali activated cement is fast-setting whereas OPC has slow-setting
characteristics [57]. Therefore, in terms of workability, the use of waste glass in AAC materials is feasible
without concerning the consistency and homogeneity.

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Fig. 4 Flow values of AAC mortar

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In order to enhance the workability of AAC mortar containing 100% WGC, different a/b ratios were adopted
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to produce the AAC mortar with the desirable flow. As indicated in Fig. 4, the flow values were effectively
increased as the a/b ratio decreased (red arrow). The improvement in workability was caused by the additional
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cement paste were available for the movement of AAC mortar. Furthermore, a lesser amount of WGC could
reduce the impediment due to the edged and angular grain shapes of WGC.

In addition, when the FA was fully replaced by the WGP in AAC mortar, a reduction of flow value was
observed. This was related to the coarser particle size and irregular shape of WGP, which would reduce the
motility of the mortar. Similar results were obtained in our previous study [58]. On the other hand, it is well
known that the addition of FA in OPC-based mortar or concrete improves the workability because of the ball-
bearing effect and the consequence of electrical surface charges [59]. Hence, the replacement of FA by WGP
resulted in a reduction in the workability. However, it can be noticed that the replacement of GGBS by 30%

9
of WGP had a little effect on the flow value. The reason may be due to the similar structure between the WGP
and the GGBS (as seen in Fig. 2). Therefore, the combined use of WGC as aggregates and WGP as a precursor
in AAC mortar seems to be attractive with respect to the workability property.

3.2 Mechanical properties

3.2.1 Effect of WGC content on the strength of AAC mortar

(a) (b)

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Fig. 5 Effect of WGC content on the strength of AAC mortar
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Fig. 5 shows the development of strength for the AAC mortar with the curing age up to 60 days. From Fig. 5a,
the compressive strength increased with curing age regardless of the replacement level of WGC. Not only did
the strength increase at early age, but it also increased at the late age. It is expected that the compressive
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strength would be further enhanced after 60 days of curing. However, the compressive strength was slowly
decreasing as the WGC content increased. This is related to the smooth surface of WGC, which resulted in
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weaker bond strength between the glass and the matrix [27]. In addition, the micro-cracks in WGC induced
during the glass crushing process might also lead to a reduction in the compressive strength [60].
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In terms of flexural strength, the development trend is different from that of the compressive strength. The
flexural strength was increased with an increase of WGC content of up to 50%, and then decreased as the
WGC content was further increased. This means that, for the flexural strength, the optimum percentage of
WGC replacement was 50. As indicated in Fig. 1b, the NFA made up of relatively round shape particles, while
the WGC exhibited angular shape and a higher aspect ratio than NFA. Such a difference would result in the
enhancement of flexural strength for the mix prepared with WGC. This speculation was verified by the
positive effect of glass fibers (with a high aspect ratio) in improving the flexural or bending strength of cement
mixtures [61,62]. However, when most of the NFA was replaced by the WGC, the weakening effect of WGC

10
due to the smooth surface and micro-cracks present would play an important role in controlling the flexural
strength. Thereby a reduction in the flexural strength was observed.

3.2.2 Effect of a/b ratio on the compressive strength of AAC mortar

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Fig. 6 Effect of a/b ratio on the compressive strength of AAC mortar
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The development of compressive strength of AAC mortars produced with different a/b ratios is given in Fig.
6. It is obvious that the a/b ratio has only a slight influence on the compressive strength regardless of the
curing ages. This phenomenon was not consistent with the case of the OPC-based system. Generally, the
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reduced a/b ratio should lead to an enhancement of strength induced by the increased OPC content. However,
in AAC mortar, the increased binder content did not contribute to the strength development. The explanation
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lied probably in the higher shrinkage due to the higher binder content [63,64]. As pointed out by many
researchers [65-67], AAC mortar/concrete has considerably higher drying shrinkage than OPC
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mortar/concrete. And, when the AAC materials were cured under dry conditions, the formation of microcracks
due to the high shrinkage would lead to lower compressive strength [68]. Hence the reduced a/b ratio (higher
binder content) was not helpful to the development of compressive strength. In addition, the effective w/b ratio
was increased for the AAC mortar with lower a/b ratios since a lesser amount of water was required to coat
the aggregates. Therefore, the effect of a/b ratio on the compressive strength was insignificant. Regardless of
the a/b ratio, the compressive strength of the mortar prepared with 100% WGC obtained at 60 days was about
30 MPa. Such a high strength was encouraging for further use of WGP in this type of AAC mortar.

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3.2.3 Effect of WGP on the compressive strength of AAC mortar

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Fig. 7 Effect of WGP on the compressive strength of AAC mortar
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Fig. 7 presents the effect of using WGP as a precursor on the compressive strength for AAC mortar with a/b
ratio of 2.0 (M2.0). In this study, 30% WGP was used to replace FA and GGBS, respectively. However, with
increase in time, M2.0 which was prepared without any WGP performed better than the composites prepared
with WGP. This is a clear indication that the use of WGP as a partial precursor replacement significantly
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reduced the strength of AAC mortar. The explanation was directly related to the lower reactivity of WGP
resulting from the coarse particle size of WGP (Fig. 2) when compared with FA and GGBS. The reduction in
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strength was also found by Torres et.al [69], who mentioned that the glass had a lower activation potential by
the alkaline solution compared to GGBS. Nonetheless, the compressive strength values of AAC mortar
prepared with WGP still exceeded 15MPa, which can meet the strength requirement for the non load bearing
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partitions [70].
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3.3 Fire resistance

The residual compressive strength and the residual strength index (RSI) of AAC mortar after exposure to 800
o
C are shown in Fig. 8. It can be found that the residual compressive strengths of the mortars prepared with
WGC were slightly lower than that of the mortar prepared without WGC. And, the residual strength tended to
be stable with the increase of WGC replacement level. These behaviors indicate that the potential melting of
WGC at the high temperature did not cause severe deterioration in strength for the AAC mortar. This result is
in agreement with the finding of Ling et al. [71], who concluded that the properties change of recycled glass
at 800 oC did not have significant effect on the strength degradation of the concrete prepared with glass cullet
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incorporation. On the contrast, the RSI values tended to increase as the WGC content in the mortars increased,
which suggests that the introduction of WGC could mitigate the strength loss due to the exposure to the high
temperature. The beneficial effect was probably attributed to the less thermal incompatibility between the
AAC paste matrix and the WGC. According to the previous investigations [72,73], the alkali-activated
aluminosilicate composites exhibited thermal shrinkages when subjected to elevated temperature exposure.
While both the soda-lime glass and quartz sand used in this study were expansive under high temperature and
the thermal expansion coefficients of quartz (18 ×10-6/ oC [74]) was much higher than that of glass (7-9×10-6/
o
C [75]). Therefore, the replacement of NFA by WGC alleviated the thermal expansion mismatch between the
contracting AAC paste and the expanding aggregates. In addition, the transition of quartz in the NFA from the
β-form to the α-form at 573 oC was accompanied by volume changes and resulted in damages of the aggregate-

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binder interface zone, thus promoted the strength loss [76]. Obviously, the different thermal expansion
between the gel matrix and aggregates was also partly responsible for the strength deterioration after exposure

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to the elevated temperature [73].

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Fig.8 Residual compressive strength and RSI of AAC mortar subjected to 800 oC
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Another interesting phenomenon is that the RSIs of the AAC mortar prepared with and without WGC were
higher than 50%. Furthermore, visual examination showed that there were no visible cracking and spalling in
any AAC specimens. By contrast, previous research [71,77] revealed that the RSIs of OPC-based composites
were approximately 20%. This difference demonstrates that the high temperature resistance of AAC mortar
was superior to OPC mortars or concrete. Similar results were obtained by Zuda and Černý [74], who found
that the thermomechanical behavior of the alkali-activated aluminosilicate composite was mostly better than
of the OPC-based composites. The improvement in the mechanical property of AAC mortar after elevated

13
temperature exposure was mainly due to the fact that the crystallization of akermanite produced in the
aluminosilicate material at 800 oC led to a formation of ceramic bond with very high thermal stability [78].
Furthermore, no calcium hydroxide present in AAC mortar also contributed to the better high temperature
performance [72].

From Fig. 8, the residual compressive strength and RSI values of AAC mortars prepared with different a/b
ratios were similar, which shows that the a/b ratio has only a slight impact on the fire resistance of AAC mortar.
The reasons may be considered from two negative effects caused by the high temperature, one is the
decomposition of reaction products [79], and the other is the thermal incompatibility between the matrix and

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the WGC as discussed before. Therefore, for the composites prepared with higher a/b ratios, the latter effect
may be dominant due to the higher aggregates content; while for the lower a/b ratio composites, the resistance
to elevated temperature exposure was probably controlled by the former effect because of the higher binder

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content. An interesting observation is that the replacement of FA and GGBS by WGP could develop higher
RSI values compared with the AAC mortar without the WGP. And, the RSI values of MGF and MGG were
able to reach 75.5% and 72.5%, respectively. The results indicate that the introduction of WGP into the AAC
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mortar effectively improved the resistance to elevated temperature exposure. The higher RSI values in WGP
blended AAC mortar may be explained by phenomena similar to those observed in WGP blended OPC mortar
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[80], i.e. the transformation behavior of unreacted WGP from solid to liquid above the melting point (below
700 oC [81]) was helpful to fill up open pores and microcracks induced by the high temperature. On the other
hand, based on the fusion characteristic, fine glass powder has been commonly used as a fluxing agent to
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accelerate the sintering progress in the fabrication of ceramic products [82,83]. As mentioned, when the AAC
mortar was subjected to high temperature, a much stronger ceramic bond would form due to the crystallization
of akermanite [78,79]. Therefore, it is believed that the vitreous phase originated from the melted WGP would
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promote the crystallization process, which contributed to the high temperature exposure resistance. However,
this speculation still need to be investigated in details.
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The glass-based AAC material has potential to be used as partition wall blocks since it not only offers the
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feasibility to massive use of waste glass in non-OPC material, but also develops good mechanical properties
and fire resistance. Nonetheless, more studies are required to shed more light on the effect of incorporation of
waste glass in the AAC material, for example, the ASR risk of glass aggregates in AAC material with high
alkali concentrations; the effect of waste glass on the drying shrinkage, efforescence and carbonation of AAC
material.

14
4 Conclusions

This study developed a good mechanical strength and fire resistance non-OPC cement mortar, which can be
used for the fabrication of new precast construction products. The following conclusions can be drawn from
this study:

·The increasing replacement of NFA by WGC gradually improved the workability of AAC mortar. The reason
mainly due to the smooth surface, non-absorption and larger particle sizes of glass. The reduction in a/b ratio
led to a large enhancement in flow values. However, the replacement of FA by WGP caused a decrease in the
workability related to the coarser particle size and irregular shape of WGP. But, there was only a slight effect

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on the flow value with the replacement of GGBS by WGP due to their similar shape.
·The compressive strength of AAC mortar slowly decreased as the WGC content increased. Nevertheless,
the flexural strength was increased with an increase of WGC content up to 50%, and then decreased as the

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WGC content was further increased.
·The a/b ratio has a little influence on the compressive strength of AAC mortar. The explanation lied probably
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in the higher shrinkage due to the higher binder content (i.e. lower a/b ratio).
·The use of WGP as a partial precursor replacement significantly reduced the strength of AAC mortar. This
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phenomenon was attributed to the low reactivity of WGP compared to the FA and GGBS. Nonetheless, the
compressive strength values of WGP blended AAC mortar still could meet the strength requirement for non
load bearing partition blocks.
·The use of waste glass in AAC mortar did not cause severe deterioration in strength when subjected to high
in

temperature (800 oC). On the contrary, the introduction of WGC could mitigate the strength loss after exposure
to the high temperature. The reason may be due to the fact that the replacement of NFA by WGC alleviated
pr

the thermal expansion mismatch between the contracting AAC paste and the expanding aggregates.
·The high temperature resistance of AAC mortar is normally considered as a superior quality to OPC mortars
or concrete. The study found that the inclusion of WGP in the AAC mortar could further improve the resistance
e

of the AAC to elevated temperature exposures.

Pr

The findings of the present investigation have shown quite encouraging results and opened up an outlet for
the recycling of WGC and WGP in AAC composites.

Acknowledgment

Financial supports from the Environment and Conservation Fund and the Woo Wheelock Green Fund for this
research project are gratefully acknowledged.

15
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