2.2 Water

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2.

2 Water

Topic 2: Molecular Biology


Understandings:

● Outline that water molecules are polar and


that hydrogen bonds form between them.
● Describe how substances can be
hydrophilic or hydrophobic.
● List examples of hydrophilic and

2.2 Essential ●
hydrophobic substances.
Explain hydrogen bonding and dipolarity,

Idea:
and the link with the cohesive, adhesive,
thermal and solvent properties of water.
● State one example of a benefit to living
organisms of each property of water.
Water is the medium of life ● Explain the use of water as a coolant in
sweat.
● Outline the modes of transport of glucose,
amino acids, cholesterol, fats, oxygen and
sodium chloride in blood, in relation to their
solubility in water.
● Compare the thermal properties of water
with those of methane.
● Outline that water molecules
are polar and that hydrogen
bonds form between them.
● Describe how substances
can be hydrophilic or
hydrophobic.
Lesson 1 ● List examples of hydrophilic
and hydrophobic
substances.
Basic Properties of Water ● Explain hydrogen bonding
and dipolarity, and the link
Kognity 2.2.0, 2.2.1, 2.2.2 with the cohesive, adhesive,
Cambridge Pg. xx-xx thermal and solvent
properties of water.
● State one example of a
benefit to living organisms
of each property of water.
Why Water?

Water is essential for life on Earth

● Water covers 71% of Earth’s surface


● Body cells are ~65% water
● Majority of biochemical reactions
occur in liquid (water-based
solutions)
● Essential reactant in photosynthesis
and product of cellular respiration
Structure of Water

● H2O: two Hydrogen atoms, one Oxygen atom


covalently bonded (sharing electrons)
● Oxygen is more electronegative than hydrogen,
so electrons have stronger pull on shared
electrons → slight negative charge on oxygen
(δ-), slight positive charge on hydrogen (δ+)
● Water is a polar molecule
● Polarity: partial charges on different parts of the
molecule
Polarity of Water

● The partial charges on water causes


attraction and repulsion at different
regions of the molecule
● Like repels like, opposites attract
● Weak hydrogen bonds form as a result
● Allows for cohesion and adhesion
○ Cohesion: water sticking to water due to
hydrogen bonds
○ Adhesion: water sticking to other polar
molecules due to hydrogen bonds
Hydrophilic & Hydrophobic

Hydrophilic: “water-loving” → other polar


molecules or charged compounds

● Ex. Sugars and salts are soluble in water

Hydrophobic: “water-hating” → non-polar or


uncharged compounds

● Ex. Fats and oils are not soluble in water


Cohesion and Adhesion

Cohesion: tendency for water to stick to water


due to hydrogen bonds
● Individual hydrogen bonds are weak → if
there are many bonds, they are
cumulatively strong

● Results in strong surface tension of water


→ acts like an elastic membrane that
allows things to float on the surface, and
to form spherical droplets
Cohesion and Adhesion

Adhesion: tendency for water to stick to other


polar molecules due to hydrogen bonds

● Ex. Glass is a polar surface water adheres to


● Results in capillary action → water (and any
dissolved substances) can climb up thin spaces
against gravity
● Allows water to travel up plant stems against
gravity
Thermal Properties of Water

High specific heat capacity: high amount of energy


(heat) required to break hydrogen bonds

● Specific heat: amount of heat required to change 1


g of a substance by 1°C

Thus water does not change temperature quickly →


allows for stability in aquatic ecosystems
Thermal Properties of Water

High latent heat of vaporization: requires a


large amount of heat to be absorbed to
change from liquid to gas
Allows water to be an effective coolant -
when water evaporates, it takes a large
amount of energy (heat) with it
● Ex. evaporation of sweat cools down
surface of the skin
● Also relates to water’s fairly high boiling
point
Water as a Solvent

● “Universal solvent”
● Can dissolve ionic compounds and polar
compounds like glucose
● All reactions in cells occur in dissolved form
in liquid
● Dissolved substances carried in blood
plasma (glucose, amino acids, sodium
chloride)
● Some substances are insoluble in water, but
can be dissolved in fat (fat soluble
substances)
Practice:
Kognity: 2.2 Water Lesson 1 Review
Questions

Read: 2.2.3, 2.2.4 on Kognity

Please complete for next class


● Outline the modes of
transport of glucose, amino
Lesson 2 acids, cholesterol, fats,
oxygen and sodium chloride
Modes of Transport and Thermal in blood, in relation to their
Properties solubility in water.
Kognity 2.2.3, 2.2.4 ● Compare the thermal
Cambridge Pg. xx-xx properties of water with
those of methane.
*You should know at least one example of a

Biological Benefits of Water benefit to living organisms of each property


of water*

Properties of Benefit to living organisms


Water

Cohesive ● Allows water to be pulled up from the roots to the leaves of plants.
properties
● Permits insects, such as pond skaters, to walk/float on the surface of water to
catch their prey.

Adhesive ● Capillary action generated by adhesive forces assists the pumping action of
properties the heart to help blood move through blood vessels.

● Adhesion of water molecules to the cell wall of xylem vessels helps water move
against gravity from the roots to the leaves.
*You should know at least one example of a

Biological Benefits of Water benefit to living organisms of each property


of water*

Properties of Benefit to living organisms


Water

Thermal ● Evaporation of sweat from body surfaces involves heat loss, which brings
properties about a cooling effect.
● The high specific heat capacity of water makes aquatic ecosystems more
stable than terrestrial.

Solvent ● Water dissolves mineral ions in the soil and transports it along xylem vessels
properties from the roots to all parts of the plant.
● Water in blood plasma dissolves a range of solutes and gases, which makes it
possible for blood to transport nutrients and gases around the body
● Water’s versatility (its ability to exist as a liquid, solid and vapour) makes
water a universal solvent and medium for numerous biochemical reactions.
Transport of Biological Molecules

● Transport of biological molecules around the body to and the various


tissues is essential for multicellular organisms
● All cells require oxygen, glucose, and minerals
● All cells produce waste products to be excreted/removed
● Most transportation occurs through blood: water-soluble molecules
dissolve in blood plasma
● Water-insoluble substances transported via lymph vessels after
absorption during digestion
Exam-Style Question! [4 marks]

Plants have developed efficient


methods for transport and for
synthesis of foods.

Outline how the properties of water


make it an ideal transport medium in
plants.
Mark Scheme [4 marks]

a. polarity of water;
b. hydrogen bonds between water molecules;
c. cohesion between water molecules/water molecules stick together;
d. cohesion allows tensions/low pressures/transpiration pull/movement upward/against
gravity;
e. adhesion to cellulose/cell walls generates tensions/pull (in xylem) OR adhesion to
xylem walls/vessel walls causes capillary rise/upward movement;
f. solvent for many substances / many substances dissolve;
g. liquid at most temperatures experienced by plants / liquid so can flow
Biological Molecules in the Blood
Glucose

● Polar → hydrophilic and water soluble


● Blood glucose must be carefully
maintained because of its effect on
osmosis

Question: what would happen if blood


glucose was very hypertonic to the glucose
in red blood cells?
Amino Acids

● Are both positively and negatively


charged
● Most are water soluble, depends on
the size of the R group
● Hydrophilic R group → easily
dissolved and transported in the
blood
● Hydrophobic R group → not easily
dissolved, transported in lower
concentrations
Fats & Cholesterol

● Non-polar → normally insoluble in


water
● Transported in lipoproteins
● Lipoprotein = single layer of
phospholipids w/ embedded
proteins surrounding the fats and
cholesterol
Oxygen

● Non-polar BUT because they


are so small, can dissolve to a
limited extent

● Oxygen binds to hemoglobin to


form oxyhemoglobin and is
carried by the red blood cells
Sodium Chloride (& Other Ions)

● Ionic compounds separate into


their component ions and dissolve
easily in the blood to be
transported
● NaCl → Na+ + Cl-
● Positive ions move towards
negative dipole of oxygen,
negative ions move towards
positive dipole of hydrogen
Water vs. Methane
Water Both Methane

● H2O ● Both are ● CH4


● Polar covalent ● Non-polar
● Can form hydrogen bonds compounds ● Cannot form hydrogen bonds
● Possesses cohesive, adhesive, ● Waste product from
● Similar size and
thermal, and solvent properties anaerobic bacteria
molecular mass ● Greenhouse gas
Thermal Properties of Water and Methane

Specific heat capacity:

● Water: 4.2 J/g/°C


● Methane: 2.2 J/g/°C Main Idea: Water can absorb
more energy before increasing in
Latent heat of vaporisation: temperature, and requires more
● Water: 2257 J/g energy to vaporise because of its
● Methane: 760 J/g ability to make hydrogen bonds
Exam Style Question [2 marks]

Distinguish between the thermal properties of


methane and water.
Mark Scheme [2 marks]

● water has higher boiling/melting point;


● water has a higher specific heat capacity;
● water has a higher latent heat of vaporization;
● differences due to water having many H-bonds/polarity between the
molecules while methane has no H-bonds/polarity;
Practice:
Kognity: 2.2 Water Lesson 2 Review
Questions

Read: Kognity 2.3.0, 2.3.1, 2.3.2

Please complete for next class

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