Technical Manual: Uv Photometric Ozone Analyzer

CHARACTERISTICS
INFORMATION
GENERAL
TECHNICAL MANUAL
OPERATION
O342 Module
INSTRUCTION
OPERATING
UV PHOTOMETRIC
OZONE ANALYZER
MAINTENANCE
PREVENTIVE
MAINTENANCE
CORRECTIVE
APPENDIX
111 bd Robespierre, 78300 POISSY – TEL. 33(0)-1.39.22.38.00 – FAX 33(0)-1.39 65.38.08

http://www.environnement-sa.com
Environnement S.A O342 MODULE Duplication prohibited
WARNING
The information in this documentation is subject to change without notice.
Environnement S.A. all rights reserved.
This document does not represent a commitment under part of Environnement S.A.
0–2 MAY 2002

Duplication prohibited O342 MODULE Environnement S.A
SUMMARY
CHAPTER 1. GENERAL INFORMATION - CHARACTERISTICS
1.1. GENERAL INFORMATION 1-3
1.2. CHARACTERISTICS 1-9
CHAPTER 2. OPERATION
2.1. PRINCIPLE OF MEASUREMENT 2-3
2.2. ANALYSIS 2-5
2.3. AUTOMATIC RESPONSE TIME 2-8
2.3. SIMPLIFIED FLOWCHART OF MAIN PROGRAM 2-9
CHAPTER 3. OPERATING INSTRUCTION
3.1. INITIAL STARTUP 3-4

3.2. PROGRAMMING THE O342 MODOLE 3-7
3.3. DESCRIPTION OF THE DIFFERENT SCREENS 3-10
3.4. CALIBRATION 3-38
CHAPTER 4. PREVENTIVE MAINTENANCE

4.1. SAFETY INSTRUCTIONS 4-3
4.2. MAINTENANCE CALENDAR 4-4
4.3. MAINTENANCE OPERATION SHEETS 4-5
4.5. O342M MAINTENANCE KIT 4-20
CHAPTER 5. CORRECTIVE MAINTENANCE
CHAPTER 6. APPENDIX
6.1 CALIBRATION PROCEDURE 6-2
MAY 2002 0–3

LIST OF TABLES
Table 3.1 – DB37 and DB25 connectors links 3–3
Table 3.2 – MUX signals 3–34
Table 5-1– List of faults and corrective actions 5–4

Table 5-2 – Board RS4i Configuration 5–7
Table 5-3 – Keyboard Interface configuration 5–8
Table 5-4 – ESTEL board configuration (when option available) 5–9
Table 5-5 – MODULE board configuration 5–11
Table 5-6 – Flowrate control board configuration and setting 5–12
LIST OF FIGURES
Figure 1.1 – O342M Presentation 1-2
Figure 1.2 – Keyboard and display 1-3
Figure 1.3 – Rear panel 1-4
Figure 1.4 – Components location 1-6
Figure 1.5 – Links between units 1-10
Figure 1.6 – Outline dimensions 1-11
Figure 2.1 - Ozone absorption spectrum 2-2

Figure 2.2 – General schematic diagram 2-4
Figure 2.3 – Acquisition of UV energies I0 and I 2-6
Figure 2.4 – Simplified flow chart of main program 2-9
Figure 2.5 – Schematic diagram of basic gas flow system 2-11
Figure 3.1 – Electrical connections 3-3

Figure 3.2 – Fluid connection 3-4
Figure 3.3 – Installation of the "sample gas" inlet 3-5
Figure 3.4 – Software overview 3-9
Figure 3.5 – Printout example 3-32
Figure 3.6 – Filtering columns 3-39
Figure 3.7 – Schematic diagram of a typical UV photometric calibration system (1) 3-42
Figure 3.8 – Schematic diagram of a typical UV photometric calibration system (2) 3-42
Figure 3.9 – Gas flow system with zero/span solenoid valve 3-50
Figure 3.10 – Gas flow system with ozone generator 3-52
Figure 4-1 – Inlet dust filter 4–5

Figure 4-2 – Exploded view of the pump. 4–9
Figure 4-3 – Maintenance on measurement cell 4–11
Figure 4-4 – Replacement of Ozone scrubber 4–12
Figure 4-5 – Solenoid valve 4–13
Figure 4-6 – Unlock and set detectors 4–15
Figure 4-7 – Replacement of measurement UV lamp 4–17
Figure 4-8 – Replacement of optional O3 generator UV lamp 4–17
Figure 5-1 – Card RS4i Configuration 5–7

Figure 5-2 – Keyboard Interface board 5–8
Figure 5-3 – ESTEL board 5–9
Figure 5-4 – MODULE board 5–10
Figure 5-5 – Flow rate control board 5–12
0–4 MAY 2002

INDEX OF PAGES
Page Date Page Date Page Date

0-1 05.2002 3-21 05.2002 5-2 05.2002
0-2 05.2002 3-22 05.2002 5-3 05.2002
0-3 05.2002 3-23 05.2002 5-4 05.2002
0-4 05.2002 3-24 05.2002 5-5 05.2002
0-5 05.2002 3-25 05.2002 5-6 05.2002
0-6 05.2002 3-26 05.2002 5-7 05.2002
3-27 05.2002 5-8 05.2002
1-1 05.2002 3-28 05.2002 5-9 05.2002
1-2 05.2002 3-29 05.2002 5-10 05.2002
1-3 05.2002 3-30 05.2002 5-119 05.2002
1-4 05.2002 3-31 05.2002 5-12 05.2002
1-5 05.2002 3-32 05.2002
1-6 05.2002 3-33 05.2002 6-1 05.2002
1-7 05.2002 3-34 05.2002 6-2 05.2002
1-8 05.2002 3-35 05.2002 6-3 05.2002
1-9 05.2002 3-36 05.2002 6-4 05.2002
1-10 05.2002 3-37 05.2002 6-5 05.2002
1-11 05.2002 3-38 05.2002 6-6 05.2002
1-12 05.2002 3-39 05.2002 6-7 05.2002
3-40 05.2002
2-1 05.2002 3-41 05.2002
2-2 05.2002 3-42 05.2002
2-3 05.2002 3-43 05.2002
2-4 05.2002 3-44 05.2002
2-5 05.2002 3-45 05.2002
2-6 05.2002 3-46 05.2002
2-7 05.2002 3-47 05.2002
2-8 05.2002 3-48 05.2002
2-9 05.2002 3-49 05.2002
2-10 05.2002 3-50 05.2002
2-11 05.2002 3-51 05.2002
2-12 05.2002 3-52 05.2002
3-1 05.2002 4-1 05.2002

3-2 05.2002 4-2 05.2002
3-3 05.2002 4-3 05.2002
3-4 05.2002 4-4 05.2002
3-5 05.2002 4-5 05.2002
3-6 05.2002 4-6 05.2002
3-7 05.2002 4-7 05.2002
3-8 05.2002 4-8 05.2002
3-9 05.2002 4-9 05.2002
3-10 05.2002 4-10 05.2002
3-11 05.2002 4-11 05.2002
3-12 05.2002 4-12 05.2002
3-13 05.2002 4-13 05.2002
3-14 05.2002 4-14 05.2002
3-15 05.2002 4-15 05.2002
3-16 05.2002 4-16 05.2002
3-17 05.2002 4-17 05.2002
3-18 05.2002 4-18 05.2002
3-19 05.2002
3-20 05.2002 5-1 05.2002
MAY 2002 0–5

Environnement S.A O3 42 MODULE Duplication prohibited
EPA Equivalency Designation.
The ozone analyzer, model O342M, is designated as an equivalent method number

EQOA-0206-148 as defined in CFR 40, Part 53, when operated under the following
conditions :
1. Analog output range 0-1 Volt.
2. Concentration range 0-500 ppb (range 1 and range 2 set to 500 ppb).
3. Ambient temperature range 10-35 °C.
4. Line voltage range 105-125 VAC, 60 or 50 Hz, or 210-250 VAC, 50Hz.
5. With 5 µm PTFE sample particulate filter.
6. Response time setting 11 (Automatic response time)
7. With or without the following options :
a) Internal Ozone generator.
b) Span external control (zero / span solenoid valve).
0–6 MAY 2002

CHAPTER 1
GENERAL INFORMATION - CHARACTERISTICS
1.1 GENERAL INFORMATION 1–3

1.1.1 PRESENTATION 1–3
1.1.2 DESCRIPTION 1–3
1.1.2.1 Front panel 1–3
1.1.2.2 Rear panel 1–5
1.1.2.3 Component locations 1–7
1.1.3 MAIN FEATURES 1–8
1.1.3.1 Standard 1–8
1.1.3.2 Optionally 1–8
1.1.4 ASSOCIATED EQUIPMENT 1–8
1.2 CHARACTERISTICS 1–9
1.2.1 TECHNICAL CHARACTERISTICS 1–9
1.2.2 OPERATING CHARACTERISTICS 1–10
1.2.3 STORAGE CHARACTERISTICS 1–10
1.2.4 INSTALLATION CHARACTERISTICS 1–10
1.2.4.1 Links between units 1–10
1.2.4.2 Dimensions and weight 1–10
1.2.4.3 Handling and storage 1–10
MAY 2002 1–1

1 GENERAL INFORMATION - CHARACTERISTICS
Figure 1-1 - O342M Presentation
1–2 MAY 2002

1.1 GENERAL INFORMATION
1.1.1 PRESENTATION
The O342M is a continuous ozone analyzer (specific for low concentrations).
It uses the principle of ozone detection by absorption in ultraviolet light.
The analyzer provides many advantages through the use of recent advanced electronic and optical
technologies and requires very limited maintenance.
The sample is taken with a Teflon tube (outside diameter 6 mm) connected to the back of the unit. The
sample is taken by an internal pump.
The measurement is indicated by a graphic display on the front panel.
1.1.2 DESCRIPTION
1.1.2.1 Front panel
The front panel includes:
a general switch
a backlit liquid crystal display
– 16 lines 40 columns (240 x 128 pixels)
– the display provides the measurement values according to the selected unit, the information
required for programming and testing the unit.
a keyboard with 6 touch-sensitive keys
The control and check functions of the unit are controlled through the keyboard.
– the function of each key varies with the different screens or menus.
Figure 1-2 - Keyboard and display
MAY 2002 1–3

2 3* 1 4* 7** 8**
*: SV block option (Zero / span inlets are not available for standard model)
** : Only available with built in ozone generator option.
Figure 1-3 - Rear panel
1–4 MAY 2002

1.1.2.2 Rear panel

The rear panel of the O342M contains the electrical connectors and fluids inlet/outlet connector.
Electrical Equipment Connections (left hand side)

– The main power supply assembly consists of a 3-contact socket (5) for standard power cable
connection, and general fuse: 0,6 A / 220 V or 1,2 A / 115 V (6).
Gas inlets/outlets
– Inlet of sample to be analyzed is composed of connection piece for 4/6 mm tube associated with a
dust filter holder equipped with Teflon filtering membrane (1).
– The "pump" outlet (2) for exhaust of the analyzed sample, consisting of a 4/6 mm Teflon
connection piece.
The rear panel could also contain the following internal options:
With ZERO/SPAN solenoid valve option :

– The zero (4) and span (3) inlets, consisting of a pneumatic fitting for a 4/6 mm tube, are used either
for connecting an outside supply of ozone trace free "ZERO AIR", or for connecting an ozone
generator device (with both gases always at atmospheric pressure).
With built in O3 generator option :
– The zero air inlet (8) 4/6 mm fitting is used to connect an outside supply of ozone trace free "ZERO
AIR".
– The O3 generator outlet (7) 4/6 mm fitting is connected to the span inlet (3).
MAY 2002 1–5

16 17 1
15
3
4
14
13
12
5
11
10
8
Figure 1-4 - Components location
1–6 MAY 2002

1.1.2.3 Components location

The components inside the unit are accessed by simply unscrewing the screws at rear and lateral
sides of the unit and removing the upper cover
CAUTION : risk of electric shocks, only skilled technician should intervene inside the analyzer.
Mechanical components (fig. 1-4)
This includes the following equipment:
– inlet dust filter (option) (1),
– filter-solenoid valve assembly (option) (17),
– measurement cell (13),
– pump (4).
After passage through the inlet dust filter (1), the sample to be analyzed is routed to a block consisting
of a 3-way solenoid valve (12) and a selective ozone scrubber (10).
The sample then goes into the measurement cell (13), where the ozone molecules selectively absorb
the UV rays encountered on the 253.7-nanometer wavelength. The measurement cell holds the
measurement detector (16) as well as the reference detector (9) and the UV lamp (8). At the outlet of
the cell, the gas is suctioned in by the pump (4), located at the end of the flow system. A flow rate
regulator assembly (10) controls the pump to maintain the flow rate to approximately 55 liters/hour.
Option
The analyzer could be equipped with a built in ozone generator (14) & (15).
Electronic components
The signals provided by the "measurement" (16) and "reference" (9) detectors as well as the signals
delivered by the barometer and the temperature and flow sensors (10) are sent to the analog-to-digital
converter, located on the module board (5), via a multiplexer. They are converted into digital signals.
The Modul board (5) holds the main + 15 V, − 15 V, + 5 V and − 5 V power supplies.
The microprocessor carries out processing of acquisitions, calculations, automatic controls and
interface control.
The RS-232 serial interface board (2) dialogs with a microcomputer either directly or through a modem
link.
The interface board (7) required for interconnections between the microprocessor board, the
keyboard, the display is installed on the front panel.
The UV lamp power pack (6) is mounted on the frame.
Option
The analyzer could be equipped with an input/output Estel board (3).
MAY 2002 1–7

1.1.3 MAIN FEATURES

1.1.3.1 Standard
– Programmable measurement range of 0.1 to 10 ppm, with a minimum detectable limit of 1 ppb for
50 seconds response time.
– Automatic check-up of parameters influent the metrology (UV energy, flow rate, temperature,
pressure) and correct running.
– Measurement values indicated in ppm or mg/m3.

– Memory storage of average measurements with a programmable period (maximum capacity: 5120
averages).
1.1.3.2 Optionally
The monitor can be equipped with the following options:
– an internal O3 generator,
– 1 to 4 Estel board(s) :
• Analog outputs of various parameters as O3 concentration and/or MUX channels.
• Remote signaling of various functions as "measurement" and "alarm".
– Ram extension for an extended memory storage capacity (24576 averages max.)
1.1.4 ASSOCIATED EQUIPMENT

– Analog recorders or data loggers.
– Numerical data acquisition systems.
– Serial printer for continuous printout of displayed measurements (programmable period), and
configuration.
1–8 MAY 2002

1.2 CHARACTERISTICS
1.2.1 TECHNICAL CHARACTERISTICS

Measurement range : programmable (10.00 ppm maximum)
Units : ppm or mg/m3 (programmable)
Noise (σ) : 0.0005 ppm. (response time 50 sec.)
Minimum detectable limit (2 σ) : 0.001 ppm. (response time 50 sec.)
Response time (0-90 %) : 10-90 s (programmable)
Zero drift : < 1 ppb /7 days
Span drift : < 1 % /7 days
Linearity : ±1%
Sample flow rate : ≈ 1 liter/min.
Temperature and pressure : automatic compensation of pressure / temperature
influence
Display : LCD 240 x 128 text and graphic modes
Control keyboard : 6 keys
Output signals (option) : 3 analog outputs: 0-1 V, 0-10 V, 0-20 mA, 4-20 mA
Power supply : 230V - 50Hz (115V - 60Hz) + ground
Consumption : – 70 V.A
– 90 V.A with optional generator O3 "on".
Working temperature : + 10 °C to 35 °C
Memorization of measurement values : Capacity: 5120 averages max (24976 with RAM
extension).
Measurement values or configuration
printout : On serial printer connected on COM2
Alarm checks : Permanent detection and indication of malfunctions:
temperature, flow rates, electrical parameters,
overshooting of programmable O3 measurement
threshold...
Tests and diagnostics for maintenance : Selection on keyboard and display of all parameters.
Backup saving time for data stored : >6 months by incorporated battery.
in RAM and of real-time clock
OPTIONS
O3 internal generator : Concentration range generated 150 to 400 ppb adjusted,
accuracy ± 5 %.
MAY 2002 1–9

Operating Characteristics
Not applicable.
1.2.2 STORAGE CHARACTERISTICS
Temperature: – 10 °C to 60 °C.
1.2.3 INSTALLATION CHARACTERISTICS

1.2.3.1 Links between units
The O342M monitor requires the following power supplies and external links:
Pump output
Zero air
Sample
Span
220V/0,6A
or
115V/1,2A
O342M
Estel in/out
RS board (option)
Figure 1-5 - Links between units
1.2.3.2 Dimensions and weight

The analyzer comes in the form of a standard 19-inch, 3-unit rack.
Length : 581 mm
Width : 483 mm
Height : 133 mm
Weight : 9 Kg
1.2.3.3 Handling and storage
The O342M monitor must be handled with care to avoid damage to the various connectors and fittings
on the rear panel.
Ensure the gas inlets and outlets on the unit are protected with caps whenever storing the monitor.
The unit is stored in a case provided for this purpose.
1–10 MAY 2002

430
5 50
54
125
36
57
7
133
483 14
38
Figure 1-6 - Outline dimensions
MAY 2002 1–11

Page intentionally left blank
1–12 MAY 2002

CHAPTER 2
OPERATION
2.1 PRINCIPLE OF MEASUREMENT 2–3

2.2 ANALYSIS 2–5
2.3 AUTOMATIC RESPONSE TIME 2–8
2.3.1 SIMPLIFIED PRINCIPLE OF OPERATION 2–8
2.3.2 PROGRAMMING THE RESPONSE TIME 2–8
2.4 SIMPLIFIED FLOWCHART OF MAIN PROGRAM 2–9
MAY 2002 2–1

2 OPERATION
1000
UV detectors response
Cesium Tellurid
Absorption 253,7
100
O3
10
Lines eliminated
by Vycor filter
302,2
313,2
312,6
1
Main lines of the low pressure
mercury vapour UV lamp
296,5
0,1
180 200 220 240 260 280 300 320
Wave length nm
Figure 2-1 - Ozone absorption spectrum
2–2 MAY 2002

2.1 PRINCIPLE OF MEASUREMENT

The ozone absorption spectrum is extended to a wavelength of 253.7 nanometers, which corresponds
to the main emission line of mercury, as shown on Figure 2-1.
The ozone absorption coefficient was experimentally defined at 253.7 nm:
absorption coefficient = 308 atm-1.cm-1

at P0= 101.3 k Pa and t0 = 273 °K (0 °C)
Calculation of this concentration after application of the Beer Lambert law is:
106  o
[O3] ppm = . Ln   at p0 and t0
α  
Calculation under measurement conditions becomes:
106  o
Cppm [O3] = . Ln   Po . t
α   P to
α l=K
K calibration coefficient.
l optical path length in cm.
i 0 being UV energy measured through measurement cell when sample does not contain ozone
molecules (passage through selective filter).
i being UV energy measured on sample containing ozone to be measured (direct passage).
The O342M calibration coefficient (according to the formula α l = k) is set at a value of 12554 for :
α = 308
l = 40.76 cm
MAY 2002 2–3

Flow rate regulation

Flow rate,
temperature &
Pump Exhaust
pressure
Sample
sensors
Cycle
solenoid
valve
Stabilized Ozone
power supply scrubber
UV lamp
UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV UV
UV UV
Reference UV UV UV UV UV UV UV UV UV UV UV Measurement
Optical benchUV
UV UV UV UV UV UV UV UV UV
UV UV UV UV UV UV UV UV UV UV UV UV UV
detector
UV UV UV UV
UV
UV UV UV UVUV UV UV UV UV UV UV UV UV
UV UV UV UV UV UV UV UV UV UV
UV UV UV UV
UV detector
UV UV UV UV UV UV UV
Module BOARD
OZONE MEASUREMENTS
Figure 2-2 - General schematic diagram
2–4 MAY 2002

2.2 ANALYSIS
In order to compensate for the drifts in the UV lamp and to make the two measurements i0 and i under
the same conditions, a "UV reference" detector integrates the energy emitted by the UV lamp. The du-
rations of the measurements i0 and i will be checked using "UV reference" detector signal so that
these two measurements can be made under the same conditions.
A measurement corresponds to the following cycle:
– passage of gas through the O3 selective filter; ventilation of measurement chamber (3 seconds),
– measurement of i0 made through "UV measurement" detector (corrected by "UV reference"),

– switch of solenoid valve,
– passage of gas directly into measurement chamber, ventilation (3 seconds),
– measurement of i made through UV measurement (corrected by "reference UV").

i.e. one complete cycle in approximately 10 seconds.
MAY 2002 2–5

Reference V
Ref. I 0-5 V
Reference
detector
- Measure.
MUX A/D
- Reference.
Measurement V
Meas. I 0-5 V
Measurement
detector
Figure 2-3 - Acquisition of UV energies I0 and I
Meas.
Ref.
t
20 samples 20 samples
Meas. One measurement each 50 µs
Ref. One measurement each 50 µs
Each 20 acquisitions (1 ms) calculation of the UV energy compensation.
2–6 MAY 2002

Acquisition of energies i0 and i (see Figure 2-3):

– The linear analog to digital converters convert the reference and measurement signals (V Ref. and
V Measurement) coming from the UV detectors into a frequency pulse train.
12 values of V measurements are averaged and compensated by the average of 12 reference

measurements: it is the calculation way to do the I or I0 metrology compensated in real time by the
measurement of UV lamp energy. The calculator performs 100 averages during each half-cycle
measurement.
The half cycle in which the sample passes through the ozone selective filter (solenoid valve off)
gives the value i0.
– The next half cycle in which the sample passes directly into the measurement chamber (solenoid
valve on) gives the value i:
The raw concentration is calculated using:
10 6  0
CB = Ln  
K  
A barometric sensor measuring the pressure P in the measurement chamber is used to make the
pressure compensation.
A sensor measuring the temperature T of the gas is used to make the temperature compensation.
The corrected compensation is calculated using:
273+ T 1013
CC = CB x x
273 P
MAY 2002 2–7

2.3 AUTOMATIC RESPONSE TIME

In order to optimize its metrology, the O342M monitor is equipped with a software function called
"automatic response time" (TR11) which enables filtration of measurements depending on evolution of
concentrations.
2.3.1 SIMPLIFIED PRINCIPLE OF OPERATION

An average of instantaneous readings is carried out corresponding to a minimum response time.
n
1
[MEAS] AVERAGE =
n ∑ [MEAS]
1
INSTANTANEOUS
n = number of instantaneous measurements which is determined by the programmed response time.

Then, a weighted average between the filtered values ( [MEAS] FILTERED ) and the average measure-
ments ( [MEAS] AVERAGE ) is recursively calculated according to the formula:
[MEAS] DISPLAYED = [MEAS] FILTERED (NEW) = X [MEAS] FILTERED (OLD) + Y [MEAS] AVERAGE
X +Y = 1
When the difference ( [MEAS] FILTERED (OLD)
− [MEAS] AVERAGE
) exceeds a determined threshold, the
value of Y is increased, up to a maximum value of 0.99 which corresponds to a fixed response time of
TRMIN.
When [MEAS] FILTERED (OLD)

− [MEAS] AVERAGE
is below the threshold, Y is progressively decreased.
2.3.2 PROGRAMMING THE RESPONSE TIME

The function of automatic response time may be activated or de-activated in the CONFIGURATION Ö
Measurement mode menu.
The minimum response time may also be modified in that menu.
See chapter 3 section 3.3.4.2 to obtain more information about programming of those functions.
2–8 MAY 2002

2.4 SIMPLIFIED FLOWCHART OF MAIN PROGRAM
I/O initialization
Memory test
Alarm check
Alarm display at end

of preheating
EV OFF EV ON
Passage through select. filter Direct passage
4-sec timeout for purge 4-sec timeout for purge

of measurement chamber of measurement chamber
MUX * measurement MUX * measurement
yes If necessary, yes

Failures Failures
failure control
no no
I o measurement I measurment
* Gas pressure
Calculation of raw concentration
6 Gas temperature
CB =
10 ln I o UV lamp set-point
(ppm) K I Flow rate of sample
Calculation of corrected concentration

T° correction
CE = CB x
273 + T x 1013
+ pressure
(ppm) 273 P
Integration of
1 to 9 samples
If mg programmed O3 mg = O3 ppm x coef. conv. O3
If offset programmed Addition of offset
(1) Result after acquisition

of all multiplexed parameters
and processing-control of
Result (1)
programmed automatisms.
Display Storage in memory Analog outputs Printing Serial

transmission
Figure 2-4 - Simplified flow chart of main program
MAY 2002 2–9

NOTES: Precautions to be taken in measuring methods for ozone and phenomena generating incor-
rect operation:
Ozone is highly reactive; there may therefore be drops in concentration on contact with sur-
faces.
The Teflon inlet dust filter is an area likely to catch a few ppb of ozone through the deposit of
dust. When there is a minor deposit of dust, it is possible to not install the filter membrane.
When there is a major deposit of dust, for low content measurements (less than 20 ppb), it
will be necessary to saturate the areas having a tendency to absorb by passing a high con-
centration of ozone (400 to 800 ppb) through them for 1 or 2 hours. This also holds true for
long external connection pieces (to be avoided). Regularly check the amount of dust cover-
ing the inlet filter and change the membrane frequently.
The ozone measurement is made over a 10-second cycle. Differences in pressure or even
variations in air turbulence in the chamber can create noise on the measurement. In order to
avoid this problem, it is imperative that the sample gas be delivered at the atmospheric pres-
sure at the inlet of the device.
By its principle, the analyzer has no long-time calibration or zero drift; on abrupt pressure
variations or abrupt, abnormal variations in the concentration of other gases absorbing in
this region of the spectrum and intervening punctually in a cycle can cause noise in the
measurement.
The gas flow system was designed to be as symmetrical as possible.
Air tightness of the 3-way solenoid valve and selective filter should be checked regularly. A
regular check should also be made on the balance of the load loss in measurement mode i
and i0.
Finally, the replacement dates for the selective filter should be kept up to date. It is advis-
able to replace them once a year (see Chap. 4).
IN SUMMARY:
• Ozone is reactive and is easily trapped.
• The gas system, solenoid valve and measurement chamber should be kept clean at all times.
• Measurement is cyclic; the pressure should be balanced between the two channels.
• The selective filter should be changed regularly.
2–10 MAY 2002

Sample inlet
Exhaust
Dust filter
Pump
Cycle
solenoid
valve
Ozone
scrubber
temperature &
Flow rate,
pressure
sensors
Optical bench
Figure 2-5 - Schematic diagram of basic gas flow system
Sample inlet
Span gas inlet
Exhaust zero air inlet
Dust filter
Pump
Solenoid valves assembly

Cycle
solenoid
valve
Ozone
scrubber
temperature &
Flow rate,
pressure
sensors
Optical bench
Figure 2-6 - Schematic diagram of gas flow system with solenoid valves option
MAY 2002 2–11

2–12 MAY 2002

CHAPTER 3.
OPERATING INSTRUCTIONS
3.1 INITIAL STARTUP 3–4

3.1.1 PRELIMINARY OPERATIONS 3–4
3.1.2 STARTING UP THE UNIT 3–6
3.2 PROGRAMMING THE O342 MODULE 3-7
3.2.1 SELECTION AND MODIFICATION OF THE PROGRAMMABLE PARAMETERS 3-7
3.2.1.1 Screen areas definition 3-7
3.2.1.2 Definition of the main functions of the 6 keyboard 3-8
3.2.2 PROGRAMMING THE OPERATING PARAMETERS 3-8
3.2.2.1 Programming the digital parameters 3-8
3.2.2.2 Programming the configurable parameters with pull-down list 3-8
3.3 DESCRIPTION OF THE DIFFERENT SCREENS 3-10
3.3.1 MAIN MENU 3-10
3.3.2 MEASUREMENT 3-11
3.3.2.1 MEASUREMENT Ö Instantaneous 3-11
3.3.2.2 MEASUREMENT Ö Average 3-12
3.3.2.3 MEASUREMENT Ö Synoptic 3-12
3.3.2.4 MEASUREMENT Ö Graphic 3-13
3.3.2.5 MEASUREMENT Ö Printout 3-16
3.3.2.6 MEASUREMENT Ö Alarms display 3-16
3.3.3 SPAN 3-17
3.3.3.1 SPAN Ö Coefficients 3-18
3.3.3.2 SPAN Ö O3 generator (optional) 3-18
3.3.3.3 SPAN Ö Cycles 3-19
3.3.3.4 SPAN Ö Pressure 3-20
3.3.3.5 SPAN Ö E2Pot 3-20
3.3.4 CONFIGURATION 3-21
3.3.4.1 CONFIGURATION Ö Date/time/language 3-21
3.3.4.2 CONFIGURATION Ö Measurement mode 3-22
3.3.4.3 CONFIGURATION Ö Offset and units 3-23
3.3.4.4 CONFIGURATION Ö Alarm limits 3-24
3.3.4.5 CONFIGURATION Ö Analog outputs 3-25
3.3.4.6 CONFIGURATION Ö Analog inputs 3-25
3.3.4.7 CONFIGURATION Ö Relays and remote control 3-26
MAY 2002 3–1

3.3.4.8 CONFIGURATION Ö Serial link 3-27

3.3.4.9 CONFIGURATION Ö Factory settings 3-27
3.3.5 STORED DATA 3-28
3.3.6 TEST 3-33
3.3.6.1 TEST Ö Optical bench 3-33
3.3.6.2 TEST Ö MUX Signals 3-34
3.3.6.3 TEST Ö Other commands 3-35
3.3.6.4 TEST Ö Serial link 3-35
3.3.6.5 TEST Ö Estel Card(s) 3-36
3.3.7 STOP MODE 3-37
3.4 CALIBRATION 3-38
3.4.1 OVERVIEW OF CALIBRATION AND CONCEPTS 3-38
3.4.1.1 Zero air generation 3-39
3.4.1.2 Ozone standard generation 3-40
3.4.1.3 Description of a complete calibration apparatus 3-40
3.4.1.4 Preparation and verification of calibration apparatus 3-43
3.4.1.5 Assay of O3 concentrations using a photometer 3-44
3.4.1.6 Internal valve for zero and span switching 3-45
3.4.2 ZERO AND SPAN CHECK 3-46
3.4.2.1 Equipment required 3-46
3.4.2.2 Procedure 3-46
3.4.2.3 Use of automatic cycles 3-46
3.4.3 TWO POINT CALIBRATION 3-47
3.4.4 MULTIPOINT CALIBRATION 3-48
3.4.4.2 Overview 3-48
3.4.5 INTERNAL OZONE GENERATOR 3-51
3.4.5.1 General operating principle 3-51
3.4.5.2 Remarks on use of Ozone generator as calibration standard 3-51
MAY 2002
3–2
3. OPERATING INSTRUCTIONS
Figure 3-1 - Electrical connections
Table 3-1 - DB37 and DB25 connectors links

RS232 / 422 serial links
COM1 COM2
2-TX 14-TX
3-RX 16-RX
4-RTS 7-GND
7-GND
20-DTR
21-TX
11-RX
ESTEL BOARDS
PIN N° CONNECTIONS PIN N° CONNECTION
1 ANA OUTPUT 1 17 REMOTE CONTROL 3
2 ANA OUTPUT 2 18 REMOTE CONTROL 4
3 ANA OUTPUT 3 19 +5VCC
4 ANA OUTPUT 4 20 ANA OUTPUT GROUND
5 ANA INPUT 1 21 ANA OUTPUT GROUND
8 ANA INPUT 4 24 ANA INPUT GROUND
9-28 RELAY 6 CONTACT 25 ANA INPUT GROUND
12-31 RELAY 3 CONTACT 34 REMOTE CONTROL GROUND
15 REMOTE CONTROL 1 37 REMOTE CONTROL GROUND
16 REMOTE CONTROL 2
NOTE : Output relays contacts are normally open and potential free.
Remote controls are done by closing a potential free dry contact
Analog inputs accept maximum 2.5 VCC.
MAY 2002 3–3

3.1 INITIAL STARTUP

The monitor is checked and calibrated in the factory before delivery.
3.1.1 PRELIMINARY OPERATIONS
Start-up first consists in carrying out the following preliminary operations:
– Visually examine the interior of the instrument in order to ensure that no element has been damaged
during transport.
– Remove the caps from the “gas” inlets and outlets on the unit (keep these aside for future
storage, see chapter 1.2.3)
– Connect the 4/6 Teflon air sampling tube to the "sample inlet" after having checked for the presence
of a Teflon filtering membrane in the inlet dust filter (fig.3-2)
– Connect the digital outputs to the DB25 connector (see Table. 3-1).
– Connect the analog inputs / outputs to the DB37 connector(s) (see Table 3-1).
Figure 3-2 - Fluid connections
MAY 2002
3–4
Funnel
Sampler tube
Teflon pipe
Wall
Figure 3-3 - Installation of the "sample gas" inlet
NOTE : Recommended height for sampling tap: 2.50 m

Maximum recommended length of gas Teflon sampling pipe: 6 m.
MAY 2002 3–5

3.1.2 STARTING UP THE UNIT

Press the ON/OFF switch located on the front panel. The analyzer goes into the «warm-up» cycle (the
duration of this cycle is a function of the time passed since the last switch off.)
The warm-up cycle is terminated when the following two conditions are satisfied:
– all metrological parameters are within operational limits,
– the analyzer has made 10 consistent measurements within ± 4 ppb.
Display at start-up:
The WARM UP message appears in the top left corner.
– Display after warm-up: the measurement display after warm-up can be chosen in Configuration Ö
Measurement mode screen. Example given here below : screen Synoptic
After some time (programmable in CONFIGURATION B Measurement mode)

STOP without action on any key, the screen passes in stand-by mode.
Pressing down any key makes it going back to display mode.
MAY 2002
3–6
3.2 PROGRAMMING THE O342 MODULE

3.2.1 SELECTION AND MODIFICATION OF THE PROGRAMMABLE PARAMETERS.
The keyboard is located under the LCD screen. The bottom line gives the function of each key for the
current screen.
The title of the menus and the selected fields are displayed in reverse video. By default the first line of
the menus is selected. In the next paragraphs, the selected fields are symbolized in white on black
background.
3.2.1.1 Screen areas definition
c Information area: displays the date and time in the top left corner. In the top right corner, the
WARM UP or SPAN message blinks. The ALARM message appears if an operating fault is de-
tected within the instrument operating parameters.
d Measurement or configuration area: displays the measurement parameters (gas, value, units...) or
the programmable parameters according to the selected menu.
e Status area and keys functions: displays the keys functions, the analyzer operating mode and the
O3 inlet ("sample" in the example above).
NOTE : In the next paragraphs, the keys are symbolized by the icon or function displayed inside a rec-
tangle.
MAY 2002 3–7

3.2.1.2 Definition of the main functions of the 6 keys

(the availability of these functions is context dependent)
Used to display the previous menu or to abort the current operation (parameter programming,
etc.)
Used to select the required sub-menu or the parameter to be modified. Also used to increase
the digit whose modification is in progress.
Used to select the required sub-menu and the parameter to be modified. Also used to de-
crease the digit whose modification is in progress.
Moves the cursor to the left (only available during numerical parameters modifications).
Moves the cursor to the right (only available during numerical parameters modifications).
Authorizes the selected parameter modification.
Used to valid the selection or the value of the parameter whose modification is in progress.
Print Used to print out the current screen.
>> Used to select the displayed parameters.
3.2.2 PROGRAMMING THE OPERATING PARAMETERS

3.2.2.1 Programming the digital parameters
Select the parameter with the or keys in the appropriate menu, press down the key
st
to access to the modification of the parameter, the 1 digit blinks. Select the digit to be modified
with the or keys then increase it with the key or decrease it with the key. The
key validates the modifications of the selected field; the key cancels the modifications of
the selected field.
3.2.2.2 Programming the configurable parameters with toggle list
Select the parameter with the or keys in the appropriate menu, press down the key
to access to the modification of the parameter, the field blinks. Select with the or keys the
wanted value in the toggle list. The key validates the modifications of the selected field; the
key cancels the modifications of the selected field.
3–8 MAY 2002

MAIN MENU
Measurement Span Configuration Stored Data Tests Stop Mode
Date/Time/
Instantaneous Coefficients Optical bench
Language
Cycle
Measurement
O3 generator MUX signals
Mode
Average
Cycle
Measure Other
Cycles
channels commands
Synoptic
Offsets and
Pressure Serial link
Cycle units
Graphic E2Pot Alarm limits Estel card *
Menu
Speed
Base
Scale Analog output *
R.S.Z.
Analog input *
Printout
Relays and
Alarm display remote control
Serial link
Factory settings
Figure 3-4 - Software overview
* note: appears in the menu only when option present
MAY 2002 3–9

3.3 DESCRIPTION OF THE DIFFERENT SCREENS

3.3.1 MAIN MENU
This screen is used to choose the menus giving access to the analyzer operating parameters.
Select the
menu with the or keys, validates the selection with the key.
Example:
ACTION DISPLAY REMARKS
– Display of the main menu, the 1ST

item is selected by default.
– Selection of the next item.
– Selection of the next item.
– Validates the selection (configura-

tion menu) and displays the sub-
menu.
– Goes back to the previous menu.
NOTE : To make the reading easier, when a sub menu is quoted in the text, the corresponding menu
is reminded before (i.e. Configuration Ö Date / time / language).
3–10 MAY 2002

3.3.2 MEASUREMENT
This screen is used to choose the measurement display mode: instantaneous, average, synoptic or
graphic, to activate the continuous printout and to display the alarms.
3.3.2.1 MEASUREMENT Ö Instantaneous
Definition of the specific keys of this screen

Sample Selects the sample gas inlet. The gas is continuously sampled through the inlet dust filter. The
measurement mode, the unit and the range are those chosen in the Configuration menu and in
the corresponding sub-menus. This mode can be interrupted at any time by starting an
automatic cycle or by manual selection of another gas inlet (zero or span).
Zero Selects the zero/span gas inlet for zero check. The function of this key depends on the equip-
ment of the analyzer.
• Zero/span solenoid valve option :
The zero/span solenoid valve is energized; the zero/span gas inlet is selected. The following
can be connected to this inlet: either a filter containing activated charcoal, connected to a dust
filter with an overall load loss of less than 20 mbar, or an ozone-free zero air available at at-
mospheric pressure.
MAY 2002 3–11

3.3.2.2 MEASUREMENT Ö Average

Sample Zero Span have the same function than the screen Measurement Ö instantaneous.
3.3.2.3 MEASUREMENT Ö Synoptic

This screen represents the entire flow circuit and displays significant operating parameter values: gas,
concentration and units (1), measurement UV detector signal (9), UV lamp current (4), reference UV
detector signal (5), MNO2 zero filter autonomy in days (6), internal temperature (7), optical bench tem-
perature (10). Pressure in the measurement cell (2). Lamp temperature (3) and current (4). Ozone
generator lamp current (8) if option available.
7
6
5 8
4 9
3
10
2

3–12 MAY 2002

3.3.2.4 MEASUREMENT Ö Graphic

This screen is used for graphic plotting of the measurement values on sample or zero / span gas inlet.
Horizontal and vertical full scales are programmable. The vertical line shows the current position : the
measurements are given on the left side of this line and the screen is automatically refreshed when
plotting arrives at the end of the screen right side.
Definition of this screen specific keys

3.3.2.4.1 Graphic Ö "Menu" screen
Pressing down the Menu key gives access to the following graphic adjustments: scrolling speed on the
screen, basis line, full scale.
The R.S.T key is used to put again the graphic to zero.
Scrolling speed
Present scale
Graphic basis
MAY 2002 3–13

3.3.2.4.2 Graphic Ö Base
Pressing down the Base key allows to adjust the value of the basis line (within a range from zero to a
value, which is just lower than the full scale).
__ Divides the present basis line by 10 (when the value basis line is 5, it puts it back to the zero
position)
_ Selects the inferior basis line among 5000, 2000, 1000, 500, 200, 100, 50, 20, 10, 5, 2, 1, 0.
+ Selects the superior basis line among 0, 1, 2, 5, 10, 20, 100, 200, 500, 1000, 2000, 5000.
++ Multiplies the basis line value by 10.
3.3.2.4.3 Graphic Ö Speed
Pressing down the Speed key allows to adjust the scrolling speed of the measurement displayed on the
screen (from 1s. mini, to 60s maxi).
3–14 MAY 2002

- 10s
Decrease the current speed of 10 seconds.
- 1s Decrease the current speed of 1 second.
+1s Increase the current speed of 1 second.
+10s Increase the current speed of 10 seconds.
The programmed duration is equivalent to the interval between the recording of each point
Example: when a scrolling speed is adjusted on 10 seconds, then the graphic screen duration is
240x10 = 2400s.
3.3.2.4.4 Graphic Ö Scale
Pressing down the Scale key allows to adjust the full scale of the graphic (minimum value is just higher
than the basis line, maximum is 10000)
__
Divides the current scale by 10 (when the scale is 5, it puts it back to the zero position)
_ Selects the current scale among 5000, 2000, 1000, 500, 200, 100, 50, 20, 10, 5, 2, 1, 0.
+ Selects the current scale among 0, 1, 2, 5, 10, 20, 50, 100, 200, 500, 1000, 2000, 5000.
++ Multiplies the current scale by 10.
MAY 2002 3–15

3.3.2.5 MEASUREMENT Ö Printout

This menu is used to start real time printout on a serial printer connected to one of the serial ports. It is
also used to define calculation period and printing rate of the average measurements (0001 to 9999
mn).
3.3.2.6 MEASUREMENT Ö Alarms display

This screen displays the operating faults in case of alarm. Possible corrections for these faults are
given in chapter 5.
3–16 MAY 2002

3.3.3 SPAN
This menu gives access to the followings functions:
• Programming the span coefficients.
• Monitoring of the O3 generator operation parameters, when analyzer is equipped with (op-
tional).
• Programming the span gas values.
• Programming the period and duration of the automatic cycles.
• Pressure sensors calibration.
Programmable digital potentiometer (E2Pot) allows to:
• adjust UV lamp current and consequently measurements and reference signal amplitude;
• adjust flow rate control point.
MAY 2002 3–17

3.3.3.1 SPAN Ö Coefficients

The "Factors" are the span factors, the one of the O3 should never be set outside the interval 12554
±5 %. This screen permits to manually modify these factors. The field Delta is not used.
The zero adjust field allows to program a zero correction value within the range of 2 ppb by steps of
0.1 ppb.
3.3.3.2 SPAN Ö O3 generator (optional)

The command line "O3 generator" appears in SPAN menu when the "O3 + Gen" Mode has been pro-
grammed in CONFIGURATION Ö Measurement mode screen.
This screen allows to display and to program ozone generation parameters:

– IG gives the current value (mA) in ozone generator UV lamp,
– O3 is the concentration value red on internal generator in span position,
– T°C is O3 generator block temperature, normally regulated at 60°C,
– E2P is the current adjustment of the UV lamp, given in number of points from 0 to 99.
3–18 MAY 2002

3.3.3.3 SPAN Ö Cycles

This screen is used to program the period and the duration (time) of the automatic cycles.
The possible automatic cycles are:
– ZERO : zero air check
– SPAN : span gas check.

The “Remote” fields are used to configure the cycles remote controls (ESTEL board option), ZERO,
and SPAN. The status programmed in the “Cyclical” fields (ON = active, OFF = inactive) governs the
analyzer reaction when a dry contact is closed on the remote controls inputs (see Table 3.1).
The “Inlet” fields allow to select gas inlets used during the automatic sequences. The reference
concentrations for automatic calibration are those programmed in the previous menu.
The “Starting time” field is used to program the time when the 24 hours or 24 hours multiple cycle are
launched. If a 24h ZERO cycle, or a 24h SPAN cycle are programmed, at start time the following
sequence is launched: ZERO then SPAN.
To inhibit an automatic cycle, program 0000h in the “Period” field.
MAY 2002 3–19

3.3.3.4 SPAN Ö Pressure

This screen is used to program the calibration curve of the pressure sensors
Pressure sensors calibration:
– Connect a reference pressure sensor in parallel to the pressure sensor to be calibrated.

Enter the slope (A) and intercept (B) values in the pressure calibration window fields.
3.3.3.5 SPAN Ö E2Pot
Sign+ and Sign- keys allow to adjust UV lamp current.
3–20 MAY 2002

3.3.4 CONFIGURATION
This menu gives access to the following functions:
• Response time programming.
• Dilution function programming.
• Analog outputs configuration.
• Unit and offset programming
• Alarm thresholds, activation and assignment of the alarm relays.
• Serial link programming.
• Reset of the main programmable parameters.
• Software serial number.
3.3.4.1 CONFIGURATION Ö Date/time/language

This screen is used to set the internal clock of the analyzer, as well as to choose the displayed
language among French, English, German, Italian and Spanish. It also shows the software version
number to remind in case of software dysfunction.
MAY 2002 3–21

3.3.4.2 CONFIGURATION Ö Measurement mode

This screen allows to program the standard mode or using O3 generator mode (optional), and the
electronic response time from about 20 sec. to 100 sec. The table bellow gives the fixed response
times corresponding to the programmed values.
Fixed response time
Programmed Value
(seconds)
01 100
02 50
03 40
04 30
05 20
Programming 11 activates the automatic response time (see chapter 2, “Principle of the automatic re-
sponse time”), the electronic response time is then 30 seconds.
The advised value is: Response time = 11.
This screen gives also access to the Dilution function: to measure very high concentrations (ex. found
in industrial environment), it is necessary to bring them to values corresponding to the range of ana-
lyzer by inserting a dilution system in the sampling line to get: CANALYZER INLET = CSAMPLE / K dilution
The real concentration display is obtained by application of a K Dilution multiplying factor to the
measured concentration.
“Latch DAC" field: when this field is ON, the analog outputs are latched during the Zero and Span cy-
cles, in order to not perturb data loggers.
“Maintenance” field: is used to trigger one of the alarm relays (see § 3.3.4.5 and table 3.1). The main-
tenance mode is reminded on the Measurement screens.
"Starting screen" field allows to program the default measurement screen after start up.
"Light screen of delay" field allows to program the duration
"Zero filter life time" allows to program a day down-counter, which triggers, when zero, filter alarms
message. The setting value depends on the analyzer using conditions. The factory setting value, 365
days, corresponds to the advised maintenance frequency (see section 4.3.3).
3–22 MAY 2002

3.3.4.3 CONFIGURATION Ö Measure channels

This screen is used to select the parameter, the display format and the unit for each measure channel.
The programming of measure channels allows to display (screen MEASUREMENT Ö Instantaneous
or screen MEASUREMENT Ö Average) and to store (menu STORED DATA) other parameters than
the one displayed by default (O3). It allows to store MUX channels and analog inputs (ESTEL option).
The channel number field is used to select the number of parameters.
• The 8 "Channels" fields are used to choose the parameter among MUX or analog inputs.
• The "Formats" fields are used to choose the display format among 4 possibilities (X.XXX,
XX.XX, XXX.X, XXXX). "Auto" manages the comma in order to display the same resolution at
any time.
The "Units" fields refer to the units programmed in screen CONFIGURATION Ö Offsets and units, or
CONFIGURATION Ö Analog inputs.
Meteo fields allow to assign the channel where meteorological parameters are connected in order to
apply a trigonometric treatment to those data.
3.3.4.4 CONFIGURATION Ö Offset and units
This screen is used to program the offset. This value is added to the measurements. It is also used to
program the conversion factor from ppm to mg/m3, when the mg/m3 unit is selected.
MAY 2002 3–23

3.3.4.5 CONFIGURATION Ö Alarm limits

2 limits are programmable for the programmed parameter: Threshold 1 and Tersely 2, which are used
to activate the relays and the alarm messages. When the "Alarms display" field is “OFF”, the displays
and the alarm relays are inhibited.
3–24 MAY 2002

3.3.4.6 CONFIGURATION Ö Analog outputs

This screen is used to choose the analog outputs parameters (only when ESTEL board option is
available) for the O3 concentration and 3 other measurement channels.
This screen is used to program the ranges for each displayed parameter. The ranges correspond to
the analog output full scale.
Range 1 corresponds to the analyzer standard range. The analyzer switches to Range2 when Range1
is exceeded, and switches from Range 2 to range 1 when 85 % of Range 1 is reached.
This screen is also used to choose the parameters unit among ppb mg/m3, mV, °C or hPa.
3.3.4.7 CONFIGURATION Ö Analog inputs

This screen is used to program the analog inputs characteristics.
The fields Name allows to enter an 8 alphanumeric characters name.
The fields units allows to choose a unit among: none, ppt, ppb, ppm, µg/m3, mg/m3, gr/m3, µg/Nm3,
mg/Nm3, gr/Nm3, µg/Sm3, mg/Sm3, gr/Sm3, %, µgr, mgr, gr, mV, U, °C, °K, hPa, mb, b, l, Nl, Sl, m3,
l/min, NI/min, Sl/min, m3/h, Nm3/h, Sm3/h, m/s or km/h, in a scrolling menu.
The fields aX + b allow to enter the linearity curve of the sensor connected on the input.
MAY 2002 3–25

3.3.4.8 CONFIGURATION Ö Relays and remote control
This screen allows to configure the function of each input / output of the ESTEL board(s).
• The "Estel card Nb" field is used to choose what board to configure.
• The "Relays" fields are used to control the relays according to the following situations :
Disable Ö Relay not assigned
General alarm Ö Any operating fault triggers the relay
Ch.1 > Thrs.1 Ö Limit 1 channel 1 exeedence triggers the relay
Overrange Ö Range 2 exeedence triggers the relay
Flow rate Ö Abnormal flow rate triggers the relay
Temperature Ö Abnormal temperature in the analyzer triggers the relay
Pressure Ö Barometric pressure in chamber
Null gas Ö On zero, relay is triggered
Span Ö On span, relay is triggered
Ref-Zero Ö On Ref-Zero, relay is triggered
Auto Span Ö On Auto Span, relay is triggered
Warm-up Ö On Warm-up, relay is triggered
Stand-by Ö On Stand-by, relay is triggered
Maintenance Ö Relay triggered when the analyzer is in maintenance mode
• "Type" fields are used to control (NC) or not (NO) the relays when alarm OFF.
3–26 MAY 2002

3.3.4.9 CONFIGURATION Ö Serial link

This screen is used to configure the Serial links (COM 1 and 2).
The 9 alphanumeric digits identification is used to define the analyzer code for remote transmission or
when the instrument is integrated into a network.
The baud rate, format and communication modes of the 2 channels are programmable among:
• Baud rate: 1200, 2400, 4800, 9600, 19200, 38400 (limited to 19200 bds at present time)
• Format : 7n1, 7o1, 7e1, 7n2, 7o2, 7e2, 8n1, 8o1, 8e1, 8n2, 8o2, 8e2
• Communication mode: Mode 4, impress. to send measurements to printer in real time, Jbus,
Special1, and Special2.
The field identification allows to program the analyzer identification when Jbus mode is used.
3.3.4.10 CONFIGURATION Ö Factory settings.
When this item is selected, pressing down the key displays the screen shown here below:
MAY 2002 3–27

3.3.5 STORED DATA

The access to stored data management is directly done from Main Menu. The stored data consists in
the average of analyzer measurements within a defined time interval.
This screen allows to parameter data recording period from 1 to 1440 min (i.e. 24 hours) and informs
about memory status:
NOTE : Free memory: from 80 Ko in standard operation, it can be increased to 464 Ko in adding
a 384 Ko memory board (optional). This board is automatically detected when switching on the
analyzer and it is indicated on the screen (1).
NOTE : Storage : it is the possible records number, it depends on free memory
NOTE : Autonomy: it is the duration (days number, months number, years number, hours,
minutes) while memory can store data, considering free space and data recording period. In the
here-above example: 9 days, 2 month, 0 year, 2 hours, 30 minutes.
Data can be edited in the form as table or histogram: this screen allows to program date and hour of
edition beginning, date and hour of edition end, histogram column width.
Menu key gives access to data display, printing functions, and memory reset-to-zero.
3–28 MAY 2002

Stored data edition in tabular form

This screen presents stored data list according to parameters defined in the screen before. The
running mode (measurement, zero, calibration…), during a memorization period, is coded in the status
column. The status codes meaning are:
00 Measurement valid
01 Range 2 over shooting
02 General alarm
04 Calibration fault
08 Zero measurement
10 Span measurement
20 Maintenance
40 Less than 2/3 of valid measurements during the average period
80 Power supply failure
FF Configuration modification
The displayed status code corresponds to the summation of the status codes (hexadecimal numbers)
that occurs during the memorization period.
Example: with an average period of 20 min:
5 min zero and 15 min measurement give the 00 status code and the displayed average is the 15 min.
measurement average.
11 min. zero and 9 min. measurement give the 08 status code and the displayed average is the 11
min. zero average.
Definition of the specific keys to this screen:

Select the previous or the next page.
Select stored data beginning or end.

<
Display the other measurement channels if more than 3 channels are

programmed in CONFIGURATION Ö Measure channels screen
MAY 2002 3–29

Stored data edition in the form as histogram

This screen displays records in the form as columns; each column corresponds to the measurements
average within the data-recording period as defined in STORED DATA screen. Only one channel is
displayed at once. The information line gives first record date and hour, the channel name, and,
alternatively blinking, full scale with unit, and data recording period.
Definition of the specific keys to this screen
Return to previous menu.
Display previous stored data plotting.
Display next stored data plotting.
X 2 zoom in.
X 2 zoom out.
Select the next measure channel, when more than one measure channel is programmed.
3–30 MAY 2002

Stored data printing
To print data, press down the Print key found in "Menu" function of "Memorized data" screen. The
blinking message "Printing …" indicates printed data output. Data printing can be suspend at any time,
pressing down F1 key. When printing is finished, the screen displays the message "Printing finished".
When none communication port is programmed on printer output (serial port), the error message
"Printing not set" is displayed.
MAY 2002 3–31

O342M[1.19]
25-08-2001
O3 MX06 MX13
HH:MN status PPB hPa ºC
10:15 000 14.7 1001.7 39.4
10:30 000 21.7 1001.4 39.5
10:45 000 21.4 1002.1 39.4
11:00 000 17.9 1002.6 39.4
11:15 000 16.0 1002.4 39.4
11:30 000 14.7 1000.7 39.4
11:45 000 13.9 1001.4 39.4
12:00 000 13.5 1002.1 39.5
12:15 000 12.0 1001.8 39.4
12:30 000 12.9 1001.6 39.3
12:45 000 12.7 1001.1 39.2
13:00 000 12.3 1000.8 39.1
13:15 000 11.8 1001.0 39.0
13:30 000 10.6 1001.3 38.9
13:45 000 9.2 1001.5 38.7
14:00 000 8.5 1001.8 38.7
14:15 000 8.0 1002.1 38.5
14:30 000 7.7 1002.3 38.3
14:45 000 6.8 1002.5 38.2
15:00 000 7.6 1002.6 38.1
15:15 000 7.5 1002.4 38.0
15:45 000 8.1 1002.4 37.9

16:00 000 8.5 1002.3 37.5
16:15 000 8.5 1002.6 37.5
16:30 000 8.7 1002.6 37.7
16:45 000 9.1 1002.5 37.8
17:00 000 9.2 1001.8 37.9
17:15 000 9.2 1002.4 38.0
17:30 000 9.0 1002.2 37.9
17:45 000 9 1 1002 0 37 9
Figure 3-5 - Printout example
Memory reset to zero

Pressing down the Reset key allows to empty storage memory. This action is irreversible: before to
do it, the software asks you to confirm. If your answer is "YES", the software resets end edition dates
and hours to the current dates and hours.
3–32 MAY 2002

3.3.6 TEST
This screen gives access to the following functions:
• Optical and flow parameters checking when maintenance operations occur.
• Serial link checking.
• Checking of the ESTEL board working (when option available)
3.3.6.1 TEST Ö Optical bench

This screen is used to follow-up the measurement parameters periodically or occasionally.

Sample Zero Span have the same function as the screen Measurement Ö Instantaneous.
EV-OFF Allows to control solenoid valve manually.
MAY 2002 3–33

3.3.6.2 TEST Ö MUX Signals

This screen is used to check the multiplexer signals.

For this screen the Sample Zero Span keys have the same function as the screen Tests Ö Optical bench.
NOTE : The "XXXX mV" displayed values will be checked according to the acceptable limits in next
table.
Table 3-2 - MUX signals (Acceptable limits on the multiplexer 1 to 16 channels)
Lower Upper
Channel Display Parameters Typical
Limit limit
1 GND Analog ground 0 mV 0 mV + 50 mV
2 Int. T° Internal temperature of the analyzer 100 mV _ 600 mV
Measurement UV lamp temperature
3 Lamp. T° regulation 100 mV 500 mV 600 mV
Gas T° Gas temperature at measurement chamber

4 100m V _ 500 mV
output.
Voltage provided by flow rate sensor placed
5 Flow 500 mV 1000 mV 2000 mV
at measurement chamber output.
Vacuum pressure inside the measurement (atmospheric
6 Pressure 300 mV 1200 mV
chamber pressure)
7 -15 V ref -15 V power supply 1200 mV 1400 mV 1500 mV
8 +15 V ref 15 V power supply 1400 mV 1500 mV 1600 mV
9 I (UV) Average current in UV lamp 0080 mV 0185 mV 0240 mV
10 I (Gene) Optional ozone generator UV lamp current 0080 mV _ 0240 mV
11 Sig. Mes. UV measurement detector signal 500 mV 4500 mV 4800 mV
12 Sig. Ref. UV reference detector signal 500 mV 4500 mV 4800 mV
13 Gen. T° Optional ozone generator temperature 500 mV 600 mV 700 mV
14 O2 Not used _ _ _
15 Aux3 Analog input - option _ _ _
16 2.5 V ref. Check of the analog / digital converter 2480 mV 2500 mV 2520 mV
3–34 MAY 2002

3.3.6.3 TEST Ö Other commands
The selection of this menu makes ineffective some controls. When the instrument
STOP is again in measurement mode, some alarms could occur.
This screen is used to check that the MODUL board is working correctly.
Jxx refers to the module board connector numbers.

are used to change status.
3.3.6.4 TEST Ö Serial link

This screen permits to check the serial link and shows the inputs / outputs which have to be strapped
when the serial link is not connected and you still want to check it
2-3: Emission/Reception, 4-6 and 7-8: modem signals.
MAY 2002 3–35

3.3.6.5 TEST Ö ESTEL Card(s)

This screen is only displayed when the option is available.
It is used to set the analog outputs and to monitor the working state of the remote controls and analog
inputs.
The “Estel card Nb:” field is used to select the board to be tested.
The “DA.C” fields are used to program the number of points generated at analog output.
The “Ax + B” fields are used to program the span factors of each output. These factors are calculated
according to the value measured at the output.
Example: for a 0-1000mV output, the point value is 1000 =0.25mV .
4000
3000 points give 3000x0,25=750mV as theoretical value.
760 mV measured at the output imply a k factor = 750 = 0,987
760
The “Out” fields are used to control the relays manually.
The "AD.C" & "Rem" fields are used to read the status of these inputs.
Definition of the specific keys to this screen
0/OFF Gives 0 pt on all the analog outputs and opens all relays contacts.
4000/ON Gives the full scale (4000 pts) on all analog outputs and closes all relays contacts.
3–36 MAY 2002

3.3.7 STOP MODE
Stop mode is used to put pumping unit off, all the other regulations keep on operation. To activate
again measurement mode, you need to go back to menu measurement, select and input
Measurement mode.
MAY 2002 3–37

3.4 CALIBRATION
IMPORTANT NOTICE:
Use of the analyzer, as an equivalent method for EPA reporting, requires periodic multipoint calibra-
tion and subsequent zero / span checks as described below. All gases for calibration must be trace-
able to a reference photometer.
3.4.1 OVERVIEW OF CALIBRATION AND CONCEPTS

To ensure the accuracy of the measurements performed using the O342M monitor, the unit must be
regularly checked, calibrated and adjusted, following the quality assurance plan of the user.
– Zero and span check :
This operation consists of comparing the monitor response, for zero air and a span point of the
range used, to the gas standards used. This check is used to measure the monitor drift in time with-
out modifying the span coefficient (K span). This check can be performed using the internal zero air
and span gas from the optional ozone generator.
Periodicity: generally 24 hours in automatic cycle mode.
– Span adjustment or two point calibration :
This procedure is used to check and correct the monitor response to the zero and a span point lo-
cated at about 80 % of the full scale of the measurement range used.
Periodicity: weekly or less frequently if the installation allows it or depending on the quality assur-
ance plan of the user.
– Multipoint calibration :
This involves a more complete check up of the monitor performance characteristics including linear-
ity.
Periodicity: quarterly or depending on quality assurance plan of the user, or following out-of-
tolerance calibration check results requiring an intervention on the monitor or following installation or
re-installation of the monitor.
3–38 MAY 2002

3.4.1.1 Zero air generation

Purified air, dried and free of any traces of ozone (< 2 ppb), connected to zero air inlet of analyzer
(with optional zero solenoid valve, option "Span External Control"), or directly to the sample gas inlet,
at atmospheric pressure. Zero air should also be free of any substances potentially absorbing at 254
nm (such as Benzene or other aromatics) and of any substances reacting with Ozone (such as NO
and C2H4).
This can be obtained using one of the following methods:
• A zero air generator with ozonizer, activated charcoal and molecular sieve (type JPAG /
INSAT).
• A cylinder of reconstituted pure air.
• A set of filtering columns (see Figure 3-6) made of inert material and whose efficiency is peri-
odically checked by comparison to a zero air generator, at the time of a multipoint calibration
(for zero and span checks and 2 points calibration only).
These filtering columns contain: 450 cc silicagel and 450 cc activated vegetable charcoal (grain 22-
631-362)
Silica gel dust filter
ANALYZER
Zero / Span inlet
Activated charcoal
Figure 3-6 - Filtering columns
MAY 2002 3–39

2001
3.4.1.2 Ozone standard generation

Use one of the three methods below, depending on the application:
• A complete calibration system containing a photometer :
This apparatus is described in § 3.4.1.3.
It is possible to use a modified version of the O342M (O342M/C) and a source of pressurized dry
clean air to comply with the requirements for an ozone calibration system. Note however that such
a photometer must never be used to sample ambient air and must always be used with dry clean
air.
• A certified ozone transfer standard :
A transfer standard is certified by relating the output of the transfer standard to one or more ozone
standards. The exact procedure varies depending on the nature and design of the transfer stan-
dard. Consult Reference 8 of appendix 6.1 for guidance.
• An internal ozone generator of the analyzer (for span checks only).
3.4.1.3 Description of a complete calibration apparatus
A complete UV calibration system consists of an ozone generator, an output port or manifold, a pho-
tometer, an appropriate source of zero air, and other components as necessary. The configuration
must provide a stable ozone concentration at the system output and allow the photometer to accu-
rately assay the output concentration to the precision specified for the photometer (see 3.4.1.3.1).
Figure 3-7 shows a commonly used configuration and serves to illustrate the calibration procedure
which follows. Other configurations may require appropriate variations in the procedural steps. All
connections between components in the calibration system downstream of the O3 generator should be
of glass, Teflon, or other relatively inert materials. Additional information regarding the assembly of a
UV photometric calibration apparatus is given in Reference 9 of appendix 7.13. For certification of
transfer standards which provide their own source of O3, the transfer standard may replace the O3
generator and possibly other components shown in Figure 3-7. See Reference 8 of appendix 6.1 for
guidance.
3.4.1.3.1 UV photometer
The photometer consists of a low-pressure mercury discharge lamp, (optional) collimation optics, an
absorption cell, a detector, and signal-processing electronics, as illustrated in Figure 3-7. It must be
capable of measuring the transmittance, I/I0, at a wavelength of 254 nm with sufficient precision such
that the standard deviation of the concentration measurements does not exceed the greater of
0.005 ppm or 3% of the concentration. Because the low-pressure mercury lamp radiates at several
wavelengths, the photometer must incorporate suitable means to assure that no O3 is generated in the
cell by the lamp, and that at least 99.5% of the radiation sensed by the detector is 254 nm radiation.
(This can be readily achieved by prudent selection of optical filter and detector response characteris-
tics). The length of the light path through the absorption cell must be known with an accuracy of at
least 99.5%. In addition, the cell and associated plumbing must be designed to minimize loss of O3
from contact with cell walls and gas handling components. See Reference 9 of appendix 6.1 for addi-
tional information
3–40 MAY 2002

3.4.1.3.2 Air flow controllers

Devices capable of regulating air flows as necessary to meet the output stability and photometer pre-
cision requirements.
3.4.1.3.3 Ozone generator
Device capable of generating stable levels of O3 over the required concentration range.
3.4.1.3.4 Output manifold
The output manifold should be constructed of glass, Teflon, or other relatively inert material, and
should be of sufficient diameter to insure a negligible pressure drop at the photometer connection and
other output ports. The system must have a vent designed to insure atmospheric pressure in the
manifold and to prevent ambient air from entering the manifold.
3.4.1.3.5 Two-way valve
Manual or automatic valve, or other means to switch the photometer flow between zero air and the O3
concentration.
3.4.1.3.6 Temperature indicator
Accurate to ±1 °C.
3.4.1.3.7 Barometer or pressure indicator
Accurate to ±2 torr.
3.4.1.3.8 Option 1
The various O3 concentrations required in steps 11 of § 3.4.1.5 and 3.a of § 3.4.4.3 may be obtained
by dilution of the O3 concentration generated in steps 6 of § 3.4.1.5 and 2.b of § 3.4.4.3. With this op-
tion, accurate flow measurements are required. The dynamic calibration system may be modified as
shown in Figure 3-8 to allow for dilution air to be metered in downstream of the O3 generator. A mixing
chamber between the O3 generator and the output manifold is also required. The flow rate through the
O3 generator (F0) and the dilution airflow rate (FD) are measured with a reliable flow or volume stan-
dard traceable to NBS. Each O3 concentration generated by dilution is calculated from:
 F0 
[ O ]'
3 OUT [ ]
= O3 OUT  
 F0 + FD 
where:
[O3]'OUT = diluted O3 concentration, ppm
F0 = flow rate through the O3 generator, liter/min
FD = diluent air flow rate, liter/min
MAY 2002 3–41

2001
F0 Output manifold
Flow
O3 generator Vent
Zero controller
air
Fz Extra outlet capped
when not in use
Flow Two way
controller valve To inlet of analyzer
Vent under calibration
Optics
Source
Detector Absorption cell
Signal processing Fp
electronics Flow
Flow meter pump Exhaust
controller
Figure 3-7 - Schematic diagram of a typical UV photometric calibration system (1)
FD
Flow
Flow meter
controller
F0
Output manifold Vent
Flow
Flow meter O3 generator
Zero controller
air Mixing
chamber Extra outlet capped
Fz when not in use
Flow Two way

controller valve To inlet of analyzer
Vent under calibration
UV Photometer
Optics
Source
Detector Absorption cell
Signal processing Fp
electronics Flow
Flow meter pump Exhaust
controller
Figure 3-8 - Schematic diagram of a typical UV photometric calibration system (2)
3–42 MAY 2002

3.4.1.4 Preparation and verification of calibration apparatus

3.4.1.4.1 General operation :
The calibration photometer must be dedicated exclusively to use as a calibration standard. It should
always be used with clean; filtered calibration gases, and never used for ambient air sampling. Con-
sideration should be given to locating the calibration photometer in a clean laboratory where it can be
stationary, protected from physical shock, operated by a responsible analyst, and used as a common
standard for all field calibrations via transfer standards.
3.4.1.4.2 Preparation :
Proper operation of the photometer is of critical importance to the accuracy of this procedure. The fol-
lowing steps will help to verify proper operation. The steps are not necessarily required prior to each
use of the photometer. Upon initial operation of the photometer, these steps should be carried out fre-
quently, with all quantitative results or indications recorded in a chronological record either in tabular
form or plotted on a graphical chart. As the performance and stability record of the photometer is es-
tablished, the frequency of these steps may be reduced consistent with the documented stability of the
photometer.
b.1) Instruction manual:
Carry out all set up and adjustment procedures or checks as described in the operation or instruction
manual associated with the photometer.
b.2) System check:
Check the photometer system for integrity, leaks, cleanliness, proper flow rates, etc. Service or re-
place filters and zero air scrubbers or other consumable materials, as necessary.
b.3) Linearity:
Verify that the photometer manufacturer has adequately established that the linearity error of the pho-
tometer is less than 3%, or test the linearity by dilution as follows: Generate and assay an O3 concen-
tration near the upper range limit of the system (0.5 or 1.0 ppm), then accurately dilute that concentra-
tion with zero air and assay it again. Repeat at several different dilution ratios. Compare the assay of
the original concentration with the assay of the diluted concentration divided by the dilution ratio, as
follows:
A1 − A 2 / R
E= x 100%
A1
where:
E = linearity error, percent
A1 = assay of the original concentration
A2 = assay of the diluted concentration
R = dilution ratio = flow of original concentration divided by the total flow
MAY 2002 3–43

2001
The linearity error must be less than 5%. Since the accuracy of the measured flowrates will affect the
linearity error as measured this way, the test is not necessarily conclusive. Additional information on
verifying linearity is contained in Reference 9 of appendix 7.13.
b.4) Intercomparison :
When possible, the photometer should be occasionally intercompared, either directly or via transfer
standards, with calibration photometers used by other agencies or laboratories.
b.5) Ozone losses:
Some portion of the O3 may be lost upon contact with the photometer cell walls and gas handling com-
ponents. The magnitude of this loss must be determined and used to correct the calculated O3
concentration. This loss must not exceed 5%. Some guidelines for quantitatively determining this loss
are discussed in Reference 9 of appendix 7.13.
3.4.1.5 Assay of O3 concentrations using a photometer
To generate and assay the ozone concentrations using a photometer or a complete calibration appa-
ratus, follow the procedure below.
• (1) Allow the photometer system to warm up and stabilize.
• (2) Verify that the flowrate through the photometer absorption cell, F allows the cell to be
flushed in a reasonably short period of time (2 liter/min is a typical flow). The precision of the
measurements is inversely related to the time required for flushing, since the photometer drift
error increases with time.
• (3) Insure that the flowrate into the output manifold is at least 1 liter/min greater than the total
flowrate required by the photometer and any other flow demand connected to the manifold.
• (4) Insure that the flowrate of zero air, FZ, is at least 1 liter/min greater than the flowrate required
by the photometer.
• (5) With zero air flowing in the output manifold, actuate the two-way valve to allow the photome-
ter to sample first the manifold zero air, then FZ. The two photometer readings must be equal (I
= I0).
NOTE : In some commercially available photometers, the operation of the two-way valve and various
other operations of this section (3.4.1.4) may be carried out automatically by the photometer.
• (6) Adjust the O3 generator to produce an O3 concentration as needed.
• (7) Actuate the two-way valve to allow the photometer to sample zero air until the absorption
cell is thoroughly flushed and record the stable measured value of I0.
• (8) Actuate the two-way valve to allow the photometer to sample the ozone concentration until
the absorption cell is thoroughly flushed and record the stable measured value of I.
• (9) Record the temperature and pressure of the sample in the photometer absorption cell. (See
Reference 9 of appendix 6.1 for guidance).
• (10) Calculate the O3 concentration from the equation below. An average of several determina-
tions will provide better precision.
3–44 MAY 2002

 −1 I  T   760  10
6
[ ]
O3 =  ln      x
OUT
 αl I 0   273   P  L
where:
[O3]OUT = O3 concentration, ppm
α = absorption coefficient of O3 at 254 nm = 308 atm-1 cm-1 at 0 °C and 760 torr
l = optical path length, cm
T = sample temperature, K
P = sample pressure, torr
L = correction factor for O3 losses from § 3.4.1.4.b 5 = (1-fraction O3 lost).
NOTE : Some commercial photometers may automatically evaluate all or part of the equation above.
It is the operator's responsibility to verify that all of the information required for this equation is ob-
tained, either automatically by the photometer or manually. For "automatic" photometers which
evaluate the first term of the equation above based on a linear approximation, a manual correction
may be required, particularly at higher O3 levels. See the photometer instruction manual and Refer-
ence 9 of appendix 6.1 for guidance.
NOTE : Model O342M/C uses the exact formula (no linear approximation to replace the logarithm) for
calculating [O3]OUT.
• (11) Obtain additional O3 concentration standards as necessary by readjusting the ozone gen-
erator and following all the steps (6) to (10) described above or by dilution (see Option 1 in §
3.4.1.3.h)
3.4.1.6 Internal valve for zero and span switching (see Erreur ! Source du renvoi introuvable.)
This feature is provided with the option "span external control".
When performing a multipoint calibration the user should connect the zero and span gas sources to
the sample gas inlet. After this calibration the zero and span sources should be connected to the cor-
responding inlets of the analyzer. The O342M should give identical responses whether the sources are
connected to the sample or the zero and span inlets of the analyzer. If not then internal valves should
be serviced. Subsequently internal valves can be used for zero and span checks and two point cali-
brations.
3.4.2 ZERO AND SPAN CHECK

3.4.2.1 Equipment required
– zero air :
Use any of the methods described in paragraph 3.4.1.1.
– Span point :
Use any of the methods described in paragraph 3.4.1.2.
MAY 2002 3–45

2001
3.4.2.2 Procedure
– Zero check
• With standard O342M, apply zero gas to sample gas inlet at atmospheric pressure.
• For O342M with zero / span solenoid valve option or internal Ozone generator option, apply
zero gas to zero inlet and use zero key to select the zero air inlet on analyzer.
Wait for measurement to stabilize. The measurement should be within ± 5 ppb of zero.
– Check of span point
Use one of the methods described in paragraph 3.4.1.2 to generate ozone.
Apply ozone to the inlet of the analyzer at atmospheric pressure.
Wait for the reading to stabilize.
The reading under span minus reading under zero air should be within 10% of generated concentra-
tion. Otherwise check quality of zero and span gases, leaks in generation system and pressure at
analyzer inlet. If everything is correct then perform a two point calibration.
3.4.2.3 Use of automatic cycles
This procedure cannot be used to adjust the zero or calibration coefficients.
To program the cycles, see menu Span Ö Cycles paragraph 3.3.3.3.
– Zero cycle (zero/span solenoid valve option) :
The zero air generator is permanently connected to the monitor zero/span gas inlet. The recom-
mended duration of the zero check is 600 seconds.
– Span check cycle :
The span point generator is permanently connected to the monitor zero/span gas inlet. The gener-
ated concentration must be below the full scale of the range used for the measurement. The rec-
ommended duration of the check is 600 seconds.
NOTE : The zero gas and calibration gas must both be supplied to the zero/span inlet one after the
other at atmospheric pressure. This can be automatized since the analyzer features two, zero and
span, control contacts accessible on the rear panel (see table 3.1).
3.4.3 TWO POINT CALIBRATION

– Zero air
Use one of the methods described under paragraph 3.4.1.1
– Span point
Use one of the first two methods described under paragraph 3.4.1.2
CAUTION : Materials in contact with zero or span gases must be made of Teflon, glass or other inert
material.
3–46 MAY 2002

3.4.3.2 Procedure
• (1) Allow sufficient time for the O342M analyzer and the photometer or the transfer standard to
warm-up and stabilize.
• (2) Allow the analyzer to sample zero air until a stable reading is obtained and adjust the ana-
lyzer zero control using procedure described in paragraph 3.3.4 It can be useful to offset the
analyzer reading using procedure described in paragraph 3.3.4.3 to facilitate observing negative
values. Note the obtained reading as [Z].
• (3) Generate an ozone concentration standard, [O 3 ] OUT , of approximately 80% of the full scale
of the range used. Allow the O342M to sample this ozone concentration standard until a stable
reading is obtained. Note the obtained reading as [O 3 ]READ .
• (4) Adjust the analyzer's span as described in § 3.2.3.1 following the formula :
 [O3]READ − Z 
K(SPAN)NEW = K(SPAN) OLD •  
 [O3] OUT 
NOTE : The factory setting for K span is usually 12554. Should the results of the calibration lead to a
deviation from this value of more than ±5%, then extreme care has to be exercised in re-checking
the whole process since such a result is likely to be inconsistent.
• Check the quality of zero air.
• Check certification of Ozone transfer (if applicable) and construction and set up of cali-
bration apparatus.
• Check for leaks.
• Check for appropriate pressure at the used inlet of the analyzer.
• If everything is correct and proper maintenance has been performed on the analyzer,
then perform a complete multipoint calibration to ascertain the linearity.
3.4.4 MULTIPOINT CALIBRATION

– Zero air
use any of the following methods :
• A zero air generator with ozonizer, activated charcoal and molecular sieve (type JPAG /
INSAT).
• A cylinder of reconstitued pure air.
– Span gas
Use one of the two methods below :
• A complete calibration system containing a photometer :
This apparatus is described in § 3.4.1.3.
It is possible to use a modified version of the O342M (O342M/C) and a source of pressurized dry
clean air to comply with the requirements for an ozone calibration system. Note however that such
a photometer must never be used to sample ambient air and must always be used with dry clean
air.
MAY 2002 3–47

2001
• A certified ozone transfer standard :

A transfer standard is certified by relating the output of the transfer standard to one or more ozone
standards. The exact procedure varies depending on the nature and design of the transfer stan-
dard. Consult Reference 8 of appendix 6.1 for guidance.
3.4.4.2 Overview
Gases will be applied at atmospheric pressure to the sample gas inlet of the analyzer.
Materials in contact with zero or span gases must be made of Teflon, glass or other inert material.
Calibration of the monitor requires precision gas generation of 7 points including zero (example : 0,
15, 30 ,45, 60, 75 and 90% of the full scale of the range used), the dilution carrier gas must be the
same as the one used for the zero measurement.
The multipoint calibration consists of 3 steps.
• (1) Install and check ozone generation apparatus.
• (2) Perform a two point calibration procedure (§ 3.4.3.2).
• (3) Generate several ozone concentrations and plot a calibration curve to check linearity.
It is recommended to connect a strip chart recorder to the analog outputs of the analyzer for data
gathering and processing. If "RS232-422" option is available, data can be collected by a computer.
3.4.4.3 Procedure
• (1-a) Install and check ozone generation apparatus according to the instruction manual of the
ozone standard use for calibration.
• (1-b) Allow sufficient time for the O342M analyzer and the photometer or the transfer standard to
warm-up and stabilize.
• (2-a) Allow the analyzer to sample zero air until a stable reading is obtained and adjust the
analyzer zero control using procedure described in paragraph 3.3.4 It can be useful to offset the
analyzer reading using procedure described in paragraph 3.3.4.3 to facilitate observing negative
values. Note the obtained reading as [Z].
• (2-b) Generate an ozone concentration standard, [O 3 ] OUT , of approximately 80% of the full
scale of the range used. Allow the O342M to sample this ozone concentration standard until a
stable reading is obtained. Note the obtained reading as [O 3 ]READ .
• (2-c) Adjust the analyzer's span as described in § 3.3.4 following the formula :
 [O3]READ − Z 
K(SPAN)NEW = K(SPAN) OLD •  
 [O3] OUT 
• (3-a) Generate several ozone concentrations following the instruction manual of the ozone
standard used for the calibration. For each ozone concentration record the corresponding ana-
lyzer response.
• (3-b) Plot the O342M responses versus the corresponding generated O3 concentrations and
draw the analyzer's calibration curve or calculate the appropriate response factor using least
squares regression.
• (3-c) Fine adjust the K span factor if necessary according to the result of (3-b).
3–48 MAY 2002

NOTE : The factory setting for K span is usually 12554. Should the results of the calibration lead to a
deviation from this value of more than ±5%, then extreme care has to be exercised in re-
checking the whole process since such a result is likely to be inconsistent.
• Check the quality of zero air.
• Check certification of Ozone transfer (if applicable) and construction and set up of cali-
bration apparatus.
• Check for leaks.
• Check for appropriate pressure at the used inlet of the analyzer.
• If everything is correct then the analyzer needs servicing (see chapter 4)
MAY 2002 3–49

2001
Sample inlet
Span gas inlet
Exhaust zero air inlet
Dust filter
Pump

Cycle
solenoid
valve
Ozone
scrubber
temperature &
Flow rate,
pressure
sensors
Optical bench
Figure 3-9 - Gas flow system with zero span solenoid valve
3–50 MAY 2002

3.4.5 INTERNAL OZONE GENERATOR

CAUTION : This feature must not be used for span adjustment in case of reference method analyzer
(compliance) monitoring. The span point check can be performed using the internal Ozone genera-
tor.
3.4.5.1 General operating principle
The zero air, obtained by filtering the ambient air, is drawned through a chamber containing a low
pressure mercury vapor lamp.
This lamp is operated by a current regulated power supply. The temperature of the unit is kept con-
stant.
The 184.9 nm wavelength UV rays emitted by the lamp convert part of the oxygen contained in the
zero air into Ozone, through the following reactions :
hv
O2  → O+O and O2+O → O3+W
A fixed Ozone concentration is therefore distributed between the analyzer optical bench by means of
the zero/span solenoid valve and the ozone outlet available on the rear part of the analyzer.
3.4.5.2 Description of the operating mode
See § 3.3.3.2 SPAN B O3 Generator
3.4.5.3 Remarks on use of Ozone generator as calibration standard
This option should not be used when using analyzer for EPA gathering data.
In principle, the analyzer cannot calibrate itself. It can nevertheless serve as a system for making per-
formance checks.
In any case, some restrictions must be indicated in order to guarantee the highest efficiency of the
system :
high system repeatability, differences not exceeding the highest of the values between ±5% and
±5 ppb, requires operation of lamp under rated conditions, i.e. at a temperature of about 60°C and a
regulated supply current of approximately 5 or 20 mA (depending on the UV lamp model). To do this,
the required concentrations will preferably be selected within the range of 80 to 250 ppb.
buildup of a current in the lamp or of large variations in its values lead to a stabilization period not ex-
ceeding a few minutes, but can go as high as 2 hours to generate a high concentration (> 500 ppb)
the required period to stabilize the temperature of the lamp. This is why it is recommended, when us-
ing 10 minutes auto span check, to generate a concentration of about 200 ppb.
MAY 2002 3–51

2001
Sample inlet
Span gas inlet Span gas outlet
Exhaust zero air inlet zero air inlet
Dust filter
Pump

Ozone generator
Activated
charcoal
Cycle
solenoid
valve
Ozone
scrubber
temperature &
Flow rate,
pressure
sensors
Optional ozone generator
Optical bench
Figure 3.10.– Gas flow system with Ozone generator
3–52 MAY 2002

4 PREVENTIVE MAINTENANCE 4–3

4.1 SAFETY INSTRUCTIONS 4–3
4.2 MAINTENANCE CALENDAR 4–4
4.3 MAINTENANCE OPERATION SHEETS 4–5
4.4 O342M MAINTENANCE KIT 4–18
MAY 2002 4–1

4–2 MAY 2002

4 PREVENTIVE MAINTENANCE
4.1 SAFETY INSTRUCTIONS
Operators must observe the safety instructions at all times.
Cut off the power supply when performing any work inside the unit.
Only qualified personnel should intervene on the unit.
The manufacturer shall not be responsible for any consequences resulting from:
– use of the monitor by non-qualified people,
– use of the monitor in other conditions than those specified in this document,
– modification of the monitor by the user,
– non-maintenance of the monitor.
A systematic periodic inspection is required.
MAY 2002 4–3

4.2 MAINTENANCE CALENDAR

By its design, the O342M requires very limited maintenance. However, to ensure the monitor's per-
formance characteristics over time, the unit must be serviced regularly. The frequencies indicated be-
low are given as an example and can vary according to operating conditions.
Operation Frequency Sheet No.
Sample inlet PTFE filter 15 to 30 days 4.3.1
Check on gas flow, optical and electrical parameters 30 days 4.3.2
Check on membrane and pump valves 6 months 4.3.3
Maintenance on measurement cell ( ) Yearly 4.3.4

*
Replacement of selective filter Yearly 4.3.5
Cleaning of solenoid valve ( ) Yearly 4.3.6

*
Realignment of measurement and reference signals 6 months 4.3.7
Replacement of UV lamp when ref. voltage value near limits Yearly 4.3.8
( ) If analyzer is used without inlet filter membrane: monthly frequency.

*
Yearly check
The monitor must be returned to laboratory for complete cleaning (measurement chambers, restric-
tors, gas flow rate, etc.) and check of all metrological parameters.
Carefully check seals around pneumatic fittings.
4–4 MAY 2002

4.3 MAINTENANCE OPERATION SHEETS

MAINTENANCE SHEET
MONITOR serial No.: OPERATION SHEET: 4.3.1

Scope: Replacement of inlet filter PAGE: 1/1 Frequency: 15 days
Sample inlet PTFE filter: "MITEX" Teflon filter - 5 µm porosity - 47 mm dia. Date
Ref.: F05-11-842
a) Unlock the filter cover (2) by rotating the locking spring (1)
b) Remove the dirty filter (3)
c) Place the new filter (4) by slipping it slightly from its paper protection(5) onto the
filter holder (6).
5 4
Figure 4-1 – Inlet dust filter
Tools required
• none
MAY 2002 4–5

MAINTENANCE SHEET

Scope: Check on gas flow and optical parameters PAGE: 1/2 Frequency: 15 days
Regular checks on gas flow and optical parameters using Measure Ö Synoptic display mode and Maintenance
Ö MUX signal (see sections 3.3.2.3 and 3.3.6.3) help to prevent foreseeable alarms (UV energy too low, meas-
urement signal too weak, abnormal accumulation of dirt in measurement chamber, inlet filter or ventilation tube
clogged, flow restrictor clogged, etc.).
The maximum ratings listed in Table 3.2 on page 3-29 and retrieval of the results on the inspection sheets in
section 4.5 and the results of the test will be used to decide whether it is necessary to carry out the following
procedures:
• Cleaning of tubes see sheet 4.3.4.

• Cleaning of optical bench windows and mirrors see sheet 4.3.4.
• Cleaning of Teflon solenoid valve see sheet 4.3.7.
• Cleaning of flow limiting valve (or "restrictor") see sheet 4.3.6.
• Readjustment of UV signals see sheet 4.3.8.
• Replacement of UV lamp see sheet 4.3.9.
Checking Gas flow Parameters

• Use a calibrated flowmeter to check that the flow rate at the sample inlet is about 1 liter/minute.
• Check pressure in <TEST> mode (see section 3.2.2.5.).
Tools required:
• 1 calibrated flowmeter.
4–6 MAY 2002

PARAMETERS REPORT
MONITOR SERIAL NO.: OPERATION SHEET : 4.3.2
Scope : Check of gas flow and optical parameters PAGE : 2/2 Frequency :
15 days
Measurement ⇒ Synoptic Test ⇒ MUX signals Clean or exchange

Channel Channel O3 Solenoid
Pressure Flowrate 3 9 scrubber cell tube Windows valve
Lamp I
DATE M R EV off EV on
T° <UV>
MAY 2002 4–7

MAINTENANCE SHEET

Scope: Check of pump valves and diaphragm PAGE: 1/1 Frequency: Yearly
Type of
Check condition of diaphragm and pump valves. Replace them if necessary.
operation Date
Replacement of diaphragm and valves
The diaphragms and valves are parts that wear out; these parts are replaced
very easily.
Replacement of diaphragm and pump valves

Power instrument off, unplug the power cord
a) Disconnect supply connector.
b) Disconnect gas flow connections.
c) Loose the 3 screws (1) fastening pump assembly to frame in order to release
the 3 pump holder slots.
d) Unscrew the 2 screws (3) fastening pump on its holder.
e) Draw a permanent mark (13) on the pump boddy (8) for reassembling pur-
pose.
f) Remove the nut (5) fastening pump boddy (8) on the vibrating blade (6).
g) Unscrew the 2 screws (7) fastening pump boddy to pump housing (9).
h) Remove pump boddy.
i) Separate the various parts..
j) Clean diaphragm (10), the two valves (11) and the gasket (12).
k) Dust off or clean the different parts with alcohol (dismount valves if only nec-
essary)
l) Check diaphragm, change it if necessary.
m) Reassemble, repeating steps above in reverse order.
Tools required
• Dia. 4 mm cross-tip screwdriver,
• Dia. 5 mm flat screwdriver,
• Combination pliers
• Alcohol solution
Type of operation: D: Replacement of diaphragm V: Replacement of valves
4–8 MAY 2002

MAINTENANCE SHEET

Scope: Check of pump valves and diaphragm PAGE: 2/2 Frequency: Yearly
10
2 3 4 11
12
13
7 8 9
Figure 4-2 – Exploded view of the pump.
MAY 2002 4–9

MAINTENANCE SHEET

Scope: Maintenance on measurement cell PAGE: 1/2 Frequency: Yearly
Date
Cleaning Tube : see Figure 4-3 - Maintenance on measurement cell
Switch off analyzer. Unplug mains power supply cord.
Pulling it up, remove cover of optical bench.
Disconnect sample input tube out off detector assembly (4).
Dismount cell measurement assembly by loosening the 2 screws.(1)
Tilt bench assembly.(2)
Loosen screws (3) by about 1 mm.
Pull out the measurement bloc. (5)
Free up optical bench glass tube (6) being careful to not tilt it too much inside the support.(2)
Clean glass windows (7) using tips slightly dampened with alcohol.
Clean optical bench glass tube (6) by pushing optical paper slightly dampened with alcohol through
it with a Teflon tube (this paper is used to avoid scratching the internal surfaces).
Mount again the whole following the reverse order.
Tools Required
• Optical paper.
• Alcohol solution.
• Teflon tube (300 mm).
• 5 mm diam screwdriver.
4–10 MAY 2002

MAINTENANCE SHEET
Scope: Maintenance on measurement cell PAGE: 2/2 Frequency: Annual
3
7 6
3
Figure 4-3 - Maintenance on measurement cell
MAY 2002 4–11

MAINTENANCE SHEET

Scope: Replacement O3 scrubber PAGE: 1/1 Frequency: Annual
Replacing O3 Scrubber (see Figure 4-4):
Date
− MNO2 scrubber (1) is a complete cartridge.
− Loose the 2 screws (2) on SV block and pull it out.
− Interchange scrubber taking care of tightness
− Mount again the whole as shown in Figure 4-4.
2 1
Figure 4-4 - Replacement of Ozone scrubber
Tools Required
• Kit, P/N P06-K-0010-A.
4–12 MAY 2002

MAINTENANCE SHEET

Scope: Cleaning of solenoid valve PAGE: 1/1 Frequency: Annual
Date
Cleaning solenoid valve :
Switch off analyzer. Unplug power cord.
Disconnect supply cable of solenoid valve.
Unscrew the two screws (1) holding the solenoid valve onto the mount.
Remove the white back part of the valve (2) only.
Clean PTFE body (2) and valve (3) with a cloth dampened with alcohol.
If membrane is worn, replace the solenoid valve.
Assemble again. Run a leak test on the analyzer.
Pay attention to mounting sense (shift of holes on footing)
Replacing solenoid valve:

If a leak is detected, replace solenoid valve.
NOTE : Similar procedure for optional solenoid valves
Figure 4-5 – Solenoid valve
Tools Required
• Kit, P/N P01-E033-00A.
• 4 mm cross type screwdriver
• 5 x 100 mm screwdriver.
• Soft clothe.
• Alcohol solution.
MAY 2002 4–13

MAINTENANCE SHEET

Scope: Check and realignment of reference and meas- PAGE: 1/2 Frequency: Annual
urement signals
Date
Checking Measurement Signals:
Check MES and REF parameters in either Span ⇒ E2Pot or Test ⇒ Signal Mux screen ("Sig.
MES." channel 11 and "Sig. REF." channel 12).
Normal value ≈ 4500 mV.
If these values are near the limits (500 and 4800 mV), readjust signals.
If it is impossible to set the two voltages to more than 3000 mV, in this case increase the power of
the UV lamp (see Span ⇒ E2Pot sub menu. If it is too short, change the UV lamp (see sheet 4.3.8).
Realigning Measurement Signals:

The MES and REF signals are adjusted using the Gain (G) potentiometers on the respective detec-
tors (Figure 4-6).
Set the zero potentiometer (Z) to get 10 mV signal. This adjustment must be done with detector put
out of bench and its window being protected from any UV beam (1).
If it is possible to set "UV REF" to at least 4000 mV, but impossible for "UV MES", there are two
possibilities:
• clean measurement cell (windows, mirrors; see sheet 4.3.4.),
• measurement UV detector faulty (to check for this possibility: invert detectors; in this case,
the problem should be the opposite).
If it is possible to adjust "UV MES" to at least 4000 mV, but impossible to adjust "UV REF", it means
that "UV REF" detector is out of work.
Tools Required
• 2 mm screwdriver.
4–14 MAY 2002

MAINTENANCE SHEET

Scope: Check and realignment of reference and meas- PAGE: 2/2 Frequency: Annual
urement signals
Figure 4-6 - Unlock and set detectors
MAY 2002 4–15

MAINTENANCE SHEET

Scope: Replacement of measurement UV lamp PAGE: 1/2 Frequency: Annual
Date
Checking UV Lamp:
If the MES and REF values are near the low limits, check these parameters in Test ⇒ Mux signals
menu (see "Corrective Maintenance").
See operation sheet 4.3.7 - Check and realignment of reference and measurement signals.
If signals remain too low, it is necessary to replace UV lamp.
Replacing measurement UV Lamp: (see Figure 4-7)

Switch off device. Disconnect power cord, unscrew the screw (1). Disconnect the two supply wires
(2) (3) and the ground wire (4) from the UV power supply board connector. Remove used lamp.
Carefully pick up new lamp by its socket (3), place it in its slot (2) and screw again (1). Connect
supply and ground wires to UV power supply board. Check the correct wiring. Switch on device.
Go into Span ⇒ E2pot screen and check I Lamp (mA).
• adjustment using – signal + for UV lamp power supply with I Lamp reading from 18 to 22
mV.
• Adjust rotational and crosswise position of lamp so as to have maximum voltage values:
measure signal, measure reference. Once this value is obtained, tighten the knurled
thumb screw.
If the MES or REF signals are saturated (4999 mV), decrease G (gain) in respective de-
tectors.
Before realigning measurement signals, it is advisable to let the lamp's UV energy and temperature
stabilize.
Date
Replacing optinal O3 generator UV lamp: (see Figure 4-8)
Switch off device. Disconnect power cord, Disconnect the lamp connector (1) , unscrew the knurled
nut (2).
Place the Oring at 2mm from the beginning of the cylindrical par of the lamp bulb (3), place the
knurled nut on the lamp, screw the assembly on the generator, reconnect the supply connector (1).
Replace the charcoal filter cartridge (5).
Tools Required
• 2 x 7.5 mm screwdriver.
4–16 MAY 2002

MAINTENANCE SHEET

Scope: Replacement of measurement UV lamp PAGE: 2/2 Frequency: Annual
2 3 4
Figure 4-7 – Replacement of measurement UV lamp
3 4
1 5
2 mm
Figure 4-8 – Replacement of optional O3 generator UV lamp
MAY 2002 4–17

4.4 O342M MAINTENANCE KIT
Standard analyzer maintenance Kit A01-K-0342-K1

1 Pump kit V02-K-0041-A
1 ozone scrubber (selective filter) F05-0096-A
1 box of 25 diaphragms (Teflon filter) SAV-K-000042-A
2 on-line filters F05-IDN-10G
Maintenance kit for analyzer with ozone generator A01-K-0342-K2

1 standard analyzer maintenance Kit A01-KO342-K1
1 charcoal filter cartridge F05-SDN-A
4–18 MAY 2002

CHAPTER 5
CORRECTIVE MAINTENANCE
Table 5-1– List of faults and corrective actions 5–4

Table 5-2 – Board RS4i Configuration 5–7
Table 5-3 – Keyboard Interface configuration 5–8
Table 5-4 – ESTEL board configuration (when option available) 5–9
Table 5-5 – MODULE board configuration 5–11
Table 5-6 – Flowrate control board configuration and setting 5–12
Figure 5-1 – Card RS4i Configuration 5–7

Figure 5-2 – Keyboard Interface board 5–8
Figure 5-3 – ESTEL board 5–9
Figure 5-4 – MODULE board 5–10
Figure 5-5 – Flow rate control board 5–12
MAY 2002 5–1

5–2 MAY 2002

5 CORRECTIVE MAINTENANCE
Corrective maintenance of the monitor should only be performed by qualified personnel using the in-
formation provided in this document.
The monitor automatically and continuously self-tests its main components. Any malfunction detected
is indicated by a plain-language message on the display and a buzzer.
Table 5.1 summarizes the main faults indicated by the unit with corresponding corrective possible ac-
tions.
In case of operating fault, the ALARM message blinks in the top right corner.
To check which operating fault is present select the menu Measurement Ö Alarms display.
MAY 2002 5–3

Table 5-1– List of faults and corrective actions
ALARM MESSAGE CAUSE POSSIBLE ACTION

Analog to digital converter
– The reference voltage – Test electrical signals (TEST Ö MUX Signals
2,5 V (multiplexer input menu).
16) is outside the de-
signed limits. If voltage displayed is greater than 2520 mV
or less than 2480 mV.
– Check 2,5 V test, + 5 V, + 15 V and - 15 V

supply voltages on Modul board.
UV SOURCE FAULT
– The UV lamp is not lit. – Turn off, then turn back on.
– There is a failure in the – Check voltage on connector.

UV power supply.
REF SIGNAL FAULT
– The UV lamp energy is – Test electrical signals (TESTS Ö MUX Sig-
not high enough. nals menu).
– Adjust position of UV lamp (see section 4.3.8)

to obtain a maximum of energy (REF signal).
– Increase gain on REF (reference) detector to

obtain 2000 < REF (reference) < 4800 (see
section 4.3.7).
If still impossible:
– Increase UV lamp supply current using Span

Ö E2pot function (read MUX signal, ADJ
lamp, max. 250 mV) so as to read more than
3000 mV in TESTS Ö Optical bench mode.
– Replace lamp if it is impossible to adjust it

(see section 4.3.8).
– The UV REF detector is out of service (see

section 4.3.7).
MEASURE SIGNAL FAULT
– If the REF signal is nor- – Clean optical bench tube (see section 4.3.4)
mal, it means that the and windows.
optical bench is dirty or
the UV MES detector is – Increase gain on measurement detector to
out of service. obtain 3000 < MES < 4800 (see section
4.3.7).
– There is not enough – Replace lamp if necessary (see section

energy from the UV 4.3.8).
lamp.
– Measurement detector is out of work (see
section 4.3.7).
5–4 MAY 2002

ALARM MESSAGE CAUSE POSSIBLE ACTION

FLOW RATE FAULT
– Flow rate not correct in – Carry out pump complete overhauling.
measurement chamber:
the pump is not running
correctly.
– Leak in gas flow system. – Check all connections.
– Measure flow rate. Compare to test sheet for

device.
– Put a flowmeter at the outlet of the device.

Plug sample inlet. The ball of the flowmeter
should drop to zero. If it does not, there is a
leak.
– Flow rate OK, no leak. – Adjust P1 of flow rate control board.

PRESSURE FAULT
– The pressure in the – Check that sample is really at atmospheric
measurement chamber pressure.
is abnormally high >
1,050 mbar or low < 500 – Check that there is no clogging.
mbar.
– Disconnect tube on pressure sensor.
– Check that MUX signal, pressure, corre-

sponds to the ambient barometric pressure. If
necessary, use Span Ö Pressure screen to
adjust its value.
GAS TEMP. FAULT
– The temperature of the – The device is not under the normal operating
sample in the measure- conditions (see section 1.2.1 for operating
ment chamber is < 10° C temperature).
or > 55° C.
OVERRANGE
– The measurement value – Change range (see section 3.3.4.3).
exceeds the range se-
lected.
OPTIC. TEMP. FAULT
– The temperature of the – Check heating connection and if the LED
UV lamp unit is abnor- control reacts (ON/OFF).
mal.
– Heating element is faulty (TIP 3055).
MAY 2002 5–5

Table 5-1– List of faults and corrective actions (following)
SYMPTOM POSSIBLE CAUSES ACTIONS

Monitor does not react when
– Power failure. – Check that power is available.
switched on (no by-default
display).
– Cord faulty. – Test continuity of cord.
– Connector not plugged

in correctly.
– Main fuse out of service. – Check fuse inserted in connector block.
– Check connection between power supply

block and Module board 24 V.
Monitor remains in warm-up
– Microprocessor board – Check display flashing.
mode (no by-default display).
faulty.
– If no flashing, check that modul board is cor-
– Reset circuit blocked. rectly set.
Replace it if necessary.
– Microprocessor 5 V fail-
ure. – If it flashes, wait 15 minutes to see if the fail-
ure is displayed.
Failure display following re- Lamp gives off too much

– Change lamp position (rotate).
placement of UV lamp. energy.
Lamp does not light up.
– Check wiring of lamp. Decrease gain at level
of REF or MEAS detector, depending on fail-
ure.
Switching power supply is protected from short circuits.

STOP When it happens, it is necessary to disconnect/ reconnect the power cord in order to reset the
power supply protection.
5–6 MAY 2002

Table 5-2 – Board RS4i Configuration
Jumpers
Symbols Nature of operation
references
SW1, SW2 Channel 1 on RS422 standard
SW3 Channel 1 on RS232 standard
Load RX bus RS422 active
ST1
Load RX bus RS422 inactive
Load TX bus RS422 active
ST2
Load TX bus RS422 inactive
ST3 Not used
NOTE : Channel 2 is on the RS232 standard.
ST3
SW2 SW3 SW1 ST2 ST1
Figure 5-1 – Card RS4i Configuration
MAY 2002 5–7

Table 5-3 – Keyboard Interface configuration
Jumpers
references Symbols Nature of operation
Keyboard inhibited
ST1
Keyboard active
P1 LCD contrast adjustment potentiometer
P1 ST1
Figure 5-2 – Keyboard Interface board
5–8 MAY 2002

Table 5-4 – ESTEL board configuration (when option available)
Jumpers
Symbols Nature of operations
references
ESTEL selection, board N° 1
ST1, ST2, ESTEL selection, board N° 2

ST8 ESTEL selection, board N° 3
ESTEL selection, board N° 4
0 V grounded (default)
ST3
Potential free contact
0-1 V, idem for the 4 DAC.
DAC1
0-10 V, idem for the 4 DAC
DAC2
0-20 mA, idem for the 4 DAC.
DAC3
DAC4 4-20 mA, idem for the 4 DAC.
P1, P2, P3,

4 mA adjustment in 4-20 mA mode
P4
DAC DAC DAC DAC

1 2 3 4
P1 P2 P3 P4
Communication
light
ST1 ST2 ST8 ST3
Figure 5-3 – ESTEL board
MAY 2002 5–9

J22
J34 PT5 PT7 PT6 PT10
PT2
J1
J2
SW1
J3 PT9
PT1
J4
PT3
J5
PT4
J6
J35
J21 J7
J23
ST1
J8
PT16
PT17
PT15
J9
ST2
J20
J10
SW4
SW3
J11
Pt12
Pt13
J12
Pt14
J13
J18
J14
J15
PT11
J16
J17
PT8
Figure 5-4 – MODULE board
5–10 MAY 2002

Table 5-5 – MODULE board configuration
Test points. Type of signal Connector Connection

PT1 Flow ratel J1 Option 1
PT2 Cell pressure J2 Option 2
PT3 UV lamp temperature J3 Cell pressure
PT4 Gaz temperature J4 Gaz temperature
PT5 A/D RUN J5 Flow rate sensor
PT6 A/D STATUS J6 Measurement detector
PT7 A/D CS J7 UV lamp temperature
PT8 0 V (GND) J8 Reference detector
PT9 0 V (GND) J9 O3 generator UV lamp
PT10 MUX output J10 Measurement UV lamp
PT11 +24VCC J11 SV Zero
PT12 +5VCC J12 SV span
PT13 +15 VCC J13 SV cycle
PT14 -15VCC J14 Auxiliary 1
PT15 I off+ J15 Auxiliary 2
PT16 I off - J16 UV lamp heating
PT17 RAM reset J17 +24VCC supply
J18 +4VCC on/off switch
J19 Not used
J20 Estel board I2C bus
J21 Synchro bus
J22 RS4i board I2C bus
Jumpers Nature of operation J23 RAM extention option
1 J24 Not used
2 Selects 27C20 (2 Mbits)
SW1 3
J25 Not used
EPROM
Configuration 1 J26 Not used
2 Selects 27C40 (4 Mbits)
3
J27 Not used
SW3 1 2 3 5V I2C Bus J28 Not used

Power supply
1 2 3 24V I2C Bus J29 Not used
=CLK/2 J30 Not used

SW4 1 2 3
Internal clock
1 2 3 = CLK (default position) J31 Not used
(default position) J32 Not used

ST1
Resets microprocessor J33 Not used
ST2 Inactive J34 Stand by LED option
Watch dog Active (default position) J35 Maintenance switch option
MAY 2002 5–11

Table 5-6 – Flowrate control board configuration and setting
Designation Nature of operations
Ground referenced to Module

Board
ST1
Direct ground (default position)
P1 Flow rate adjustment
P2 Pump frequency adjustment
PT0 Ground
PT1 Flow rate signal
PT2 Pump supply voltage
P2 PT2 PT2 ST1
P1
PT0
Figure 5-5 – Flow rate control board
5–12 MAY 2002

6 CHAPTER 6
APPENDIX
APPENDIX 6.1 CALIBRATION PROCEDURE 6-2
MAY 2002 6–1

6.1 CALIBRATION PROCEDURE
as the ratio I/I0 , where I is the intensity of light which passes

1. Principle
through the cell and is sensed by the detector when the cell
contains an O3 sample, and I0 is the intensity of light which
The calibration procedure is based on the photometric assay
passes through the cell and is sensed by the detector when
of ozone (O3) concentrations in a dynamic flow system. The
the cell contains zero air. It is assumed that all conditions of
concentration of O3 in an absorption cell is determined from
the system, except for the contents of the absorption cell, are
a measurement of the amount of 254 nm light absorbed by
identical during measurement of I and I0. The quantities
the sample. This determination requires knowledge of (1)
defined above are related by the Beer-Lambert absorption
the absorption coefficient (α) of O3 at 254 nm, (2) the opti-
law,
cal path length (l) through the sample, (3) the transmittance
of the sample at a wave-length of 254 nm, and (4) the tem-
perature (T) and pressure (P) of the transmittance is defined
I
Transmittance = = e -acl (1)
I0
where: A complete UV calibration system consists of an ozone

generator, an output port or manifold, a photometer, an ap-
α = absorption coefficient of O3 at 254 nm = 308±4 atm-1 propriate source of zero air, and other components as neces-
cm-1 at 0 °C and 760 torr. (1, 2, 3, 4, 5, 6, 7) sary. The configuration must provide a stable ozone concen-
c = O3 concentration in atmospheres tration at the system output and allow the photometer to
accurately assay the output concentration to the precision
l = optical path length in cm specified for the photometer (3.1). Figure 1 shows a com-
monly used configuration and serves to illustrate the calibra-
In practice, a stable O3 generator is used to produce O3 con- tion procedure which follows. Other configurations may
centrations over the required range. Each O3 concentration is require appropriate variations in the procedural steps. All
determined from the measurement of the transmittance (I/I0) connections between components in the calibration system
of the sample at 254 nm with a photometer of path length l downstream of the O3 generator should be of glass, Teflon,
and calculated from the equation, or other relatively inert materials. Additional information
regarding the assembly of a UV photometric calibration
1 apparatus is given in Reference 9. For certification of trans-
c(atm) = − (1n I / I 0 ) (2a) fer standards which provide their own source of O3, the
αl transfer standard may replace the O3 generator and possibly
other components shown in Figure 1; see Reference 8 for
or, guidance.
6
10 3.1 UV photometer. The photometer consists of a low-
c(ppm) = − (1n I / I 0 ) (2b) pressure mercury discharge lamp, (optional) collimation
αl
optics, an absorption cell, a detector, and signal-processing
The calculated O3 concentrations must be corrected for O3 electronics, as illustrated in Figure 1. It must be capable of
losses which may occur in the photometer and for the tem- measuring the transmittance, I/I0, at a wavelength of 254 nm
perature and pressure of the sample. with sufficient precision such that the standard deviation of
the concentration measurements does not exceed the greater
2. Applicability. of 0.005 ppm or 3% of the concentration. Because the low-
pressure mercury lamp radiates at several wavelengths, the
This procedure is applicable to the calibration of ambient air photometer must incorporate suitable means to assure that
O3 analyzers, either directly or by means of a transfer stan- no O3 is generated in the cell by the lamp, and that at least
dard certified by this procedure. Transfer standards must 99.5% of the radiation sensed by the detector is 254 nm
meet the requirements and specifications set forth in Refer- radiation. (This can be readily achieved by prudent selection
ence 8. of optical filter and detector response characteristics). The
length of the light path through the absorption cell must be
3. Apparatus known with an accuracy of at least 99.5%. In addition, the
cell and associated plumbing must be designed to minimize
6–2 MAY 2002

loss of O3 from contact with cell walls and gas handling performance and stability record of the photometer is estab-
components. See Reference 9 for additional information. lished, the frequency of these steps may be reduced consis-
tent with the documented stability of the photometer.
3.2 Air flow controllers. Devices capable of regulating air
flows as necessary to meet the output stability and photome- 5.2.1 Instruction manual: Carry out all set up and adjustment
ter precision requirements. procedures or checks as described in the operation or in-
struction manual associated with the photometer.
3.3 Ozone generator. Device capable of generating stable
levels of O3 over the required concentration range. 5.2.2 System check: Check the photometer system for integ-
rity, leaks, cleanliness, proper flowrates, etc. Service or
3.4 Output manifold. The output manifold should be con- replace filters and zero air scrubbers or other consumable
structed of glass, Teflon, or other relatively inert material, materials, as necessary.
and should be of sufficient diameter to insure a negligible
pressure drop at the photometer connection and other output 5.2.3 Linearity: Verify that the photometer manufacturer has
ports. The system must have a vent designed to insure at- adequately established that the linearity error of the pho-
mospheric pressure in the manifold and to prevent ambient tometer is less than 3%, or test the linearity by dilution as
air from entering the manifold. follows: Generate and assay an O3 concentration near the
upper range limit of the system (0.5 or 1.0 ppm), then accu-
3.5 Two-way valve. Manual or automatic valve, or other rately dilute that concentration with zero air and reassay it.
means to switch the photometer flow between zero air and Repeat at several different dilution ratios. Compare the assay
the O3 concentration. of the original concentration with the assay of the diluted
concentration divided by the dilution ratio, as follows:
3.6 Temperature indicator. Accurate to ±1 °C.
A1 − A 2 / R
3.7 Barometer or pressure indicator. Accurate to ±2 torr. E= x 100% (3)
A1
4. Reagents
where:
4.1 Zero air. The zero air must be free of contaminants
which would cause a detectable response from the 03 ana- E = linearity error, percent
lyzer, and it should be free of NO, C2H4 and other species A1 = assay of the original concentration
which react with O3. A procedure for generating suitable A2 = assay of the diluted concentration
zero air is given in Reference 9. As shown in Figure 1, the R = dilution ratio = flow of original concentration divided
zero air supplied to the photometer cell for the I0 reference by the total flow
measurement must be derived from the same source as the
The linearity error must be less than 5%. Since the accuracy
zero air used for generation of the ozone concentration to be
of the measured flowrates will affect the linearity error as
assayed (I measurement). When using the photometer to
measured this way, the test is not necessarily conclusive.
certify a transfer standard having its own source of ozone,
Additional information on verifying linearity is contained in
see Reference 8 for guidance on meeting this requirement.
Reference 9.
5. Procedure
5.2.4 Intercomparison. When possible, the photometer
5.1 General operation. The calibration photometer must be should be occasionally intercompared, either directly or via
dedicated exclusively to use as a calibration standard. It transfer standards, with calibration photometers used by
should always be used with clean, filtered calibration gases, other agencies or laboratories.
and never used for ambient air sampling. Consideration
5.2.5 Ozone losses: Some portion of the O3 may be lost upon
should be given to locating the calibration photometer in a
contact with the photometer cell walls and gas handling
clean laboratory where it can be stationary, protected from
components. The magnitude of this loss must be determined
physical shock, operated by a responsible analyst, and used
and used to correct the calculated O3 concentration. This loss
as a common standard for all field calibrations via transfer
must not exceed 5%. Some guidelines for quantitatively
standards.
determining this loss are discussed in Reference 9.
5.2 Preparation. Proper operation of the photometer is of
5.3 Assay of O3 concentrations.
critical importance to the accuracy of this procedure. The
following steps will help to verify proper operation. The
5.3.1 Allow the photometer system to warm up and stabilize.
steps are not necessarily required prior to each use of the
photometer. Upon initial operation of the photometer, these 5.3.2 Verify that the flowrate through the photometer ab-
steps should be carried out frequently, with all quantitative sorption cell, F allows the cell to be flushed in a reasonably
results or indications recorded in a chronological record short period of time (2 liter/min is a typical flow). The preci-
either in tabular form or plotted on a graphical chart. As the
MAY 2002 6–3

sion of the measurements is inversely related to the time sibility to verify that all of the information required for equa-
required for flushing, since the photometer drift error in- tion 4 is obtained, either automatically by the photometer or
creases with time. manually. For "automatic" photometers which evaluate the
first term of equation 4 based on a linear approximation, a
5.3.3 Insure that the flowrate into the output manifold is at manual correction may be required, particularly at higher O3
least 1 liter/min greater than the total flowrate required by levels. See the photometer instruction manual and Reference
the photometer and any other flow demand connected to the 9 for guidance.
manifold.
5.3.11 Obtain additional O3 concentration standards as nec-
5.3.4 Insure that the flowrate of zero air, FZ, is at least 1 essary by repeating steps 5.3.6 to 5.3.10 or by Option 1.
liter/min greater than the flowrate required by the photome-
ter. 5.4 Certification of transfer standards. A transfer standard is
certified by relating the output of the transfer standard to one
5.3.5 With zero air flowing in the output manifold, actuate or more ozone standards as determined according to section
the two-way valve to allow the photometer to sample first 5.3. The exact procedure varies depending on the nature and
the manifold zero air, then FZ. The two photometer readings design of the transfer standard. Consult Reference 8 for
must be equal (I = I0). guidance.
NOTE: In some commercially available photometers, the 5.5 Calibration of ozone analyzers. Ozone analyzers are
operation of the two-way valve and various other operations calibrated as follows, using ozone standards obtained di-
in section 5.3 may be carried out automatically by the pho- rectly according to section 5.3 or by means of certified trans-
tometer. fer standard.
5.3.6 Adjust the O3 generator to produce an O3 concentration 5.5.1 Allow sufficient time for the O3 analyzer and the pho-
as needed. tometer or transfer standard to warmup and stabilize.
5.3.7 Actuate the two-way valve to allow the photometer to 5.5.2 Allow the O3 analyzer to sample zero air until a stable
sample zero air until the absorption cell is thoroughly flus- response is obtained and adjust the O3 analyzer's zero con-
hed and record the stable measured value of I0. trol. Offsetting the analyzer's zero adjustment to +5% of
scale is recommended to facilitate observing negative zero
5.3.8 Actuate the two-way valve to allow the photometer to drift. Record the stable zero air response as "Z".
sample the ozone concentration until the absorption cell is
thoroughly flushed and record the stable measured value 5.5.3 Generate an O3 concentration standard of approxi-
of I. mately 80% of the desired upper range limit (URL) of the O3
analyzer. Allow the O3 analyzer to sample this O3 concentra-
5.3.9 Record the temperature and pressure of the sample in tion standard until a stable response is obtained.
the photometer absorption cell. (See Reference 9 for guid-
ance). 5.5.4 Adjust the O3 analyzer's span control to obtain a con-
venient recorder response as indicated below:
5.3.10 Calculate the O3 concentration from equation 4. An
average of several determinations will provide better preci- recorder response (% scale) =
sion.
 [O 3 ]OUT 
 −1 I   T   760  10
6  x 100 + Z (5)
[O ] = ln     x (4)  URL 
 αl I 0   273   P 
3 OUT
L
where:
where:
URL = upper range limit of the O3 analyzer, ppm
[O3]OUT = O3 concentration, ppm Z = recorder response with zero air, % scale
α = absorption coefficient of O3 at 254 nm = 308 atm-1 cm-1
Record the O3 concentration and the corresponding analyzer
at 0 °C and 760 torr
response. If substantial adjustment of the span control is
l = optical path length, cm
necessary, recheck the zero and span adjustments by repeat-
T = sample temperature, K
ing steps 5.5.2 to 5.5.4.
P = sample pressure, torr
L = correction factor for O3 losses from 5.2.5 = (1-fraction
5.5.5 Generate several other O3 concentration standards (at
O3 lost).
least 5 others are recommended) over the scale range of the
NOTE: Some commercial photometers may automatically O3 analyzer by adjusting the O3 source or by Option 1. For
evaluate all or part of equation 4. It is the operator's respon-
6–4 MAY 2002

each O3 concentration standard, record the O3 and the corre-
REFERENCES
sponding analyzer response.
1. E.C.Y. Inn and Y. Tanaka, "Absorption coefficient of
5.5.6 Plot the O3 analyzer responses versus the correspond-
Ozone in the Ultraviolet and Visible Regions", J. Opt. Soc.
ing O3 concentrations and draw the O3 analyzer's calibration
Am., 43, 870 (1953).
curve or calculate the appropriate response factor.
2. A.G. Hearn, "Absorption of Ozone in the Ultraviolet and
5.5.7 Option 1: The various O3 concentrations required in
Visible Regions of the Spectrum", Proc. Phys. Soc. (Lon-
steps 5.3.11 and 5.5.5 may be obtained by dilution of the O3
don), 78, 932 (1961).
concentration generated in steps 5.3.6 and 5.5.3. With this
option, accurate flow measurements are required. The dy-
3. W.B. De More and O. Raper, "Hartley Band Extinction
namic calibration system may be modified as shown in Fig-
Coefficients of Ozone in the Gas Phase and in Liquid Nitro-
ure 2 to allow for dilution air to be metered in downstream
gen, Carbon Monoxide, and Argon", J. Phys. Chem., 68, 412
of the O3 generator. A mixing chamber between the O3 gen-
(1964).
erator and the output manifold is also required. The flowrate
through the O3 generator (F0) and the dilution air flowrate 4. M. Griggs, "Absorption Coefficients of Ozone in the
(FD) are measured with a reliable flow or volume standard Ultraviolet and Visible Regions", J. Chem. Phys., 49, 857
traceable to NBS. Each O3 concentration generated by dilu- (1968).
tion is calculated from:
5. K. H. Becker, U. Schurath, and H. Seitz, "Ozone Olefin
 
[ O ]'
3 OUT = [ O3]OUT  F0 
 F0 + FD 
(6)
Reactions in the Gas Phase. 1. Rate Constants and Activa-
tion Energies", Int'l Jour. of Chem. Kinetics, VI, 725 (1974).
6 M. A. A. Clyne and J. A. Coxom, "Kinetic Studies of Oxy-

where:
halogen Radical Systems", Proc. Roy. Soc., A303, 207
(1968).
[O3]'OUT = diluted O3 concentration, ppm
F0 = flowrate through the O3 generator, liter/min
7. J. W. Simons, R.J. Paur, H. A. Webster, and E. J. Bair,
FD = diluent air flowrate, liter/min
"Ozone Ultraviolet Photolysis. VI. The Ultraviolet Spec-
trum", J. Chem. Phys., 59, 1203 (1973).
8 "Transfer Standards for Calibration of Ambient Air Moni-

toring Analyzers for Ozone", EPA Publication available
from EPA, Department E (MD-77), Research Triangle Park,
NC 27711.
9 "Technical Assistance Document for the Calibration of

Ambient Ozone Monitors", EPA Publication available from
EPA, Department E (MD-77), Research Triangle Park, NC
27711.
MAY 2002 6–5

Figure 1 - Schematic diagram of a typical UV photometric calibration system
Figure 2 - Schematic diagram of a typical UV photometric calibration system
6–6 MAY 2002

Technical Manual: Uv Photometric Ozone Analyzer

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CHARACTERISTICS

111 bd Robespierre, 78300 POISSY – TEL. 33(0)-1.39.22.38.00 – FAX 33(0)-1.39 65.38.08

0–2 MAY 2002

CHAPTER 3. OPERATING INSTRUCTION

3.1. INITIAL STARTUP 3-4

CHAPTER 4. PREVENTIVE MAINTENANCE

CHAPTER 5. CORRECTIVE MAINTENANCE

MAY 2002 0–3

Table 5-1– List of faults and corrective actions 5–4

Figure 2.1 - Ozone absorption spectrum 2-2

Figure 3.1 – Electrical connections 3-3

Figure 4-1 – Inlet dust filter 4–5

Figure 5-1 – Card RS4i Configuration 5–7

0–4 MAY 2002

Page Date Page Date Page Date

3-1 05.2002 4-1 05.2002

MAY 2002 0–5

EPA Equivalency Designation.

The ozone analyzer, model O342M, is designated as an equivalent method number

0–6 MAY 2002

GENERAL INFORMATION - CHARACTERISTICS

1.1 GENERAL INFORMATION 1–3

MAY 2002 1–1

1 GENERAL INFORMATION - CHARACTERISTICS

Figure 1-1 - O342M Presentation

1–2 MAY 2002

1.1 GENERAL INFORMATION

Figure 1-2 - Keyboard and display

MAY 2002 1–3

1–4 MAY 2002

1.1.2.2 Rear panel

Electrical Equipment Connections (left hand side)

With ZERO/SPAN solenoid valve option :

MAY 2002 1–5

1–6 MAY 2002

1.1.2.3 Components location

MAY 2002 1–7

1.1.3 MAIN FEATURES

– Measurement values indicated in ppm or mg/m3.

1.1.4 ASSOCIATED EQUIPMENT

1–8 MAY 2002

1.2.1 TECHNICAL CHARACTERISTICS

MAY 2002 1–9

1.2.2 STORAGE CHARACTERISTICS

1.2.3 INSTALLATION CHARACTERISTICS

Figure 1-5 - Links between units

1.2.3.2 Dimensions and weight

1–10 MAY 2002

Figure 1-6 - Outline dimensions

MAY 2002 1–11

Page intentionally left blank

1–12 MAY 2002

2.1 PRINCIPLE OF MEASUREMENT 2–3

MAY 2002 2–1

Figure 2-1 - Ozone absorption spectrum

2–2 MAY 2002

2.1 PRINCIPLE OF MEASUREMENT

absorption coefficient = 308 atm-1.cm-1