Fired Heaters
Fired Heaters
Fired Heaters
E3
Since
1976 43
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Sep 2019
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Sep 2019
IR: 0.7 to 400 µ. Heater 0.7 to 14 µ Why only CO2 and H2O?
Symmetrical molecules O2 + N2 do not absorb
Partial Pressure or
Heat transfer across space without physical contact. A Binary H2O and CO2 molecular bonds bend 0.35
H2
0.30
surface phenomena related to surface temperature and vibrate. Kinetic energy 0.25 CH4
Solid radiation is in full spectrum. Surface phenomena. H2O emissivity is the highest 10° Oil
Gas radiation - Thickness or Depth related. Limited range. Gaseous fuels radiate better
Wavelengths: Shorter as energy level/ temperature rises Fuel H2O/ (H2O+CO2)
0% Xs Air 20% 40%
Sun. Much of its radiation in shorter wavelengths, visible light Heavy oil 1/ (0.3-0.42)
3 0.7
Distillates 1/ (0.42-0.5) 700°C
2
0.6
It may appear that radiation is from flame, Natural Gas 2/ (0.6-0.7) 900°C
Gas emissivity, εG
3
0.5
But bulk is from hot CO2 and H2O in flue gas, in infrared range 1100°C
90% from gas; 10% from flame
Gas emissivity εG depends on gas temperature, 0.4
partial pressure of H2O + CO2 + SO2 - “p” and 0.3
▪ H2 has no visible flame. Oil flame appears luminous as it cracks to soot depth of gas cloud or mean beam length, L.
during combustion 0.2
High Xs air reduces εG
0.1 0.0 0.5 1.0 1.5
L = 3.6*V/Ae. Wimpress pL, atm.m
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Fraction absorbed α
10-15 kCal/~, 2-3 Btu/~) 0.8 Reflected
0.6
Reflection boosts radiation transfer.
Radiation Effective: Direct 75%; 1st reflection 68%; 2nd 61%; 3rd 54% 0.4 Direct
D
Refractory
Flame and gas (CO2/H2O) to tubes and refractory Take 100 rays from a single point 0.2
Tubes to refractory and gas cloud S Direct 40 rays x 0.75 = 30 units 0.01 2 3 4
Refractory to tubes and gas cloud Once reflected 30 rays x 0.68 = 20.4 Spacing S/ tube dia d, S/D
Convection Twice reflected 15 rays x 0.61 = 9.2
Thrice reflected 15 rays x 0.54 = 8.1
Flue gas recirculates between tubes and refractory - thermo Re-circulating
siphon effect. Heat to front + back of tubes and refractory Total 100 rays 67.7 units
Flue Gas
Between gas components. 70% heat in non-radiating O2 Gas Cloud
Refractory re-radiation enhances gas emissivity + heats
and N2. Convection to CO2 and H2O that radiate tube backside
Refractory
From tube to heated fluid Larger the tube spacing or more gap between tubes, OD L
less direct radiation and more reflected radiation
Conduction thru scale and tube wall Tubes usually on 2D spacing. S = 2D -≈ 1.8 OD
To tubes/ fluid Tube to wall 1½ D. Beyond 1½ D, rear side absorption Acp S
Gas cloud remains at Av Radiant Flux:
Front: Flame + gas cloud radiation + convection
residual or equilibrium Based tube outside area = πDL
Back: Convection + Refractory radiation
firebox temperature, Effective Area of Cold Plane (Acp) receiving Acp = nSL if single side fired
Thru tube wall. From wall to process fluids radiation = αSL αAcp Acp = 2nSL if double side fired,
receives heat from
flame and radiates it but “α” direct only
Bulk of heat transfer in radiant section is by convection between gases to tubes and refractory
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Sep 2019
Cgr
Cgt
Refractory
Rgt Rrt CCRra
Rgr
3 Zones: Gradient in Tube and Gas Temperature based on:
180°
1. Source = Gas cloud + Flame 0.9 Size and shape of firebox
0.8 Ar/αAcp =5
2. Sink = Tubes and 0.7 3 ▪ Squat firebox: Less gas temperature gradient 60°
0.6 1 ▪ Long cylinder: More gradient
3. both enclosed by Refractory that absorbs no heat 0.5 0 Single sided firing
but reradiates back to source, to sink and to itself 0.4 Proportion of wall area covered by tube
0.3 Flow of fluid w.r.t flue gas flow
0.2
Refractory 0.1 Tube to tube spacing
Enhances heat to tubes - back and front 0.2 0.3 0.4 0.5 0.6 0.7 Tube to wall spacing and Double sided firing
More effective - close to tube (square-of-distance- Gas emissivity, εG
Type of firing & firing density impacting recirculation
effect) + high emissivity Ar = Uncovered refractory
area = Total Refractory area,
Contribution more in side/central/ bridge-wall Single sided firing: Max front or fireside 180°flux
At minus αAcp
fired. But low mean beam length and flue gas 50% higher than average flux on 2D spacing; front
recirculation 60° is 80% more
Once refractory’s role is understood, abandoned Double sided firing: 25% more on front 60°
X
Refractory
2nd row of tubes common in older designs. Larger tube spacing evens out maximum flux rate
Doubles the cost but adds 25% more area Peak film temp- 2D = 450°C 3D = 433°C
Why 2 or D only?
Efforts on polished reflecting surface on refractory X Why not 2.25D?
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Cgr
Cgt
Refractory
Rgt Rrt CCRra
Rgr
Impact of T4 relationship Emissivity, ε and Absorptivity, α depend on temperature/
Net exchange between two surfaces: wavelength. Higher the temperature, lower in metals; exception
q1 4 - T24)/(1/ε1 - 1/ε2 -1) + convection part, hc Ao(T1 - T2) non-metals like refractory
2 A1F σ(T1
Polished and clean metal surfaces - low ε; oxidized and rough metal
Changes in T2 hardly impacts T1 surfaces - high ε. Usual tube ε = 0.9
Simple heat transfer analysis - stirred tank or single zone.
if T2 < ½T1, flux gradients minor Computerized methods - multiple small zones
Tg = 870° Tt = 370
Temperature gradients expected in wall firing tall and narrow fired
Crude Oil Heater reactors
▪ Tin = 300°C Tout = 370 Tav = 335 Tt = 370 Tg = 870° Tg4 = (870+273)4
= 17,06,80,89,89,601
Conduction and convection decided by temperature difference or
▪ Tt4 is about 10% of Tg4 ∆t. Radiation decided by temperature level. WB = σT4. Higher
Tg4 = (370+273)4
▪ 10% variation in Tt has little impact on Tg = 1,70,94,00,75,601 sensitivity to temperature
▪ Some correlations ignore Tt. In:Out flux = 1.05:1.0
Multiple sources + multiple receptors @ temperature gradients in
In case of fired reactors T2 and T1 are close different firebox zones - can be solved by a network analysis as in an
electrical circuit with differing potential
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Sep 2019
Qr = Radiant duty S S
Qin = Heat input into firebox
φoverall = Overall exchange factor D
C = Empirical coefft based on Tg L Acp
Se = Equivalent effective area
Wilson, Lobo & Hottel (1932) Literature “bookish” correlations 6” pipe on 12” pitch
Qr = Qin/ (1+G(Qin/αAcp)½/4200). Only Xs air. Firebox Ar, pL, Tg, Tt not in S = 12/6.625 = 1.81
Hottel (1938) require
Qr = αAcpφoverallσ(Tg4 - Tt4). pL, εgas,εeffective ,firebox geometry considered
4” pipe on 8” pitch
Firebox layout to find Tg, as if equations S = 8/4.5 = 1.77
Mekler (1938)
Qr = 1.74e-8CSe(Tg4 - Tt4). pL, εgas ,εeffective ,firebox geometry not considered
are good for rating only Take S/D = 1.8
Lobo & Evans (1939) - Widely used Assume a radiant duty, decide firebox lay
Qr = 1.73e-8αAcpφ(Tg4 - Tt4) + 7φ(Tg4 - Tt4)
out, calculate Ar, αAcp, Tg, and check duty Ao ≈ 2αAcp
pL, εgas ,εeffective ,firebox geometry + convection considered. εtube = 0.9
85 tests; 19 different furnaces; Xs air = 6-170% q/A = 3,000 to 54,000 Btu/h.ft2; hc = 10 W/~, kCal/~ , 2
Ar/ αAcp = 0.45-6.65. Error 5-16%. Modern: Xs air = 5-40% Ar/αAcp = 0.5-1 Which tube area? Btu/~ units based on Ao.
Hottel & Sarofim (1967) Tg Flux specified on tube OD area, Ao = πDL Based on αAcp
Qr = Acp σ εeffective (Tg4 - Tt4) Projected tube area, At = DL Taking εeffective = 0.57,
pL, εgas , firebox geometry not considered. εeffective based
on tube pitch and εtube free to input Effective plane area, Acp = SL = 1.8DL hc = 10*2/0.57
= 35 W/~, kCal/~
Ao/π = Acp/1.8 Ao≈2αAcp
Tg = Based on both heat
= 7 Btu/~ units,
transfer and heat balance
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Sep 2019
VC Heater. Duty = 3 MW
Tin / Tout = 250/ 450°C
Stack Gas ∆T = 140°C
Stack Gas T = 390°C
Verify heat duty = ẃ(Hout-Hin)
Select heater type, say VC No dew point issue
Select stack gas temperature = Fluid inlet Fuel = Refinery Gas
temperature + 30 ~ 150°C
Check if inlet fluid temperature results in Fuel LHV = 46,250 kJ/kg
Flue gas water dew point (≈ 60-70°C) and/or Ex Air = 20%
Acid dew point (≈ 150°C). Stack gas T > Dew Thermal eff = 82.2 %
Point
Find thermal efficiency based on stack gas Casing loss = 2%
temperature, Xs air and 1-3% casing loss Fired Duty = 30/0.802
Find fuel fired, flue gas and air demand = 3.74 MW
NHV Air Air kg/ Fuel = 291 kg/h
Fuel kCal/kg kg/kg 10,000 kCal
H2 28,670 34.8 12.10 Air = 5,427 kg/h
C 8,110 11.6 14.30 Flue gas = 5,718 kg/h
S 5,650 4.4 7.80
Methane 13,290 17.3 13.00 Combustion Air Demand: 3.4 kg/10,000
Ethane 12,420 16.1 13.00 kJ;14.0 kg/ 10,000 kcal; 7.8 lb/ 10,000 Btu
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Sep 2019
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Sep 2019
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Two Phase Pressure Drop Equilibrium Flash To API RP 530. Steam coils to ASME
Vaporization Chart
0% Vaporized
state. Stress at that point is called Yield Stress
Plastic deformation, on further stress
remains permanent even when load is removed
60% Vaporized Stress causing plastic deformation before fracture is Ultimate
Tensile Stress
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Sep 2019
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Sep 2019
Snuffing Atomizing
Given
ID = 0.6m (2’) L = 0.9m (3’); Tg = 1,540°C (2800°F) and Tw = 150°C
(300°F). 20% Xs. Q = 1.2 MW (4 MMBtu/h)
qr
Snuffing Steam
F = Ac/At = πDL/(πDL + 2πD²/4) = 0.75
Purge firebox of unignited hydrocarbon, before light up to avoid an
pL = 0.24*0.6 = 0.144 at.m (0.48 atm.ft) explosion
εg = 0.12; εt = 0.79; (1/εg - 1/εt -1) = 8.6 Failure to purge - repeated cause of firebox explosions
q/A = Fσ(T14 - T24)/(1/ε1 - 1/ε2 -1) = 53.3 kW/m² ~ (17,000 Btu/h.ft²) LP steam @ firebox volume in 5 minutes. Additional purge connections
qc to header boxes. Note: Use steam density at atmospheric pressure
hc = 7.45 W/~ (1.31 Btu/~). 10.34 kW/ kW/m² (3,275 Btu/ h.ft²) Use snuffing steam to put out any small fire caused by tube leak
qr + qc = 63.6 kW/m² ~ (20,300 Btu/ h.ft²) Run FD fan for few minutes, if no LP steam OR use steam/ air ejectors
Application: Water bath, steam bath, salt bath and reboiler Atomizing Steam
Atomizing steam - to shear and froth fuel oil. @ 25-45% oil flow
150 - 750mm (0.5-3’) dia x 1.5 - 9m (5-30’) long Soot Blower Steam + Plant Air
Steam: 4,500 kg/h for retractable. Air: 80-100 Nm³/h for its pneumatic
motor
From: Engineering Data Book, GPSA, Section 8, Ex 8-6 and 8-13
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Regularly remove internal coking and deposits to avoid hot spots Furnace Operations, R D Reed
and premature tube failure Petroleum Refinery Engg, W L Nelson,
Gas oil circulation: Softens and removes deposits. Not for heavy coking Chapter 18
Chemical cleaning: Circulating inhibited acid or chemical + water wash Engineering Data Book, GPSA, Section 8
for salt deposits API Publications
Hydroblasting: High pressure water jet. Abrasive grit. Shot/sand Spec 12K Specification for Indirect Type
Steam: air decoking: In-situ combustion with steam and air Oilfield Heaters
Tubes in 1 pass are decoked. Tubes in other passes kept cool with steam Std 530/ISO 13704 Calculation of Heater-
Tube Thickness in Petroleum Refineries
Pigging - abrasive pigs with external studs and grit RP 535 Burners for Fired Heaters in
Pigging avoids temperature shock. Faster. May damage 180° bends General Refinery Services
RP 556 Instrumentation, Control, and
Less damage than decoking or acid wash Protective Systems for Gas Fired Heaters
May pig with water after steaming. Intelligent Pig Std 560/ISO 13705 Fired Heaters for
Decoking Pig
Increase pig size incrementally General Refinery Services
Mechanical turbine thru Mule Ear Plugs RP 573 Inspection of Fired Boilers and
Also: Pre-heat train and Convection Section cleaning
Heaters
Burner: Oil & Gas gun cleaning
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Sep 2019
Stay Safe. The best for many years of safe and sustained operations
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