Designation: G 3 – 89 (Reapproved 2004)

Standard Practice for

Conventions Applicable to Electrochemical Measurements
in Corrosion Testing1
This standard is issued under the fixed designation G 3; the number immediately following the designation indicates the year of original
adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A superscript
epsilon (e) indicates an editorial change since the last revision or reapproval.

1. Scope measurements in corrosion testing. In this convention, the

1.1 This practice covers conventions for reporting and positive direction of electrode potential implies an increasingly
displaying electrochemical corrosion data. Conventions for oxidizing condition at the electrode in question. The positive
potential, current density, electrochemical impedance and ad- direction has also been denoted as the noble direction because
mittance, as well as conventions for graphical presentation of the corrosion potentials of most noble metals, such as gold, are
such data are included. more positive than the nonpassive base metals. On the other
1.2 This standard does not purport to address all of the hand, the negative direction, often called the active direction, is
safety concerns, if any, associated with its use. It is the associated with reduction and consequently the corrosion
responsibility of the user of this standard to establish appro- potentials of active metals, such as magnesium. This conven-
priate safety and health practices and determine the applica- tion was adopted unanimously by the 1953 International Union
bility of regulatory limitations prior to use. of Pure and Applied Chemistry as the standard for electrode
potential (1).3
2. Referenced Documents 4.2 In the context of a specimen electrode of unknown
2.1 ASTM Standards: 2 potential in an aqueous electrolyte, consider the circuit shown
IEEE/ASTM SI 10 Standard for Use of the International in Fig. 1 with a reference electrode connected to the ground
System of Units (SI) (the Modern Metric System) terminal of an electrometer. If the electrometer reads on scale
when the polarity switch is negative, the specimen electrode
3. Significance and Use potential is negative (relative to the reference electrode).
3.1 This practice provides guidance for reporting, display- Conversely, if the electrometer reads on scale when polarity is
ing, and plotting electrochemical corrosion data and includes positive, the specimen potential is positive. On the other hand,
recommendations on signs and conventions. Use of this prac- if the specimen electrode is connected to the ground terminal,
tice will result in the reporting of electrochemical corrosion the potential will be positive if the meter is on scale when the
data in a standard format, facilitating comparison between data polarity switch is negative, and vice versa.
developed at different laboratories or at different times. The NOTE 1—In cases where the polarity of a measuring instrument is in
recommendations outlined in this standard may be utilized doubt, a simple verification test can be performed as follows: connect the
when recording and reporting corrosion data obtained from measuring instrument to a dry cell with the lead previously on the
electrochemical tests such as potentiostatic and potentiody- reference electrode to the negative battery terminal and the lead previously
namic polarization, polarization resistance, electrochemical on the specimen electrode to the positive battery terminal. Set the range
switch to accommodate the dry cell voltage. The meter deflection will now
impedance and admittance measurements, galvanic corrosion,
show the direction of positive potential.
and open circuit potential measurements. Also, the corrosion potential of magnesium or zinc should be negative
in a 1 N NaCl solution if measured against a saturated standard calomel
4. Sign Convention for Electrode Potential electrode (SCE).
4.1 The Stockholm sign invariant convention is recom-
mended for use in reporting the results of specimen potential 5. Sign Convention for Electrode Potential Temperature
Coefficients
5.1 There are two types of temperature coefficients of
1
This practice is under the jurisdiction of ASTM Committee G01 on Corrosion electrode potential: isothermal temperature coefficients and the
of Metals and is the direct responsibility of Subcommittee G01.11 on Electrochemi- thermal coefficients. The sign convention recommended for
cal Measurements in Corrosion Testing. both types of temperature coefficients is that the temperature
Current edition approved Nov 1, 2004. Published November 2004. Originally
approved in 1968. Last previous edition approved in 1999 as G 3 – 89 (1999).
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [email protected]. For Annual Book of ASTM
3
Standards volume information, refer to the standard’s Document Summary page on The boldface numbers in parentheses refer to the list of references at the end of
the ASTM website. this practice.

Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)

F G
d~DE!
di DE 5 0
5 Rp 5
babc
2.303~ba 1 bc!icorr
(1)

where:
ba = anodic Tafel slope,
bc = cathodic Tafel slope, and
DE = the difference E − Ecorr, where E is the specimen
potential.
Fig. 2 is a plot of polarization, E − Ecorr, versus current density
i (solid line) from which the polarization resistance Rp has been
determined as the slope of the curve at the corrosion potential
Ecorr.
7.3 Potential Reference Points—In plots where electrode
potentials are displayed, some indication of the conversion of
the values displayed to both the standard hydrogen electrode
scale (SHE) and the saturated calomel electrode scale (SCE) is
NOTE 1—The electrode potential of specimen is negative as shown.
FIG. 1 Schematic Diagram of an Apparatus to Measure Electrode
recommended if they are known. For example, when electrode
Potential of a Specimen potential is plotted as the ordinate, then the SCE scale could be
shown at the extreme left of the plot and the SHE scale shown
coefficient is positive when an increase in temperature pro- at the extreme right. An alternative, in cases where the
duces an increase (that is, it becomes more positive) in the reference electrode was not either SCE or SHE, would be to
electrode potential. Likewise, the second temperature coeffi- show on the potential axis the potentials of these electrodes
cient is positive when an increase in temperature produces an against the reference used. In cases where these points are not
increase (that is, it becomes more positive) in the first tem- shown on the plot, an algebraic conversion could be indicated.
perature coefficient. For example, in the case of a silver-silver chloride reference
electrode (1 M KCl), the conversion could be shown in the title
6. Sign Convention for Current and Current Density box as:
6.1 The sign convention in which anodic currents and SCE 5 E 2 0.006 V (2)
current densities are considered positive and cathodic currents SHE 5 E 1 0.235 V
and current densities are negative is recommended. When the
where E represents electrode potential measured against the
potential is plotted against the logarithm of the current density,
silver-silver chloride standard (1 M KCl).
only the absolute values of the current density can be plotted.
In such plots, the values which are cathodic should be clearly NOTE 2—A table of potentials for various common reference electrodes
differentiated from the anodic values if both are present. is presented in Appendix X2.

7. Conventions for Displaying Polarization Data 7.4 Units—The recommended unit of potential is the volt.
In cases where only small potential ranges are covered,
7.1 Sign Conventions—The standard mathematical practice
millivolts or microvolts may be used. The SI units for current
for plotting graphs is recommended for displaying electro-
density are ampere per square metre or milliampere per square
chemical corrosion data. In this practice, positive values are
centimetre (IEEE/ASTM SI-10). Still in use are units ex-
plotted above the origin on the ordinate axis and to the right of
pressed in amperes per square centimetre, and microamperes
the origin on the abscissa axis. In logarithmic plots, the
per square centimetre.
abscissa value increases from left to right and the ordinate
value increases from bottom to top. 7.5 Sample Polarization Curves—Sample polarization plots
7.2 Current Density-Potential Plots—A uniform convention employing these recommended practices are shown in Figs.
is recommended for plotting current density-potential data, 2-6. Fig. 3 and Fig. 4 are hypothetical curves showing active
namely, plot current density along the abscissa and potential and active-passive anode behavior, respectively. Fig. 5 and Fig.
along the ordinate. In current density potential plots, the 6 are actual polarization data for Type 430 stainless steel (UNS
current density may be plotted on linear or logarithmic axes. In 43000) (4) and two aluminum samples (5). Fig. 3 and Fig. 4 are
general, logarithmic plots are better suited to incorporation of exhibited to illustrate graphically the location of various points
wide ranges of current density data and for demonstrating Tafel used in discussion of electrochemical methods of corrosion
relationships. Linear plots are recommended for studies in testing. The purpose of Fig. 5 and Fig. 6 is to show how various
which the current density or potential range is small, or in cases types of electrode behavior can be plotted in accordance with
where the region in which the current density changes from the proposed conventions.
anodic to cathodic is important. Linear plots are also used for
the determination of the polarization resistance Rp, which is 8. Conventions for Displaying Electrochemical
defined as the slope of a potential-current density plot at the Impedance Data
corrosion potential Ecorr. The relationship between the polar- 8.1 Three graphical formats in common use for reporting
ization resistance Rp and the corrosion current density icorr is as electrochemical impedance data are the Nyquist, Bode, and
follows (2, 3): Admittance formats. These formats are discussed for a simple

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)

FIG. 2 Hypothetical Linear Polarization Plot

electrode system modelled by an equivalent electrical circuit as 8.2 Nyquist Format (Complex Plane, or Cole-Cole):
shown in Fig. 7. In the convention utilized the impedance is 8.2.1 The real component of impedance is plotted on the
defined as: abscissa and the negative of the imaginary component is
Z 5 Z8 1 j Z9 (3) plotted on the ordinate. In this practice positive values of the
real component of impedance are plotted to the right of the
where: origin parallel to the x axis (abscissa). Negative values of the
Z = real or in-phase component of impedance,
imaginary component of impedance are plotted vertically from
Z9 = the imaginary or out-of-phase component of imped-
ance, and the origin parallel to the y axis (ordinate).
j2 = −1. 8.2.2 Fig. 8 shows a Nyquist plot for the equivalent circuit
The impedance magnitude or modulus is defined as of Fig. 7. The frequency dependence of the data is not shown
|Z|2 = (Z8)2 + (Z9). For the equivalent electrical circuit shown in explicitly on this type of plot. However, the frequency corre-
Fig. 7, the imaginary component of impedance sponding to selected data points may be directly annotated on
21 the Nyquist plot. The magnitude of the appropriate impedance
Z9 5 2pfC (4) components increases when moving away from the origin of
the corresponding axes. Higher frequency data points are
where: typically located towards the origin of the plot while lower
f = frequency in cycles per second (or hertz, Hz, where one frequency points correspond to the increasing magnitude of the
Hz is equal to 2p radians/s, and w = 2pf, where the impedance components.
units for w are radians/s), and 8.2.3 Recommended units for both axes are ohm·cm2. The
C = capacitance in farads.
units ohm·cm2 are obtained by multiplying the measured
The phase angle, u is defined as:
resistance or impedance by the exposed specimen area. For a
u 5 arctan ~Z9/Z8!. (5) resistor and capacitor, or dummy cell equivalent circuit, the
The admittance, Y, is defined as assumed area is 1 cm2. Regarding the impedance data shown in
1/Z 5 Y 5 Y8 1 jY9 (6) Fig. 8 for the circuit of Fig. 7, the distance from the origin to
the first (high frequency) intercept with the abscissa corre-
where: sponds to Rs. The distance between the first intercept and the
Y8 = real or in-phase component of admittance, and second (low frequency) intercept with the abscissa corresponds
Y9 = the imaginary of out-of-phase component of admit- to Rp.
tance.
8.3 Bode Format:

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)

FIG. 3 Hypothetical Cathodic and Anodic Polarization Diagram

FIG. 4 Hypothetical Cathodic and Anodic Polarization Plots for a Passive Anode

8.3.1 Electrochemical impedance data may be reported as plotted to the right of the origin parallel to the x axis (abscissa)
two types of Bode plots. In the first case, the base ten logarithm and increasing values of impedance magnitude are plotted
of the impedance magnitude or Modulus, |Z|, is plotted on the vertically from the origin parallel to the y axis (ordinate). The
ordinate and the base ten logarithm of the frequency is plotted origin itself is chosen at appropriate nonzero values of imped-
on the abscissa. In this practice increasing frequency values are ance magnitude and frequency.

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)

FIG. 5 Typical Potentiostatic Anodic Polarization Plot for Type 430 Stainless Steel in 1.0 N H2SO4

FIG. 6 Typical Polarization Plots for Aluminum Materials in 0.2 N NaCl Solution

8.3.2 Fig. 9 shows a typical plot for the simple electrical logarithm of the frequency is plotted on the abscissa. In this
circuit model of Fig. 7. The magnitude of the high frequency practice increasing values of the negative of the phase angle are
impedance where the impedance magnitude is independent of plotted in the vertical direction from the origin along the y axis
frequency corresponds to Rs. The difference in magnitude (ordinate). In this format, a pure capacitive behavior is plotted
between the low frequency and the high frequency frequency- as a positive value of 90°. Fig. 10 shows a typical plot for the
independent regions of impedance magnitude corresponds to simple electrode model shown in Fig. 7.
Rp. These resistances are identical to those on the Nyquist 8.3.4 The units for the frequency on both plots are either
format plot shown in Fig. 8. hertz (cycles per second) or radians per second (radians per
8.3.3 In the second type of Bode plot, the negative of the second = 2p radians per cycle multiplied by the number of
phase angle, −u, is plotted on the ordinate and the base ten cycles per second). The units of the impedance magnitude are

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)

FIG. 7 Equivalent Electrical Circuit Model for a Simple Corroding

Electrode

FIG. 9 Typical Plot for Simple Electrical Model of Fig. 7

FIG. 8 Nyquist Plot for Equivalent Circuit of Fig. 7

ohm·cm2. The units ohm·cm2 are obtained by multiplying the

measured resistance or impedance by the exposed specimen
area. The units of the phase angle are degrees.
8.4 Admittance Format (Complex Plane)—The real compo-
nent of admittance is plotted on the abscissa and the imaginary
component of admittance is plotted on the ordinate. In this
practice positive values of the real component of admittance
are plotted to the right of the origin parallel to the x axis
(abscissa). Values of the imaginary component of impedance
are plotted vertically from the origin parallel to the y axis
(ordinate). Recommended units for both axes are ohm−1· cm−2.
The units ohm−1· cm2 are obtained by dividing the measured
admittance (ohm−1) by the exposed specimen area. The fre-
quency dependence of the data is not shown explicitly on this FIG. 10 Typical Plot for Simple Electrode Model Shown in Fig. 7
type of plot. The magnitudes of the appropriate admittance
components increase when moving away from the origin of the
corresponding axes. trode potential; linear polarization; Nyquist; polarization resis-
tance; potentiodynamic polarization; reference electrode
9. Keywords
9.1 ac impedance; Bode; convention; electrochemical im-
pedance spectroscopy; electrochemical measurement; elec-

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)
APPENDIXES

(Nonmandatory Information)

X1. INFORMATION ON OTHER CONVENTIONS

X1.1 Comparison of Gibbs-Ostwald Convention to If this electrode potential were negative, then the metal surface
Nernst-Latimer Convention would be active and the reaction would tend to occur sponta-
X1.1.1 Another sign convention, the Nernst-Latimer con- neously because the free energy is negative.
vention, has been used extensively by physical and analytical X1.2.2 Consider the effect of increasing the concentration of
chemists in describing electrochemical reactions. This conven- the metal ions in solution in Eq 4. The equilibrium electrode
tion is based on the relationship: potential of the metal surface would become more noble
DG 5 2nFE* (X1.1) according to the relationship:
DE 5 1~RT/nF! ln ~a2/a1! (X1.7)
where:
DG = change in Gibbs free energy, where:
n = number of charges per atom, a2 = metal ion activity of the more concentrated solution,
F = electrochemical equivalent in faradays, and a1 = metal ion activity of less concentrated solution,
E* = potential according to the Nernst-Latimer conven- R = appropriate gas law constant, and
tion. DE = electrode potential in the concentrated solution minus
A consequence of this convention is that the sign of the electrode potential in the dilute solution.
potential depends upon the way that the reaction is written. For Thus, increases in the activity of the oxidized species, for
example, the anodic dissolution of copper can be expressed as: example, M++(aq), tend to increase the electrode potential. On
Cu0 → Cu11~aq! 1 2e (X1.2) the other hand, an increase in the activity of a reduced species
will decrease the electrode potential. For example, consider the
where: half-cell reaction:
Cu0 = metallic copper, crystalline, unit activity,
Cu++(aq) = cupric ion in aqueous solution, and 2 OH2~aq! → H2O 1 1 / 2 O2~g! 1 2e (X1.8)
e = one unit negative charge (an electron) Increasing the hydroxyl ion concentration reduces the elec-
while the plating of copper can be written as: trode potential of this reaction.
Cu11~aq! → Cu0 2 2e (X1.3)
X1.3 Electrode Potential Temperature Coefficients
In these two cases, the potential would have opposite signs
even though both reactions occur simultaneously on a speci- X1.3.1 There are two types of temperature coefficients for
men. Tables of potentials for the oxidation of various metals electrochemical reactions. The isothermal temperature coeffi-
relative to the standard state hydrogen potential have had wide cient (7) is based on the definition that the half-cell reaction:
circulation (6). These values have been called “oxidation
1 / 2 H2 ~g, 1 atm! 5 H1 ~aq, a 5 1! 1 e (X1.9)
potentials” to denote the use of the Nernst-Latimer convention.
Thus, the term “electrode potential” now implies the use of the where:
Gibbs-Stockholm convention. H2(g, 1 atm) = hydrogen gas at one atmosphere pressure
and
X1.2 Consequences of the Gibbs-Stockholm Convention H+(aq, a = 1) = hydrogen ion in aqueous solution at unit
X1.2.1 To explore the consequences of the Gibbs- activity.
Stockholm convention, further consider a corroding metal has a zero electrode potential at any temperature.
surface: X1.3.1.1 Thus, this temperature coefficient is given by the
M0 → M11~aq! 1 2e (X1.4)
change in potential of a cell composed of the specimen
electrode and a standard hydrogen half cells. More formally,
The whole cell reaction with a hydrogen reference electrode the first temperature coefficient is given by:
would then be:
~dE/dT!iso 5 DS/nF (X1.10)
M0 1 2H1~aq! → M11~aq! 1 H2~g! (X1.5)
where:
where: (dE/dT)iso = isothermal temperature coefficient of elec-
H2(g) = hydrogen in gaseous state. trode potential,
The Gibbs free energy change would be given by the expres- T = absolute temperature, and
sion: DS = entropy change for whole cell reaction.
DG 5 1 nFE (X1.6) X1.3.1.2 Therefore, an increase in the electrode potential
with increasing temperature results in a positive temperature
where: coefficient and signifies an increase in the entropy of the
E = measured electrode potential of Eq 4.
overall reaction including the reference half cell.

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)
X1.3.2 The thermal temperature coefficient is defined by a when the temperature coefficients are expressed in mV/deg C
metal-metal ion half cell at test temperature connected to an (7).
identical half cell at a reference temperature. These cells are X1.3.3 The second temperature coefficient is given by the
complicated by the effect of thermal diffusion (Soret effect) and second temperature derivative and is related to DCp, the sum of
are not truly reversible. In general, if thermal diffusion is the heat capacities of the products minus the heat capacities of
prevented, the thermal temperature coefficient is related to the the reactants by the expression:
isothermal temperature coefficient by a constant value which
represents the entropy change in the reference electrode. Thus, dE2/dT2 5 DCp/nFT (X1.12)
for a standard hydrogen electrode: Thus, the second temperature coefficient is positive when the
~dE/dT!iso 5 ~dE/dT!th 2 0.871 (X1.11) corresponding first temperature coefficient increases with in-
creasing temperature. See Ref 7 for a more complete
where:
(dE/dT)th = thermal temperature coefficient of electrode discussion.
potential,

X2. STANDARD REFERENCE POTENTIALS AND CONVERSION TABLE (7, 8)

X2.1 See Table X2.1 for reference potentials and conver-

sion factors.
TABLE X2.1 Reference Potentials and Conversion Factors
Potential (V) at 25°C Thermal Tempera-
Electrode ture CoefficientA
E8 B E9 C (mV/°C)
+
(Pt)/H2(a = 1)/H (a = 1)(SHE) 0.000 ... +0.87
Ag/AgCl/1 M KCl +0.235 ... +0.25
Ag/AgCl/0.6 M Cl−(seawater) +0.25 ... ...
Ag/AgCl/0.1 M Cl− +0.288 ... +0.22
Hg/Hg2Cl2/sat KCl (SCE) +0.241 +0.244 +0.22
Hg/Hg2Cl2/1 M KCl +0.280 +0.283 +0.59
Hg/Hg2Cl2/0.1 M KCl +0.334 +0.336 +0.79
Cu/CuSO4sat +0.30 ... +0.90
Hg/Hg2SO4/H2SO4D +0.616 ... ...
A
To convert from thermal to isothermal temperature coefficients, subtract 0.87
mV/°C. Thus the isothermal temperature coefficient for Ag-AgCl is − 0.62 mV/°C.
B
E8 is the standard potential for the half cell corrected for the concentration of
the ions.
C
E9 also includes the liquid junction potentials for a saturated KCl salt bridge.
To convert from one scale to another, add the value indicated.
D
Potential given is for a range of H2SO4 molalities as discussed in Ref (10).
From (E8) To SHE Scale To SCE Scale (E8)
H2/H+ ... −0.241
Ag/AgCl/1 M KCl +0.235 −0.006
Ag/AgCl/0.6 M Cl (seawater) +0.25 +0.009
Ag/AgCl/0.1 M Cl +0.288 +0.047
Hg/Hg2/Cl2/sat KCl (SCE) +0.241 ...
Hg/Hg2Cl2, 1 M +0.280 +0.039
Hg/Hg2Cl2, 0.1 M +0.334 +0.093
Cu/CuSO4 sat +0.30 +0.06
Hg/Hg2SO4/H2SO4 +0.616 ...

Example:
An electrode potential of + 1.000 V versus SCE would be (1.000 + 0.241)6
+ 1.241 V versus SHE. An electrode potential of − 1.000 V versus SCE would give
(−1.000 + 0.241) = −0.759 V versus SHE.

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---
 G 3 – 89 (2004)
REFERENCES

(1) Christiansen, J. A., and Pourbaix, M., Comptes. rend 17th Conf. fourth Ed., Chemical Rubber Publishing Co., Cleveland, 1952, pp.
IUPAC Stockholm, 1953, pp. 82–84. 1554–1556, 1575.
(2) Stern, M., Corrosion, CORRA, Vol 15, 1958, p. 440t. (7) de Bethune, A. J., The Encyclopedia of Electrochemistry, Hampel, C.
(3) Oldham, K. B., and Mansfeld, F., Corrosion, CORRA, Vol 27, 1971, A., Editor, Reinhold Publishing Co., 1964, New York, pp. 432–4.
p. 434. (8) Janz, G. J., and Kelly, F. J., The Encyclopedia of Electrochemistry,
(4) “The Reproducibility of Potentiostatic and Potentiodynamic Anodic Hampel, C. A., Editor, Reinhold Publishing Co., New York, 1964, p.
Polarization Measurements,” Report of Task Group 2 to ASTM G-1 1013.
Subcommittee XI, June 29, 1967. (9) Ives, D. J. G., and Janz, G. J., “Reference Electrodes, Theory and
(5) Ketcham, S. J., and Haynie, F. H., Corrosion, CORRA, Vol 19, 1963, Practice,” Academic Press, New York, 1961, (pp. 159–160, 189,
p. 242t. 404–405).
(6) Hodgman, C. D., Editor, Handbook of Chemistry and Physics, Thirty- (10) Stokes, R. H. Transactions of the Faraday Society 44, 295 (1948).

ASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned
in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk
of infringement of such rights, are entirely their own responsibility.

This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards
and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the
responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should
make your views known to the ASTM Committee on Standards, at the address shown below.

This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,
United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above
address or at 610-832-9585 (phone), 610-832-9555 (fax), or [email protected] (e-mail); or through the ASTM website
(www.astm.org).

Copyright
Reproduced
Licensee=Istanbul
Not
No reproduction
for Resale,
ASTM
by 12/21/2004
IHS
or
International
Teknik
networking
underUniversitesi/5956919001
license
09:07:00
permitted
with
MST
ASTM
without license from IHS
--````,`,`,,,````,`,,``,,,`,,,`-`-`,,`,,`,`,,`---