[GHS-MSDS]

1. Identification

A. Product name : DTE-2085

B. Recommended Use and Restriction on Use
1) General
Mode l use : THINNER
2) Restriction on use : Recommendations for purposes other use restrictions.
C. Manufacturer / Supplier / distributor information
1) Company name : NOROO Paint & Coatings Co., Ltd.
2) Address : 351, Bakdal-ro, Manan-gu, Anyang-si, Gyeonggi-do, Korea
3) Emergency telephone number : +82-31-467-6114

2. Hazard identification

A. GHS Classification : Flammable liquids Category 2 ▷Acute toxicity (dermal) Category 4 ▷Acute toxicity (inhalation:
vapor) Category 3 ▷Carcinogenicity Category 2 ▷Reproductive toxicity Category 1A ▷Reproductive toxicity Category
2 ▷Serious eye damage/irritation Category 2A ▷Specific target organ toxicity(Single exposure) Category 3
▷Specific target organ toxicity(Repeated exposure) Category 1 ▷Specific target organ toxicity(Repeated exposure)
Category 2 ▷Skin corrosion/irritation Category 2 ▷Aspiration hazard Category 1
B. GHS label elements
1)Hazard symbols :

2)Signal words : DANGER

3)Hazard statements : Highly flammable liquid and vapour ▷Harmful in contact with skin ▷Toxic if inhaled
▷Suspected of causing cancer ▷May damage fertility or the unborn child ▷Suspected of damaging fertility or
the unborn child ▷Causes serious eye irritation ▷May cause respiratory irritation, May cause drowsiness and
dizziness. ▷Causes damage to organs through prolonged or repeated exposure ▷May cause damage to organs
through prolonged or repeated exposure ▷Causes skin irritation ▷May be fatal if swallowed and enters airways
4)Precautionary statements
- Keep away from heat/sparks/open flames/hot surfaces. No smoking. ▷Keep container tightly
Prevention :closed. ▷Ground/bond container and receiving equipment. ▷Use explosion-proof
electrical/ventilating/lighting/equipment. ▷Use only non-sparking tools. Flammable liquids
(chapter 2.6) 1, 2, 3 ▷Take precautionary measures against static discharge. ▷Wear protective
gloves/protective clothing/eye protection/face protection. ▷Avoid breathing
dust/fume/gas/mist/vapours/spray. ▷Use only outdoors or in a well-ventilated area. ▷Obtain
special instructions before use. ▷Do not handle until all safety precautions have been read and
understood. ▷Use personal protective equipment as required. ▷Wash hands thoroughly after
handling. ▷Do not breathe dust/fume/gas/mist/vapours/spray. ▷Do not eat, drink or smoke when
using this product.
- Response :IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. ▷In case of fire: Use Suitable extinguishing media for extinction ▷IF ON SKIN:
Wash with plenty of soap and water. ▷Call a POISON CENTER or doctor/physician if you feel
unwell. ▷Specific measures ▷Wash contaminated clothing before reuse. ▷IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing. ▷Immediately call
a POISON CENTER or doctor/physician ▷Specific treatment ▷If exposed or concerned: Get medical
advice/attention. ▷IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. ▷If eye irritation persists: Get medical
advice/attention. ▷Get medical advice/attention if you feel unwell. ▷If skin irritation
occurs: Get medical advice/attention. ▷Take off contaminated clothing and wash before reuse.
 ▷IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. ▷Do NOT induce vomiting.
- Storage : Store in a well-ventilated place. Keep cool. ▷Store in a well-ventilated place. Keep container
tightly closed. ▷Store locked up.
- Disposal :Dispose of contents/container in accordance with local/regional/national/international
regulation
C. Other hazards which do not result in classification : (NFPA Classification)
NFPA grade
Chemical Name
Health Flammability Reactivity
Xylene NO DATA NO DATA NO DATA
Toluene 2 3 0
Ethylbenzene 2 3 0

3. Composition/information on ingredients

Chemical Name Trade names and Synonyms CAS-NO Content(%)

Xylene Xylene 1330-20-7 45~60
Toluene Toluene 108-88-3 35~45
Ethylbenzene Ethylbenzene 100-41-4 7~15

4. First-aid measures

A.Eye Contact : If irritation, pain, swelling, and tears or glaring may occur, immediately take a doctor's treatment
Rinse exposed eyes with plenty of water for at least 15minutes.
B.Skin Contact : Immediately wash off with soap and water for at least 15 minutes. If irritation or pain may occur, take
a doctor’s examination on exposed area. Discard clothing, and then wash off exposed area with soap and water.
C.Inhalation : Discard contaminated clothing and shoes, and keep personal away. If breathing is difficult, administer
oxygen If inhaled or swallowed, do not perform the inhalation phase of breathing Take an emergency medical examination
by a doctor Perform the artificial respiration using the pocket mask installed the one way valves, or other inhaled
medical devices. If the cessation of breathing may occur, perform the artificial respiration Avoid from source of
exposure, and then moved into an area with fresh air
D.Ingestion Contact : It is need to be considered that early removal of some ingested material by cautious gastric
lavage must be weighed against potential complications of bleeding or perforation Get a doctor's attention immediately
if ingestion of large amounts of materials. Take an appropriate medical treatment depending on the symptoms. Do not
induce vomiting, and then if vomiting occurs, keep head below hips to prevent aspiration into lungs. Induce vomiting
E.Notes to Physician : There is no specific antidote and take an appropriate medical treatment.

5.Fire-fighting measures

A.Suitable (Unsuitable) extinguishing media

1)Suitable extinguishing media : Extinguished agent as powder foam or carbon dioxide, and regular foam
2)(Unsuitable) extinguishing media : Water is not an appropriate extinguished agent
3)Case of bic fire : Use an appropriate protect device depend on the fire scenario Evacuate more than 800m if an
explosion hazard may occur. Spread a large amount of the extinguished agent as a mist form with staying upwind
B.Specific hazards arising from the chemical
1)Pyrolysate : Carbon dioxide, toxic carbon compounds/Nitrogen compounds/sulfur compounds
2)Fire and Explosion danger : Intermediate levels of fire hazard. Explosive vapor/air mixture can be made at a
temperature of 100℃.
C.Special protective actions for fire-fighters
1)Personal Precautions, protective equipment : Respirator or air respirator, heat resistant clothing, heat resistant
hat, heat resistant gloves, heat resistant boots
2)Emergency procedures : Keep unauthorized personnel out except the fire-suppression personnel Cool containers with
water until well after fire is out. If there is no risk, move to move containers from fire area. Perform a fire
fighting using an appropriate extinguished agent.

6.Accidental release measures

A.Personal Precautions, protective equipment and emergency procedures
1)Personal Precautions, protective equipment : Respirator for organic gases other appropriate protective equipment /
protection / protective gloves
2)Emergency procedures : Do not contact with the skin Do work with the personal protected devices such as respirator
for organic gases other appropriate protective equipment / protection / protective gloves Spread water for reducing
the suppression of generated steam Take an action if there is no risk
B.Environmental precautions
1)Atmosphere : Stay upwind and keep out of low areas. Spread water for reducing the suppression of generated steam
2)Soil : Use absorbent to collect the appropriate container. Trap spilled material at bottom in deep water pockets,
excavated holding areas or within sand bag barriers.
3)Under water : Collect spilled material with mechanic devices Use absorbent to collect the appropriate container.
C.Methods and materials for containment and cleaning up
1)Small spill : Appropriate container for disposal of spilled material collected. Absorb for use sand or other non-
combustible material.
2)Large spill : Notification to central government, local government. When emissions at least of the standard amount
Keep unnecessary people away, isolate hazard area and deny entry.

7.Handling and storage

A.Precautions for safe handling : Use local ventilations and a full ventilation system when handling Close the container
for minimizing the petroleum steam Ground for preventing the static discharge Keep or handle followed by Dangerous
goods Safety Management Act
B.Conditions for safe storage, including any incompatibilities : Stored in an isolated place, Freezing note, Hot body
care Do not contact to strong oxidizer or acid Keep proper temperature : 5~35℃ Outdoor Storage is to avoid direct
sunlight. Because of evaporation and contamination concerns, The vessel is fully enclosed and kept in ventilated
indoor

8.Exposure controls/personal protection

A.Exposure Limits
1)Xylene
1-1.ACGIH : A4
1-2.Biological exposure indices : NO DATA
2)Toluene
2-1.ACGIH : A4
2-2.Biological exposure indices : NO DATA
3)Ethylbenzene
3-1.ACGIH : A3
3-2.Biological exposure indices : NO DATA
B.Engineering Controls : ▷ Spread water for reducing the suppression of generated steam ▷ Stay upwind and keep out of
low areas.. ▷ NO DATA. ▷ NO DATA.
C.Personal Protective Equipment
1)Respiratory protection : Use the personal protect respirator for organic solvent or higher level of capacity when
workers are supposed to be exposed under unsuitable respiratory working condition, or longer period exposure than
standard level. Wear respirator should be authorized by Korea Occupational Safety and Health Agency
2)Eye protection : Let workers do wear the safety glasses in case hazard caused by mist may be expected. Cleansing
Organization (saline) or install washing facilities and an emergency washing facilities in the place close to
workplace. Use the protect respirator for organic solvent or higher level of capacity.
3)Hand protection : Wear the chemical protection of gloves Do the workers wear the impermeable protective gloves made
from rubber/PVC due to skin irritation may be supposed by chronicle/long period exposure.
4)Skin protection : Wear appropriate chemical protective clothing. Work after wearing the impermeable protective apron
made by rubber/PVC in case hazard caused by exposure or spill, if needed wear the impermeable whole body protective
clothing.

9.Physical and chemical properties

A.Appearance : 투명액체
B.Odor : 방향성
C.Odor threshold : NO DATA
D.PH : NO DATA
E.Melting point/Freezing point : NO DATA
F.Initial Boiling Point/Boiling Ranges : NO DATA
G.Flash point : 4
H.Evaporating Rate : NO DATA
I.Flammability(solid, gas) : NON Flammable
J.Upper/Lower Flammability or explosive limits : NO DATA
K.Vapour pressure : NO DATA
L.Solubility : NO DATA
M.Vapour density : NO DATA
N.Specific gravity : 0.86 ±0.02(25℃)
O.Partition coefficient of n-octanol/water : NO DATA
P.Autoignition temperature : 480
Q.Decomposition temperature : NO DATA
R.Viscosity : 1~3 CPS(25℃)
S.Molecular weight : NO DATA

10.Stability and reactivity

A.Chemical stability : NO DATA

B.Possibility of hazardous reactions : Avoid contaminants and friction Do not contact with heat, spark, flame or other
flammable sources
C.Conditions to avoid : Oxidation agent, metal and combustable materials
D.Hazardous decomposition products : Thermal decomposition products (carbon etc.,)
11.Toxicological information

A.Information on the likely routes of exposure

1)Respiratory tracts : Adverse lung effects, Dyspnoea, Hypothermia, Vomitting
2)Oral : Vomitting, Diarrhea, Stomach pain, Irregular heartbeat
3)Skin : Irritation, Burn, Adverse nerve effects
4)Eye : Irritation, eye damage
B.Delayed and immediate effects and also chronic effects from short and long term exposure
1)Xylene
1-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : LD50 = 1590mg/kg(mouse)
c. Inhalation : LC50 = 10 ~ 20 mg/L
1-2. Skin corrosion/irritation : Stimulus-induced severe
1-3. Serious eye damage/irritation : Middle stimulus
1-4. Respiratory sensitization : NO DATA
1-5. Skin sensitization : NO DATA
1-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
1-7. Germ cell mutagenicity : NO DATA
1-8. Reproductive toxicity : NO DATA
1-9. STOT-single exposure : Causes acting anesthetic
1-10. STOT-repeated exposure : Human eye, nose irritation, headache, chest pain, brain disorders, respiratory
distress, cyanosis, fever, leukopenia causes, respiratory system, nervous system dysfunction Causes
1-11. Aspiration hazard : NO DATA
2)Toluene
 2-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
2-2. Skin corrosion/irritation : skinIrritation, rabbit, Irritation, OECD Guide line 404 human, skin Irritation,
guinea pig, skin Irritation
2-3. Serious eye damage/irritation : NO DATA
2-4. Respiratory sensitization : NO DATA
2-5. Skin sensitization : NO DATA
2-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
2-7. Germ cell mutagenicity : NO DATA
2-8. Reproductive toxicity : Heritage in human epidemiological studies, increased neonatal dysplasia,
malformations, decreased estrogen levels, in animal studies, toxicity does not appear in the first generation
of the second generation in fetal death, birth defects symptoms appear
2-9. STOT-single exposure : Prayer is considered a central nervous system stimulating organs, acting anesthetic
indicates
2-10. STOT-repeated exposure : Human headaches, memory loss, chronic central nervous system disorders, hematuria,
proteinuria, renal dysfunction, such as brain atrophy, stem cell localization, hepatotoxicity and Causes
2-11. Aspiration hazard : Hydrocarbons, and the dynamic viscosity ratio of 0.65 mm2 / s (25 ℃) of
3)Ethylbenzene
3-1. Acute toxicity
a. Oral : LD50 = 3500 ㎎/㎏ Rat
b. Dermal : LD50 = 15400 ㎎/㎏ Rabbit
c. Inhalation : Steam LC50 = 4000 ppm 4 hr Rat (Equivalents : 17.4 mg/L)
3-2. Skin corrosion/irritation : skin Irritation test result weak Irritation
3-3. Serious eye damage/irritation : Rabbit eye irritation test results in a slight conjunctival irritation,
recoverable damage.
3-4. Respiratory sensitization : NO DATA
3-5. Skin sensitization : NO DATA
3-6. Carcinogenicity
6-1. IARC : Group 2B
6-2. OSHA : NO DATA
6-3. ACGIH : A3
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
3-7. Germ cell mutagenicity : Micronucleustest Negative (7)
3-8. Reproductive toxicity : Maternal toxicity in mice and rats do not appear in the fetal dose toxicity (urinary
tract malformations) appears.
3-9. STOT-single exposure : NO DATA
3-10. STOT-repeated exposure : NO DATA
3-11. Aspiration hazard : Hydrocarbons. Swallowing the liquid by aspiration may cause chemical pneumonia. Ties
seongryul 0.74 mm2 / s (25 ℃)

12.Ecological information

A.Ecotoxicity
1)Xylene
1-1. Fish : NO DATA
1-2. Crustaceans : NO DATA
1-3. Algae : NO DATA
2)Toluene
2-1. Fish : NO DATA
 2-2. Crustaceans : NO DATA
2-3. Algae : NO DATA
3)Ethylbenzene
3-1. Fish : LC50 = 9.09 ㎎/ℓ 96 hr
3-2. Crustaceans : LC50 = 0.4 ㎎/ℓ 96 hr
3-3. Algae : NO DATA
B.Persistence and degradability
1)Xylene
1-1. Persistence : NO DATA
1-2. Degradability : NO DATA
2)Toluene
2-1. Persistence : NO DATA
2-2. Degradability : NO DATA
3)Ethylbenzene
3-1. Persistence : NO DATA
3-2. Degradability : NO DATA
C.Bioaccumulative potential
1)Xylene
1-1. Bioaccumulative potential : NO DATA
1-2. Biodegration : NO DATA
2)Toluene
2-1. Bioaccumulative potential : NO DATA
2-2. Biodegration : NO DATA
3)Ethylbenzene
3-1. Bioaccumulative potential : NO DATA
3-2. Biodegration : NO DATA
D.Mobility in soil
1) Xylene
▷ NO DATA
2) Toluene
▷ NO DATA
3) Ethylbenzene
▷ log Kow = 3.15 (11)
E.Other adverse effects
1) Xylene
▷ NO DATA
2) Toluene
▷ NO DATA
3) Ethylbenzene
▷ NO DATA

13.Disposal considerations

A.Disposal methods : Spilled material should keep in the airtighted container, and consign according to Waste Mateial
Management Act
B.Special precautions for disposal : Discard it followed by appropriate regulations Prohibit the unauthorized disposal
and incineration due to adversely affect natural ecosystems

14.Transport information

A.UN number : 1263

B.Proper shipping name : PAINT (including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid
filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound)
C.Hazard class : 3
D.Packing group : Ⅱ
E.Marine pollutant : be applicable
F.Special precautions for user related to transport or transportation measures
1)EmS FIRE SCHEDULE : F-E
2)EmS SPILLAGE SCHEDULE : S-E

15. Regulatory information

1)Xylene
1-1. Information of EU Classification
▷ Classification : R10Xn; R20/21Xi; R38
▷ Risk Phrases : R: 10-20/21-38
▷ Safety Phrase : S: (2-)25
1-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 45.3599 kg 100 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
1-3. Rotterdam Convention listed ingredients : NO DATA
1-4. Stockholm Convention listed ingredients : NO DATA
1-5. Montreal Protocol listed ingredients : NO DATA
2)Toluene
2-1. Information of EU Classification
▷ Classification : F; R11Repr. Cat. 3; R63Xn; R48/20-65Xi; R38R67
▷ Risk Phrases : R: 11-38-48/20-63-65-67
▷ Safety Phrase : S: (2-)36/37-46-62
2-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 453.599 kg 1000 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
2-3. Rotterdam Convention listed ingredients : NO DATA
2-4. Stockholm Convention listed ingredients : NO DATA
2-5. Montreal Protocol listed ingredients : NO DATA
3)Ethylbenzene
3-1. Information of EU Classification
▷ Classification : F; R11Xn; R20
▷ Risk Phrases : R: 11-20
▷ Safety Phrase : S: (2-)16-24/25-29
3-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 453.599 kg 1000 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
3-3. Rotterdam Convention listed ingredients : NO DATA
3-4. Stockholm Convention listed ingredients : NO DATA
3-5. Montreal Protocol listed ingredients : NO DATA

16.Other information
A.Reference : Occupational Health and Safety Act
Korea Industrial Safety Corporation Preparation of Material Safety Data Sheet
KOSHA CODE W-05-2007【The guideline for MSDS , 2012.】
B.Issue date : 2004-02-16
C.Revision number and Last date revised : 1.(2013-07-01)
D.Other : " WWW.NOROO.CO.KR"
 [GHS-MSDS]
1. Identification

A. Product name : DVB-2085(C) A

B. Recommended Use and Restriction on Use
1) General use : insulations varnish
Model
2) Restriction on use : Recommendations for purposes other use restrictions.
C. Manufacturer / Supplier / distributor information
1) Company name : NOROO Paint & Coatings Co., Ltd.
2) Address : 351, Bakdal-ro, Manan-gu, Anyang-si, Gyeonggi-do, Korea
3) Emergency telephone number : +82-31-467-6114

2. Hazard identification

A. GHS Classification : Flammable liquids Category 2 ▷Acute toxicity (inhalation: vapor) Category 4 ▷Reproductive
toxicity Category 2 ▷Serious eye damage/irritation Category 2A ▷Specific target organ toxicity(Single exposure)
Category 3 ▷Specific target organ toxicity(Repeated exposure) Category 2 ▷Skin sensitization Category 1 ▷Skin
corrosion/irritation Category 2 ▷Aspiration hazard Category 1
B. GHS label elements
1)Hazard symbols :

2)Signal words : DANGER

3)Hazard statements : Highly flammable liquid and vapour ▷Harmful if inhaled ▷Suspected of damaging fertility
or the unborn child ▷Causes serious eye irritation ▷May cause respiratory irritation, May cause drowsiness
and dizziness. ▷May cause damage to organs through prolonged or repeated exposure ▷May cause an allergic
skin reaction ▷Causes skin irritation ▷May be fatal if swallowed and enters airways
4)Precautionary statements
- Keep away from heat/sparks/open flames/hot surfaces. No smoking. ▷Keep container tightly
Prevention :closed. ▷Ground/bond container and receiving equipment. ▷Use explosion-proof
electrical/ventilating/lighting/equipment. ▷Use only non-sparking tools. Flammable liquids
(chapter 2.6) 1, 2, 3 ▷Take precautionary measures against static discharge. ▷Wear protective
gloves/protective clothing/eye protection/face protection. ▷Avoid breathing
dust/fume/gas/mist/vapours/spray. ▷Use only outdoors or in a well-ventilated area. ▷Obtain
special instructions before use. ▷Do not handle until all safety precautions have been read and
understood. ▷Use personal protective equipment as required. ▷Wash hands thoroughly after
handling. ▷Do not breathe dust/fume/gas/mist/vapours/spray. ▷Contaminated work clothing should
not be allowed out of the workplace.
- Response :IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. ▷In case of fire: Use Suitable extinguishing media for extinction ▷IF INHALED:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. ▷Specific
treatment. ▷If exposed or concerned: Get medical advice/attention. ▷IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. ▷If eye irritation persists: Get medical advice/attention. ▷Call a POISON
CENTER or doctor/physician if you feel unwell. ▷Get medical advice/attention if you feel
unwell. ▷IF ON SKIN: Wash with plenty of soap and water. ▷If skin irritation or rash occurs:
Get medical advice/attention. ▷Wash contaminated clothing before reuse. ▷If skin irritation
occurs: Get medical advice/attention. ▷Take off contaminated clothing and wash before reuse.
▷IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. ▷Do NOT induce vomiting.
- Storage : Store in a well-ventilated place. Keep cool. ▷Store locked up. ▷Store in a well-ventilated
 place. Keep container tightly closed.
- Disposal :Dispose of contents/container in accordance with local/regional/national/international
regulation
C. Other hazards which do not result in classification : (NFPA Classification)
NFPA grade
Chemical Name
Health Flammability Reactivity
Toluene 2 3 0
Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin 1 1 0
Xylene NO DATA NO DATA NO DATA
4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane 2 1 0
2,2'-[(1-Methylethylidene)bis(4,1-phenyleneoxymethylene)]bisoxirane hom opolymer NO DATA NO DATA NO DATA
Acetone 1 3 0
α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-
NO DATA NO DATA NO DATA
ethanediyl)]

3. Composition/information on ingredients

Chemical Name Trade names and Synonyms CAS-NO Content(%)

Toluene Toluene 108-88-3 40~50
Fatty acids, (C=18)-unsatd., dimers Fatty acids, (C=18)-unsatd., dimers
polymers with bisphenol A and polymers with bisphenol A and 67989-52-0 20~35
epichlorohydrin epichlorohydrin
Xylene Xylene 1330-20-7 5~15
4,4'-(1-methylethylidene)bisphenol 4,4'-(1-methylethylidene)bisphenol
25068-38-6 5~15
polymer with (chloromethyl)oxirane polymer with (chloromethyl)oxirane
2,2'-[(1-Methylethylidene)bis(4,1- 2,2'-[(1-Methylethylidene)bis(4,1-
phenyleneoxymethylene)]bisoxirane hom phenyleneoxymethylene)]bisoxirane hom 25085-99-8 5~15
opolymer opolymer
Acetone Acetone 67-64-1 3~6
α,α'-[(1-Methylethylidene)di-4,1- α,α'-[(1-Methylethylidene)di-4,1-
phenylene]bis[ω-hydroxypoly(oxy-1,2- phenylene]bis[ω-hydroxypoly(oxy-1,2- 32492-61-8 2~6
ethanediyl)] ethanediyl)]

4. First-aid measures

A.Eye Contact : If irritation, pain, swelling, and tears or glaring may occur, immediately take a doctor's treatment
Rinse exposed eyes with plenty of water for at least 15minutes.
B.Skin Contact : Immediately wash off with soap and water for at least 15 minutes. If irritation or pain may occur, take
a doctor’s examination on exposed area. Discard clothing, and then wash off exposed area with soap and water.
C.Inhalation : Discard contaminated clothing and shoes, and keep personal away. If breathing is difficult, administer
oxygen If inhaled or swallowed, do not perform the inhalation phase of breathing Take an emergency medical examination
by a doctor Perform the artificial respiration using the pocket mask installed the one way valves, or other inhaled
medical devices. If the cessation of breathing may occur, perform the artificial respiration Avoid from source of
exposure, and then moved into an area with fresh air
D.Ingestion Contact : It is need to be considered that early removal of some ingested material by cautious gastric
lavage must be weighed against potential complications of bleeding or perforation Get a doctor's attention immediately
if ingestion of large amounts of materials. Take an appropriate medical treatment depending on the symptoms. Do not
induce vomiting, and then if vomiting occurs, keep head below hips to prevent aspiration into lungs. Induce vomiting
E.Notes to Physician : There is no specific antidote and take an appropriate medical treatment.

5.Fire-fighting measures
A.Suitable (Unsuitable) extinguishing media
1)Suitable extinguishing media : Extinguished agent as powder foam or carbon dioxide, and regular foam
2)(Unsuitable) extinguishing media : Water is not an appropriate extinguished agent
3)Case of bic fire : Use an appropriate protect device depend on the fire scenario Evacuate more than 800m if an
explosion hazard may occur. Spread a large amount of the extinguished agent as a mist form with staying upwind
B.Specific hazards arising from the chemical
1)Pyrolysate : Carbon dioxide, toxic carbon compounds/Nitrogen compounds/sulfur compounds
2)Fire and Explosion danger : Intermediate levels of fire hazard. Explosive vapor/air mixture can be made at a
temperature of 100℃.
C.Special protective actions for fire-fighters
1)Personal Precautions, protective equipment : Respirator or air respirator, heat resistant clothing, heat resistant
hat, heat resistant gloves, heat resistant boots
2)Emergency procedures : Keep unauthorized personnel out except the fire-suppression personnel Cool containers with
water until well after fire is out. If there is no risk, move to move containers from fire area. Perform a fire
fighting using an appropriate extinguished agent.

6.Accidental release measures

A.Personal Precautions, protective equipment and emergency procedures

1)Personal Precautions, protective equipment : Respirator for organic gases other appropriate protective equipment /
protection / protective gloves
2)Emergency procedures : Do not contact with the skin Do work with the personal protected devices such as respirator
for organic gases other appropriate protective equipment / protection / protective gloves Spread water for reducing
the suppression of generated steam Take an action if there is no risk
B.Environmental precautions
1)Atmosphere : Stay upwind and keep out of low areas. Spread water for reducing the suppression of generated steam
2)Soil : Use absorbent to collect the appropriate container. Trap spilled material at bottom in deep water pockets,
excavated holding areas or within sand bag barriers.
3)Under water : Collect spilled material with mechanic devices Use absorbent to collect the appropriate container.
C.Methods and materials for containment and cleaning up
1)Small spill : Appropriate container for disposal of spilled material collected. Absorb for use sand or other non-
combustible material.
2)Large spill : Notification to central government, local government. When emissions at least of the standard amount
Keep unnecessary people away, isolate hazard area and deny entry.

7.Handling and storage

A.Precautions for safe handling : Use local ventilations and a full ventilation system when handling Close the container
for minimizing the petroleum steam Ground for preventing the static discharge Keep or handle followed by Dangerous
goods Safety Management Act
B.Conditions for safe storage, including any incompatibilities : Stored in an isolated place, Freezing note, Hot body
care Do not contact to strong oxidizer or acid Keep proper temperature : 5~35℃ Outdoor Storage is to avoid direct
sunlight. Because of evaporation and contamination concerns, The vessel is fully enclosed and kept in ventilated
indoor

8.Exposure controls/personal protection

A.Exposure Limits
1)Toluene
1-1.ACGIH : A4
1-2.Biological exposure indices : NO DATA
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1.ACGIH : NO DATA
2-2.Biological exposure indices : NO DATA
3)Xylene
3-1.ACGIH : A4
3-2.Biological exposure indices : NO DATA
 4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1.ACGIH : NO DATA
4-2.Biological exposure indices : NO DATA
5)Acetone
5-1.ACGIH : A4
5-2.Biological exposure indices : NO DATA
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1.ACGIH : NO DATA
6-2.Biological exposure indices : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1.ACGIH : NO DATA
7-2.Biological exposure indices : NO DATA
B.Engineering Controls : ▷ Spread water for reducing the suppression of generated steam ▷ Stay upwind and keep out of
low areas.. ▷ NO DATA. ▷ NO DATA.
C.Personal Protective Equipment
1)Respiratory protection : Use the personal protect respirator for organic solvent or higher level of capacity when
workers are supposed to be exposed under unsuitable respiratory working condition, or longer period exposure than
standard level. Wear respirator should be authorized by Korea Occupational Safety and Health Agency
2)Eye protection : Let workers do wear the safety glasses in case hazard caused by mist may be expected. Cleansing
Organization (saline) or install washing facilities and an emergency washing facilities in the place close to
workplace. Use the protect respirator for organic solvent or higher level of capacity.
3)Hand protection : Wear the chemical protection of gloves Do the workers wear the impermeable protective gloves made
from rubber/PVC due to skin irritation may be supposed by chronicle/long period exposure.
4)Skin protection : Wear appropriate chemical protective clothing. Work after wearing the impermeable protective apron
made by rubber/PVC in case hazard caused by exposure or spill, if needed wear the impermeable whole body protective
clothing.

9.Physical and chemical properties

A.Appearance : light yellow liquid

B.Odor : Specific odor
C.Odor threshold : NO DATA
D.PH : NO DATA
E.Melting point/Freezing point : NO DATA
F.Initial Boiling Point/Boiling Ranges : NO DATA
G.Flash point : 4
H.Evaporating Rate : NO DATA
I.Flammability(solid, gas) : NON Flammable
J.Upper/Lower Flammability or explosive limits : NO DATA
K.Vapour pressure : NO DATA
L.Solubility : NO DATA
M.Vapour density : NO DATA
N.Specific gravity : 0.92~0.96(25℃)
O.Partition coefficient of n-octanol/water : NO DATA
P.Autoignition temperature : NO DATA
Q.Decomposition temperature : NO DATA
R.Viscosity : 7~11cps(25℃)
S.Molecular weight : NO DATA

10.Stability and reactivity

A.Chemical stability : NO DATA

B.Possibility of hazardous reactions : Avoid contaminants and friction Do not contact with heat, spark, flame or other
flammable sources
C.Conditions to avoid : Oxidation agent, metal and combustable materials
D.Hazardous decomposition products : Thermal decomposition products (carbon etc.,)
11.Toxicological information

A.Information on the likely routes of exposure

1)Respiratory tracts : Adverse lung effects, Dyspnoea, Hypothermia, Vomitting
2)Oral : Vomitting, Diarrhea, Stomach pain, Irregular heartbeat
3)Skin : Irritation, Burn, Adverse nerve effects
4)Eye : Irritation, eye damage
B.Delayed and immediate effects and also chronic effects from short and long term exposure
1)Toluene
1-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
1-2. Skin corrosion/irritation : skinIrritation, rabbit, Irritation, OECD Guide line 404 human, skin Irritation,
guinea pig, skin Irritation
1-3. Serious eye damage/irritation : NO DATA
1-4. Respiratory sensitization : NO DATA
1-5. Skin sensitization : NO DATA
1-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
1-7. Germ cell mutagenicity : NO DATA
1-8. Reproductive toxicity : Heritage in human epidemiological studies, increased neonatal dysplasia,
malformations, decreased estrogen levels, in animal studies, toxicity does not appear in the first generation
of the second generation in fetal death, birth defects symptoms appear
1-9. STOT-single exposure : Prayer is considered a central nervous system stimulating organs, acting anesthetic
indicates
1-10. STOT-repeated exposure : Human headaches, memory loss, chronic central nervous system disorders, hematuria,
proteinuria, renal dysfunction, such as brain atrophy, stem cell localization, hepatotoxicity and Causes
1-11. Aspiration hazard : Hydrocarbons, and the dynamic viscosity ratio of 0.65 mm2 / s (25 ℃) of
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
2-2. Skin corrosion/irritation : Causes of skin stimulus
2-3. Serious eye damage/irritation : Causes eye irritation
2-4. Respiratory sensitization : NO DATA
2-5. Skin sensitization : NO DATA
2-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
2-7. Germ cell mutagenicity : NO DATA
2-8. Reproductive toxicity : NO DATA
2-9. STOT-single exposure : NO DATA
2-10. STOT-repeated exposure : NO DATA
2-11. Aspiration hazard : NO DATA
3)Xylene
3-1. Acute toxicity
a. Oral : NO DATA
 b. Dermal : LD50 = 1590mg/kg(mouse)
c. Inhalation : LC50 = 10 ~ 20 mg/L
3-2. Skin corrosion/irritation : Stimulus-induced severe
3-3. Serious eye damage/irritation : Middle stimulus
3-4. Respiratory sensitization : NO DATA
3-5. Skin sensitization : NO DATA
3-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
3-7. Germ cell mutagenicity : NO DATA
3-8. Reproductive toxicity : NO DATA
3-9. STOT-single exposure : Causes acting anesthetic
3-10. STOT-repeated exposure : Human eye, nose irritation, headache, chest pain, brain disorders, respiratory
distress, cyanosis, fever, leukopenia causes, respiratory system, nervous system dysfunction Causes
3-11. Aspiration hazard : NO DATA
4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1. Acute toxicity
a. Oral : LD50 > 1000 ㎎/㎏ Rat
b. Dermal : LD50 > 20000 ㎎/㎏ Rabbit
c. Inhalation : NO DATA
4-2. Skin corrosion/irritation : - rabbit skin Irritation(CERI Hazard data 2002) - Annex 1 to the 7th EU Directive
revision of the classification R38 (skin on Causes Irritation) - rabbit 의 STANDARD DRAIZE TEST : show more
stimulus to the middle
4-3. Serious eye damage/irritation : - Having a rabbit eye irritation (CERI Hazard Data, 2002) - STANDARD DRAIZE
TEST rabbit show in the middle or stimulation
4-4. Respiratory sensitization : NO DATA
4-5. Skin sensitization : Revision of the EU Directive Annex 1 to the classification of the 7th R43 (may cause
sensitization by skin contact. Apply)
4-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
4-7. Germ cell mutagenicity : In vitro CHL cells, without metabolic activation in the Positive salt vivo test was
over, metabolic activation in the test Negative. - Salmonella typhimuriumtest the Positive
4-8. Reproductive toxicity : NO DATA
4-9. STOT-single exposure : NO DATA
4-10. STOT-repeated exposure : NO DATA
4-11. Aspiration hazard : NO DATA
5)Acetone
5-1. Acute toxicity
a. Oral : LD50 = 5280 ㎎/㎏ Rat (EHC(1990), SIDS(1997))
b. Dermal : LD50 = 12870 ㎎/㎏ rabbit (EHC(1990), PATTY(1994), SIDS(1997))
c. Inhalation : Steam LC50 = 32000 ppm Rat
5-2. Skin corrosion/irritation : (using rabbit) skin Irritation test result non-irritating
5-3. Serious eye damage/irritation : Irritating to eyes of the person vapor exposure is stopped, but not sustained
stimulation. The destruction of the corneal epidermis Restored in 4-6 days.
5-4. Respiratory sensitization : NO DATA
5-5. Skin sensitization : negative test result mouse, guinea pig test results negative
5-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
 6-3. ACGIH : A4
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
5-7. Germ cell mutagenicity : Micronucleustest Negative
5-8. Reproductive toxicity : High concentration of rats exposed (11000ppm (20mg / L)) in the mild symptoms of
toxicity occur,
5-9. STOT-single exposure : People in the nose, airway, bronchial irritation, exposure to high concentrations
headaches, dizziness, loss of strength of the leg, causing fainting.
5-10. STOT-repeated exposure : NO DATA
5-11. Aspiration hazard : Seongryul tie 0.426 ㎟ / s (calculated)
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
6-2. Skin corrosion/irritation : NO DATA
6-3. Serious eye damage/irritation : NO DATA
6-4. Respiratory sensitization : NO DATA
6-5. Skin sensitization : NO DATA
6-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
6-7. Germ cell mutagenicity : NO DATA
6-8. Reproductive toxicity : NO DATA
6-9. STOT-single exposure : NO DATA
6-10. STOT-repeated exposure : NO DATA
6-11. Aspiration hazard : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
7-2. Skin corrosion/irritation : NO DATA
7-3. Serious eye damage/irritation : NO DATA
7-4. Respiratory sensitization : NO DATA
7-5. Skin sensitization : NO DATA
7-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
7-7. Germ cell mutagenicity : NO DATA
7-8. Reproductive toxicity : NO DATA
7-9. STOT-single exposure : NO DATA
7-10. STOT-repeated exposure : NO DATA
7-11. Aspiration hazard : NO DATA

12.Ecological information

A.Ecotoxicity
1)Toluene
1-1. Fish : NO DATA
1-2. Crustaceans : NO DATA
 1-3. Algae : NO DATA
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1. Fish : NO DATA
2-2. Crustaceans : NO DATA
2-3. Algae : NO DATA
3)Xylene
3-1. Fish : NO DATA
3-2. Crustaceans : NO DATA
3-3. Algae : NO DATA
4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1. Fish : LC50 = 1.41 ㎎/ℓ 96 hr Oryzias latipes
4-2. Crustaceans : EC50 = 1.7 ㎎/ℓ 48 hr
4-3. Algae : NO DATA
5)Acetone
5-1. Fish : LC50 > 100 ㎎/ℓ 96 hr
5-2. Crustaceans : NO DATA
5-3. Algae : NO DATA
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1. Fish : NO DATA
6-2. Crustaceans : NO DATA
6-3. Algae : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1. Fish : NO DATA
7-2. Crustaceans : NO DATA
7-3. Algae : NO DATA
B.Persistence and degradability
1)Toluene
1-1. Persistence : NO DATA
1-2. Degradability : NO DATA
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1. Persistence : NO DATA
2-2. Degradability : NO DATA
3)Xylene
3-1. Persistence : NO DATA
3-2. Degradability : NO DATA
4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1. Persistence : log Kow = 2.821 (Estimates)
4-2. Degradability : NO DATA
5)Acetone
5-1. Persistence : NO DATA
5-2. Degradability : NO DATA
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1. Persistence : log Kow = 1.58
6-2. Degradability : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1. Persistence : NO DATA
7-2. Degradability : NO DATA
C.Bioaccumulative potential
1)Toluene
1-1. Bioaccumulative potential : NO DATA
1-2. Biodegration : NO DATA
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1. Bioaccumulative potential : NO DATA
2-2. Biodegration : NO DATA
3)Xylene
3-1. Bioaccumulative potential : NO DATA
 3-2. Biodegration : NO DATA
4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1. Bioaccumulative potential : BCF = 0.56 ~ 0.67 (Exposure concentrations:10ug/l, 5.6<= BCF=<6.8(Exposure
concentrations:1ug/l))
4-2. Biodegration : Biodegradability = 0 (%) 28 day
5)Acetone
5-1. Bioaccumulative potential : NO DATA
5-2. Biodegration : NO DATA
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1. Bioaccumulative potential : BCF = 0.7327 (Predicted value by logKow=1.58 )
6-2. Biodegration : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1. Bioaccumulative potential : NO DATA
7-2. Biodegration : NO DATA
D.Mobility in soil
1) Toluene
▷ NO DATA
2) Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
▷ NO DATA
3) Xylene
▷ NO DATA
4) 4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
▷ NO DATA
5) Acetone
▷ NO DATA
6) α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
▷ Koc = 10
7) 4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
▷ NO DATA
E.Other adverse effects
1) Toluene
▷ NO DATA
2) Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
▷ NO DATA
3) Xylene
▷ NO DATA
4) 4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
▷ NO DATA
5) Acetone
▷ NO DATA
6) α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
▷ NO DATA
7) 4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
▷ NO DATA

13.Disposal considerations

A.Disposal methods : Spilled material should keep in the airtighted container, and consign according to Waste Mateial
Management Act
B.Special precautions for disposal : Discard it followed by appropriate regulations Prohibit the unauthorized disposal
and incineration due to adversely affect natural ecosystems

14.Transport information
A.UN number : 1263
B.Proper shipping name : PAINT (including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid
filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound)
C.Hazard class : 3
D.Packing group : Ⅱ
E.Marine pollutant : be applicable
F.Special precautions for user related to transport or transportation measures
1)EmS FIRE SCHEDULE : F-E
2)EmS SPILLAGE SCHEDULE : S-E

15. Regulatory information

1)Toluene
1-1. Information of EU Classification
▷ Classification : F; R11Repr. Cat. 3; R63Xn; R48/20-65Xi; R38R67
▷ Risk Phrases : R: 11-38-48/20-63-65-67
▷ Safety Phrase : S: (2-)36/37-46-62
1-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 453.599 kg 1000 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
1-3. Rotterdam Convention listed ingredients : NO DATA
1-4. Stockholm Convention listed ingredients : NO DATA
1-5. Montreal Protocol listed ingredients : NO DATA
2)Fatty acids, (C=18)-unsatd., dimers polymers with bisphenol A and epichlorohydrin
2-1. Information of EU Classification
▷ Classification : NO DATA
▷ Risk Phrases : NO DATA
▷ Safety Phrase : NO DATA
2-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : notapplicable
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : notapplicable
2-3. Rotterdam Convention listed ingredients : NO DATA
2-4. Stockholm Convention listed ingredients : NO DATA
2-5. Montreal Protocol listed ingredients : NO DATA
3)Xylene
3-1. Information of EU Classification
▷ Classification : R10Xn; R20/21Xi; R38
▷ Risk Phrases : R: 10-20/21-38
▷ Safety Phrase : S: (2-)25
3-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 45.3599 kg 100 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
3-3. Rotterdam Convention listed ingredients : NO DATA
3-4. Stockholm Convention listed ingredients : NO DATA
3-5. Montreal Protocol listed ingredients : NO DATA
4)4,4'-(1-methylethylidene)bisphenol polymer with (chloromethyl)oxirane
4-1. Information of EU Classification
▷ Classification : Xi; R36/38R43N; R51-53
▷ Risk Phrases : R: 36/38-43-51/53
▷ Safety Phrase : S: (2-)28-37/39-61
4-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : notapplicable
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : notapplicable
4-3. Rotterdam Convention listed ingredients : NO DATA
4-4. Stockholm Convention listed ingredients : NO DATA
4-5. Montreal Protocol listed ingredients : NO DATA
5)Acetone
5-1. Information of EU Classification
▷ Classification : F; R11Xi; R36R66R67
▷ Risk Phrases : R: 11-36-66-67
▷ Safety Phrase : S: (2-)9-16-26
5-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 2267.995 kg 5000 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : notapplicable
5-3. Rotterdam Convention listed ingredients : NO DATA
5-4. Stockholm Convention listed ingredients : NO DATA
5-5. Montreal Protocol listed ingredients : NO DATA
6)α,α'-[(1-Methylethylidene)di-4,1-phenylene]bis[ω-hydroxypoly(oxy-1,2-ethanediyl)]
6-1. Information of EU Classification
▷ Classification : NO DATA
▷ Risk Phrases : NO DATA
▷ Safety Phrase : NO DATA
6-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : notapplicable
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : notapplicable
6-3. Rotterdam Convention listed ingredients : NO DATA
6-4. Stockholm Convention listed ingredients : NO DATA
6-5. Montreal Protocol listed ingredients : NO DATA
7)4,4'-(1-Methylethylidene)bisphenol polymer with (chloromethyl)oxirane polymer with cashew, nutshell liq.
7-1. Information of EU Classification
▷ Classification : NO DATA
▷ Risk Phrases : NO DATA
▷ Safety Phrase : NO DATA
7-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : NO DATA
▷ CERCLA Section 103 (40CFR302.4) : NO DATA
▷ EPCRA Section 302 (40CFR355.30) : NO DATA
▷ EPCRA Section 304 (40CFR355.40) : NO DATA
▷ EPCRA Section 313 (40CFR372.65) : NO DATA
7-3. Rotterdam Convention listed ingredients : NO DATA
7-4. Stockholm Convention listed ingredients : NO DATA
7-5. Montreal Protocol listed ingredients : NO DATA
16.Other information

A.Reference : Occupational Health and Safety Act

Korea Industrial Safety Corporation Preparation of Material Safety Data Sheet
KOSHA CODE W-05-2007【The guideline for MSDS , 2012.】
B.Issue date : 2007-06-28
C.Revision number and Last date revised : 7.(2015-04-27 오전 10:37:55)
D.Other : " WWW.NOROO.CO.KR"
 [GHS-MSDS]
1. Identification

A. Product name : DVB-2085(C) B

B. Recommended Use and Restriction on Use
1) General use : hardener
2) Restriction on use : Recommendations for purposes other use restrictions.
C. Manufacturer / Supplier / distributor information
1) Company name : NOROO Paint & Coatings Co., Ltd.
2) Address : 351, Bakdal-ro, Manan-gu, Anyang-si, Gyeonggi-do, Korea
3) Emergency telephone number : +82-31-467-6114

2. Hazard identification

A. GHS Classification : Flammable liquids Category 2 ▷Acute toxicity (oral) Category 4 ▷Acute toxicity (dermal)
Category 4 ▷Reproductive toxicity Category 2 ▷Serious eye damage/irritation Category 2A ▷Specific target organ
toxicity(Single exposure) Category 3 ▷Specific target organ toxicity(Repeated exposure) Category 2 ▷Skin
sensitization Category 1 ▷Skin corrosion/irritation Category 2 ▷Respiratory sensitization Category 1 ▷Aspiration
hazard Category 1
B. GHS label elements
1)Hazard symbols :

2)Signal words : DANGER

3)Hazard statements : Highly flammable liquid and vapour ▷Harmful if swallowed ▷Harmful in contact with skin
▷Suspected of damaging fertility or the unborn child ▷Causes serious eye irritation ▷May cause respiratory
irritation, May cause drowsiness and dizziness. ▷May cause damage to organs through prolonged or repeated
exposure ▷May cause an allergic skin reaction ▷Causes skin irritation ▷May cause allergy or asthma symptoms
or breathing difficulties if inhaled ▷May be fatal if swallowed and enters airways
4)Precautionary statements
- Keep away from heat/sparks/open flames/hot surfaces. No smoking. ▷Keep container tightly
Prevention :closed. ▷Ground/bond container and receiving equipment. ▷Use explosion-proof
electrical/ventilating/lighting/equipment. ▷Use only non-sparking tools. Flammable liquids
(chapter 2.6) 1, 2, 3 ▷Take precautionary measures against static discharge. ▷Wear protective
gloves/protective clothing/eye protection/face protection. ▷Wash hands thoroughly after
handling. ▷Do not eat, drink or smoke when using this product. ▷Obtain special instructions
before use. ▷Do not handle until all safety precautions have been read and understood. ▷Use
personal protective equipment as required. ▷Avoid breathing dust/fume/gas/mist/vapours/spray.
▷Use only outdoors or in a well-ventilated area. ▷Do not breathe
dust/fume/gas/mist/vapours/spray. ▷Contaminated work clothing should not be allowed out of the
workplace. ▷In case of inadequate ventilation wear respiratory protection.
- Response :IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. ▷In case of fire: Use Suitable extinguishing media for extinction ▷IF SWALLOWED:
Call a POISON CENTER or doctor/physician if you feel unwell. ▷Rinse mouth. ▷IF ON SKIN: Wash
with plenty of soap and water. ▷Specific measures ▷Wash contaminated clothing before reuse.
▷If exposed or concerned: Get medical advice/attention. ▷IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
▷If eye irritation persists: Get medical advice/attention. ▷IF INHALED: Remove victim to fresh
air and keep at rest in a position comfortable for breathing. ▷Get medical advice/attention if
you feel unwell. ▷If skin irritation or rash occurs: Get medical advice/attention. ▷Specific
 treatment ▷If skin irritation occurs: Get medical advice/attention. ▷Take off contaminated
clothing and wash before reuse. ▷IF INHALED: If breathing is difficult, remove victim to fresh
air and keep at rest in a position comfortable for breathing. ▷If experiencing respiratory
symptoms: Call a POISON CENTER or doctor/physician. ▷IF SWALLOWED: Immediately call a POISON
CENTER or doctor/physician. ▷Do NOT induce vomiting.
- Storage : Store in a well-ventilated place. Keep cool. ▷Store locked up. ▷Store in a well-ventilated
place. Keep container tightly closed.
- Disposal :Dispose of contents/container in accordance with local/regional/national/international
regulation
C. Other hazards which do not result in classification : (NFPA Classification)
NFPA grade
Chemical Name
Health Flammability Reactivity
Toluene 2 3 0
Tetrahydromethyl-1,3-isobenzofuranedione 2 1 0

3. Composition/information on ingredients

Chemical Name Trade names and Synonyms CAS-NO Content(%)

Toluene Toluene 108-88-3 80~95
Tetrahydromethyl-1,3-isobenzofuranedione Tetrahydromethyl-1,3-isobenzofuranedione 11070-44-3 5~20

4. First-aid measures

A.Eye Contact : If irritation, pain, swelling, and tears or glaring may occur, immediately take a doctor's treatment
Rinse exposed eyes with plenty of water for at least 15minutes.
B.Skin Contact : Immediately wash off with soap and water for at least 15 minutes. If irritation or pain may occur, take
a doctor’s examination on exposed area. Discard clothing, and then wash off exposed area with soap and water.
C.Inhalation : Discard contaminated clothing and shoes, and keep personal away. If breathing is difficult, administer
oxygen If inhaled or swallowed, do not perform the inhalation phase of breathing Take an emergency medical examination
by a doctor Perform the artificial respiration using the pocket mask installed the one way valves, or other inhaled
medical devices. If the cessation of breathing may occur, perform the artificial respiration Avoid from source of
exposure, and then moved into an area with fresh air
D.Ingestion Contact : It is need to be considered that early removal of some ingested material by cautious gastric
lavage must be weighed against potential complications of bleeding or perforation Get a doctor's attention immediately
if ingestion of large amounts of materials. Take an appropriate medical treatment depending on the symptoms. Do not
induce vomiting, and then if vomiting occurs, keep head below hips to prevent aspiration into lungs. Induce vomiting
E.Notes to Physician : There is no specific antidote and take an appropriate medical treatment.

5.Fire-fighting measures

A.Suitable (Unsuitable) extinguishing media

1)Suitable extinguishing media : Extinguished agent as powder foam or carbon dioxide, and regular foam
2)(Unsuitable) extinguishing media : Water is not an appropriate extinguished agent
3)Case of bic fire : Use an appropriate protect device depend on the fire scenario Evacuate more than 800m if an
explosion hazard may occur. Spread a large amount of the extinguished agent as a mist form with staying upwind
B.Specific hazards arising from the chemical
1)Pyrolysate : Carbon dioxide, toxic carbon compounds/Nitrogen compounds/sulfur compounds
2)Fire and Explosion danger : Intermediate levels of fire hazard. Explosive vapor/air mixture can be made at a
temperature of 100℃.
C.Special protective actions for fire-fighters
1)Personal Precautions, protective equipment : Respirator or air respirator, heat resistant clothing, heat resistant
hat, heat resistant gloves, heat resistant boots
2)Emergency procedures : Keep unauthorized personnel out except the fire-suppression personnel Cool containers with
water until well after fire is out. If there is no risk, move to move containers from fire area. Perform a fire
fighting using an appropriate extinguished agent.
6.Accidental release measures

A.Personal Precautions, protective equipment and emergency procedures

1)Personal Precautions, protective equipment : Respirator for organic gases other appropriate protective equipment /
protection / protective gloves
2)Emergency procedures : Do not contact with the skin Do work with the personal protected devices such as respirator
for organic gases other appropriate protective equipment / protection / protective gloves Spread water for reducing
the suppression of generated steam Take an action if there is no risk
B.Environmental precautions
1)Atmosphere : Stay upwind and keep out of low areas. Spread water for reducing the suppression of generated steam
2)Soil : Use absorbent to collect the appropriate container. Trap spilled material at bottom in deep water pockets,
excavated holding areas or within sand bag barriers.
3)Under water : Collect spilled material with mechanic devices Use absorbent to collect the appropriate container.
C.Methods and materials for containment and cleaning up
1)Small spill : Appropriate container for disposal of spilled material collected. Absorb for use sand or other non-
combustible material.
2)Large spill : Notification to central government, local government. When emissions at least of the standard amount
Keep unnecessary people away, isolate hazard area and deny entry.

7.Handling and storage

A.Precautions for safe handling : Use local ventilations and a full ventilation system when handling Close the container
for minimizing the petroleum steam Ground for preventing the static discharge Keep or handle followed by Dangerous
goods Safety Management Act
B.Conditions for safe storage, including any incompatibilities : Stored in an isolated place, Freezing note, Hot body
care Do not contact to strong oxidizer or acid Keep proper temperature : 5~35℃ Outdoor Storage is to avoid direct
sunlight. Because of evaporation and contamination concerns, The vessel is fully enclosed and kept in ventilated
indoor

8.Exposure controls/personal protection

A.Exposure Limits
1)Toluene
1-1.ACGIH : A4
1-2.Biological exposure indices : NO DATA
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1.ACGIH : NO DATA
2-2.Biological exposure indices : NO DATA
B.Engineering Controls : ▷ Spread water for reducing the suppression of generated steam ▷ Stay upwind and keep out of
low areas.. ▷ NO DATA. ▷ NO DATA.
C.Personal Protective Equipment
1)Respiratory protection : Use the personal protect respirator for organic solvent or higher level of capacity when
workers are supposed to be exposed under unsuitable respiratory working condition, or longer period exposure than
standard level. Wear respirator should be authorized by Korea Occupational Safety and Health Agency
2)Eye protection : Let workers do wear the safety glasses in case hazard caused by mist may be expected. Cleansing
Organization (saline) or install washing facilities and an emergency washing facilities in the place close to
workplace. Use the protect respirator for organic solvent or higher level of capacity.
3)Hand protection : Wear the chemical protection of gloves Do the workers wear the impermeable protective gloves made
from rubber/PVC due to skin irritation may be supposed by chronicle/long period exposure.
4)Skin protection : Wear appropriate chemical protective clothing. Work after wearing the impermeable protective apron
made by rubber/PVC in case hazard caused by exposure or spill, if needed wear the impermeable whole body protective
clothing.

9.Physical and chemical properties

A.Appearance : light yellow liquid

B.Odor : Specific odor
C.Odor threshold : NO DATA
D.PH : NO DATA
E.Melting point/Freezing point : NO DATA
F.Initial Boiling Point/Boiling Ranges : NO DATA
G.Flash point : 4
H.Evaporating Rate : NO DATA
I.Flammability(solid, gas) : NON Flammable
J.Upper/Lower Flammability or explosive limits : NO DATA
K.Vapour pressure : NO DATA
L.Solubility : NO DATA
M.Vapour density : NO DATA
N.Specific gravity : 0.89 ± 0.2(25℃)
O.Partition coefficient of n-octanol/water : NO DATA
P.Autoignition temperature : NO DATA
Q.Decomposition temperature : NO DATA
R.Viscosity : 0.02±0.01poise(
S.Molecular weight : NO DATA

10.Stability and reactivity

A.Chemical stability : NO DATA

B.Possibility of hazardous reactions : Avoid contaminants and friction Do not contact with heat, spark, flame or other
flammable sources
C.Conditions to avoid : Oxidation agent, metal and combustable materials
D.Hazardous decomposition products : Thermal decomposition products (carbon etc.,)
11.Toxicological information

A.Information on the likely routes of exposure

1)Respiratory tracts : Adverse lung effects, Dyspnoea, Hypothermia, Vomitting
2)Oral : Vomitting, Diarrhea, Stomach pain, Irregular heartbeat
3)Skin : Irritation, Burn, Adverse nerve effects
4)Eye : Irritation, eye damage
B.Delayed and immediate effects and also chronic effects from short and long term exposure
1)Toluene
1-1. Acute toxicity
a. Oral : NO DATA
b. Dermal : NO DATA
c. Inhalation : NO DATA
1-2. Skin corrosion/irritation : skinIrritation, rabbit, Irritation, OECD Guide line 404 human, skin Irritation,
guinea pig, skin Irritation
1-3. Serious eye damage/irritation : NO DATA
1-4. Respiratory sensitization : NO DATA
1-5. Skin sensitization : NO DATA
1-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
1-7. Germ cell mutagenicity : NO DATA
1-8. Reproductive toxicity : Heritage in human epidemiological studies, increased neonatal dysplasia,
malformations, decreased estrogen levels, in animal studies, toxicity does not appear in the first generation
of the second generation in fetal death, birth defects symptoms appear
1-9. STOT-single exposure : Prayer is considered a central nervous system stimulating organs, acting anesthetic
indicates
1-10. STOT-repeated exposure : Human headaches, memory loss, chronic central nervous system disorders, hematuria,
proteinuria, renal dysfunction, such as brain atrophy, stem cell localization, hepatotoxicity and Causes
 1-11. Aspiration hazard : Hydrocarbons, and the dynamic viscosity ratio of 0.65 mm2 / s (25 ℃) of
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1. Acute toxicity
a. Oral : LD50 = 1900 ㎎/㎏ Rat
b. Dermal : LD50 = 2000 ㎎/㎏ Rat
c. Inhalation : NO DATA
2-2. Skin corrosion/irritation : (using rabbit) skin Irritation testresult middle stimulus.
2-3. Serious eye damage/irritation : Using the rabbit eye irritation test results - stimulus
2-4. Respiratory sensitization : Respiratory irritation have been reported in humans.
2-5. Skin sensitization : Causes skin sensitization in humans.
2-6. Carcinogenicity
6-1. IARC : NO DATA
6-2. OSHA : NO DATA
6-3. ACGIH : NO DATA
6-4. NTP : NO DATA
6-5. EU CLP : NO DATA
2-7. Germ cell mutagenicity : NO DATA
2-8. Reproductive toxicity : NO DATA
2-9. STOT-single exposure : NO DATA
2-10. STOT-repeated exposure : NO DATA
2-11. Aspiration hazard : NO DATA

12.Ecological information

A.Ecotoxicity
1)Toluene
1-1. Fish : NO DATA
1-2. Crustaceans : NO DATA
1-3. Algae : NO DATA
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1. Fish : NO DATA
2-2. Crustaceans : NO DATA
2-3. Algae : EC50 = 55 ㎎/ℓ 24 hr
B.Persistence and degradability
1)Toluene
1-1. Persistence : NO DATA
1-2. Degradability : NO DATA
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1. Persistence : NO DATA
2-2. Degradability : NO DATA
C.Bioaccumulative potential
1)Toluene
1-1. Bioaccumulative potential : NO DATA
1-2. Biodegration : NO DATA
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1. Bioaccumulative potential : BCF < 2.4
2-2. Biodegration : NO DATA
D.Mobility in soil
1) Toluene
▷ NO DATA
2) Tetrahydromethyl-1,3-isobenzofuranedione
▷ NO DATA
E.Other adverse effects
1) Toluene
▷ NO DATA
2) Tetrahydromethyl-1,3-isobenzofuranedione
▷ NO DATA
13.Disposal considerations

A.Disposal methods : Spilled material should keep in the airtighted container, and consign according to Waste Mateial
Management Act
B.Special precautions for disposal : Discard it followed by appropriate regulations Prohibit the unauthorized disposal
and incineration due to adversely affect natural ecosystems

14.Transport information

A.UN number : 1263

B.Proper shipping name : PAINT (including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid
filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound)
C.Hazard class : 3
D.Packing group : Ⅱ
E.Marine pollutant : be applicable
F.Special precautions for user related to transport or transportation measures
1)EmS FIRE SCHEDULE : F-E
2)EmS SPILLAGE SCHEDULE : S-E

15. Regulatory information

1)Toluene
1-1. Information of EU Classification
▷ Classification : F; R11Repr. Cat. 3; R63Xn; R48/20-65Xi; R38R67
▷ Risk Phrases : R: 11-38-48/20-63-65-67
▷ Safety Phrase : S: (2-)36/37-46-62
1-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : 453.599 kg 1000 lb
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : pertinent
1-3. Rotterdam Convention listed ingredients : NO DATA
1-4. Stockholm Convention listed ingredients : NO DATA
1-5. Montreal Protocol listed ingredients : NO DATA
2)Tetrahydromethyl-1,3-isobenzofuranedione
2-1. Information of EU Classification
▷ Classification : Xi; R41R42/43
▷ Risk Phrases : R: 41-42/43
▷ Safety Phrase : S: (2-)22-24-26-37/39
2-2. U.S. Federal regulations
▷ OSHA PROCESS SAFETY (29CFR1910.119) : notapplicable
▷ CERCLA Section 103 (40CFR302.4) : notapplicable
▷ EPCRA Section 302 (40CFR355.30) : notapplicable
▷ EPCRA Section 304 (40CFR355.40) : notapplicable
▷ EPCRA Section 313 (40CFR372.65) : notapplicable
2-3. Rotterdam Convention listed ingredients : NO DATA
2-4. Stockholm Convention listed ingredients : NO DATA
2-5. Montreal Protocol listed ingredients : NO DATA
16.Other information

A.Reference : Occupational Health and Safety Act

Korea Industrial Safety Corporation Preparation of Material Safety Data Sheet
KOSHA CODE W-05-2007【The guideline for MSDS , 2012.】
B.Issue date : 2012-04-26
C.Revision number and Last date revised : 1.(2013-07-18)
D.Other : " WWW.NOROO.CO.KR"