PHYSICAL

CHEMISTRY
Part-I
For
IIT-JEE
OLYMPIAD & KVPY
(A Surety in IIT-JEE Selection)

By :

Ankit Agarwal
B.Tech (IIT-Delhi), Gold Medalist

Published by :

G. R. BATHLA & SONS

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ISBN : 978-93-88599-59-7

9 789388 599597

First Edition : 2018

Second Edition : 2019
New Edition

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No part of this book may be reproduced in any form or by any means without the prior written permission of the author and the
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The author and the publisher have made every effort to provide authentic, accurate and up-to-date matter in this book. However,
they do not take any legal responsibility for any misinterpretations or errors inadvertently overlooked.
PREFACE to the Second Edition

Over a period of time, results from a few institutes have been exceptional in JEE Main as well as Advanced. The
heart of shining results revolves around exceptional faculty team in these institutes and its wonderful education
system.
GRB Kota Question Bank (Physical Chemistry) has been written to assist those sincere students who are unable to
access huge volume of questions solved in these various reputed institutes.
The GRB Kota Question Bank is a collection (from a research of more than 16 years) of all important questions framed
and discussed in reputed coaching institutes, as well as relevant questions of National Olympiads of various countries like
India, US, UK, Canada, Australia etc. Many of my students have brought laurels to our country by fetching Gold Medals in
IJSO, ICHO as well as cracked JEE Advanced in TOP-100 ranks.
All varieties of questions viz. Single choice (sub-topicwise), Multiple choice, Assertion-reasoning, Comprehension
Based, Matrix-match and Subjective (integer type) has been covered for students’ benefit. The book has been written in
two parts. Part-I contains all the class 11 topics taught in reputed coaching institutes, while Part-II contains topics of class
12.
The sequence of the chapters in the book is the same as taught in leading coaching institutes of INDIA. Hence, any
coaching institute can very well use this book, for exhaustive problem solving for their students.
What makes this book special?—A Chapter on ‘Graphical interpretation’ has been introduced in Part-II. This
chapter covers graph based questions from all physical chemistry chapters. This will play an important role in
concept building.
It is almost guaranteed that, a student who solves the questions given in the GRB Kota Question Bank will be miles
ahead in his / her preparation of JEE/KVPY/Chemistry Olympiad/ IJSO.
To help the student more, hints and solutions have also been given to almost all the questions. GRB Kota Question
Bank has been designed in such a manner that any student who has studied NCERT of Class X, XI and XII can easily learn
advance concepts from this book.
I would like to sincerely acknowledge my Teachers, my Students, my Parents, my Friends, my Wife and my lovely
Daughters, who encouraged and supported me to compile this book. A special thanks to my colleagues—Dr. Sonal Rajora,
Mr. Girish Gaur and Mr. ShashikantVaishnav, who also contributed in their respective subjects to bring out a complete
study material for the benefit of students at large. I am also thankful to Shri Manoj Kumar Bathla, Proprietor, G.R. Bathla
& Sons and Mr. Sugam Bathla for publishing and distributing the book across India.
Special thanks to my students Niyati, Jash, Sovesh, Poojan, Jaysheel, Mudita, Shrey, Dhruv, Naman, Mohit, Pratham
who helped in making appropriate corrections/modifications in the book.
Any suggestions/ improvements from the readers are most welcome!

July, 2019 Author

Note : Students and honourable teachers may feel free to give valuable suggestions on the mail
[email protected] to improve the quality of the book.
 (iv)

NOTE TO THE STUDENTS

Dear Student,
It is your great fortune to have this book in your hands. If this book is carefully handled then, be assured that you are
successful! Only time is separating your success.
Based on my teaching experience of more than 16 years, I would suggest the following to get the best out of this book:-
1. Always keep an OMR handy while solving questions. Avoid solving questions in the book. If you can’t arrange an
OMR, then, write your answers in an A4 sheet.
2. Always solve questions in a timed manner. Ideal time duration is 60 minutes.
3. Before the time is complete, do not see the answers or solutions.
4. Be honest, while checking the answers. The questions you miss or wrongly attempt must be marked in RED.
5. Reattempting these RED marked questions, will help you tone up your preparation.
6. After 60 minutes, do some introspection of what better can be done with the missed or wrongly attempted
questions. Reviewing the concepts for those problems is a must.
7. Be observant in checking all the options. Sometimes, rejection of options may help you arrive at the correct
answer.
8. For Physical Chemistry, in a span of 60 minutes we can solve approximately 30 questions. So, our target should be
to solve at least 20 questions and go upto30 eventually.
9. After attempting a chapter completely, please do attempt graph based questions from Graphical Interpretation
chapter (Part-II of Physical Chemistry), so that fine tuning of concepts from that topic is done.
Do remember, that key to success in Physical Chemistry is to not get stuck with a single problem, MOVE ON! Let
your higher intelligence work on it. After your complete attempt of 20-30 questions, come back to resolve those stuck up
questions.
This book will help you achieve mastery in Physical Chemistry through problem solving.
All the Best for your Future! Your future is now in your hands…
 (v)

ABOUT THE AUTHOR

Ankit Agarwal is a popular name in the realm of Chemistry. He is a B.Tech from IIT
Delhi (Gold Medalist) and his passion to interact with bright minds plus his interest and love
for Chemistry led him to teach and guide many IIT-JEE, Chemistry Olympiad aspirants. Over
a period of 16 years, many of his students have brought laurels to the country by getting Gold
medals in Olympiad and Top Ranks in IIT-JEE etc.
His intent to share his in-depth knowledge of the subject with many sincere students, who
cannot come in direct contact with him, has made him write this book.
Currently, he is a senior faculty of Chemistry in a reputed institute of Kota.
 (vi)

Physical Chemistry : Part -I

1. Mole Concept, Stoichiometry, Concentration Terms 1–117
2. Gaseous State 118–187
3. Atomic Structure 188–238
4. Chemical Equilibrium 239–293
5. Redox Reactions 294–333
6. Thermodynamics 334–460

Physical Chemistry : Part - II

7. Solid State 1–33
8. Chemical Kinetics and Nuclear Chemistry 34–140
9. Liquid Solutions 141–197
10. Surface Chemistry 198–220
11. Ionic Equilibrium 221–288
12. Electrochemistry 289–356
13. Graphical Interpretation 357–448
CONTENTS
Chapters Pages

1. MOLE CONCEPT, STOICHIOMETRY, CONCENTRATION TERMS 1–117

v Straight Objective Type 1
v Reasoning Type 41
v Multiple Objective Type 42
v Comprehension Type 50
v Match the Column Type 61
v Subjective Type 64
v Answer Key 72
v Hints and Solutions 77

2. GASEOUS STATE 118–187

v Straight Objective Type 118
v Reasoning Type 144
v Multiple Objective Type 145
v Comprehension Type 151
v Match the Column Type 155
v Subjective Type 157
v Answer Key 165
v Hints and Solutions 168

3. ATOMIC STRUCTURE 188–238

v Straight Objective Type 188
v Reasoning Type 205
v Multiple Objective Type 206
v Comprehension Type 211
v Match the Column Type 216
v Subjective Type 218
v Answer Key 222
v Hints and Solutions 225
 (viii)

4. CHEMICAL EQUILIBRIUM 239–293

v Straight Objective Type 239
v Reasoning Type 259
v Multiple Objective Type 261
v Comprehension Type 264
v Match the Column Type 270
v Subjective Type 271
v Answer Key 274
v Hints and Solutions 277

5. REDOX REACTIONS 294–333

v Straight Objective Type 294
v Reasoning Type 310
v Multiple Objective Type 311
v Comprehension Type 314
v Match the Column Type 316
v Subjective Type 317
v Answer Key 320
v Hints and Solutions 322

6. THERMODYNAMICS 334–460
v Straight Objective Type 334
v Reasoning Type 382
v Multiple Objective Type 383
v Comprehension Type 390
v Match the Column Type 402
v Subjective Type 405
v Answer Key 417
v Hints and Solutions 421
 Mole Concept, Stoichiometry,
Concentration Terms
1
Chapter

STRAIGHT OBJECTIVE TYPE and pressure. The ratio of total number of atoms of
these gases present in different flask would be :
A. Mole Calculations (a) 1 : 1 : 1 : 1 (b) 1 : 2 : 2 : 3
1. If the atomic mass of sodium is 23, the number of (c) 2 : 1 : 2 : 3 (d) 3 : 2 : 2 : 1
moles in 46 g of sodium is : 8. Which of the following expressions is correct (n =
(a) 1 (b) 2 number of moles of the gas, NA = Avogadro
(c) 2.3 (d) 4.6 constant, m = mass of 1 molecule of the gas, N =
2. The charge on 1 g-ion of Al3+ is : (NA = Avogadro’s number of molecules of the gas)?
number, e = charge on one electron) (a) n = m NA (b) m = NA
1 1 (c) N = nNA (d) m = n/NA
(a) NAe coulomb (b) ´ NAe coulomb
27 3 9. The volume of 1 mole of a gas at standard
1 temperature and pressure is :
(c) ´ NAe coulomb (d) 3 × NAe coulomb
9 (a) 11.35 litres (b) 22.7 litres
3. Which of the following contains the greatest (c) 100 litres (d) 22.4 litres
number of atoms? 10. One mole of a gas is defined as :
(a) 1.0 g of butane (C4H10) (a) the number of molecules in one litre of gas
(b) 1.0 g of nitrogen (N2) (b) the number of molecules in one formula weight
(c) 1.0 g of silver (Ag) of gas
(d) 1.0 g of water (H2O) (c) the number of molecules contained in 12 grams
4. A gaseous mixture contains CO2(g) and N2O(g) in of (12 C) isotope
2 : 5 ratio by mass. The ratio of the number of (d) the number of molecules in 22.7 litres of a gas at
molecules of CO2(g) and N2O (g) is : S.T.P.
(a) 5 : 2 (b) 2 : 5 11. If two moles of an ideal gas at 546 K occupies a
(c) 1 : 2 (d) 5 : 4 volume of 44.8 litres, the pressure must be :
5. A sample of aluminium has a mass of 54.0 g. What (a) 2 atm (b) 3 atm
is the mass of the same number of magnesium (c) 4 atm (d) 1 atm
atoms? (At. wt. Al = 27, Mg = 24) 12. A container consists of O2 gas at 4 atm pressure and
(a) 12 g (b) 24 g 400 K. If the volume of the container is 8.21 litre
(c) 48 g (d) 96 g then calculate number of oxygen atoms present in
6. The weight of a molecule of the compound C60H22 is : the container.
(a) 1.09 ´ 10–21 g (b) 1.24 ´ 10–21 g (a) 2 (b) 1.5 × NA
–23 23 (d) 12.04 × 1023
(c) 5.025 ´ 10 g (d) 16.023 ´ 10–23 g (c) 6.023 × 10
7. Four 1-1 litre flasks are separately filled with the 13. 2 moles of nitrogen atoms at STP occupy a volume
gases H2, He, O2 and O3 at the same temperature of :
2 GRB Kota Question Bank : Physical Chemistry for JEE (Vol. 1)

(a) 11.35 L (b) 45.4 L is 22.4 %, then molecular mass of the compound will
(c) 22.7 L (d) 5.6 L be :
14. Under the same conditions, two gases have the (a) 3000 (b) 750
same number of molecules. They must : (c) 12000 (d) 600
(a) be noble gases 24. A sample of clay contains 50% silica and 10% water.
(b) have equal volumes The sample is partially dried by which it loses 8 gm
(c) have a volume of 22.4 dm3 each water. If the percentage of silica in the partially
(d) have an equal number of atoms dried clay is 52, what is the percentage of water in
15. 3 g of a hydrocarbon on combustion in excess of the partially dried clay?
oxygen produces 8.8 g of CO2 and 5.4 g of H2O. The (a) 2.0 % (b) 6.4%
data illustrates the law of : (c) 10.4% (d) 2.4%
(a) conservation of mass (b) multiple proportions 25. Which of the following samples must have molar
(c) constant proportions (d) none of these mass greater than a mixture of CO and CO2?
16. The mass of 1 mole of neutrons (mn = 1.675 × 10–27 (a) Pure Ne
kg) is : (b) Mixture of CH4 and SO3
(a) 1.800 × 10–3 kg (b) 1.008 × 10–4 kg (c) Mixture of O3 and SO2
–3
(c) 1.080 × 10 kg (d) 1.008 × 10–3 kg (d) Pure O2
17. 1021 molecules are removed from 200 mg of CO2. 26. 1 gm-atom of nitrogen may represent :
The moles of CO2 left are : (a) 6.02 × 1023 N2 molecules
(a) 2.88 × 10–3 (b) 28.2 × 10–3 (b) 22.4 lit. of N2 at 1 atm and 273 K
(c) 288 × 10 –3 (d) 28.8 × 103 (c) 11.2 lit. of N2 at 1 atm and 0°C
(d) 28 g of nitrogen
18. If the mass of 0.25 moles of an element X is 2.25 g,
the mass of one atom of X is about : 27. The mass of CO2 that must be mixed with 20 gm of
(a) 1.5 × 10–24 g (b) 2.5 × 10–23 g oxygen such that 27 mL of a sample of the resulting
(c) 1.5 × 10–23 g (d) 2.5 × 10–24 g mixture would contain equal number of molecules
of each gas :
19. From 392 mg of H2SO4, 1.204 ´ 1021 molecules of
(a) 13.75 gm (b) 27.50 gm
H2SO4 are removed. How many moles of H2SO4 are
(c) 41.25 gm (d) 55 gm
left?
(a) 2 ´ 10–3 (b) 1.2 ´ 10–3 28. The mass of 3.2 × 105 atoms of an element is
(c) 4 ´ 10 –3 (d) 1.5 ´ 10–3 8.0 × 10–18 gm. The atomic mass of the element is
about :
20. The number of molecules of water in 333 g of
(a) 2.5 × 10–22 (b) 15
Al2 (SO4)3 ⋅ 18H2O is :
(c) 8.0 × 10–18 (d) 30
(a) 18 ´ 6.022 ´ 1023 (b) 9 ´ 6.022 ´ 1023
29. 132 amu of B12 will contain :
(c) 18 (d) 36
(a) 12NA atoms of boron
21. The atomic weight for a triatomic gas is a. The
(b) 1 atom of boron
correct formula for the number of moles of gas in its
(c) 1 molecule of boron
w g is :
(d) NA molecules of boron
3w w
(a) (b) 30. Which of the following contains largest number of
a 3a
a atoms?
(c) 3wa (d)
3w (a) 4 gm carbon (b) 12 gm calcium
22. Which of the following will have maximum number (c) 6.35 gm copper (d) 22.4 gm cadmium
of C atoms? [C = 12, Ca = 40, Cu = 63.5, Cd = 112]
(a) 5.8 g of glyoxal (C2H2O2) 31. The only incorrect information related with 9.6 g
(b) 3.1 g of acetone (C3H6O) ozone is :
(c) 11.6 g of fumaric acid (C4H4O4) (a) contains 0.2 g molecules of ozone
(d) 12 g of urea (CON2H4) (b) contains 0.6 g atoms of oxygen
23. An organic compound contains 14 atoms of carbon (c) occupy 4.48 L at 273 K and 1 bar
per molecule. If mass % of carbon in the compound (d) occupy 4.48 L at 273° C and 2 atm.
Mole Concept, Stoichiometry, Concentration Terms 3

32. Total number of neutrons present in 4g of heavy 42. How many moles of magnesium phosphate,
water (D2O) is : (Where NA represents Avogadro’s Mg3(PO4)2 will contain 0.25 mole of oxygen atoms?
number) (a) 0.02 (b) 3.125 ´ 10–2
(a) 2.4 NA (b) 4 NA (c) 1.25 ´ 10 –2 (d) 2.5 ´ 10–2
(c) 1.2 NA (d) 2 NA 43. Number of atoms in 560g of Fe (atomic mass 56g
33. 30 g of element x contains 18.069 ´ 1023 atoms of x. mol–1) is :
Calculate gram-molecular mass of x2. (a) twice that of 70g N (b) half that of 20 g H
(a) 20 amu (b) 10 amu (c) both (a) and (b) (d) none of these
(c) 10 g (d) 20 g 1 1
44. If we consider that th in place of th mass of
34. If a sample of CuSO4 ⋅ 5H2 O contains 64 g S. 6 12
carbon atom is taken to be the relative atomic mass
Calculate mass of H present in sample. (S = 32)
unit, the mass of one mole of a substance will :
(a) 10 g (b) 20 g
(a) decrease twice
(c) 5 g (d) 40 g
(b) increase two fold
35. Volume at STP of 0.44 gm of CO2 is the same as that (c) remains unchanged
of : (d) be a function of the molecular mass of the
(a) 0.02 gm of hydrogen gas substance
(b) 0.085 gm of ammonia gas 45. How many moles of electron weigh in one kilogram?
(c) 320 mg of sulphur dioxide gas
1
(d) none of the above (a) 6.023 ´ 1023 (b) × 10 31
9.108
36. The sodium salt of methyl orange has 7% sodium. 6.023 1
What is the minimum molecular weight of the (c) × 1054 (d) × 10 8
9.108 9.108 × 6.023
compound?
46. Which has maximum number of atoms :
(a) 420 (b) 375
(a) 24 g of C (12) (b) 56 g of Fe (56)
(c) 329 (d) 295
(c) 27 g of Al (27) (d) 108 g of Ag (108)
37. In the preceding problem, if the compound contains
47. Which of the following statement is correct?
12.8% nitrogen and 9.8% sulphur how many
nitrogen and sulphur atoms are present per atom of (a) 1 mole of electron has 1.6 ´ 10–19 C of charge
sodium? (b) 1 mole of electrons weigh 0.548 mg
(c) 1 mole of electrons weigh 5.48 mg
(a) 2 and 1 (b) 1 and 3
(d) 1 mole of electrons weigh 0.548 kg
(c) 1 and 2 (d) 3 and 1
48. 5.85 g of NaCl is dissolved in 1 L of pure water. The
38. Which of the following will contain same number of
number of ions in 1 mL of this solution is :
atoms as 20 g of calcium?
(a) 6.02 ´ 1019 (b) 1.2 ´ 1022
(a) 24 g magnesium (b) 12 g carbon 20
(c) 1.2 ´ 10 (d) 6.02 ´ 1020
(c) 8 g oxygen gas (d) 16 g oxygen atom
49. How many gram ions of SO4−2 are present in 1 gram
39. A sample of ammonium phosphate (NH4)3PO4
contains 3.18 mol of H atoms. The number of moles molecule of K2SO4 ⋅ Al2(SO4)3 ⋅ 24H2O?
of O atoms in the sample is : (a) 2 (b) 3
(a) 0.265 (b) 0.795 (c) 1 (d) 4
(c) 1.06 (d) 3.18 50. If KOTA CLASSES is written by a graphite pencil,
40. Cortisone is a molecular substance containing 21 it weighs 3.0 × 10–10 gm. How many carbon atoms
atoms of carbon per molecule. The mass percentage are present in it? (NA = 6 × 1023)
of carbon in cortisone is 69.98%. Its molar mass is : (a) 1.5 × 1013 (b) 5 × 1012
(c) 2 × 1033 (d) 1.5 × 1010
(a) 176.5 (b) 252.2
(c) 287.6 (d) 360.1 51. A compound contains 7 carbon atoms, 2 oxygen
41. The molar mass of normal water is ... as compared atoms and 1.0 × 10–23 gm of other elements. The
to heavy water. molecular mass of compound is : (NA = 6 × 1023)
(a) 10% less (b) 10% high (a) 122 (b) 116
(c) 2% less (d) zero % less (c) 148 (d) 154
4 GRB Kota Question Bank : Physical Chemistry for JEE (Vol. 1)

52. Total number of electrons present in 4.4 gm oxalate 63. Calculate the number of oxygen atoms and its
ion (C2O42–) is : weight in 50 gm of CaCO3.
(a) 0.05 NA (b) 2.3 NA (a) 6.02 × 1023 and 12 gm
(c) 2.2 NA (d) 2.1 NA (b) 9.033 × 1023 and 24 gm
53. Which of the following options correctly represent (c) 9.033 × 1023 and 12 gm
mass of 10 molecules of Marshall’s acid? (d) 6.02 × 1023 and 24 gm
(a) 10 amu (b) 1940 amu 64. Equal masses of oxygen, hydrogen and methane are
(c) 1940 gm (d) 10 gm taken in identical conditions. What is the ratio of
54. Which of the following options consist of substances the volumes of the gases under identical
that will illustrate law of reciprocal proportions? conditions?
(a) Water, carbon-dioxide and ethanol (a) 16 : 1 : 8 (b) 1 : 16 : 2
(b) Ammonia, water and di-nitrogen pentaoxide (c) 1 : 16 : 8 (d) 2 : 16 : 1
(c) Ferrous oxide, Ferric oxide and Fe3O4 65. Which of the following options correctly represent
(d) Nitrous oxide, Nitric oxide and sulphur di-oxide the increasing order of number of O atoms in the
55. Identify the option containing maximum number of following samples?
atoms. (P) 1.8 gm of glucose
(a) 18 mg of glucose (b) 2 mg of hydrogen gas (Q) 1 gm-atom of oxygen.
(c) 10 mg of H2O (d) 7.8 mg of benzene (R) Mixture of ozone and oxygen gas having total 5
millimoles of the two gases.
56. 13.5 gm of aluminium when changes to Al3+ ion in
(S) Mixture of CO(g) and NO(g) having total 20
solution, will lose :
millimoles of the two gases.
[Al = 27, NA = 6 × 1023] (a) (R) < (S) < (P) < (Q) (b) (S) < (P) < (Q) < (R)
(a) 18.0 × 1023 electrons (b) 6.0 × 1023 electrons (c) (P) < (R) < (S) < (Q) (d) (S) < (R) < (Q) < (P)
(c) 3.0 × 1023 electrons (d) 9.0 × 1023 electrons
66. If equal mass of following substance are taken then
57. One of the following combinations illustrate law of which will have maximum number of molecules.
reciprocal proportions : (a) C6H12O6 (b) C12H22O11
(a) N2O3, N2O4, N2O5 (b) NaCl, NaBr, NaI (c) C2H6 (d) CO2
(c) CS2, CO2, SO2 (d) PH3, P2O3, P2O5
67. Law of multiple proportion is illustrated by :
58. The weight of 1 × 1022 molecules of CuSO4.5H2O is : (a) Calcium carbonate and Barium carbonate
(a) 41.59 g (b) 415.9 g (b) Sodium chloride and potassium chloride
(c) 4.159 g (d) 0.4159 g (c) Sulphur dioxide and sulphur trioxide
59. The largest number of molecules is in : (d) Carbon dioxide and sulphur dioxide
(a) 34 g of water (b) 28 g of CO2
68. 1 atom of X, 2 atoms of Y and 3 atoms of Z combine
(c) 46 g of CH3OH (d) 54 g of N2O5
together to give a molecule XY2Z3. Now we take 10
60. A substance contains 7% by mass of N and 4% by gm of X and 2 × 1023 atoms of Y and 0.06 moles of Z
mass of oxygen. Calculate minimum possible molar in a container, to give 5.6 gm of XY2Z3. What is the
mass of the substance. molar mass of Z?
(a) 200 (b) 300 Given : MX = 60 gm/mol MY = 80 gm/mol
(c) 400 (d) 600 (a) 25 (b) 24
61. Molar mass of electron is nearly : (NA = 6 ×1023 ) (c) 32 (d) 20
(a) 9.1 × 10–31 kg mol–1 (b) 9.1 × 10–31 gm mol–1 69. 1.61 gm of anhydrous ZnSO4 was placed in moist air
(c) 54.6 × 10–8 gm mol–1 (d) 54.6 × 10–8 kg mol–1 after few days its weight was found to be 2.87 gm.
62. Which one of the following pairs of gases contains What is the molecular formula of hydrated salt?
the same number of molecules? [Zn = 65]
(a) 16 g of O2 and 14 g of N2 (a) ZnSO4 ⋅ H2O (b) ZnSO4 ⋅ 3H2O
(b) 8 g of O2 and 22 g of CO2 (c) ZnSO4 ⋅ 7H2O (d) ZnSO4 ⋅ 10H2O
(c) 28 g of N2 and 22 g of CO2 70. A rock contains 1.02% Al2O3 and 1.80% SiO2 (by
(d) 32 g of CO2 and 32 g of N2 mass). Apart from free SiO2, some SiO2 in the rock
is present as kaolin (Al2O3 ⋅ 2SiO2). All Al2O3 in the
Mole Concept, Stoichiometry, Concentration Terms 5

rock is present as kaolin. The mass percentage of [NA = 6 ×1023 ]

free SiO2 in the rock is : (Al = 27, Si=28) (a) 0.001 (b) 0.27
(a) 1.2% (b) 0.6% (c) 0.01 (d) 0.027
(c) 1.8% (d) 0.8% 78. In the blood of an infant there are about 1.3 × 1012
71. A gaseous mixture contains SO3 (g) and C2H6 (g) in red blood cells, which contain a total of 0.15 gm of
a 16 : 15 ratio by mass. The ratio of total number of iron ions. On an average, how many iron ions are
atoms present in C2H6(g) and SO3 (g) is : present, in each red blood cell of an infant? [Fe = 56]
(a) 2 : 5 (b) 1 : 5 (a) 8.8 × l023 (b) 4.7 × 1013
(c) 1.2 × 10 9 (d) 3.0 × 108
(c) 5 : 1 (d) 5 : 2
72. Haemoglobin (C2952 H4664 N812 O832 S8 Fe4, molar 79. Ratio of number of protons to neutrons present in
mass = 65248 g/mol) is the oxygen carrier in blood. 27.83 × 1029 molecules of ND4+ :
An average adult has about 5.0 L of blood. Every (where D is 1H2)
milliliter of blood has approximately 6.0 × 109 27.83 × 1019
erythrocytes, or red blood cells and every red blood (a) (b) 1
NA
cell has about 3.0 × 108 haemoglobin molecules. The
mass of haemoglobin molecules in an average adult (c) 27.83 (d) 27.83 × 1019
is : (NA = 6 × 1023) 80. At certain temperature, two moles of A combines
(a) 978.72 gm (b) 652.48 gm with five moles of B to produce two moles of C.If
(c) 434.99 gm (d) 0.015 gm atomicity of A and B is 2, the formula of compound
C is :
73. A sample of protein was analysed for metal content
(a) AB3 (b) A2B5
and analysis revealed that it contained magnesium
(c) AB5 (d) A5B2
and titanium in equal amounts, by mass. If these
are the only metallic species present in the protein 81. Which of the following will occupy greater volume
and it contains 0.008% metal by mass, the under the similar conditions of pressure and
minimum possible molar mass of the protein is : temperature?
[Mg = 24, Ti = 48] (a) 6 gm oxygen (b) 0.98 gm hydrogen
(a) 600000 (b) 150000 (c) 5.25 gm nitrogen (d) 1.32 gm helium
(c) 300000 (d) 1200000 82. The number of electrons in 3.1 mg NO −3 is :
74. Total number of protons, neutrons and electrons (a) 32 (b) 1.6 × 10–3
present in 14 mg of 6C14 is : (c) 9.6 × 1020 (d) 9.6 × 1023
(Take NA = 6 × 1023) 83. The number of neutrons in 0.45 g water, assuming
(a) 1.2 × 1022 (b) 1.2 × 1025 that all the hydrogen atoms are H1 atoms and all
(c) 7.2 × 1021 (d) 1.08 × 1022 the oxygen atoms are O16 atoms, is :
75. Which of the following has the smallest number of (a) 8 (b) 0.2
molecules? (c) l.2 ×1023 (d) 4.8 × 1024
(a) 22.7 mL of CO2 gas at STP 84. The volume of one mole of water at 277 K is 18 ml.
(b) 22 g of CO2 gas One ml of water contains 20 drops. The number of
(c) 11.35 L of CO2 gas at STP molecules in one drop of water will be :
(d) 0.1 moles of CO2 gas (a) 1.07 × 1021 (b) 1.67 × 1021
(c) 2.67 × 1021 (d) 1.67 × 1020
76. If a mole is defined to be 3 × 1024 (instead of
Avogadro’s Number, 6 × 1023), what would be the 85. 1.61 gm of Na2SO4 ⋅ 10H2O contains same number
mass of one mole of Argon atoms? [Atomic mass of of oxygen atoms as present in :
Ar on conventional scale is 40] (a) 0.98 gm H2SO4 (b) 0.08 gm SO2
(a) 40 gm (b) 200 gm (c) 1.78 gm H2S2O7 (d) 0.05 gm CaCO3
(c) 20 g (d) 8 gm 86. The number of hydrogen atoms in 0.9 gm glucose,
77. 1.19 gm mixture of Cu, Zn and Al contains 50% C6H12O6 is same as :
copper by weight and 3 × 1021 atoms of zinc. Find (a) 0.048 gm hydrazine, N2H4
gram atoms of aluminium in given mixture? (b) 0.17 gm ammonia, NH3
(At. mass of Al = 27; Cu = 63.55; Zn = 65.0) (c) 0.30 gm ethane, C2H6
(d) 0.03 gm hydrogen, H2
6 GRB Kota Question Bank : Physical Chemistry for JEE (Vol. 1)

87. The number of g molecules of oxygen in 6.02 × 1024 96. The number of nitrogen atoms in 3.68 g of
CO molecules is : K4[Fe(CN)6] is : [N0= Avogadro number]
(a) 1 g molecule (b) 0.5 g molecule (a) 0.06 (b) 0.01 N0
(c) 5 g molecule (d) 10 g molecule (c) 0.06 N0 (d) none of these
88. One atomic mass unit in kilogram is : 97. An unknown compound contains 8% sulphur by
1 12 mass. Calculate :
(a) (b)
NA NA (P) Least molecular weight of the compound and
1 1000 (Q) Molecular weight if one molecule contains 4
(c) (d)
1000N A NA atoms of S
P Q P Q
89. Rearrange the following (P to S) in the order of (a) 200, 400 (b) 300, 400
increasing masses. (c) 400, 1600 (d) 400, 1200
(P) 0.5 mole of O3
98. The ratio of the masses of methane and ethane in a
(Q) 0.5 gm molecule of nitrogen
gas mixture is 4 : 5. The ratio of number of their
(R) 3.011 × 1023 molecule of O2
molecules in the mixture is :
(S) 11.35 L of CO2 at STP
(a) 4 : 5 (b) 3 : 2
(a) S < R < Q < P (b) Q < R < S < P
(c) 2 : 3 (d) 5 : 4
(c) R < Q < P < S (d) P < Q < R < S
18 99. How many H atoms are in 3.42 g of C12H22O11?
90. Number of electrons in 36 mg of 8 O −2 ions are :
(a) 6.0 × 1023 (b) 1.3 × 1023
(Take NA = 6 × 1023) 22
(c) 3.8 × 10 (d) 6.0 × 1021
(a) 1.2 × 1021 (b) 9.6 × 1021
100. If 1.50 g of H2C2O4.2H2O were heated to drive off
(c) 1.2 × 1022 (d) 1.9 × 1022
the water of hydration, how much anhydrous
91. The number of g-atoms of nitrogen in its 7 gm is H2C2O4 would remain?
equal to number of g-atoms in : (a) 0.34 g (b) 0.92 g
(a) 6 gm Mg (b) 28 gm Fe (c) 1.07 g (d) 1.50 g
(c) 30 gm Ca (d) 20 gm Hg
101. How many millimoles of methane, CH4, are present
92. From 2 mg calcium, 1.2 × 1019 atoms are removed. in 6.4 g of this gas?
The number of g-atoms of calcium left is : (a) 0.40 (b) 4.0
(a) 5 × 10–5 (b) 2 × 10–5 (c) 40 (d) 4.0 × 102
(c) 3 × 10–5 (d) 5 × 10–6
102. Adipic acid, HOOC(CH2)4COOH, is used in making
93. The shape of Tobacco Mosaic Virus (TMC) is nylon. What is the total number of atoms in 1.0 g of
cylindrical, having length and diameter 3000 Å and adipic acid?
170 Å, respectively. The density of the virus is 0.08
gm/ml. The molecular weight of TMC is : Molar Mass, g ⋅ mol–1
(a) 3.28 (b) 5.44 × 10–24 Adipic acid 146.26
(c) 5.44 × 10 –18 (d) 3.28 × 106
(a) 20 (b) 4.1 × 1021
94. Same mass of glucose (C6H12O6) and acetic acid (c) 8.2 × 1022 (d) 7.2 ×1024
(CH3COOH) contain :
103. How many moles are there in 2.24 m3 of any gas 190
(a) same number of carbon atoms torr and 273° C?
(b) same number of hydrogen atoms
(a) 1.25 moles (b) 12.5 moles
(c) same number of oxygen atoms
(c) 1.25 × 10–3 moles (d) 1.25 × 103 moles
(d) all of the above
104. How many ozone molecules are in 3.20 g of O3?
95. 400 gm mixture of AB and AC2 contains 26.25% of A
(a) 4.0 × 1022 (b) 6.0 × 1022
by mass. Select the incorrect statement(s).
(c) 1.2 × 1023 (d) 6.0 × 1023
(Atomic masses of A = 15, B = 25, C = 22.5)
(a) % mass of AB is 10 105. Number of neutrons in 5.5 gm T2O (T is 1H3) are :
(b) Number of moles of AC2in the mixture is 4 (a) 0.25 NA (b) 2.5 NA
(c) Number of moles of AB is 1 (c) 3 NA (d) 4 × NA
(d) Total moles of A atoms in mixture is 7
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