DSolv-Ex SDS 2015

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Satety Data Sheet (SDS)

Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 1 of 10

1 PRODUCT AND COMPANY IDENTIFICATION


Manufacturer
Delta Tech Service, Inc.
397 W. Channel Rd.
Benicia, CA 94510

Contact: Delta Tech Service, Inc.


Phone: +1-707-745-2080
Fax: +1-707-745-6730
Web: www.deltatechservice.com

Product Name: DSolv-EX


Revision Date: 5/3/2015
Version: 1.00
SDS Number: 215
Common Name: Solvent-Based Cleaner
CAS Number: MIXTURE
Chemical Family: Mixed Hydrocarbons
Chemical Formula: *** PROPRIETARY ***
Synonyms: DSolv-X
Product Use: Solvent based cleaner that is used to dissolve and break up heavy oil and coke deposits.
Product Emergency Phone: +1-707-745-2080
Transportation Emergency Phone: +1-707-745-2080

2 HAZARDS IDENTIFICATION

NFPA: Health = 1, Fire = 2, Reactivity = 0


HMIS III: H2/F2/PH0

2
2
2
1 0
0

H I Splash Goggles,
Gloves, Apron, Vapor
Respirator
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


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GHS Signal W ord:


DANGER

GHS Hazard Pictograms:

GHS Classifications:
Physical, Flammable Liquids, 3
Health, Aspiration hazard, 1
Health, Acute toxicity, 4 Dermal
Health, Skin corrosion/irritation, 2
Health, Serious Eye Damage/Eye Irritation, 2 A
Health, Acute toxicity, 4 Inhalation
Health, Specific target organ toxicity - Single exposure, 3
GHS Phrases:
H226 - Flammable liquid and vapor
H304 - May be fatal if swallowed and enters airways
H312 - Harmful in contact with skin
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H332 - Harmful if inhaled
H335 - May cause respiratory irritation
GHS Precautionary Statements:
P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking
P233 - Keep container tightly closed.
P242 - Use only non-sparking tools.
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray.
P262 - Do not get in eyes, on skin, or on clothing.
P264 - Wash skin thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+361+353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338 - IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present
and easy to do. Continue rinsing.
P321 - Specific treatment (see supplementary first aid instructions on this label).
P332+313 - If skin irritation occurs: Get medical advice/attention.
P337+313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P370+378 - In case of fire: Use water spray, water fog, alcohol-resistant foam, dry chemical or carbon dioxide for
extinction.
P391 - Collect spillage. Hazardous to the aquatic environment.
P403+235 - Store in a well ventilated place. Keep cool.
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


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P405 - Store locked up.
P501 - Dispose of contents/container to an approved waste disposal plant.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Ingredients:
Cas # I Percentage I Chemical Name
-------------------------------------------------------------------------------------------------------
25551-13-7 I 50-70% I Trimethyl benzene
95-63-6 I 10-35% I 1,2,4-Trimethylbenzene
98-82-8 I 0-6% I Cumene
1330-20-7 I 0-3% I Mixed Xylenes

4 FIRST AID MEASURES

Inhalation: If inhaled, move person into fresh air. Monitor respiratory function. If breathing is difficult, provide oxygen.
If not breathing, give artificial respiration. If symptoms persist, obtain medical attention.
Skin Contact: Promptly flush skin with water for at least 15 minutes to ensure all chemical is removed. Remove
contaminated clothing and wash before reuse. If reddening develops and/or persists, obtain medical
attention.
Eye Contact: Flush with large amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. Remove
contact lenses if present and easy to do so. If irritation persists, obtain medical attention.
Ingestion: Rinse mouth with water. Do NOT induce vomiting unless instructed to do so. Material can enter lungs
(aspiration hazard) during swallowing or vomiting resulting in lung inflammation or other lung injury. Never
give anything by mouth to an unconscious person. Get immediate medical attention.

Most important symptoms and effects, both acute and delayed:


The most important known symptoms and effects are described in the labelling (see Section 2) and/or Section 11. Inhalation of
high concentrations of this material, as could occur in enclosed spaces or improper use, may be associated with cardiac
arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. This material has
an aspiration hazard. Any potential danger from aspiration must be weighed against possible oral toxicity when determining
whether to induce vomiting. Consider activated charcoal and/or gastric lavage.

Indication of any immediate medical attention and special treatment needed:


No data available.

5 FIRE FIGHTING MEASURES

Flammability: Combustible Liquid Class II


Flash Point: 38.0 °C (100.2 °F)
Flash Point Method: (TCC)
Burning Rate: No data available
Autoignition Temp: 462.8 °C (865.4 °F)
LEL: 1.0% (V)
UEL: 7.0% (V)

Extinguishing Media:
Water Spray
Water Fog
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 4 of 10
Carbon Dioxide
Alcohol-Resistant Foam
Dry Chemical

Special Hazards Arising From the Substance or Mixture:


Aldehydes Carbon
Oxides Hydrocarbon
particulate Nitrogen
Oxides (NOx) Sulfur
Oxides

Advice for Firefighters:


Firefighters should wear full-face, positive-pressure respirators.

Further Information:
If incinerated, may release toxic fumes.
Use water spray to cool unopened containers.
Do NOT use high volume water jet to extinguish fire, as the force of the water jet may cause fire to spread.
Beware of vapors accumulating to form explosive concentrations.
Vapors can accumulate in low areas.
See Section 7 for more information on safe handling.
See Section 8 for more information on personal protection equipment.
See Section 13 for disposal information.

6 ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures:


Use personal protective equipment.
Keep from contacting skin or eyes.
Avoid breathing vapors, mist or gas.
Ensure adequate ventilation.
Evacuate personnel to safe areas.
Remove all sources of ignition.
Stay upwind of any spills.
Treat any vapors as toxic.
If any equipment is necessary, ensure that it is non-sparking and electrically-protected.

Environmental Precautions:
Prevent further release (leakage/spillage) if safe to do so.
Do not allow product to enter drains.
Do not allow to drain to environment.

Methods and Materials for Containments and Cleaning Up:


Ensure adequate ventilation.
Contain spillage and absorb with liquid-binding, non-combustible material (sand, diatomite, universal binders, vermiculite) and
placed in container for disposal. Do NOT use sawdust.
Contaminated organic material such as rags may spontaneously combust and must be placed in an appropriate metal waste
disposal container.
Spill may also be diluted with equal volume of water and absorbed (as above) or collect with an electrically-protected vacuum
cleaner or by wet-brushing. Collected waste should then be placed in container for disposal.
Dispose of contaminated material according to Section 13.

Reference to Other Sections:


Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 5 of 10
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for information on proper disposal.

7 HANDLING AND STORAGE

Handling Precautions: Wear protective clothing. Avoid cotton, wool or leather.


Avoid breathing vapors or mist.
Avoid contact with eyes, skin, or clothing.
Keep containers closed when not in use.
Do not expose containers to open flame, excessive heat, or direct sunlight.
Keep away from sources of ignition.
Do not smoke while using material.
Take measures to prevent the buildup of electrostatic charge.
Use proper bonding/grounding during product transfer as described in document NFPA 77.
Do not puncture or drop containers.
Handle with care and avoid spillage on the floor (slippage).
Keep material out of reach of children.
Keep material away from incompatible materials.
Wash thoroughly after handling.
DO NOT CUT, DRILL, GRIND OR W ELD ON OR NEAR THIS CONTAINER.
Storage Requirements: Keep container tightly closed.
Avoid inhalation of vapors or mist upon opening container.
Store in a well-ventilated place.
Do not store at elevated temperatures.
Do not store in direct sunlight.
Store away from strong acids, strong bases, strong oxidizing agents, Halogens and metallic
salts.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Use
local exhaust at filling zones and where leakage and dust formation is probable. Use
mechanical (general) ventilation for storage areas. Use appropriate ventilation as required to
keep Exposure Limits in Air below TLV & PEL limits.
Personal Protective Equip: Eye/face protection:
When using material use safety goggles, gloves, apron and vapor respirator according to
HMIS PP, H. All safety equipment should be tested and approved under appropriate
government standards such as NIOSH (US) or EN 166 (EU).

Skin protection:
Handle with gloves made from PVC, butyl-rubber, neoprene, nitrile or fluorinated-rubber.
Gloves must be inspected prior to use. Use proper glove removal technique (without touching
glove's outer surface) to avoid skin contact. Dispose of contaminated gloves according to
applicable laws and laboratory practices.

Body Protection:
Chemically resistant gloves, apron, safety goggles and vapor respirator are recommended.
Type of protective equipment should be selected based on concentration amount and
conditions of use of this material.
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


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Respiratory protection:
Full-face vapor respirator may be required as backup to engineering controls when proper
engineering controls are not in place to keep TLV and PEL limits below defined thresholds.

Control of environmental exposure:


Prevent leakage or spillage if safe to do so. Do not let material enter drains.
Components with workplace control parameters:

Component(s): Trimethyl benzene; 1,2,4-Trimethylbenzene; Cumene; Mixed Xylenes


CAS No(s): 25551-13-7; 95-63-6; 98-82-8; 1330-20-7
USA NIOSH (TWA/REL): 25 ppm
USA ACGIH (TWA/TLV): 25 ppm
USA ACGIH (STEL/TLV): 150 ppm
USA OSHA - Table Z-1 Limits for Air Contaminants (TWA): 50 ppm
USA OSHA - Table Z-1 Limits for Air Contaminants (STEL): 150 ppm
USA OSHA Occupational Exposure Limits Table Z-1 Limits for Air Contaminants (TWA): 50 ppm

Biological occupational exposure limits:

Component: Xylene
CAS-No: 1330-20-7
Parameters: Methylhippuric acids
Biological Spoecimen: Urine
USA ACGIH Biological Exposure Indices: 1,500 mg/g

9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Clear, colorless liquid


Physical State: Liquid Odor: Aromatic
Odor Threshold: Not determined Molecular Formula: MIXTURE
Particle Size: No data available Solubility: Negligible
Spec Grav./Density: 0.872 g/ml (7.23 lbs/gal) Softening Point: Not determined
Viscosity: Not determined Percent Volatile: 100%
Sat. Vap. Conc.: Not determined Heat Value: Not determined
Boiling Point: > 148.9 °C (300.0 °F) Freezing/Melting Pt.: -53.0 °C (-64.0 °F)
Flammability: (solid, gas): Combustible Liquid Class Flash Point: 38.0 °C (100.2 °F)
Partition Coefficient: Not determined Octanol: Not determined
Vapor Pressure: (mm Hg @ 20 °C): 2.10 Vapor Density: (air = 1): 3.5
pH: DNA VOC: 872 g/l
Evap. Rate: (N-Butyl Acetate = 1): 25 Bulk Density: Not determined
Molecular weight: MIXTURE Auto-Ignition Temp: 462.8 °C (865.4 °F)
Decomp Temp: Not determined UFL/LFL: (% v/v): 7.0/1.0

10 STABILITY AND REACTIVITY

Stability: Product is stable under normal conditions.


Conditions to Avoid: Incompatibilities, flames, ignition sources.
Materials to Avoid: Strong acids, strong bases, strong oxidizing agents, Halogens and metallic salts.
Hazardous Decomposition: Aldehydes, Carbon Oxides, Hydrocarbon particulate, Nitrogen Oxides (NOx) and Sulfur
Oxides.
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


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Hazardous Polymerization: Will not occur.

11 TOXICOLOGICAL INFORMATION

Component(s): Trimethyl benzene; 1,2,4-Trimethylbenzene; Cumene; Mixed Xylenes


CAS No(s): 25551-13-7; 95-63-6; 98-82-8; 1330-20-7

Acute Toxicity:
LD50 Oral - Rat: 2,260 mg/kg LD50
Oral - Mouse: 7,000 mg/kg NOAEL
Feed - Rat: 535.8 mg/kg LD50
Dermal - Rabbit: > 1,700 mg/kg
LC50 Inhalation - Rat: 4,800 ppm (4 h)

Skin Corrosion/Irritation: Rabbit skin - Irritating to skin (24 h).

Serious Eye Damage/Eye Irritation: Rabbit eyes - Mild eye irritation (24 h).

Respiratory or Skin Sensitation: Guinea Pig skin - Did no cause sensitization in laboratory animals.

Germ Cell Mutagenicity: No data available.

Carcinogenicity: This product is or contains a component that is possibly classifiable as to their carcinogenicity (Cumene)
and a component that is not classifiable as to its carcinogenicity (Mixed Xylenes) to humans based on their IARC, ACGIH,
NTP, or OSHA classification.

IARC: 28 - Group 28: Possibly carcinogenic to humans (Cumene); 3 - Group 3: Not classifiable as to its carcinogenicity
to humans (Mixed Xylenes).
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

Reproductive Toxicity: This material may be harmful to the human fetus based on positive test results with laboratory
animals.

Specific Target Organ Toxicity • Single Exposure: Respiratory system - May cause respiratory irritation.

Specific Target Organ Toxicity • Repeated Exposure: No data available.

Aspiration Hazard: My be fatal if swallowed and enters airways.

Additional Information:
Component: Trimethy benzene; RTECS: DC3220000
Component: 1,2,4-Trimethylbenzene; RTECS: DC3325000
Component: Cumene; RTECS: GR8575000
Component: Mixed Xylenes; RTECS: ZE2100000
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 8 of 10

12 ECOLOGICAL INFORMATION

Component(s): Trimethyl benzene; 1,2,4-Trimethylbenzene; Cumene; Mixed Xylenes


CAS No(s): 25551-13-7; 95-63-6; 98-82-8; 1330-20-7

Toxicity:

Toxicity to fish:
LC50 - Oncorhynchus mykiss (Rainbow Trout): 4.8 mg/l (96 h)
LC50 - Carassius auratus (Goldfish): 12.52 mg/l (96 h)
LC50 - Morone saxatillis: 2.0 mg/l (96 h)
Flow-through test LC50 - Pimephales promelas (Fathead Minnow): 7.72 mg/l (96 h)

Toxicity to daphnia and other aquatic invertebrates:


EC50 - Daphnia magna (Water Flea): 75.49 mg/l (24 h)
EC50 - Daphnia: 2.14 mg/l (48 h)
Immobilization EC50 - Daphnia magna (Water Flea): 6.0 mg/l (48 h)
Static test EC50 - Daphnia magna (Water Flea): 3.6 mg/l (48 h)

Toxicity to algae:
EC50 - Pseudokirchneriella subspicatus (Green Algae): 2.6 mg/l (72 h)
Growth Inhibition EC50 - Pseudokirchneriella subcapitata: 72.0 mg/l (14 d)

Persistence and Degradability:


Not readily biodegradable.

Bioaccumulative potential:
No data available.

Mobility in Soil:
No data available.

Results of PBT and vPvB assessment:


Not required/conducted.

Other Adverse Effects:


An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with
long lasting effects.

13 DISPOSAL CONSIDERATIONS

Product: Hazardous wastes shall be managed responsibly. All entities that store, transport or handle hazardous waste shall
take the necessary measures to prevent risks of pollution, release into the environment or damage to people and animals.
Contact a licensed professional waste disposal service to dispose of this material.

Contaminated Packaging: Dispose of as unused product.


Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 9 of 10

14 TRANSPORT INFORMATION

DOT (US)
Non-regulated material, liquid

15 REGULATORY INFORMATION
COMPONENT / (CAS/PERC) / CODES
----------------------------------------------------------------
*Trimethyl benzene (25551137 50-70%) MASS, OSHAWAC, PA, SARA311/312, TSCA, TXAIR

*1,2,4-Trimethylbenzene (95636 15-20%) MASS, NJHS, PA, SARA311/312, SARA313, TSCA, TXAIR

*Cumene (98828 0-6%) CERCLA, HAP, MASS, NJHS, OSHAW AC, PA, PROP65, SARA313, TOXICRCRA, TSCA, TXAIR,
TXHWL

*Mixed Xylenes (1330207 0-3%) CERCLA, CSWHS, EPCRAW PC, HAP, MASS, NJHS, OSHAWAC, PA, SARA313,
TOXICRCRA, TSCA, TXAIR, TXHWL

REGULATORY KEY DESCRIPTIONS


----------------------------------------------------------------
CERCLA = Superfund clean up substance
CSWHS = Clean Water Act Hazardous substances
EPCRAWPC = EPCRA Water Priority Chemicals
HAP = Hazardous Air Pollutants
MASS = MA Massachusetts Hazardous Substances List
NJHS = NJ Right-to-Know Hazardous Substances
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
PROP65 = CA Prop 65
SARA311/312 = SARA 311/312 Toxic Chemicals
SARA313 = SARA 313 Title III Toxic Chemicals
TOXICRCRA = RCRA Toxic Hazardous Wastes (U-List)
TSCA = Toxic Substances Control Act
TXAIR = TX Air Contaminants with Health Effects Screening Level
TXHWL = TX Hazardous Waste List
Satety Data Sheet (SDS)
Delta Tech Service, Inc.

SDS Number: 215 DSolv-EX Revision Date: 5/3/2015


Page 10 of 10

16 OTHER INFORMATION

Disclaimer:

The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in
combination with any other material in any process. The information set forth herein is furnished free of charge and is based
on technical data that Delta Tech Service, Inc. believes to be reliable. It is intended for use by persons having technical skill
and at their own discretion and risk. Since conditions of use are outside of Delta Tech Service, Inc.'s control, Delta Tech
Service, Inc. makes no warranties, expressed or implied, and assumes no liability in connection with any use of this
information. Nothing herein is to be taken as a license to operate under, or a recommendation to infringe upon, any patents.

Preparation Information:

GHS Conversion Services


www.ghsconversionservices.com
(414) 336-2546

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