Chemical Principles 5th Edition Atkins Test Bank
Chemical Principles 5th Edition Atkins Test Bank
Chemical Principles 5th Edition Atkins Test Bank
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Chemical Principles 5th Edition Atkins Test Bank
2. Which set of quantum numbers, n, l, ml, could correspond to one of the highest energy
electrons in Zr?
A) 4, 2, 2 B) 4, 2, +3 C) 3, 2, 2 D) 4, 3, 2
Ans: A
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5. What is the only secondary quantum number associated with the 4s orbital?
A) l = 0 D) l = 3
B) l = 1 E) l = 4
C) l = 2
Ans: A
6. What are the possibilities of the spin quantum number for Mg?
A) ms = 1 D) ms = - ½
B) ms = 0 E) Both C and D
C) ms =
Ans: E
10. How many nodes are present in a 3s- and a 3p-orbital, respectively?
A) 2;1 B) 0; 1 C) 0; 2 D) 1; 1 E) 2; 2
Ans: E
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Chapter 2: Quantum Mechanics In Action: Atoms
11. Nodal planes in orbitals can be accounted for by the wavelike behavior of electrons.
Ans: True
15. What shape do the p-orbitals have that each accommodates one nodal plane?
A) A spherical shape.
B) A dumbbell shape centered at the nucleus.
C) A clover leaf shape centered at the nucleus.
D) A clover leaf shape centered above and below the nucleus.
E) A toroidal shape around a dumbbell.
Ans: B
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Chapter 2: Quantum Mechanics In Action: Atoms
20. The three quantum numbers for an electron in a hydrogen atom in a certain state are n =
4, l = 1, ml = 1. The electron is located in what type of orbital?
A) 4s B) 3p C) 3d D) 4d E) 4p
Ans: E
21. The three quantum numbers for an electron in a hydrogen atom in a certain state are n =
4, l = 2, ml = 1. The electron is located in what type of orbital?
A) 4p B) 3p C) 4s D) 4d E) 3d
Ans: D
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Chapter 2: Quantum Mechanics In Action: Atoms
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Chapter 2: Quantum Mechanics In Action: Atoms
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Chapter 2: Quantum Mechanics In Action: Atoms
46. All the following can have the ground-state electron configuration [Xe]4f 145d10 except
A) Pb4+. B) Hg2+. C) Bi5+. D) Tl+. E) Au+.
Ans: D
47. All the following can have the ground-state electron configuration [Kr]4d10 except
A) Cd2+. B) Ag+. C) Pd. D) In+. E) Sn4+.
Ans: D
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Chapter 2: Quantum Mechanics In Action: Atoms
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Chapter 2: Quantum Mechanics In Action: Atoms
1 1310
2 1011
3 418
4 2080
5 947
A) 2 B) 5 C) 3 D) 1 E) 4
Ans: C
59. From the data below, which elements are likely to be nonmetals?
1 1310
2 980
3 418
4 2080
5 947
A) 3 and 5 B) 3 only C) 1 and 4 D) 1 and 2 E) 2 and 5
Ans: C
60. Which of the following is likely to form ions two units lower in charge than expected
from the group number?
A) Tl B) Hg C) Zn D) Se E) Cd
Ans: A
61. Which of the following is likely to form ions two units lower in charge than expected
from the group number?
A) Hg B) Cd C) Sb D) Ge E) Zn
Ans: C
62. Given the elements Cl, Ge, and K and three values of possible first ionization energies,
418, 1255, 784 kJmol1, match the atoms with their first ionization energies.
A) Cl (418), Ge (784), and K (1255 kJmol1)
B) Cl (1255), Ge (784), and K (418 kJmol1)
C) Cl (784), Ge (1255), and K (418 kJmol1)
D) Cl (1255), Ge (418), and K (784 kJmol1)
E) Cl (418), Ge (1255), and K (784 kJmol1)
Ans: B
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Chapter 2: Quantum Mechanics In Action: Atoms
63. If the second ionization energy of copper is 1958 kJ·mol-1, the first ionization energy is
likely to be greater than 1958 kJ·mol-1. True or false?
Ans: False
64. Consider the following ground-state electronic configurations. Which atom has both the
highest first ionization energy and the highest electron affinity?
A) [Ne] 3s23p5 B) [Ne] 3s23p3 C) [Ne] 3s23p1 D) [Ne] 3s23p4
Ans: A
67. Consider the following ground-state electronic configurations. Which atom has the
highest electron affinity?
A) [He] 2s22p5 B) [He] 2s22p3 C) [He] 2s22p1 D) [He] 2s22p4
Ans: A
70. Consider the following ground-state electronic configurations. Which atom has the
lowest first ionization energy?
A) [Ne] 3s23p5 B) [Ne] 3s23p3 C) [Ne] 3s23p1 D) [Ne] 3s23p4
Ans: C
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Chapter 2: Quantum Mechanics In Action: Atoms
72. What are the subshell notation and the number of orbitals having the quantum numbers
n = 4, l = 3?
A) 4d and 5 B) 4p and 3 C) 3f and 7 D) 3d and 5 E) 4f and 7
Ans: E
73. What are the subshell notation and the number of orbitals having the quantum numbers
n = 4, l = 2?
A) 4d and 10 B) 4f and 14 C) 4d and 5 D) 4p and 3 E) 4f and 7
Ans: C
74. Which of the following would be most reactive with air and water?
A) Ba B) Mg C) Ga D) Br
Ans: A
76. Which of the following elements has the least metal character?
A) In B) Ge C) Te D) I E) Tl
Ans: D
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Chapter 2: Quantum Mechanics In Action: Atoms
84. How many nodal planes are expected for 2s and 4f orbitals, respectively?
A) 0 and 4 B) 0 and 3 C) 2 and 4 D) 1 and 4 E) 1 and 3
Ans: B
87. When an electron is added to a gaseous chlorine atom, 349 kJmol1 of energy is
released. What is the ionization energy of a gaseous chloride ion?
Ans: +349 kJmol1
88. Which of the following atoms has the highest electron affinity?
A) Ar B) P C) Al D) Si
Ans: D
89. Because of fluorine’s high electronegativity, less energy is required to make F2 from F
than to make O2 from O. True or false?
Ans: False
90. Which of the following has the largest effective nuclear charge?
A) F
B) Na
C) Li
D) He
E) N
Ans: A
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Chapter 2: Quantum Mechanics In Action: Atoms
95. Which of the following has the largest effective nuclear charge?
A) Al
B) Si
C) P
D) S
E) Cl
Ans: E
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Chemical Principles 5th Edition Atkins Test Bank
98. How many unpaired electrons exist in the ground state of a Cu+ ion?
A) 0
B) 2
C) 1
D) 3
E) 5
Ans: A
99. Which of the following pairs of elements has members with similar properties?
A) B and Si
B) Li and Be
C) Mg and Al
D) Na and Ca
E) Se and I
Ans: A
100. Which of the following pairs of elements has members with similar properties?
A) Mg and Al
B) Li and Be
C) Mg and Ge
D) Na and Ca
E) None of the above.
Ans: E
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