SAFETY DATA SHEET

1. Identification
Important information *** This Safety Data Sheet is only authorised for use by HP for HP Original products. Any
unauthorised use of this Safety Data Sheet is strictly prohibited and may result in legal action
being taken by HP. ***
Product identifier 1CP99Series
Other means of identification
Synonyms HP A30 Orange Water Based Ink
Recommended use of the chemical and restrictions on use
Recommended use Inkjet printing
Restrictions on use Not available.
Manufacturer/Importer/Supplier/Distributor information
Company identification HP Inc.
2501-06, 12-16 & Pt. 07,
Cityplaza One,
1111 King’s Road,
Taikoo Shing,
Hong Kong
Telephone 852-3077-2688

HP Inc health effect line

(Toll-free within US) 1-800-457-4209
(Direct) 1-760-710-0048
HP Inc. Customer Care
Line
(Toll-free within the US) 1-800-474-6836
(Direct) 1-208-323-2551
Email: [email protected]
Telephone +85230772688

2. Hazards identification
Physical hazards Not classified.
Health hazards Sensitization, skin Category 1
Environmental hazards Not classified.

Label elements

Signal word Warning

Hazard statement
H317 May cause an allergic skin reaction.
Precautionary statement
Prevention
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
Response
P302 + P352 IF ON SKIN: Wash with plenty of water.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 + P364 Take off contaminated clothing and wash it before reuse.
Storage Not available.
Disposal

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 P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Other hazards which do not Potential routes of overexposure to this product are skin and eye contact. Inhalation of vapor and
result in classification ingestion are not expected to be significant routes of exposure for this product under normal use
conditions. Complete toxicity data are not available for this specific formulation.
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Hazardous components
Chemical name Common name and synonyms CAS number %
2,4,7,9-Tetramethyl-5-decyne-4,7-di 9014-85-1 <1
ol, ethoxylated
1,2-Benzisothiazolin-3-one 2634-33-5 <0.1
(Benzisothiazolinone)
2-Methyl-2h-isothiazol-3-one 2682-20-4 <0.1
(Methylisothiazolinone)
Alcohols, C11-15-secondary, 68131-40-8 <0.1
ethoxylated
Non-hazardous components
Chemical name Common name and synonyms CAS number %
Water 7732-18-5 85-95
Orange colorant Proprietary <5
Cyclo Amide Proprietary <2.5
Composition comments This ink supply contains an aqueous ink formulation.

4. First-aid measures
Inhalation Move to fresh air. If symptoms persist, get medical attention.
Skin contact Wash affected areas thoroughly with mild soap and water. Get medical attention if irritation
develops or persists.
Eye contact Do not rub eyes. Immediately flush with large amounts of clean, warm water (low pressure) for at
least 15 minutes or until particles are removed. If irritation persists get medical attention.
Ingestion If ingestion of a large amount does occur, seek medical attention.
Most important Not available.
symptoms/effects, acute and
delayed

5. Fire-fighting measures
Suitable extinguishing media Dry chemical, CO2, water spray or regular foam.
Unsuitable extinguishing None known.
media
Specific hazards arising from Not applicable.
the chemical
Special protective equipment Not available.
and precautions for firefighters
Specific methods None established.

6. Accidental release measures

Personal precautions, Wear appropriate personal protective equipment.
protective equipment and
emergency procedures
Methods and materials for Dike the spilled material, where this is possible. Absorb with inert absorbent such as dry clay, sand
containment and cleaning up or diatomaceous earth, commercial sorbents, or recover using pumps.
Environmental precautions Do not let product enter drains. Do not flush into surface water or sanitary sewer system.

7. Handling and storage

Precautions for safe handling Avoid contact with skin, eyes and clothing.
Conditions for safe storage, Keep out of the reach of children. Keep away from excessive heat or cold.
including any incompatibilities

8. Exposure controls/personal protection

Exposure limit values No exposure limits noted for ingredient(s).

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Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines Exposure limits have not been established for this product.
Appropriate engineering Use in a well ventilated area.
controls
Individual protection measures, such as personal protective equipment
Eye/face protection Not available.
Skin protection
Hand protection Not available.
Other Use personal protective equipment to minimize exposure to skin and eye.
Respiratory protection Not available.
Thermal hazards Not available.
General hygiene Handle in accordance with good industrial hygiene and safety practice.
considerations

9. Physical and chemical properties

Appearance
Physical state Liquid.
Form Liquid.
Color Orange.
Odor Not available.
Odor threshold Not available.
pH 8 - 9.5
Melting point/freezing point Not available.
Initial boiling point and boiling Not available.
range
Flash point 288.0 °F (142.2 °C) Pensky-Martens Closed Cup
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Relative vapor density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 1.03 g/cm³
Oxidizing properties Not determined
VOC 12 g/l Method 24

10. Stability and reactivity

Reactivity Not available.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous Will not occur.
reactions
Conditions to avoid Not available.
Incompatible materials Incompatible with strong bases and oxidizing agents.
Hazardous decomposition Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide, carbon
products dioxide and/or low molecular weight hydrocarbons.

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11. Toxicological information
Information on likely routes of exposure
Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard.
Skin contact Contact with skin may result in mild irritation.
Eye contact Contact with eyes may result in mild irritation.
Ingestion Health injuries are not known or expected under normal use.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Components Species Test Results
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) (CAS 2634-33-5)
Acute
Dermal
LD50 Rat > 2000 mg/kg (OECD 402)
Oral
LD50 Mouse 1150 mg/kg
Rat 1020 mg/kg
670 mg/kg (OECD 401)
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated (CAS 9014-85-1)
Acute
Inhalation
LC50 Rat 20 mg/l, 1 h Dusts, mists and fumes. The
data are derived from the evaluations or
test results achieved with similar products
(conclusion by analogy).
Oral
LD50 Rat 6300 mg/kg
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) (CAS 2682-20-4)
Acute
Dermal
LD50 Rat 242 mg/kg (OECD 402)
Inhalation
LC50 Rat 0.11 mg/l, 4 h (OECD 403)
Oral
LD50 Rat 120 mg/kg
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Irritation Corrosion - Skin
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) Corrosive, rabbit (OECD 404)
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) Irritating (4 h, rabbit)
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated Not irritating, The data are derived from the evaluations or
test results achieved with similar products (conclusion by
analogy).
Test Duration: 24 h
Serious eye damage/eye Based on available data, the classification criteria are not met.
irritation
Eye
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) Causes serious eye damage (rabbit)
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) Corrosive, based on OECD 404 results
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated Risk of serious damage to eyes, The data are derived from
the evaluations or test results achieved with similar products
(conclusion by analogy).
Species: Rabbit
Respiratory or skin sensitization
Respiratory sensitization Based on available data, the classification criteria are not met.
Skin sensitization Non-sensitizer- Local Lymph Node Assay (OECD 429).

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 Sensitization
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated May cause sensitization by skin contact.
Skin sensitization
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) Causes sensitization (Guinea pig, OECD 406)
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) Sensitzing, mice (OECD 429), Sensitzing, guinea pigs
(OECD 406)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated Ames (OECD 471), Chromosomal aberration (OECD 473),
gene mutation (OECD 476), negative. The data are derived
from the evaluations or test results achieved with similar
products (conclusion by analogy).
ACGIH Carcinogens
Not available.
Controlled and Prohibited Carcinogens List
Not available.
Reproductive toxicity Based on available data, the classification criteria are not met.
Specific target organ toxicity - Based on available data, the classification criteria are not met.
single exposure
Specific target organ toxicity - Based on available data, the classification criteria are not met.
repeated exposure
Aspiration hazard Based on available data, the classification criteria are not met.
Further information Complete toxicity data are not available for this specific formulation

12. Ecological information

Aquatic toxicity This product has not been tested for ecological effects.
Ecotoxicity
Components Species Test Results
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) (CAS 2634-33-5)
Acute
EC50 Activated sludge 12.8 mg/l, 3 h (OECD 209)
Other EC50 Pseudokirchnerella subcapitata 0.11 mg/l, 72 h OECD (201)
NOEC Pseudokirchnerella subcapitata 0.055 mg/l, 72 h (OECD 201)
Aquatic
Acute
Crustacea EC50 Daphnia magna 4.4 mg/l, 48 h
2.9 mg/l, 48 h (OECD 202)
Fish LC50 Oncorhynchus mykiss 2.15 mg/l, 96 h (OECD 203)
0.8 mg/l, 96 h
2,4,7,9-Tetramethyl-5-decyne-4,7-diol, ethoxylated (CAS 9014-85-1)
Acute
LC50 Scophtalmus maximus (turbot) 52 mg/l, 96 h
Aquatic
Acute
Crustacea EC50 Daphnia magna 88 mg/l, 48 h The data are derived from
the evaluations or test results achieved
with similar products (conclusion by
analogy). (OECD 202)
LC50 Acartia tonsa 166 mg/l, 48 h
Fish LC50 Pimephales promelas 36 mg/l, 96 h The data are derived from
the evaluations or test results achieved
with similar products (conclusion by
analogy). (OECD 203)
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) (CAS 2682-20-4)
Acute
EC50 Activated sludge 34.6 mg/l (DIN 38412-3)
Other EC50 Pseudokirchnerella subcapitata 0.445 mg/l, 120 h (OECD 201)

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 Components Species Test Results
Aquatic
Acute
Crustacea EC50 Daphnia magna 1.68 mg/l, 48 h (OECD 202)
Fish LC50 Rainbow Trout 6 mg/l, 96 h (OECD 203)
Chronic
Crustacea NOEC Daphnia magna 0.0442 mg/l, 21 d (OECD 211)
Fish NOEC Oncorhynchus mykiss 4.93 mg/l, 98 d (OECD 210)
Persistence and degradability Not available.
Biodegradability
Percent degradation (Aerobic biodegradation-ready)
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) 85 %, Not readily biodegradable (OECD 301C)
Test Duration: 63 d
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) 54.1 %, (OECD 301B)
Test Duration: 29 d
Bioaccumulative potential Not available.
Partition coefficient n-octanol / water (log Kow)
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) 0.7 (OECD 117)
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) -0.32 (OECD 107)
Bioconcentration factor (BCF)
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) 6.62, (OECD 305)
Species: Bluegill (Lepomis macrochirus)
2-Methyl-2h-isothiazol-3-one (Methylisothiazolinone) 48.1, Viscera (1972)
Species: Bluegill (Lepomis macrochirus)
5.75, Carcass (1972)
Species: Bluegill (Lepomis macrochirus)
Mobility in soil
Adsorption
Soil/sediment sorption - log Koc
1,2-Benzisothiazolin-3-one (Benzisothiazolinone) 0.97, (OECD 121)
Other adverse effects Not available.

13. Disposal considerations

Disposal instructions Do not dispose of together with general office waste. Do not allow this material to drain into
sewers/water supplies.
Dispose of waste material according to Local, State, Federal, and Provincial Environmental
Regulations.
Ensure collection and disposal with an appropriately licensed waste contractor.
HP's Planet Partners (trademark) supplies recycling program enables simple, convenient recycling
of HP original inkjet and LaserJet supplies. For more information and to determine if this service
is available in your location, please visit http://www.hp.com/recycle.
Waste from residues / unused Not available.
products
Contaminated packaging Not available.

14. Transport information

DOT
UN number Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Not available.
Subsidiary risk -
Packing group Not available.
Environmental hazards
Marine pollutant No
Special precautions for user Not available.
IATA
UN number Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Not available.
Subsidiary risk -

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 Packing group Not available.
Environmental hazards No
Special precautions for user Not available.
IMDG
UN number Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Not available.
Subsidiary risk -
Packing group Not available.
Transport hazard class(es)
Marine pollutant No
EmS Not available.
Special precautions for user Not available.
ADR
UN number Not available.
UN proper shipping name Not Regulated
Transport hazard class(es)
Class Not available.
Subsidiary risk -
Hazard No. (ADR) Not available.
Tunnel restriction code Not available.
Packing group Not available.
Environmental hazards No
Special precautions for user Not available.
Further information Not a dangerous good under DOT, IATA, ADR, IMDG, or RID.

Transport in bulk according to Annex II of MARPOL73/78 and the IBC code: Not applicable.

15. Regulatory information

Safety, health and environmental regulations specific for the product in question
Controlled and Prohibited Carcinogens: Listed substance
Not regulated.
CWC. Chemical Weapons (Convention) Ordinance, Schedules of Chemicals 1-3 (L.N. 62 of 2004, as amended)
Not regulated.
Drug Precursors for Imports and Exports
Not regulated.
Drug Precursors Subject to Conditional Exports
Not regulated.
Listed Substances (Factories and Industrial Undertakings (Dangerous Substances) Regulations, First Schedule, as
amended)
Not regulated.
Narcotics and Psychotropic Substances
Not regulated.
Ozone Depleting Substances (ODS) (Ozone Layer Protection Ordinance, Cap. 403, July 1989)
Not regulated.
Other information .
International regulations HP complies with chemical regulatory requirements in chemical substance notification laws, where
applicable. All chemical substances are notified or exempt from notification or listed in the
inventory as existing substances in the following countries: US (TSCA), Canada (DSL/NDSL),
Australia (AICIS), Japan (ISHL, ENCS), Philippines (PICCS), New Zealand (NZIoC) and China
(IECSC). For guidance on importation and/or additional requirements for registration schemes
such as EAEU, EU, South Korea, Turkey, UK, India and Taiwan, please contact the Sustainability
and Compliance Center ([email protected]).
Stockholm Convention
Not applicable.
Rotterdam Convention
Not applicable.
Montreal Protocol
Not applicable.
Kyoto protocol
Not applicable.

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 Basel Convention
Not applicable.

16. Other information, including date of preparation or last revision

Issue date 01-Jun-2018
Revision date 21-Feb-2023
Version # 07
Disclaimer This Safety Data Sheet document is provided without charge to customers of HP. Data is the most
current known to HP at the time of preparation of this document and is believed to be accurate. It
should not be construed as guaranteeing specific properties of the products as described or
suitability for a particular application. This document was prepared to the requirements of the
jurisdiction specified in Section 1 above and may not meet regulatory requirements in other
countries.

This safety data sheet is meant to convey information about HP inks (toners) provided in HP
Original ink (toner) supplies. If our Safety Data Sheet has been provided to you with a refilled,
remanufactured, compatible or other non-HP Original supply please be aware that the information
contained herein was not meant to convey information about such products and there could be
considerable differences from information in this document and the safety information for the
product you purchased. Please contact the seller of the refilled, remanufactured or compatible
supplies for applicable information, including information on personal protective equipment,
exposure risks and safe handling guidance. HP does not accept refilled, remanufactured or
compatible supplies in our recycling programs.

Revision information 1. Product and Company Identification: EU Poison Centre

Regulatory information: International regulations
Explanation of abbreviations

ACGIH American Conference of Governmental Industrial Hygienists

CAS Chemical Abstracts Service
CERCLA Comprehensive Environmental Response Compensation and Liability Act
CFR Code of Federal Regulations
COC Cleveland Open Cup
DOT Department of Transportation
EPCRA Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
REC Recommended
REL Recommended Exposure Limit
SARA Superfund Amendments and Reauthorization Act of 1986
STEL Short-Term Exposure Limit
TCLP Toxicity Characteristics Leaching Procedure
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
VOC Volatile Organic Compounds

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