Chemistry 120 Fall 2016

Instructor: Dr. Upali Siriwardane

e-mail: [email protected]
Office: CTH 311
Phone 257-4941
Office Hours: M,W,F 9:30-11:30 am T,R 8:00-10:00 am or by
appointment;
Test Dates:
September 23, 2016 (Test 1): Chapter 1,2 &3
October 13, 2016 (Test 2): Chapter 4 & 5
October 31, 2016 (Test 3): Chapter 6, 7 & 8
November 15, 2016 (Test 4): Chapter 9, 10 & 11
November 17, 2016 (Make-up test) comprehensive:
Chapters 1-11
Chapter 2. Measurements in Chemistry
2-1 Measurement Systems
2-2 Metric System Units
Metric Length Units
Metric Mass Units
Metric Volume Units
2-3 Exact and Inexact Numbers
2-4 Uncertainty in Measurement and Significant Figures
Origin of Measurement Uncertainty
Guidelines for Determining Significant Figures
2-5 Significant Figures and Mathematical Operations
Rounding Off Numbers
Operational Rules
2-6 Scientific Notation
Converting from Decimal to Scientific Notation
Significant Figures and Scientific Notation
Multiplication and Division in Scientific Notation
Calculators and Scientific Notation
Uncertainty and Scientific Notation
Chapter 2. Measurements in Chemistry
2-7 Conversion Factors
Conversion Factors Within a System of Units
Conversion Factors between Systems of Units
2-8 Dimensional Analysis
2-9 Density
Density as a Conversion Factor
2-10 Temperature Scales
Conversions Between Temperature Scales
Temperature Readings and Significant Figures
What’s covered in this chapter?
• Science and the scientific method
• Measurements – what they are and what
do the numbers really mean?
• Units – metric system and imperial system
• Numbers – exact and inexact
• Significant figures and uncertainty
• Scientific notation
• Dimensional anaylsis (conversion factors)
 The scientific method
• In order to be able to develop explanations for
phenomena.
• After defining a problem
– Experiments must be designed and conducted
– Measurements must be made
M
E – Information must be collected
T – Guidelines are then formulated based on a pool of
H observations
O
D
• Hypotheses (predictions) are made, using this data, and
then tested, repeatedly.
• Hypotheses eventually evolve to become laws and these
are modified as new data become available
• An objective point of view is crucial in this process.
Personal biases must not surface.
 The scientific method
• At some level, everything is based on a
model of behavior.
• Even scientific saws change because
there are no absolutes.
 Measurements
• An important part of most experiments involves the
determination (often, the estimation) of quantity, volume,
dimensions, capacity, or extent of something – these
determinations are measurements

• In many cases, some sort of scale is used to determine a

value such as this. In these cases, estimations rather
than exact determinations need to be made.
 SI Units

• Système International d’Unités

 Prefix-Base Unit System
Prefixes convert the base units into units that
are appropriate for the item being measured.
Know these prefixes and conversions

3.5 Gm = 3.5 x 109 m = 3500000000 m

So,
and 0.002 A = 2 mA
 Temperature:
A measure of the average
kinetic energy of the particles
in a sample.

Kinetic energy is the energy an

object possesses by virtue of
its motion

As an object heats up, its

molecules/atoms begin to
vibrate in place. Thus the
temperature of an object
indicates how much kinetic
energy it possesses.

Farenheit: oF = (9/5)(oC) + 32 oF
Temperature
• In scientific
measurements, the
Celsius and Kelvin
scales are most often
used.
• The Celsius scale is
based on the
properties of water.
0C is the freezing point of
water.
100C is the boiling point
of water.
 Temperature

• The Kelvin is the SI

unit of temperature.
• It is based on the
properties of gases.
• There are no
negative Kelvin
temperatures.
K = C + 273

0 (zero) K = absolute zero = -273 oC

 Volume
• The most commonly
1 m = 10 dm
used metric units for (1 m)3 = (10 dm)3
volume are the liter (L) 1 m3 = 1000 dm3
and the milliliter (mL). or
0.001 m3 = 1 dm3
A liter is a cube 1
dm long on each These are conversion factors
side.
1 dm = 10 cm
A milliliter is a cube (1 dm)3 = (10 cm)3
1 dm 3 = 1000 cm 3
1 cm long on each
or
side. 0.001 dm3 = 1 cm3

1 m = 10 dm = 100 cm Incidentally, 1 m3 = 1x106 cm3

 Density:

Another physical property of a

substance – the amount of mass per
unit volume

mass
Density does not have an
assigned SI unit – it’s a m
combination of mass and
d=
length SI components.
V volume
e.g. The density of water at room temperature (25oC) is ~1.00 g/mL; at 100oC = 0.96 g/mL
 Density:
• Density is temperature-sensitive,
because the volume that a sample
occupies can change with temperature.
• Densities are often given with the
temperature at which they were
measured. If not, assume a
temperature of about 25oC.
 Accuracy versus Precision
• Accuracy refers to the proximity of a
measurement to the true value of a
quantity.
• Precision refers to the proximity of
several measurements to each other
(Precision relates to the uncertainty
of a measurement).

For a measured quantity, we can generally improve its accuracy by making more
measurements
Measured Quantities and
Uncertainty
The measured quantity, 3.7, is an estimation;
however, we have different degrees of confidence
in the 3 and the 7 (we are sure of the 3, but not
so sure of the 7).

Whenever possible, you should estimate a

measured quantity to one decimal place
smaller than the smallest graduation on a scale.
Uncertainty in Measured Quantities
• When measuring, for example, how much an apple
weighs, the mass can be measured on a balance.
The balance might be able to report quantities in
grams, milligrams, etc.
• Let’s say the apple has a true mass of 55.51 g. The
balance we are using reports mass to the nearest
gram and has an uncertainty of +/- 0.5 g.
• The balance indicates a mass of 56 g
• The measured quantity (56 g) is true to some extent
and misleading to some extent.
• The quantity indicated (56 g) means that the apple
has a true mass which should lie within the range 56
+/- 0.5 g (or between 55.5 g and 56.5 g).
 Significant Figures
• The term significant figures refers to the
meaningful digits of a measurement.
• The significant digit farthest to the right in the
measured quantity is the uncertain one (e.g.
for the 56 g apple)
• When rounding calculated numbers, we pay
attention to significant figures so we do not
overstate the accuracy of our answers.

In any measured quantity, there will be some uncertainty associated

with the measured value. This uncertainty is related to limitations of the
technique used to make the measurement.
 Exact quantities
• In certain cases, some situations will utilize
relationships that are exact, defined quantities.
– For example, a dozen is defined as exactly 12 objects
(eggs, cars, donuts, whatever…)
– 1 km is defined as exactly 1000 m.
– 1 minute is defined as exactly 60 seconds.
• Each of these relationships involves an infinite
number of significant figures following the
decimal place when being used in a calculation.

Relationships between metric units are exact (e.g. 1 m = 1000 mm, exactly)
Relationships between imperial units are exact (e.g. 1 yd = 3 ft, exactly)
Relationships between metric and imperial units are not exact (e.g. 1.00 in = 2.54 cm)
 Significant Figures
When a measurement is presented to you in a problem, you need to know how many
of the digits in the measurement are actually significant.

1. All nonzero digits are significant. (1.644 has four

significant figures)
2. Zeroes between two non-zero figures are
themselves significant. (1.6044 has five sig figs)
3. Zeroes at the beginning (far left) of a number are
never significant. (0.0054 has two sig figs)
4. Zeroes at the end of a number (far right) are
significant if a decimal point is written in the
number. (1500. has four sig figs, 1500.0 has five
sig figs)
(For the number 1500, assume there are two
significant figures, since this number could be
written as 1.5 x 103.)
 Rounding
• Reporting the correct number of significant
figures for some calculation you carry out
often requires that you round the answer to
the correct number of significant figures.
• Rules: round the following numbers to 3 sig
figs
(this would round to 5.48, since 5.483 is closer to
– 5.483 5.48 than it is to 5.49)

– 5.486 (this would round to 5.49)

If calculating an answer through more than one step,

only round at the final step of the calculation.
 Significant Figures
• When addition or subtraction is
performed, answers are rounded to the
least significant decimal place.
Example: 20.4 + 1.332 + 83 = 104.732 = 105

“rounded”
• When multiplication or division is
performed, answers are rounded to the
number of digits that corresponds to the
least number of significant figures in any
of the numbers used in the calculation.
Example: 6.2/5.90 = 1.0508… = 1.1
 Significant Figures
• If both addition/subtraction and multiplication/division are
used in a problem, you need to follow the order of
operations, keeping track of sig figs at each step, before
reporting the final answer.

1) Calculate (68.2 + 14). Do not round the answer, but keep in mind how many sig figs
the answer possesses.
2) Calculate [104.6 x (answer from 1st step)]. Again, do not round the answer yet, but
keep in mind how many sig figs are involved in the calculation at this point.
3) , and then round the answer to the correct sig figs.
 Significant Figures
• If both addition/subtraction and multiplication/division are
used in a problem, you need to follow the order of
operations, keeping track of sig figs at each step, before
reporting the final answer.

Despite what our calculator

tells us, we know that this
number only has 2 sig figs.
Despite what our calculator
tells us, we know that this
number only has 2 sig figs.

Our final answer should

be reported with 2 sig figs.
 An example using sig figs
• In the first lab, you are required to measure
the height and diameter of a metal cylinder, in
order to get its volume
• Sample data: V = pr2h
height (h) = 1.58 cm
diameter = 0.92 cm; radius (r) = 0.46 cm
2 sig figs 3 sig figs
Volume = pr2h = p(0.46 cm)2(1.58 cm)
= 1.050322389 cm3 If you are asked to
report the volume,
you should round your
Only operation here
is multiplication
Answer = 1.1 cm3 answer to 2 sig figs
 Calculation of Density
• If your goal is to report the density of the
cylinder (knowing that its mass is 1.7 g), you
would carry out this calculation as follows:

Then round the answer to the proper

number of sig figs

m 1.7 g g
d  3  1.61855066...
g
V 1.050322389cm cm 3  1.6 cm 3
Please keep in mind that although the “non-rounded”
volume figure is used in this calculation, it is still understood
that for the purposes of rounding in this problem, it contains
only two significant figures (as determined on the last slide)

Use the non-rounded volume figure for the calculation of the density. If a rounded volume
of 1.1 cm3 were used, your answer would come to 1.5 g/cm3
 Dimensional Analysis
(conversion factors)

• The term, “dimensional analysis,” refers to

a procedure that yields the conversion of
units, and follows the general formula:

 Desired _ Units 
Given _ Units   Desired _ Units
 Given _ Units 

conversion factor
 Some useful conversions
This chart shows all metric – imperial
(and imperial – metric) system
conversions. They each involve a
certain number of sig figs.

Metric - to – metric and imperial –

to – imperial conversions are exact
quantities.

Examples:

16 ounces = 1 pound exact

relationships
1 kg = 1000 g
 Sample Problem
• A calculator weighs 180.5 g. What is its
mass, in kilograms?
“given units” are grams, g

 Desired _ Units 
Given _ Units   Desired _ Units
 Given _ Units 

“desired units” are kilograms. Make a ratio that involves both units.
Since 1 kg = 1000g conversion factor is made using this relationship

 Desired _ Units   1kg 


180.5 g  
  180.5 g    0.1805kg
 Given _ Units   1000g 
Both 1 kg and 1000 g are exact numbers
The mass of the calculator has four sig figs. here (1 kg is defined as exactly 1000 g);
(the other numbers have many more sig figs) assume an infinite number of decimal
The answer should be reported with four sig figs places for these
 Dimensional Analysis
• Advantages of learning/using dimensional analysis for
problem solving:
– Reinforces the use of units of measurement
– You don’t need to have a formula for solving most
problems

How many moles of H2O are present in 27.03g H2O?

Sample Probelm
 Sample Problem
• A car travels at a speed of 50.0 miles per hour
(mi/h). What is its speed in units of meters per
second (m/s)? a measured quantity

• Two steps involved here: 0.621 mi = 1.00 km

– Convert miles to meters 1 km = 1000 m
– Convert hours to seconds 1 h = 60 min
1 min = 60 s
 Desired _ Units 
Given _ Units   Desired _ Units
 Given _ Units 

mi  1km   1000m  1h  1 min  m m

50.0     
 22.3653605296...  22. 4
h  0.621mi   1km  60 min  60 s  s s
should be 3 sig figs