SAFETY DATA SHEET

FloGuard

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : FloGuard

Other means of identification : N/A

Recommended use :
Drag Reducing Agent; Friction Reducer

Restrictions on use : For Commercial use only

Company : Drillchem Drilling Solutions, LLC

PO Box 13107
Spring, TX 77393 USA
Office: (281) 713-8941

Emergency telephone : (800) 424-9300 (24 Hours) CHEMTREC

number

Issuing date : 02/14/2018

Section: 2. HAZARDS IDENTIFICATION

GHS Classification This material is considered hazardous by the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
Flammable liquids : Category 2
Skin irritation : Category 2
Eye irritation : Category 2B
Aspiration hazard : Category 1
Reproductive toxicity : Category 2
Specific target organ toxicity : Category 3 Single Exposure, Category 3 Repeated Exposure
Acute Toxicity, Aquatic : Category 2

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Highly flammable liquid and vapor. May be fatal if swallowed and enters
airways. Causes skin irritation. Causes eye irritation. Causes respiratory
irritation. Harmful if inhaled. May cause drowsiness or dizziness. Suspected of
damaging fertility or the unborn child. May cause damage to organs through
prolonged or repeated exposure

Precautionary Statements : Prevention:

Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood.
Do not breathe fumes, mists, vapors or spray. Do not eat, drink, or smoke

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when using this product. Was thoroughly after handling. Keep away from
heat/sparks/open flames/hot surfaces. No Smoking. Keep container tightly
closed. Ground/Bond container and receiving equipment. Use only non-
sparking tools. Keep container tightly closed. Take protective measures
against static discharge. Ground / Bond container and receiving equipment.
Use only non- sparking tools. Use only outdoor or in a well-ventilated area.
Wear protective gloves, protective clothing, eye protection and face protection.
Response:
If swallowed: immediately call a poison center/doctor. Do not induce
vomiting. Store locked up.
If on skin or hair: Take off immediately all contaminated clothing. Rinse skin
with plenty of water or shower. If skin irritation occurs: Get medical
advice/attention. If exposed or concerned: Get medical advice/attention
If in eyes: Rinse cautiously water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. If eye irritation persists: Get medical advice/attention.
If inhaled: removed person to fresh air and keep comfortable for breathing.
If Inhaled: Call a Poison Control Center or doctor / physician if you well
unwell. Rinse mouth. Take off contaminated clothing and wash before
reuse.
In case of fire: use carbon dioxide, dry chemical, alcohol resistant foam,
water spray or fog. If use water, do not use a solid-water-stream as it may
scatter and spread fire.
Storage:
Store in a secure, cool, well-ventilated place.
Disposal:
Dispose of contents/container in accordance with national/local regulations.

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Components Name CAS number Weight %

Alkanes 426260-76-6 20.0 - 70.0

Methylbenzene 108-88-3 20.0 – 40.0
Proprietary Proprietary 10.0 – 30.0
The product contains materials and concentrations considered to be trade secrets.

Section: 4. FIRST AID MEASURES

In case of eye contact : Immediately hold eyelids apart and flush eyes with plenty of water. Remove
contact lenses, if present and easy to do. Continue rinsing. Get medical
attention if irritation develops and persists.
In case of skin contact : Immediately flush skin with plenty of water. Remove contaminated clothing,
including shoes, after flushing has begun. Get medical attention if irritation
develops and persists. Thoroughly wash (or discard) clothing and shoes before
reuse.
If swallowed : Do not induce vomiting. Contact a physician or poison control immediately. If

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vomiting occurs, keep head low so that stomach content doesn’t get into the
lungs.
If inhaled : Call a POISON CENTER or doctor/physician if Inhaled or if you feel unwell. If
breathing is difficult, remove to fresh air and keep at rest in a position
comfortable for breathing. Give oxygen or artificial respiration if needed.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
If it is suspected that fumes are still present, the rescuer should wear an
appropriate mask or self-contained breathing apparatus. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation.

Aspiration Hazard : Aspiration into the lungs can cause severe lung damage and is a medical
emergency. Never give anything by mouth to an unconscious person. Call a
physician or hospital emergency room immediately. If victim is drowsy or
unconscious and vomiting, place on the left side with the head down. If
possible do not leave victim unattended and observe closely for adequacy of
breathing.

Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed

Section: 5. FIREFIGHTING MEASURES

Flamability of product : Flammable Class, OSHA Category: 3

Flash Point 15° F (-9,0°C); Closed Cup

Suitable extinguishing media : Carbon dioxide, Dry chemical, alcohol resistant foam, water spray or fog. Do not
discharge extinguishing waters into the aquatic environment.

Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread fire.
media

Specific hazards during : Sealed containers may rupture when heated.

firefighting

Hazardous thermal :
combustion products May include oxides of carbon (carbon monoxide & carbon dioxide). Avoid
Contact with strong oxidizers which can produce irritating fumes.

Special protective equipment : Wear full protective clothing, including helmet, NIOSH-approved self-
for firefighters contained positive pressure or pressure demand breathing apparatus,
protective clothing and face mask in positive pressure mode. Use water to
cool containers exposed to flames. Prevent human exposure to fire,
fumes, smoke, and products of combustion. Move containers from fire
area if you can do so without risk.

Section: 6. ACCIDENTAL RELEASE MEASURES

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Personal precautions, : No action shall be taken involving any personal risk or without suitable training.
protective equipment and Evacuate surrounding areas. Keep unnecessary and unprotected personnel
emergency procedures from entering. Do not touch or walk through spilled material. Avoid breathing
vapor or mist. Provide adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Put on appropriate personal protective equipment (see
section 8).

Environmental precautions : Prevent further leakage or spillage if safe to do so. Avoid dispersal of spilled
material and runoff and contact with soil, waterways, drains and sewers.

Methods and materials for : Eliminate all ignition sources (no smoking, flares, sparks or flames
containment and cleaning up to immediate area). Stop the flow of material, if this is without risk.
Dike the spilled material, where this is possible.
Prevent entry into waterways, sewer, basements, or confined areas.

Small spill - Stop leak if without risk. Move containers from spill
area. Wipe up with an inert, absorbent material. Clean surface
thoroughly to remove residual contamination. Dispose of via a
licensed waste disposal contractor.
Large spill - Stop leak if without risk. Move containers from spill
area. Approach release from upwind. Dike spill area and do not allow
product to reach sewage system or surface or ground water. Notify
any reportable spill authorities. Contain and collect spillage with non-
combustible, absorbent material such as sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to
local regulations. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as the
spilled product.
Never return spills to original containers for re-use. Clean up in
accordance with all applicable regulations. For waste disposal, see
section 13 of the SDS.

If RQ (Reportable Quantity) is exceeded or if spills enter a body of water, report immediately to the USEPA’s
National Response Center at (800) 424-8802. Check with your local and state regulators regarding their
reporting requirements.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : DANGER. HIGHLY FLAMMABLE LIQUID. Keep away from heat and
sources of ignition. Ground all equipment and container materials. Put on
appropriate personal protective equipment (see section 8). Eating,
drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Workers should wash hands and face before eating and drinking. Do
not ingest. Avoid contact with eyes, skin and clothing. Avoid
breathing vapor or mist. Use only with adequate ventilation. Empty
containers retain product residue and can be hazardous. Do not
reuse container.
Take protective measures against static discharge. Ground / Bond
container and receiving equipment. Use explosion-proof electrical,
ventilating, lighting, and equipment. Use only non-sparking tools.

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Conditions for safe storage : Store in accordance with local regulations. Store in a dry, cool and well-
ventilated area, away from oxidizers and other incompatible materials
(see section 10). Keep container tightly closed and sealed until ready
for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental
contamination.

Suitable material : Keep in properly labelled containers.

Unsuitable material : Not determined

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limits TWA STEL Other

Ingredients: List name ppm mg/m3 ppm mg/m3 ppm mg/m3

Alkanes U.S. ACGIH 400 -- 500 -- 400 1600 --
Methylbenzene U.S. ACGIH 20 -- -- --- 200 -- --
(Skin)

Consult local authorities for acceptable exposure limits.

Only components of this product with established exposure limits appear in the box above.

Engineering measures : A system of local and/or general exhaust is recommended to keep

employee exposures below the Airborne Exposure limits during storage and
operational usage. Local exhaust ventilation is generally preferred because
it can control the emissions of the contaminant at its source, preventing
dispersion of it into the general work area. Eye wash stations and
emergency showers are recommended.

Personal protective equipment

Eye protection : Use chemical safety goggles and/or full-face shield where splashing is possible.
Maintain eye wash station and quick-drench facilities in work area. Safety
glasses with side-shields. If splashes are likely to occur, wear goggles and face-
shield.
Hand protection : Chemical-resistant gloves: Nitrile or Neoprene gloves.

Skin protection : Wear impervious protective clothing, including boots, gloves (Chemical-resistant
Nitrile or Neoprene), lab coat, apron or coveralls, as appropriate, to prevent skin
contact. Closed toe shoes recommended.

Respiratory protection : If the exposure limit is exceeded, an approved full-face piece respirator must be
used. For emergencies or instances where the exposure levels are not known,
use a full-face piece positive- pressure, air-supplied respirator. Air purifying
respirators do not protect workers in oxygen-deficient atmospheres.

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Ensure that eyewash stations and safety showers are close to the

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workstation location. Take off contaminated clothing and wash hands before re-
use. Handle in accordance with good industrial hygiene and safety practice.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Colour : Clear
Odour : Organic Solvent

Flash point : 15 ºF (-9.0 ºC); TAG Closed Cup

pH : Not available
Odour Threshold : Not available
Melting point/freezing point : Not available
Initial boiling point and boiling : 88 – 111ºC (190 – 231ºF)
range
Evaporation rate : Not available
Flammability (solid, gas) : Not available
Upper explosion limit : Upper: 6.7%
Lower explosion limit : Lower: 1.2%,
Vapour pressure : Not available
Relative vapour density : Not available
Relative density : 6.2 lbs./gal
Density : 6.2 lbs./gal
Water solubility : Not available
Solubility in other solvents : Oil Soluble
Partition coefficient: n- : Not available
octanol/water
Auto-ignition temperature : >430F
Thermal decomposition : Not available
temperature
Viscosity, dynamic : Not available
Viscosity, kinematic : Not available
Molecular weight : Not available
VOC : 100%

Section: 10. STABILITY AND REACTIVITY

Reactivity : Not reactive under normal handling and storage condtions.

Chemical stability : Stable when store below 120F.

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Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Heat, sparks and flames.

Incompatible materials : Strong oxidizers, strong acids, strong alkali

Hazardous decomposition : Carbon oxides (carbon monoxide and carbon dioxide) when subjected to
products combustion.

Section: 11. TOXICOLOGICAL INFORMATION

Article I. Acute Toxicity (Component Data);

Product/ingredient name Result Species Dose Exposure
Methylbenzene LD50 Dermal Rabbit 12,196 mg/kg
LD50 Oral Rat 5,580 mg/kg
LC50 Inhalation Rat 49 mg/L 4 hours (vapor)
Alkanes LD50 Dermal Rabbit > 2000 mg/kg
LD50 Oral Mouse 15,000 mg/ kg
LC50 Inhalation Rat 103 mg/L 4 hours (vapor)

Information on likely routes of : Eye contact. Skin contact. Ingestion. Inhalation.

exposure

Potential Health Effects

Eyes : Contact can cause irritation and risk of serious damage to the eyes. Contact
may cause irritation with redness, tearing and pain.

Skin : Harmful if absorbed through the skin. Absorption may result in systemic effects.
Frequent or prolonged contact may defat and dry the skin, leading to discomfort
and dermatitis (rash).

Ingestion : May be harmful if swallowed. Cannot be made non-poisonous. May cause CNS
depression and dizziness.

Inhalation : Do not breathe fumes, mist, vapors, or spray. May cause irritation to the
respiratory tract.

Chronic Exposure : Significant exposure may adversely affect people with chronic diseases of the
respiratory system, skin, and/or eyes. May cause CNS depression and adverse
effects to the kidneys, and even death.

Target Organs : Central Nervous System, Blood, Kidneys, Liver, Eyes, Gastrointestinal
Tract, Lungs, Respiratory System, Mucous Membranes, and Skin.

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Experience with human exposure

Eye contact : Watering and irritation to the eyes.

Skin contact : Repeated or prolonged contact may cause drying, brittleness, cracking and
irritation. Prolonged and repeated contact can product toxic effects.

Ingestion : Irritation, vomiting, and diarrhea.

Inhalation : Irritation to the respiratory system.

Medical conditions : Persons with pre-existing medical conditions of the following organs or organ
aggravated by over exposure systems may be aggravated by exposure to this material: Skin, respiratory
system, central nervous system (CNS). Also, eye problems, or impaired liver,
kidney, blood or respiratory function may be more susceptible to the effects of
the substance.

Toxicity

Product
Acute toxicity : Inhalation: dust, mist: Harmful if inhaled. In high concentrations, vapors are
narcotic and may cause headache, fatigue, dizziness and nausea.
Skin corrosion/irritation : Causes skin irritation.

Serious eye damage/eye : Causes moderate eye irritation.

irritation
Respiratory or skin : Not expected to be a skin sensitizer.
sensitization
Carcinogenicity : This product has not been tested itself.

Reproductive effects : no data available

Germ cell mutagenicity : May cause genetic defects.
Teratogenicity : Contains material reported to cause adverse effects in animal tests.
STOT - single exposure : May cause drowsiness or dizziness. May cause respiratory irritation.
STOT - repeated exposure : no data available
Aspiration toxicity : May be fatal if swallowed and enters airways.

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity
Ingredient name/CAS number Result Species Exposure
Methylbenzene EC50: 6.56 mg/L Daphnia magna (Water flea) 48 hours
LC50: 10-100 mg/L Gambusia affinis (Fish) 96 Hr.
Oncorhynchus mykiss
LC50: 538 mg/L (Rainbow Trout) 96 Hr.

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Alkanes EC50: 1.5 mg/L Daphnia magna (Water flea) 48 hours

LC50: 1 mg/L Carassius auratus (Goldfish) 96 Hr.

Aquatic ecotoxicity: : No data on product itself. Component data is given above.

Persistence and :
Biodegradability Hydrocarbons from this product which do partition to air are
expected to rapidly photodegrade.

Mobility in Soil : Expected to have low mobility in soil.

Other Adverse effects : Toxic to aquatic life with long lasting effects; has potential to
bioaccumulate.

Section: 13. DISPOSAL CONSIDERATIONS

Waste Disposal : Dispose of this material and its container at hazardous or special
waste collection point. Do not allow this material to drain into
sewers/water supplies. Do not contaminate ponds, waterways or
ditches with chemical or used container. This product, in its present
state, when discarded or disposed of, is a hazardous waste according
to Federal regulations.

Disposal should be in accordance with applicable regional, national and local

laws and regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8:

EXPOSURE CONTROLS/PERSONAL PROTECTION for
additional handling information and protection of employees.

Contaminated Packaging : Dispose of in accordance with local, state, and federal regulations. Keep this
product out of sewers and waterways. Empty containers may retain some
product residues. Empty containers should be taken to an approved waste
handling site for recycling or disposal.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance
with the selected mode of transport.

Land transport (DOT)

Proper shipping name : Flammable Liquid, N.O.S. (contains Toluene, Alkanes), 3, UN 1993, PG II
UN/ID No. : UN 1993
Transport hazard class(es) : 3
Packing group : II
DOT Reportable Quantity : Toluene 1,000 l lbs.

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Section: 15. REGULATORY INFORMATION

HCS Classification : Category 2: Flammable Liquid

Category 1: Aspiration Hazard
Category 2: Acute Toxicity Dermal
Category 2B: Eye Irrigation
Category 2: Reproduction toxicity
Category 3: STOT, Single Exposure
Category 3: STOT, Repeated Exposure
Category 2: Acute Toxicity, Aquatic
Category 2: Chronic Toxicity, Aquatic

EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity : Methylbenzene: 1000 lbs

SARA 302 : No chemicals in this material are subject to the reporting requirements
of SARA Title III, Section 302.
SARA 313 : The following components are subject to reporting levels established
by SARA Title III, Section 313: Methylbenzene: 1000 lbs
Superfund Amendments & Reauthorization Act of 1986 (SARA)
Acute Hazard: Yes
Chronic Hazard: Yes
Fire Hazard: Yes
Pressure Hazard: No
Reactivity Hazard: No

US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpart D):
Listed : Yes

Section: 16. OTHER INFORMATION

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NFPA: HMIS III:

Flammability

HEALTH 2
2 FLAMMABILITY 2

Instability
Health

2 0 PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Special hazard.

Revision Date : 02/14/18

Version Number : 1.0

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in the text.

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