24-09-2023 - JR - Super60 - NUCLEUS & STERLING BT - Jee-Adv (2022-P2) - WTA-20&WTA-15 - Key & Sol's

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60_NUCLEUS & STERLING BT WTA-20/WTA-15 Date: 24-09-2023
Time: 09:00AM to 12:00PM JEE-ADVANCE-2022_P2 Max. Marks: 180

KEY SHEET
MATHEMATICS
1 7 2 4 3 9 4 5 5 4 6 6

7 5 8 7 9 ABCD 10 AB 11 BC 12 ABC

13 AC 14 AB 15 B 16 A 17 C 18 A

PHYSICS
19 6 20 5 21 8 22 8 23 7 24 6

25 2 26 4 27 AB 28 B 29 ABC 30 ABC

31 BD 32 AC 33 A 34 C 35 B 36 A

CHEMISTRY
37 7 38 5 39 5 40 7 41 4 42 3

43 5 44 3 45 ABC 46 ACD 47 A 48 BC

49 AC 50 ABCD 51 C 52 B 53 B 54 D
Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

SOLUTIONS
MATHEMATICS
1. Equation of plane passing through (3, 8, 2) and parallel to
3x  2y  2z  15  0 is 3x  2y  2z  21  0 (i)
x   1 

Let general point on line y  4  3 (ii)
z  3  2 
From (i) and (ii)   2
Thus x = 5, y = 11, z = 8
Distance = 7
2. x 3  x 2  4x  4  0
x 2 (x  1)  4(x  1)  0
(x 2  4)(x  1)  0 x  2, 2,1
2
m  2
n 1
4
cos  
9

3. C : r1  (7iˆ  6ˆj  2k)
ˆ   (3iˆ  2ˆj  4k),
ˆ R

D: r2  (5iˆ  3jˆ  4k)
ˆ  (2iˆ  ˆj  3k)
ˆ R

As CD || r  CD  k(2iˆ  2ˆj  k) ˆ
Solving and get   2,   1, k  3
CD  3 22  22  12  9
4. 4x + 7y + 4z + 81 = 0 …(i)
5x + 3y + 10z = 25 … (ii)
Equation of plane passes through inter section of (i) and (ii)
(4x + 7y + 4z + 81)+  (5x + 3y + 10z – 25)
 4  5  x   7  3  y   4  10  kˆ  81 – 25  0 ...(iii)
Plane (iii)  to (i)
So 4  4  5   7  4  3   4  4  10   0
  –1
Put   –1 in …(iii)
– x  4 y– 6 z  106  0 …(iv)
106
Distance of (4) from (0, 0, 0) = k (given)  k  0  k  212
1  16  36

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 2


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s
5. E : r   –1  j  k     i  2 j  0k     i  0 j  k 
i j k

n1 2 0
1 0 1
 i  2 – j 1  kˆ  –2

n  2i – j – 2k
2(x + 4) – 1(y – 2) – 2 (z – 2) = 0
2x – y – 2z + 8 + 2 + 4 = 0
2x – y – 2z + 14 = 0

F : r .  2i – j – 2k   –14

E : r .  2i – j – 2k   –5
 
E F

r   –4i  2 j  2k     2i – j – 2k 
B  –4  2 2 –  2 – 2 


B lie on plane r. 2i – j – 2k ˆ  –5 
2  –4  2  –  2 –   – 2  2 – 2   –5
8  4 – 2   – 4  4  –5
9  9
 1
B  –2,1,0 
A  –4,2,2 C  –3,0, 4
i j k
 
AB  AC  2 –1 –2
1 –2 2
 i  –6  – j  6  – 3k  –6i – 6 j – 3k
1   1
AB  AC  36  36  9
2 2
81 9
 
2 2

 P  2P P  m2P P  n 2P 
6. Centroid  , , 
 2 2m 2n 
k1  k 2  k 3  2

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 3


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

7. OP = h 2  k 2   2  P
DR of OP:
h k 
 , , 
P P P
h k 
Eq. plane in normal from: x y z P
P P P
hx  ky  z  P 2
 P2 
A   , 0, 0 
 h 
 P2 
B   0, , 0 
 k 
 P2 
C   0, 0, 
  
Ar (ABC)  A 2 xy  A 2 yz  A 2 zx
Where: A 2 xy = Area of projection of ABC on xy plane
P2 / h 0 1
1 2 P4
Axy = 0 P /k 1 
2 2 | hk |
0 0 1
P2 P4
Ayz = , Azx =
2 | k | 2 | h |
5
P
Area =
2hk
| AB ||    | a
8.
| OC || r | b
Eq of line OC  r  t r
Eq of line AB =   (  )
(  0)  (  )  r
Shortest distance between them=
| (   )  r |
[ ]
d=
absin 
dabsin  = [ ]
1
v= abd sin 
6
k=6
9. Three planes meet at two points it means they have infinitely many solutions, so
2 1 1
1 1 1  0
 1 3
 2(3  1)  1(3  1)  (1  1)  0  4
P1 : 2x  y  z  1
P2 : x  y  z  2
P3 : 4x  y  3z  5

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 4


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s
P on XOY plane  (1, 1, 0)
(which can be obtained by putting z = 0 in any two of the given planes.) Q on YOZ plane 
 1 3 
 0, , 
 2 2
(which can be obtained by putting x = 0 in any two of the given planes.)
 Straight line perpendicular to plane P3 passing through P is :
x 1 y 1 z
 
4 1 3
 1 3
PQ  iˆ  ˆj  kˆ
2 2

 OP  i ˆ
Projection of PQ on x-axis  =1
| ˆi |
 1 1 1 
Centroid of  OPQ is  , ,  .
3 2 2
     
 | bc | | ca | | a b | 
10. Y = surface area = 2             
 [abc] [abc] [abc] 
 1 1 1 
2      
 | a | cos  | b | cos  | c | cos  
2 1
  4  cos  
cos  2

x  6 y  10 z  14
11.  
5 3 8
General point on above line.
B   5 – 6,3 – 10,8 – 14 
Dr’s of line AB   5 – 6 – 7  ,  3 – 10 – 2  ,  8 – 14 – 4 
 5 – 13,3 – 12,8 – 18
Dr’s of line BC  5,3,8

Since angle between AB & BC is
4
cos 
 5 – 3 5  3  3 – 12  8  8 – 18 
4 2 2
52  32  82 . 5 – 13    3 – 12    8 – 18 
2

1 25  9  64 – 15 – 36 – 144


 
2 2 2
2 98 5 – 13   3 – 12    8 – 18 
After squaring & solving above equation we gert
  3,2
Hence equation of line are
x–7 y–2 z–4
 
2 –3 6
x–7 y–2 z–4 x –7 y –2 z –4
&     
–3 –6 –2 3 6 2

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 5


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

x y z
12. (a, b, c) equation of line AB is  
2 –3 6
Its DR’s are < 2, – 3, 6 >
Let the coordinates be < 2r, – 3r, 6r >
DR’s of PN are < 2r – 1, 3r – 2, 6r – 5 >
It is perpendicular to AB
 2 (2r – 1)– 3(–3r – 2) + 6(6r – 5) = 0
4r – 2 + 9r + 6 + 36r – 30 = 0
26
49r = 26 i.e. r 
49
 52 78 156 
(a) Coordinates of N are  ,– , 
 49 49 49 
(b) Let the coordinates of Q be (2r, – 3r, 6r), then DR’s of PQ are < 2r – 1, – 3r – 2, 6r – 5 >. Since,
PQ is parallel to the plane.
 3  2r – 1  4  –3r – 2  5  6r – 5   0
6r – 3 – 12r – 8  30r – 25  0
3
24r  36, r 
2
 9 
Coordinates of Q are  3, – ,9 
 2 
x –1 y – 2 z – 5
Equation of PN is  
3 –176 –89
13. Plane P1 contains the line

r  ˆi  ˆj  k 
ˆ   ˆi – ˆj– k 
ˆ , hence contains the

Point ˆi  ˆj  k 
ˆ and is normal to vector ˆi  ˆj . 
Hence, equation of plane is.

 r – ˆi  ˆj  kˆ  . ˆi  ˆj  0


Or x + y = 2
Plane P2 contains the line

r  ˆi  ˆj  k  
ˆ And point ˆj
ˆ   ˆi – ˆj – k
Hence, equation of plane is
x – 0 y –1 z – 0
1– 0 1–1 1– 0  0
1 –1 –1
Or x + 2y – z = 2
If  is the acute angle between P1 and P2, then
 
n1.n2
cos     
 
ˆi  ˆj . ˆi  2ˆj – kˆ 
n1 n2 2. 6

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Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

3 3
 
2. 6 2
3 
  cos –1 
2 6
As L is contained in P2    0

14. As L is at a constant distance from P1 and P2, L is parallel to both P1 and P2. If direction ratios of L are
a, b, c then
a + 2b – c = 0
2a – b + c = 0
a –b c
  
2 – 1 1  2 –1 – 4
a b c
  
1 –3 –5
So equation of line L is
x y z
     say 
1 –3 –5
A point on L is  , –3, –5 
Let I  , ,   be foot of perpendicular of P  , –3, –5  on the plane
P1 : x  2y – z  1  0
Then IP is normal to the plane P1. Therefore
 –    3   5
   k  say 
1 2 –1
     k,   2k – 3,   –k – 5
As I lies on P1
   k   2  2k – 3  –  –k – 5   1  0
1
 6k  –1  k  –
6
1 1 1
Thus,    – ,   –3 – ,   –5 
6 3 6
 1 1 1 
 M    – , –3 – , –5     R 
 6 3 6 
 1 1 1
For   0,  – , – ,   M
 6 3 6
1  –5 –2 
And For   ,  0, , M
6  6 3 

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 7


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s
15. Let the line L1 be x = y, z = 1. Any point on this line is of the form (a, a, 1)

Let coordinates of Q be (a, a, 1)


Direction rations of PQ are
 – a,  – a,  – 1.
As PQ  L1
1  – a   1  – a   0   – 1  0
 a  .
Coordinates of Q are  , ,1 .
Direction rations of PQ are 0,0,  – 1 .
Let line L2 be x = – y, z = – 1. Any point on L2 is of the form (b, – b, – 1).
Let coordinates of R be (b, – b, – 1) Direction rations of PR be  – b,   b,   1
As PR  L 2 , we get
1  – b    –1   b   0    1  0
 b  0.
Thus coordinates of R (0, 0, – 1)
Direction ratios of PR are , ,   1
As QP  PR,    1   – 1  0
   –1,1
Reject   1 as for   1 , P and Q coincide.

16. Given points are coplanar,


1 1 1 1
2–x 2 2 1
 0
2 2– y 2 1
2 2 2–z 1
(Volume of the tetrahedron with given vertices is zero)
1 1 1 1
1– x 1 1 0
 0
1 1– y 1 0
1 1 1– z 0
1– x 1 1
 1 1– y 1 0
1 1 1– z

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 8


Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s
1 –1 1 1
R  R 2 – R1 
 x –y 0  0 2
 R 3  R 3 – R1 
x 0 –z
 x  0  y  – z  –y  z y – x   0
x yy zz xx y z
1 1 1
   1
x y z

17. (c) The plane passing through a and containing the line
r  b  c also passes through the point b and is parallel to the vector c,
So, it is normal to the vecotr  a – b   c
Thus, the equation of the plane is
 r – a  . a – b   c  0
 r – a  .a  c – b  c   0
 r.  a  c – b  c   a.  a  c – b  c 
 r.  a  c – b  c   –a.  b  c 
 r.  b  c  c  a  – a b c   0
 Length of the perpendicular form the origin to this plane
0.  b  c  c  a  – a b c 

bc ca


a b c 
bc  ca

18. (a) Let AB = a, AD = b, then AC = a + b


Given, AB1  1a, AD1  2b, AC1   3  a  b 
B1D1  AD1 – AB1   2b – 1a

Since, vector D1C1 and B1D1 are collinear, we have D1C1 = kB1D1 for some k  R .
 AC1 – AD1  k .B1D1
  3  a  b  –  2b  k.   2b – 1a 
  3 a    3 –  2  b  k. 2b – k .1a
Thus,  3  – k 1 and  3 –  2  k  2
– 3  3 – 2
k   1 2  1 3   2 3
1 2
1 1 1
  
 3 1  2
Sec: Jr.Super60_NUCLEUS & STERLING BT Page 9
Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

PHYSICS
19. F = 0.1 + 2Sl
Liquid will have 2 surface in contact with ring

20. Surface Energy = S(ΔA) = S [2 x (5cm)2]


21. Excess pressure is double than first. Hence radius is half of first one.

22. Because of no g, liquid will climb in complete tube and will stop at upper end.

23. Tube of insufficient length.


(Height) x (Radius of curvature) = constant.

24. Let P1 in the broader tube & P2 that in the narrower tube
Pressure just below the meniscus in the
2T
broader tube  P1 –
r1
2T
narrower tube  P2 –
r2
Difference of these pressure is
 2T   2T 
 P1 –  –  P2 – hg
 r1   r2 

1 1
P1 – P2  h  g – 2T  – 
 r1 r2 
P1 – P2  0.2  103  9.8 – 2  72  10 –3
 1 1 

 7.2  10 –4 1.44  10 –3 
P1 – P2  1860 Nm –2

25. Force by liquid on plate is difference of force due to excess pressure inside the drop
and surface tension.
2 D2 D
F  D – 
D 4 2

1 1 1
26. – 
2mm 4mm R

27. Property of liquid surface

28. Conceptual

29. Lami’s Theorem


Sec: Jr.Super60_NUCLEUS & STERLING BT Page 10
Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

30. Force due to pressure


Force on element
dF   p0  gR sin    2R cos   Rd cos  

/2 /2 /2


2 2 3
 Fpr   dF   2p R 0 cos d   2R cos 2  sin d
0 0 0
2 3
p0 R 2gR
 
2 3
Or : Fpr = (pressure at geometrical centre)  (area)
 4R  R 2 p0 R 2 2gR 3
  p0  g   
 3  2 2 3
Force due to surface tension
Fs   surface tension    length   T  2T  Fnet  Fpr – Fs

31. Conceptual

32. Conceptual

33. Soap decreases surface tension of water. The attractive forces between the water
molecules decreases

34. Equating pressure at upper level of liquid 2.


2S
P0 –  2gh  P0  1gh
r

35. Buoyancy (on half displaced liquid) + Surface tension force = weight of drop

36. Equating weight of liquid to surface tension of liquid,


ρπr2Lg = 2 x S (2πr)

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Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

CHEMISTRY

37.

6  3 1 5
38. 5
3

39. Substituent at 2, 3, 4, 5, 6

40. 1+6=7
41. 4
42.

x=4
y=9
z =2
Ans -3

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Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s
CHO, COOH,
43. CONH 2 , COOCH 3
C  N
Ans -5

44. C, D, F are correct

45.
Iso-propyl-3-( 2 -bromo- 3 -hydroxypropylidene) cyclopentane carboxylate

3-Methychlorocarbonyl l-6-(N,N-diethylamino) hex-4-en-1-oic acid

Isoctane

46. IUPAC name is 2-Methylpropane nitrile


Common name
Isobutyronitrile
Isopropyl cyanide

47. (i) Not homologies but functional isomer


(ii) Correct
(iii) Correct
(iv) Correct

48. BC

49.

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Sri Chaitanya IIT Academy 24-09-2023_Jr.S60_NUCLEUS & STERLING BT_Jee-Adv(2022-P2)_WTA-20 & WTA-15_Key & Sol’s

50. ABD

51.

CHO CONH 2
| |
52. CH 3  C H  C H  C CH  C OOH
| 5 4 |3 2 1
6
Br COCl
5-Bromo-3-Carbamoyl-3-chloroformyl-4-formyl hexanoic acid

53.

6 5 4 3 2
54. CH 3  C H  CH 2  C H  C H  COOH
| | |
COOH COOH C H 3
1

2, 3, 5 – Hexanetricarboxylicacid

Sec: Jr.Super60_NUCLEUS & STERLING BT Page 14