Safety Data Sheet: SECTION 1: Identification of The Substance/mixture and of The Company/undertaking

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Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 1 of 9

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


YETI LUBE

Further trade names


Article number:
550-0000
550-0001
550-0001M
550-0006
550-0018
550-0250
550-6018
555-0000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
To insulate gypsum plaster from wax
1.3. Details of the supplier of the safety data sheet
Company name: YETI Dentalprodukte GmbH
Street: Industriestrasse 3
Place: D-78234 Engen
Telephone: +49 7733-9410-0 Telefax: +49 7733-9410-22
Responsible Department: [email protected]
Responsible for the safety data sheet: [email protected]
1.4. Emergency telephone +49 7733-9410-0 (Mo-Do 8:00 - 16:30, Fr 8:00 - 15:00)
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Regulation (EC) No. 1272/2008
Hazard categories:
Skin corrosion/irritation: Skin Corr. 1B
Serious eye damage/eye irritation: Eye Dam. 1
Hazard Statements:
Causes severe skin burns and eye damage.
Causes serious eye damage.
2.2. Label elements
Regulation (EC) No. 1272/2008
Hazard components for labelling
Sodium tetradecyl sulfate
Signal word: Danger

Pictograms:

Hazard statements
H314 Causes severe skin burns and eye damage.
Precautionary statements
P260 Do not breathe mist/vapor/spray.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 2 of 9

P280 Wear protective gloves/protective clothing/eye protection/face protection.


P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international/
regulations.
Additional advice on labelling
Classification in compliance with the assessment procedure specified in the Regulation (EC) no 1272/2008.
2.3. Other hazards
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this product are a
PBT / vPvB substance.

SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
Complex mixture based on: GLYCERIN / Glycerol.
Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
139-88-8 Sodium tetradecyl sulfate 10 - < 25 %
205-380-3
Acute Tox. 4, Acute Tox. 4, Skin Corr. 1B; H312 H302 H314
Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


General information
Remove contaminated soaked clothing immediately.
In case of irritation consult a physician.
After inhalation
Ensure of fresh air. Get medical attention, if respiratory irritation develops or if breathing becomes difficult . In
case of the person being unconscious put him/her in a stable side position.
After contact with skin
Wash off with soap and plenty of water. Consult a doctor if skin irritation persists. Take off contaminated
clothing and wash it before reuse.
After contact with eyes
Remove contact lens. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting. Rinse out mouth and give plenty of water to drink. Never give anything by mouth to an
unconscious person. Summon a doctor immediately. Do not give neutralising liquids.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 3 of 9

4.2. Most important symptoms and effects, both acute and delayed
No data available.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media
Use fire fighting measures that suit the environment and products stored.
5.2. Special hazards arising from the substance or mixture
None
5.3. Advice for firefighters
No specific precautions required.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


High risk of slipping due to leakage/spillage of product. Use personal protection equipment. Keep away
noninvolved persons.
6.2. Environmental precautions
Rinse with plenty of water.
Do not discharge into the drains/surface waters/ground water.
6.3. Methods and material for containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder). Shovel into suitable
container for disposal.
Use explosion-proof equipment / fittings and non-sparking tools.
6.4. Reference to other sections
Observe protective instructions (see Sections 7 and 8).
Information for disposal see section 13.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Advice on safe handling
Do not keep containers unlocked. Observe the minimum standards in accordance with TRGS 500. Handle in
accordance with the general hygienic rules. When using do not eat, drink or smoke. Wash hands before
breaks and at the end of workday. Contaminated work clothing should not be allowed out of the workplace.
Avoid formation of Aerosols.
Advice on protection against fire and explosion
Vapours are heavier than air. In use, may form flammable/explosive vapour-air mixture. Take precautionary
measures against static discharges (earthing (grounding ) at pouring ).
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Provide solvent-resistant and impermeable floor. Provide floor with bunding. Prevent penetration into the
ground. Store in the original container.
Advice on storage compatibility
Keep away from food, drink and animal feeding stuffs. Do not store together with oxidizing and self-igniting
products.
Do not store with: Medicinal product, Substances which form flammable gases with water, Organic peroxides.
Further information on storage conditions
Use only in well-ventilated areas. Keep containers tightly closed in a cool, well-ventilated place.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 4 of 9

7.3. Specific end use(s)


Application in the dental field for insulating gypsum plaster from wax

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

56-81-5 Glycerol, mist - 10 TWA (8 h) WEL


- - STEL (15 min) WEL

8.2. Exposure controls


Appropriate engineering controls
Technical measures and the application of suitable work processes have priority over the use of personal
protective equipment.
Protective and hygiene measures
Avoid contact with eyes and skin. Wash hands before breaks and immediately after handling the product .
When using do not eat, drink or smoke. Take off immediately all contaminated clothing.
Eye/face protection
Tightly fitting goggles (EN 166).
Hand protection
Protective gloves resistant to chemicals made off butyl , minimum coat thickness 0.7 mm, permeation
resistance (wear duration) > 240 minutes, i.e. protective glove <Butoject 898> made by www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN 374
carried out under lab conditions. Requirements can vary as a function of the use. Therefore it is necessary to
adhere additionally to the recommendations given by the manufacturer of protective gloves.
Respiratory protection
Not necessary.
Environmental exposure controls
Do not empty into drains.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Physical state: Liquid
Colour: according to product specification
Odour: Characteristic
Test method
pH-Value (at 20 °C): 9,5 DIN 19268
Changes in the physical state
Melting point: Not determined
Initial boiling point and boiling range: 100 °C
Sublimation point: Not determined
Softening point: Not determined
Pour point: Not determined
Flash point: 160 °C ISO 1523
Sustaining combustion: No data available
Flammability

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 5 of 9

Solid: Not determined


Gas: Not determined
Explosive properties
The product is not explosive. Heating will cause pressure rise with risk of bursting.
Lower explosion limits: 0,9 vol. %
Upper explosion limits: 11,6 vol. %
Ignition temperature: 400 °C
Auto-ignition temperature
Solid: Not determined
Gas: Not determined
Decomposition temperature: Not determined
Oxidizing properties
Not determined
Vapour pressure: 23 hPa
(at 20 °C)
Vapour pressure: Not determined
Density (at 20 °C): 1,12 g/cm³ ISO 2811-1
Bulk density: Not determined
Water solubility: Completely miscible
(at 20 °C)
Solubility in other solvents
Not determined
Partition coefficient: Not determined
Viscosity / dynamic: Not determined
Viscosity / kinematic: Not determined
Flow time: 20 s 6 DIN 53211/4
(at 20 °C)
Vapour density: Not determined
Evaporation rate: Not determined
Solvent separation test: Not determined
Solvent content: 0%
9.2. Other information
Solid content: 16,5%

No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
No decomposition if stored and applied as directed. Heating will cause pressure rise with risk of bursting.
10.2. Chemical stability
Chemically stable.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Avoid temperatures above 35 °C.Protect against direct sun radiation.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 6 of 9

10.5. Incompatible materials


Not known.
10.6. Hazardous decomposition products
No known hazardous decomposition products.

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity
Based on available data, the classification criteria are not met.
The product:
ATEmix/oral: > 2000 mg/kg (Value calculated)
ATEmix/dermal: > 4500 mg/kg (Value calculated)
CAS No Chemical name
Exposure route Dose Species Source Method
139-88-8 Sodium tetradecyl sulfate
oral ATE 500
mg/kg
dermal ATE 1100
mg/kg

Irritation and corrosivity


Causes severe skin burns and eye damage.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Further information
Ingestion of aqueous solution causes gastrointestinal burns.

SECTION 12: Ecological information


12.1. Toxicity
No data available.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB assessment
According to Regulation (EC) No 1907/2006 (REACH) none of the substances, contained in this product are a
PBT / vPvB substance.
12.6. Other adverse effects
No data available.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 7 of 9

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Advice on disposal
This material and its container must be disposed of as hazardous waste. If recycling is not practicable, dispose
of in compliance with local regulations. The waste code number must be agreed with the disposer /
manufacturer.
Waste disposal number of waste from residues/unused products
070601 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease,
soaps, detergents, disinfectants and cosmetics; aqueous washing liquids and mother liquors;
hazardous waste
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken
for reuse.
Contaminated packagings are to be treated like the product itself.

SECTION 14: Transport information

Land transport (ADR/RID)


14.1. UN number: UN 1760
14.2. UN proper shipping name: CORROSIVE LIQUID, N.O.S. (Sodium tetradecyl sulfate)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8

Classification code: C9
Special Provisions: 274
Limited quantity: 5L
Excepted quantity: E1
Transport category: 3
Hazard No: 80
Tunnel restriction code: E
Inland waterways transport (ADN)
14.1. UN number: UN 1760
14.2. UN proper shipping name: CORROSIVE LIQUID, N.O.S. (Sodium tetradecyl sulfate)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8

Classification code: C9
Special Provisions: 274
Limited quantity: 5L
Excepted quantity: E1
Marine transport (IMDG)

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 8 of 9

14.1. UN number: UN 1760


14.2. UN proper shipping name: CORROSIVE LIQUID, N.O.S. (Sodium tetradecyl sulfate)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8

Special Provisions: 223, 274


Limited quantity: 5L
Excepted quantity: E1
EmS: F-A, S-B
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1760
14.2. UN proper shipping name: CORROSIVE LIQUID, N.O.S. (Sodium tetradecyl sulfate)
14.3. Transport hazard class(es): 8
14.4. Packing group: III
Hazard label: 8

Special Provisions: A3 A803


Limited quantity Passenger: 1L
Passenger LQ: Y841
Excepted quantity: E1
IATA-packing instructions - Passenger: 852
IATA-max. quantity - Passenger: 5L
IATA-packing instructions - Cargo: 856
IATA-max. quantity - Cargo: 60 L
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Handle in accordance with good industrial hygiene and safety practice.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
The transport takes place only in approved and appropriate packaging.

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2004/42/EC (VOC): 0%
Information according to 2012/18/EU Not subject to 2012/18/EU (SEVESO III)
(SEVESO III):
National regulatory information
Water contaminating class (D): 2 - clearly water contaminating
15.2. Chemical safety assessment
For this substance a chemical safety assessment has not been carried out.

Revision No: 1,4 GB - EN Print date: 01.02.2018


Safety Data Sheet

according to Regulation (EC) No 1907/2006

YETI LUBE
Revision date: 01.02.2018 Product code: 11294-0002 Page 9 of 9

SECTION 16: Other information

Changes
Update 2018
Abbreviations and acronyms
ADR: Accord européen relatif au transport international des marchandises Dangereuses par Route
(Agreement concerning the international carriage of Dangerous goods by Road)
IMDG-Code: International Maritime Code for Dangerous Goods
ICAO: International Civil Aviation Organisation (IATA: The International Air Transport Association)
GHS: Globally Harmonized System of Classification, Labelling and Packaging of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS-Nr.: Chemical Abstracts Service
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Skin Corr. 1B; H314 Calculation method
Eye Dam. 1; H318 Calculation method

Relevant H and EUH statements (number and full text)


H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
Further Information
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the product
(in this sense consult information on use and on product), but to liberation of major amounts in case of
accidents and irregularities.
The information describes exclusively the safety requirements for the product(s) and is based on the present
level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal
warranty regulations.
(n.a. = not applicable; n.d. = not determined)

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 1,4 GB - EN Print date: 01.02.2018