User Manual

Portamess® 913 pH and

Portamess® 913 X pH
Warranty
Defects occurring within 3 years from delivery date shall be remedied
free of charge at our plant (carriage and insurance paid by sender).
Sensors and accessories: 1 year.

Subject to change without notice.

Return of products
Please contact our Service Team. Ship the cleaned device to the
address you have been given.
If the device has been in contact with process fluids, it must be
­decontaminated/disinfected before shipment. In that case,
please attach a corresponding certificate, for the health and
safety of our service personnel.

Disposal
Please observe the applicable local or national regulations
concerning the disposal of “waste electrical and electronic
equipment”.

Knick
Elektronische Messgeräte
GmbH & Co. KG
Beuckestr. 22
14163 Berlin, Germany
Tel. +49-30-80191-0
Fax +49-30-80191-200
Internet: http://www.knick.de
[email protected]
Changes for Software Version 3
In addition to one- and two-point calibration, the meter can perform a three-
point calibration.
Three-point calibration must be activated in a new configuration step
(3P-CAL On/OFF, see page 20). During calibration, you can stop the proce-
dure after each completed buffer evaluation by pressing the meas key.
Depending on the number of buffer evaluations made, the meter performs a
one-, two-, or three-point calibration.
With three-point calibration the zero and slope are calculated using a mean
straight line (to DIN 19268). Therefore, there is still only one zero point and
one slope for Sensoface® evaluation.
The calibration record has been supplemented by the third buffer.

3
Safety Precautions
Be sure to read and follow these instructions!

If you have to open the Portamess® 913 X pH to change

the batteries, make sure that it is outside the hazardous
area. If repairs are necessary, the meter must be sent in
to the factory.
Never operate the remote interface or printer within a
hazardous area.

Whenever it is likely that the protection has been impaired, the meter shall
be made inoperative and secured against unintended operation.
The protection is likely to be impaired if, for example:

• the meter shows visible damage

• the meter fails to perform the intended measurements

• after prolonged storage at temperatures above 70 °C

• after severe transport stresses

Before recommissioning the meter, a professional routine test shall be

­performed. This test should be carried out at our ­factory.

Information
4
Safety Information
Additional safety notes for ATEX

The Portamess® 91. X pH portable pH meter has been designed and manu-
factured under consideration of the valid European standards and regula-
tions and is suitable for use in areas with an explosion hazard.
Compliance with the European Harmonized Standards for use in hazard-
ous locations is confirmed by the Declaration of Conformity, the EC-Type-
Examination Certificate and the Statement of Conformity / Validity of the
EC-Type-Examination Certificate. These are included in the user manual.
When using the Portamess® 91. X pH portable pH meter, the conditions of
EN 60079-14 “Electrical systems in hazardous areas” must be observed.
Prerequisite to safe use of the equipment is the observance of the specified
ambient conditions and temperature ranges.
Never open the meter inside a hazardous area.

Warning For applications in hazardous locations, only use the

­battery types listed in the table below.
The batteries must be from the same manufacturer and
of identical type and capacity.
Never use new and used batteries together.

Additional safety notes for ATEX

5
Batteries for applications in hazardous locations

Batteries (3 x each) Temp. class Ambient temperature range

Duracell MN1500 T4 –10 °C ≤ Ta ≤ +40 °C

Energizer E91 T3 –10 °C ≤ Ta ≤ +50 °C
Power One 4106 T3 –10 °C ≤ Ta ≤ +50 °C
Panasonic Pro Power LR6 T3 –10 °C ≤ Ta ≤ +50 °C

The batteries listed in the table are used instead of the Varta batteries Type
4006, Type 8006 and Type 3706 listed in the EC-Type-Examination Certificate.
These batteries were tested according to IEC 60079-0:2007, IEC 60079-11:
2006 by a notified body and the test results were set out in an IECEx test
report.
Equipped with the batteries listed in the table, the Model 91. X pH portable
pH meter may be used in hazardous areas.
Be sure to observe the temperature classes and ambient temperature ranges
listed in the table for the different battery types.

Application in hazardous locations of Zone 0

Warning When using the equipment in hazardous locations of
Zone 0, there is a danger of releasing explosive atmo-
sphere and penetration by flames from outside into the
hazardous area Zone 0.

The following should therefore be observed:

The Model ZU 6979 X0 pH/Pt1000 combination electrode, connected to the
pH/temperature measuring loop of the Model 91. X portable pH meter, may
only be used briefly in portable application in containers with Zone 0.
The Model ZU 6979 X0 pH/Pt1000 combination electrode may only be used
for portable application in the hazardous area Zone 0 when the ground
­terminal is connected to the local equipotential bonding (see page 53).
The Portamess® 91. X pH portable pH meter itself (handheld unit) may only
be used in hazardous areas Zone 1.

Application in Hazardous Locations of Zone 0

6
Conventions Used in this Manual

ITALICS are used for texts which appear in the

­Portamess® 913 (X) PH display.
Bold print is used to represent the texts of keys,
e.g. cal.
Display examples

or

keys whose functions are explained are frequently

shown in the left-hand column.

Note Notes provide important information which should

always be observed when using the meter.

Caution Caution means that the instructions given must

always be followed to prevent malfunctions or
­damage to the device.

Warning Warning means that the instructions given must

always be followed for your own safety. Failure to
­follow these instructions may result in injuries.

Conventions Used in this Manual

7
Table of Contents

Safety Precautions.......................................................................... 4
Be sure to read and follow these instructions!.......................................4
Additional safety notes for ATEX..................................................................5
Application in hazardous locations of Zone 0........................................6
Conventions Used in this Manual.................................................. 7
1 The Model 913 (X) pH................................................................. 11
Package contents.............................................................................................11
Intended use / Short description...............................................................11
2 Operation.................................................................................... 13
Meter design......................................................................................................13
Display.................................................................................................................14
Keypad.................................................................................................................14
Sensoface® electrode monitoring..............................................................16
Connection and start-up...............................................................................16
Configuration....................................................................................................18
Calibration..........................................................................................................22
Measurement....................................................................................................27
Data memory.....................................................................................................28
Data logger........................................................................................................29
Clock mode........................................................................................................31
Serial interface..................................................................................................32
Standard settings for ZU 0244 Lab Printer.............................................33
Printing measured values and records....................................................33
3 Troubleshooting......................................................................... 35
Sensoface® electrode monitoring..............................................................35
Error messages..................................................................................................37
4 Maintenance............................................................................... 41
Changing the batteries..................................................................................41
Cleaning the meter.........................................................................................42

Table of Contents
8
Appendix........................................................................................ 43
Accessories.........................................................................................................43
Specifications for Model 913 (X) pH.........................................................44
Specifications for ZU 0244 Printer.............................................................45
EC-Type-Examination Certificate................................................................46
Statement of Conformity..............................................................................49
EC Declarations of Conformity....................................................................50
Connection for Measurement in Hazardous Area Zone 0................53
5 General Information on Measurement..................................... 54
Notes on pH measurement..........................................................................54
Glossary.......................................................................................... 60
Index............................................................................................... 62

Table of Contents
9
10
1 The Model 913 (X) pH

Package contents
Please check the completeness of the shipment after
unpacking.
The package should include:
• Portamess® 913 (X) pH incl. batteries and
sensor quiver
• Carrying strap
• User manual
• Quickstart instructions in German, English and French
• Interface cable incl. adapter
• Paraly® transfer program

Intended use / Short description

• T he Portamess® 913 (X) pH is used for pH and
­temperature measurement in industry, environment,
food processing and waste-water treatment.
• Operation of the Portamess® 913 X pH is also
­permitted in hazardous areas Zone 1.
• The meter meets the EMC requirements of 89/336/
EEC and the recommendations as per NAMUR NE 21.
• The meter is IP 66 protected to EN 60 529 (jet water
from all directions).
• Temperature compensation is automatic with a
Pt 1000 temperature detector, an NTC 30 kΩ (auto-
matic recognition during power-on) or through
manual temperature input.
• Calibration can be carried out with buffer solutions
from various, preselectable buffer sets. The buffer is
then automatically recognized by the Calimatic®.

The Model 913 (X) pH

11
 • You can also calibrate manually by entering individual
buffer values.
• The Sensoface® electrode monitoring system checks the
connected electrode and provides information on its state.
• The data logger records up to 100 measured pH or mV
­values together with temperature, date and time.
Recording can be done either manually, interval- or event-
controlled.
• Only three alkaline AA batteries are required for
­uninterrupted operation for approx. 2,000 hours.
• The Paraly® software allows complete remote control of
the Portamess® 913 (X) pH via PC. All measured values and
parameters can be read out and easily processed further
(e.g. using Microsoft Excel).
• Measured values and meter record can also be sent
­directly to a printer via the serial interface.

Caution Never use the remote interface in hazardous areas!

The Model 913(X) pH

12
2 Operation
Meter design

1 Electrode connection
3 Reference electrode connection
2, 3 Temperature probe connection
4 PC/printer interface connection
5 Sensor quiver

Operation
13
Display
Rinse Electrode Wait, cal timer,
­electrode response electrode response
Stir buffer time
Battery solution
empty Press cal key

Senso­ Measurement
face® units

Temperature
detection using
Clock Pt1000/ NTC
Zero/
slope
Error Read
­message Manual
memory Main ­temperature
Secondary ­display detection
Write display
memory

Keypad
Pressing on/off switches the meter on or off. When
the meter is switched off, one of the Sensoface® status
indicators is visible in the display. After power-on, the
meter automatically performs a self test and checks
which temperature detector is connected. After that, it
automatically goes to pH measuring mode.
Note You can also switch the meter on by pressing meas.
However, in this case only a short test is performed
and the temperature detector is not identified. The
meter assumes that the last temperature detector
identified is used.
Pressing meas returns the meter to measuring mode
from any function. Pressing meas while in measuring
mode selects the desired measured variable (pH or
mV) for the main display.

Operation
14
 For manual temperature specification (no temperature
▲ ▼
detector connected), the temperature is set using
and . These keys are also used to set the clock,
to select the memory locations and to edit selected
parameters.
Pressing cal starts calibration. With calibration, the
meter is adjusted to the electrode. You can choose
between one or two-point calibration either using
Calimatic® automatic buffer recognition or with
­manual buffer entry.
Pressing clock switches the meter into the clock mode.
All measurement processes are canceled and battery
consumption is reduced to a minimum.
Pressing STO activates the data memory for writing
measured values.

Pressing RCL activates the data memory for reading

measured values.

Pressing print sends the currently measured value to a

printer or PC.

Pressing RCL and print prints out the data stored in

memory.

Pressing cal and print prints out the meter record.

Pressing cal + on/off simultaneously when the meter

+ is switched off, opens the configuration menu. Keep
the cal key depressed and then press the on/off key.
Note When pressing two keys at the same time, make sure
that the key shown on the left is pressed first.

Operation
15
Sensoface® electrode monitoring
The Sensoface® automatic electrode monitoring
­system provides information on the electrode state.
Zero point, slope, response time, impedance and
­drying out are evaluated.
In addition, Sensoface® reminds you to regularly
­calibrate the meter.

For more detailed information on the displayed

electrode state and the individual evaluations of the
parameters, please see chapter “Troubleshooting and
Maintenance” (page 35).

Connection and start-up

Sensor Commercially available electrodes with a nominal
­connection ­electrode zero point of pH 7 and the following plugs
can be connected:
– Coaxial standard plug to DIN 19 262
and/or
– 4-mm banana plug.

Connection Connection.................................................. Socket

assignment
Combination electrode..................................................... 1
Single measuring electrode............................................ 1
Single reference electrode............................................... 3
Integrated temperature detector of
combination electrodes.................................................... 2
Separate temperature probe......................................2, 3
Remote interface................................................................. 4

Operation
16
 If no temperature detector has been connected, the
meter operates with the manually set temperature and
man appears in the display.
Note If the Portamess® 913 (X) pH is connected to a PC and
is used to take measurements in grounded liquid,
measuring errors may result.
Note Prior to first measurement, the buffer set to be used
must be selected and the meter calibrated. If required,
the clock must be set.
Start-up With the meter switched-off, one of the Sensoface®
­status indicators is always visible.
Note Even with the meter switched off, the calibration
data and the contents of the data memory remain
­permanently stored.
Pressing on/off switches the meter into measuring
mode. After power-on, the meter determines the con-
nected temperature detector and performs a self test:
• Simultaneous appearance of all display segments,
­symbols and Sensoface® indicators
• Display of Model No. 913
• Display of software version
• Display of selected buffer set
Note The temperature detector is only recognized during
the power-on procedure after pressing on/off.

Note The meter can also be switched on with meas.

However, in this case only a short test is performed
and the temperature detector is not identified. The
meter assumes that the last temperature detector
identified is used.

Operation
17
Configuration
Note If you calibrate using the Knick buffer set, generally you
do not have to change the configuration.
The following basic settings can be changed in the
­configuration:
• Calibration timer interval
• Automatic calibration (Calimatic®) on or off (manual),
buffer set for automatic calibration
• Three-point calibration on or off
• Automatic switch-off
after 1 hour or 12 hours
• Remote interface:
Printer output on/off, baud rate
• Temperature display
°C or °F
• Date and time format
24 hours and day, month, year or
12 hours (am/pm) and month, day, year

To activate the configuration, hold down cal with the

+ meter switched off and then press on/off.
The menu items of the configuration menu are worked
through in sequence.

To change the setting of the respective menu item,

▲ ▼
press or .
Pressing STO switches to the next menu item and
saves the displayed settings.
Pressing meas exits the configuration menu at any time.
The value last displayed and possibly hanged will then
not be saved.

Operation
18
Calibration With the calibration timer, the period of time can be
timer specified within which calibration should occur.
The interval range is 0 to 1,000 hours.
When approx. 80 % of the preset interval has passed,
the calibration timer switches the Sensoface® display
from to . When the total interval has run out, the
display is set to .
The timer is reset with a calibration.
To switch off the calibration timer, enter 0 as the inter-
val. (Factory setting: calibration timer off ).
Automatic You can select whether you wish to calibrate with the
or manual Calimatic® automatic buffer recognition system or with
­calibration manual entry of the individual buffer values.
When calibrating with Calimatic® automatic buffer rec-
ognition (AutCal On), you only have to enter the buffer
set used once in the configuration menu. The buffer
values are stored at the correct temperature. During
calibration the meter then automatically recognizes the
buffer used (factory setting: automatic calibration on,
Knick technical buffers).
Select the buffer set with the buffers used in the buffer
set selection. Various calibration buffer sets are stored in
the Portamess® 913 (X) pH.

The following buffer sets are permanently stored in the

meter:
BUFFER –00– Knick technical buffers
pH 2.00 4.01 7.00 9.21
BUFFER –01– Mettler Toledo technical buffers
(former Ingold)
pH 2.00 4.01 7.00 9.21
BUFFER –02– Merck/Riedel
pH 2.00 4.00 7.00 9.00 12.00
BUFFER –03– DIN 19 267
pH 1.09 4.65 6.79 9.23 12.75
BUFFER –04– Ciba (94)
pH 2.06 4.00 7.00 10.0

Operation
19
 BUFFER –05– NIST
pH 1.68 4.00 7.00 10.01 12.46
BUFFER –06– DIN 19 266 and NIST (NBS)
pH 1.679 4.006 6.865 9.180
BUFFER –07– HACH
pH 4.00 7.00 10.18

Note The meter can only operate properly if the buffer solu-
tions used correspond to the selected, activated buffer
set. Other buffer solutions, even those with the same
nominal values, demonstrate a different temperature
behavior. This leads to measurement errors.
For manual buffer specification (AutCal OFF), the pH
value of the buffer solution must be entered for the
­correct temperature.
This allows calibration using any other buffer solutions.
Three-point You can choose whether you want to perform three-
calibration point calibration in addition to one- or two-point
on/off ­calibration.
With three-point calibration turned on (3P-Cal On), you
can calibrate with a third buffer solution after two-
point calibration has been completed. The sequence of
the buffer solutions is unimportant. With three-point
calibration zero point and slope are calculated using a
mean straight line (to DIN 19268).
With three-point calibration turned off (3P-Cal OFF), only
one- or two-point calibration is possible (default setting:
(3P-Cal OFF).

Operation
20
Automatic To protect the batteries, the meter switches off
switch-off ­automatically when not operated for a longer time.
You can select whether switch-off is to take place after
one hour or after twelve hours (factory setting: 1 hour).
If the data logger is active and during remote interface
operation, the auto switch-off feature is disabled.
Interface If the Portamess® 913 (X) pH is controlled by a PC and
interface conflicts occur when the print key is pressed,
you should deactivate the print function (Print OFF)
(factory setting: Print On, 4,800 bauds).

The transmission speed can be set to 600, 1200, 2400,

4800 or 9600 bauds.
The transmission speed must correspond to that set in
the printer or PC.
Data format and protocol are permanently set to 7 bits,
one stop bit, even parity and XON/XOFF protocol
(NAMUR NE28).
Temperature The temperature can be displayed either in °C or °F
display (factory setting: °C).

Time and date The time and date format can be set to either 24 hours
format and day.month.year or 12 hours am/pm and month.day
(factory setting: 24 hours and day.month.year).

Operation
21
Calibration
By calibration, the pH meter is adjusted to zero point and
slope of the electrode used.
Calimatic® For calibration using Calimatic® automatic buffer recogni-
automatic tion, you only have to enter the buffer set used once in
­calibration the configuration menu. With the patented Calimatic®
system, the meter automatically recognizes the buffer
solutions, calculates the electrode zero point and slope
(based on 25 °C) and carries out the corresponding
adjustment. It does not matter which buffer solution is
taken first.
Note The meter can only operate properly when the buffer
solutions used correspond with the buffer set selected in
the configuration menu.
Other buffer solutions, even with the same nominal val-
ues, may demonstrate different temperature behavior,
which leads to measurement errors.

Pressing cal activates calibration.

Calibration can be exited by pressing meas. If exited prior
to entry of the first calibration point, zero and slope of
the last calibration are displayed for a moment.
Immerse electrode and temperature detector in the first
buffer solution. This can be any of the selected solutions.
Press cal again to calibrate to the first buffer solution.
If you do not want to calibrate, press meas to cancel the
process.

During buffer recognition the lower line indicates the

temperature while the hourglass indicator flashes.

The nominal value of the recognized buffer solution is

displayed for approx. 5 s. Electrode and temperature
detector must remain in the first buffer solution until the
display prompts for the second buffer.

Operation
22
Note The response times of electrode and temperature detec-
tor are considerably reduced if you first move the elec-
trode in the buffer solution and then keep it still to read
the ­values. This provides stable values more quickly.
The electrode stability is checked and the measured mV
value displayed. Stability check can be overridden by
pressing cal. However, this reduces calibration accuracy.

Calibration with the first buffer is complete.

Remove electrode and temperature detector from the
first buffer solution and rinse off both thoroughly.
• If you want to perform one-point calibration, press
meas to terminate the calibration now. The meter then
shows the newly determined zero point in the main
­display and the old slope in the lower display and
returns to pH measuring mode.
• For two-point calibration, immerse the electrode and
temperature detector in the second buffer solution.
Press cal to continue the calibration. The calibration
­process runs again as for the first buffer.
Note Only with three-point calibration turned on (3P-CAL On,
see page 20), the calibration menu offers the possibil-
ity to evaluate a third buffer solution after two-point cali-
bration has been completed.
With three-point calibration turned off (3P-CAL OFF, see
page 20), the calibration procedure is automatically
ended at this point.
With three-point calibration turned on (3P-CAL On), you
can now evaluate a third buffer solution.
• For two-point calibration, press meas to terminate the
calibration. The meter then shows the newly deter-
mined zero point in the main display and the new slope
in the lower display and returns to pH measuring mode.

Operation
23
 • If you want to perform a three-point calibration,
immerse the electrode and temperature detector in
the third buffer solution. Press cal to continue the cali-
bration. The calibration process runs again as for the
previous buffers and is automatically terminated. Zero
and slope are calculated using a mean straight line
(DIN 19268).
At the end of the calibration, the zero point and slope
(based on 25 °C) of the electrode are displayed.
Then the meter switches back to measuring mode.

Manual For calibration with manual buffer entry, you must first
­calibration disable the Calimatic. Then, you must enter the pH value
of the buffer solution used for the correct temperature.
This allows to calibrate with any buffer solution.
Pressing cal activates calibration.
Calibration can be exited by pressing meas. In that case,
zero and slope of the last calibration are displayed for a
moment.
Enter the temperature-corrected pH of your buffer
­solution using and . Press cal to start calibration.
The buffer value set is stored so that you do not have
to enter it for the next calibration (which must be
­performed at the same temperature).
If the temperature has changed, the pH value must be
adjusted before proceeding.
Note The response times of electrode and temperature detec-
tor are considerably reduced if you first move the elec-
trode in the buffer solution and then keep it still to read
the ­values. This provides stable values more quickly.
The electrode stability is checked and the measured mV
value displayed. Stability check can be overridden by
pressing cal. However, this reduces calibration accuracy.

Operation
24
 Calibration with the first buffer is complete.
Remove electrode and temperature detector from the
first buffer solution and rinse off both thoroughly.
• If you want to perform one-point calibration, press
meas to terminate the calibration now. The meter then
shows the newly determined zero point in the main
­display and the old slope in the lower display and
returns to pH measuring mode.
• For two-point calibration, immerse the electrode and
temperature detector in the second buffer solution.
Enter the pH value of the second buffer solution.
Press cal to continue the calibration. The calibration
­process runs again as for the first buffer.
Note Only with three-point calibration turned on (3P-CAL On,
see page 20), the calibration menu offers the possibil-
ity to evaluate a third buffer solution after two-point
­calibration has been completed.
With three-point calibration turned off (3P-CAL OFF, see
page 20), the calibration procedure is automatically
exited at this point.
With three-point calibration turned on (3P-CAL On), you
can now evaluate a third buffer solution.
• For two-point calibration, press meas to terminate the
calibration. The meter then shows the newly deter-
mined zero point in the main display and the new slope
in the lower display and returns to pH measuring mode.
• If you want to perform a three-point calibration,
immerse the electrode and temperature detector in
the third buffer solution. Enter the pH value of the third
buffer solution. Press cal to continue the calibration.
The calibration process runs again as for the previous
buffers and is automatically terminated. Zero and slope
are calculated using a mean straight line (to DIN 19268).
At the end of the calibration, the zero point and slope
(based on 25 °C) of the electrode are displayed.
Then, the meter switches back to measuring mode.

Operation
25
 Converting slope % –> mV/pH
% mV/pH % mV/pH
78 46.2 91 53.9
79 46.8 92 54.5
80 47.4 93 55.1
81 48.0 94 55.6
82 48.5 95 56.2
83 49.1 96 56.8
84 49.7 97 57.4
85 50.3 98 58.0
86 50.9 99 58.6
87 51.5 100 59.2
88 52.1 101 59.8
89 52.7 102 60.4
90 53.3 103 61.0

Operation
26
Measurement
Measuring Pressing meas accesses the measuring mode from all
mode functions. In the measuring mode, the main display
indicates the measured variable and the secondary dis-
play shows the temperature. The measured variable is
selected with meas.
You can choose between the following variables:
• pH
• Electrode potential [mV]

Note The response times of electrode and temperature detec-

tor are considerably reduced if you first move the elec-
trode in the buffer solution and then keep it still to read
the ­values. This provides stable values more quickly.

Manual The man indicator signals that no temperature detec-

temperature tor is connected. The meter operates with the manually
specification specified temperature. The specified temperature can be
edited using and .

Operation
27
Data memory
Up to one hundred measured values can be stored in the
data memory together with temperature, date and time.
Storage is performed either manually or automatically
using the data logger. The currently measured value (pH
or mV) is stored
Write memory
At pressing STO, the currently measured value is shown
in the display (HOLD).
Now you can select any memory location using and .
Press STO to store the measured value in the selected
memory location. After storing, the memory location
number is automatically incremented and the meter
returns to measuring mode.
Read memory
Pressing RCL displays the last measured values stored.
Now you can select any memory location using and .
Pressing RCL switches between the measured value and
time/date of storage. This allows, for example, searching
for a value that was stored at a certain time.
Pressing meas returns to measuring mode.

Clear memory
To clear the entire data memory, press STO to access
memory mode and then clock to access data logger
mode.
Select Clear (Clr) using or .

By confirming this with STO, the entire memory area is

cleared.
If you do not want to clear the memory, press meas to
cancel.

Operation
28
Data logger
Data logger The data logger records up to 100 measured values
together with temperature, time and date. Data storage
is performed either manually (at the press of a key), inter-
val- or event-controlled. The data logger always saves the
­currently measured variable (pH or mV).
Press STO to access memory mode and then clock to
access data logger mode. Now, choose between three
­different recording modes and the parameter setting of
the data logger using or .

Pressing STO confirms the selected mode. In the

Continue and Start mode this also starts the data logger.
The current memory location is shown in the display.
If ”Clear“ has been selected, all memory locations are
cleared and the meter returns to measuring mode.
Pressing meas exits the data logger mode.

Data logging modes

After pressing STO, logging is continued after the
­memory location in which the last measured value was
stored (continue).
Press meas to exit logging.
After pressing STO, the entire data memory is cleared
without starting the data logger (clear).

After pressing STO, the entire data memory is cleared.

Storage begins from memory location “00” (start).
Press meas to exit logging.

Operation
29
Setting the data logger parameters
In the parameter setting mode, you select whether data
logging is to be interval-controlled, event-controlled or
manual. Press STO to access the logging functions.

To select interval-controlled logging of measured values,

press STO and set the interval in which the recording is
to take place using and . The interval range is between
5 seconds and 60 minutes. Default time (factory-set) is
2 minutes. After selecting your interval time, press STO to
enter the value.
With event-controlled data logging, a measured value is
not saved until it deviates from the last memory value by
the preset differential value. Using the time which is also
stored, you can determine when the value has changed.
The differential value is entered in the subsequent
parameter-setting step.
Note The differential value is always based on the currently
set measured variable (pH or mV). This means that if dif-
ferential pH values are to be logged, the meter must be
set to pH measurement prior to parameter setting and
data logging.
With manual data logging, the measured values are saved
by pressing STO.

After selecting the above parameters, select “Continue”

or “Start” using the and keys and then press STO to
commence logging.
Note The data logger does not stop after reaching the last
memory location (99). Recording is automatically contin-
ued with memory location number 00. To avoid losing
data by overwriting, download stored data and clear the
logger before beginning a new set of data. Be aware of
this when using interval-controlled data logging.

Operation
30
Clock mode
Pressing clock activates the clock mode.
The time and date are displayed.
In this mode, the battery consumption of the meter is
reduced to a minimum.
Setting the clock:
To set the time or date, the clock mode must be activat-
ed. Press STO and clock simultaneously to set the clock.
The time display flashes.
The time can be set using and .

When the correct time is displayed, press STO.

Then set the date.

When the correct date is displayed, press STO.

Then set the year.
Press STO to confirm the year. The meter returns to clock
mode.
Press the meas key to return to measuring mode.

Operation
31
Serial interface
Note If the Portamess® 913 (X) pH has been connected to a
PC and measurement are taken in a grounded liquid,
­measurement errors may result.
With the remote interface, you can directly send data to a
printer with serial port or set up a direct connection to a
computer. Via the computer, the meter can be completely
remote controlled and all data and parameters can be
read. Using the printer (e.g. Model ZU 0244), you can
directly print measured values, stored data and records.

Interface The RS 232 interface can be defined for all common baud
parameters rates.
Setting is carried out in the configuration menu
• Baud rate: 600 Bd
1,200 Bd
2,400 Bd
4,800 Bd (default setting)
9,600 Bd
Data format and protocol are permanently set to:
• 7 data bits
• even parity
• one stop bit
• XON/XOFF protocol
Note For the command set of the Portamess® 913 (X) pH, refer
to the online help of the Paraly® transfer software.

Operation
32
Interface cable Only one interface cable is required to operate a
printer or PC. By simply turning the plug around on the
Portamess® 913 (X) pH, the cable can be used to connect
to either a printer or a PC.

Printer PC
Connection assignment

Standard settings for ZU 0244 Lab Printer

Meter Parameter Setting
­configuration Baud rate 4800
Printer On

Printing measured values and records

Note Make sure that the print function is activated in the
­configuration (Print On) and the baud rate corresponds to
that of the printer.
Printing measured values
Press print while in measuring mode to print out the
currently measured value. The measured value is printed
with temperature, date, time and a three-digit identifica-
tion number. The identification number is reset when the
meter is switched off.
Printing the memory
Press RCL and then print to print out the stored data.
All data points are printed with temperature, date, time
and memory location number (Sxx).
Printing individual data points
Press RCL. Select the desired data point using and .
Press print to start printing.

Operation
33
Note If Sensoface® was during data logging, the memory
location will be marked with *, and if the measurement
range (pH, mV, °C) was exceeded, it will be marked with
#.
Printing the record
To print out the meter record, press cal, then print.
The record printout contains:
• a calibration record with the exact data from the last
calibration,
• the settings of the configuration menu,
• a record of the last self-test and
• a list of the current Sensoface® criteria.

Operation
34
3 Troubleshooting
Sensoface® electrode monitoring

The automatic Sensoface® electrode monitoring system

provides information on the electrode state. It evaluates
zero point, slope and response time of the electrode.
In addition, Sensoface® requests calibration at regular
­intervals.

Note Sensoface® is specially designed for monitoring pH

­electrodes.

Note The deterioration of the electrode condition is signified by

or of the Sensoface® indicator (”smiley”).
This evaluation is permanent. An improvement can only
take place after a calibration.
This Sensoface® indicator provides information on the
electrode response time, i.e. on the amount of time an
­electrode requires to supply a stable measured value.
The value is determined during calibration.
Due to wear, aging and as the result of incorrect handling,
e.g. drying out, the swelling layer of the glass membrane
of an electrode may recede. This leads to a longer response
time and the electrode becomes sluggish.
The electrode response is slow. You should consider
maintaining or replacing the electrode. It may be
possible to achieve an improvement by cleaning or,
for an electrode returned to duty after dry storage, by
rehydrating.
The electrode response is very slow. Correct measure-
ment is no longer ensured. The electrode should be
maintained. If appropriate maintenance fails to rem-
edy the situation, the electrode should be replaced.

Troubleshooting
35
 This Sensoface® display provides information on the electrode
zero point and the slope.
Zero and slope of the electrode are still okay, however
the electrode should be maintained or replaced soon.
Zero and/or slope of the electrode have reached values
which no longer ensure proper calibration. It is advisable
to replace the electrode.
Note The zero and slope values are determined during calibration.
Therefore, the condition for accurate information is proper
­calibration. For this reason, always use fresh buffer solutions.
Using the calibration timer, you can set an interval within
which calibration should take place.
The calibration timer continues to run with the meter switched
off.
Zero and slope of the electrode are still okay, however
the electrode should be maintained or replaced soon.
Zero and/or slope of the electrode have reached values
which no longer ensure proper calibration. It is advisable
to replace the electrode.

Troubleshooting
36
Error messages
Sensor If there are problems with a sensor, an error message appears
problems and the measured-value display flashes.
ERROR 1 Problem with the electrode
Possible causes:
• Electrode defective
• Too little electrolyte in the electrode
• Electrode not connected
• Break in electrode cable
• Wrong electrode connected
• Measured pH less than –2 or greater than +16
ERROR 2 Problem with the electrode
Possible causes:
• Electrode defective
• Electrode not connected
• Break in electrode cable
• Measured electrode potential is less than -1,300 mV or
greater than +1,300 mV

ERROR 3 Problem with the temperature detector

Possible causes:
• Temperature detector defective
• Short circuit in temperature detector
• Wrong temperature detector connected
• Measured temperature less than -20 °C or
greater than +120 °C

Note When changing the temperature detector (also for electrodes

with integrated temperature detector), note that the tem-
perature detector type (Pt 1000/NTC 30 kΩ) is only recognized
when the meter is switched on with on/off.

Troubleshooting
37
Calibration If errors occur during calibration, or if the determined elec-
error trode data are outside the valid range, an error message
­messages appears (ERROR 4 ... ERROR 11).

ERROR 4 The electrode zero point determined during calibration is out-

side the permissible range. The zero point is less than pH 6 or
greater than pH 8.
This message appears in measuring mode following a calibra-
tion. It can only be remedied by recalibration with fresh buffer
solutions.
Possible causes:
• Electrode ”worn out“
• Buffer solutions unusable or falsified
• Buffer does not belong to configured buffer set
• Temperature detector not immersed in buffer solution
(for automatic temperature compensation)
• Wrong buffer temperature set (for manual temperature
specification)
• Electrode used has different nominal zero point
ERROR 5 The electrode slope determined during calibration lies outside
the permissible range. The slope is less than 78 % or greater
than 103 %. This message appears in measuring mode follow-
ing a calibration. It can only be remedied by recalibration with
fresh buffer solutions.
Possible causes:
• Electrode ”worn out“
• Buffer solutions unusable or falsified
• Buffer does not belong to configured buffer set
• Temperature detector not immersed in buffer solution
(for automatic temperature compensation)
• Wrong buffer temperature set (for manual temperature
specification)
• Electrode used has different nominal slope

Troubleshooting
38
ERROR 8 The meter has recognized two identical buffer solutions.
This message is only displayed during calibration.
Calibration must be repeated with fresh buffer solutions.
Possible causes:
• Same or similar buffer solution was used for both calibration
steps
• Buffer solutions unusable or falsified
• Electrode defective
• Electrode not connected
• Break or short circuit in electrode cable
ERROR 9 The meter cannot recognize the buffer solution used.
This message is only displayed during calibration.
Calibration must be repeated with fresh buffer solutions.
Possible causes:
• Buffer does not belong to configured buffer set
• Electrode defective
• Electrode not connected
• Break in electrode cable
• Wrong buffer temperature set (for manual temperature
specification)
ERROR 10 During manual calibration, the buffer solutions were not used
in the specified order. Calibration must be repeated.
ERROR 11 Calibration was cancelled after approx. 2 minutes because the
electrode drift was too large.
This message is only displayed during calibration.
Calibration must be repeated with fresh buffer solutions.
Possible causes:
• Electrode defective or dirty
• No electrolyte in the electrode
• Electrode cable insufficiently shielded or defective
• Strong electric fields influencing the measurement
• Major temperature fluctuation of the buffer solution
• No buffer solution or extremely diluted

Troubleshooting
39
ERROR 14 If the clock has not been set, e.g. after battery replacement,
this error message is displayed. To clear the message, set the
clock (see page 31).
ERROR 15 If errors occur during transmission via the RS 232 interface, this
error message appears.
This message will not occur if ”Printer On“ is configured.
Possible causes:
• No valid end character transmitted (receiver overflow)
• Wrong transmission rate (baud rate) set (see page 21)
• Error during transmission
• Wrong data format (see page 21) e.g. parity bit

ERROR 18 If the meter detects an error during the self-test, this error
message appears.
Possible causes:
• Configuration or calibration data are defective.
Completely reconfigure and recalibrate the meter.
ERROR 19 Error in the factory settings or system memory.
FAIL appears in the display.
Possible causes:
• EPROM or RAM defective
• Error in meter factory settings

Note This error message should normally not occur as the data are
protected from loss by multiple safety functions.
Should this error message nevertheless appear, no remedy is
available. The meter must be repaired and recalibrated at the
factory.

Troubleshooting
40
4 Maintenance
Changing the batteries

When the battery symbol appears in the display, the

­batteries need replacement. However, you can still use the
meter for a few days. When the battery voltage continues
to drop, the meter will switch itself off. (Since battery con-
sumption is higher when the remote interface is used, the
battery ­symbol is displayed earlier in that case.)
Never change the batteries within a hazardous area.
Use only the batteries specified on page 6.
Make sure that the meter is carefully closed again and that
the protective cover is properly mounted on the meter after
changing the batteries (see also “Additional safety notes for
ATEX“, page 5).
To replace the batteries, you need 3 alkaline AA cells and a
screwdriver (either straight-blade or Philips).
• Close the protective cover and remove the sensor quiver.
• Lift the hook, unscrew the four screws on the back of the
meter and remove the lid.
• Remove the old batteries from the battery holder.
• Insert the new batteries in the specified direction.
• Make sure the protective cover is in the notches provided
and the rubber seal is correctly seated, especially near the
pH socket.
• Remount the lid and secure it with the screws.
Be sure to tighten the screws thoroughly.
• Remount the sensor quiver.

Note When changing the batteries, all calibration and configu-

ration data are retained. The calibration timer runs out.
Time and date must be reset. The meter switches to pH
measurement (as does the event-controlled data logger).
The current memory location is set to 00.

Maintenance
41
Caution If you want to store the meter for a longer time,
the batteries must always be removed beforehand.
Leaky batteries may damage the meter.

Cleaning the meter

To remove dust and dirt, the external surfaces of the meter
may be cleaned with water, and also with a mild household
cleaner if necessary.

Caution Beware of electrostatic charging when using the meter in

hazardous areas!
For example, never wipe the meter with a dry cloth.

Maintenance
42
Appendix
Accessories
Ref. No.
Printer ZU 0244
Printer paper (5 rolls) ZU 0249
Printer ribbon (5 ribbons) ZU 0250
Sensor quiver, 5 pieces (for leak-proof storage ZU 0262
of pH sensor)
Calibration buffer set with 250 ml each of ZU 0261
Knick technical buffer solutions pH 4, 7, 9
and KCl
Knick technical buffer pH 4 (set of 30 bags for ZU 0263
one calibration each)
Knick technical buffer pH 7 (set of 30 bags for ZU 0264
one calibration each)
Knick technical buffer pH 9 (set of 30 bags for ZU 0265
one calibration each)
KCl solution, 250 ml ZU 0062
Sensors pH/Pt 1000 combination electrode SE 101N
Body: plastic, 110 mm
pH/Pt 1000 combination electrode SE 102N
Body: glass, 110 mm
pH combination puncture electrode SE 104N
Body: plastic, 99 mm
Pt 1000 temperature probe ZU 0156

Appendix
43
Specifications for Model 913 (X) pH

Ranges pH: –2.00 to +16.00

mV: –1,300 to +1,300
°C: –20.0 to +120.0
Display LC display 35 x 67 mm, character height 15 mm
Measurement cycle Approx. 1 s
Measurement error pH: < 0.01
(+ 1 count) mV: < 0.1 % meas. value + 0.3 mV
°C: < 0.3 K
Input DIN 19 262
Input resistance > 1 x 1012 Ω
Input current < 1 x 10–12 A
(20 °C)
Electrode Calimatic® automatic calibration with automatic buffer
­standardization ­recognition (German patent 29 37 227)
Manual electrode standardization
Meter and electrode Sensoface®: evaluates the calibration interval, zero point,
monitoring electrode slope, response time and glass
­impedance of the electrode, optical indication
good/average/poor
Calibration timer: monitors the calibration intervals,
configurable from 1 to 1,000 hours,
can be disabled
Meter self test: during power-on
Temperature Pt 1000 / NTC 30 kΩ (automatic recognition during power-on)
­compensation or manual
Data memory 100 memory locations: pH/mV, temp, time, date
Data logger Manual, interval- or event-controlled
Remote interface Serial RS 232 interface, bidirectional, asynchronous, baud rate
user-definable, can be used as either printer or computer interface
Data retention Configuration and calibration data >10 years
Auto switch-off After either 1 or 12 hours

Appendix
44
EMC Emitted interference: EN 61326 Class B
Immunity to interference:
EN 61326, EN 63326/A1 and NAMUR NE 21
Explosion protection II 2(1)G Ex ia IIC T3/T4 Ga, PTB 01 ATEX 2162 X
(913 X pH only)
Ambient Operation: –10 to +50 °C (T3)
temperature –10 to +40 °C (T4)
Transport and storage: –20 to +70 °C
Power supply 3 AA (LR 6) batteries, alkaline-manganese
For hazardous-area applications:
Temperature class T4 (–10 ... +40 °C): Duracell MN1500
Temperature class T3 (–10 ... +50 °C):
Energizer E91, Power One 4106, Panasonic Pro Power LR6
See page 6
Operating time approx. 2,000 h1), clock mode > 2 years
Enclosure Material: PA, IP 66 protected, with integrated sensor quiver
Dimensions 133 x 160 x 30 mm (w x h x d)
Weight Approx. 560 g including batteries

1) Due to storage, the service life of the included batteries may be shorter.

Specifications for ZU 0244 Printer

Printer type Matrix printer
Interface Serial RS 232 interface
Paper Normal paper, width 57.5 mm (2.25 inches)
Data transfer Baud rate: 4,800 bauds, data bits: 7, stop bits: 1, parity: even,
protocol: no
Power supply 230 V AC ± 10 %
Dimensions 197 x 73 x 153 mm (w x h x d)
Weight Approx. 1.2 kg including plug-in power pack

Appendix
45
EC-Type-Examination Certificate
46
EC-Type-Examination Certificate
47
EC-Type-Examination Certificate
48
Statement of Conformity
49
EC Declarations of Conformity
50
EC Declarations of Conformity
51
52
 Anschluß
Connection

Equipotential bonding cable

from ZU6979X0
beim

Portamess 913 X pH
Cable length max. 3 m
for Measurement

ZU 6979X0
Equipotential bonding pH/Pt1000 combination
electrode

Zone 1 Zone 0

Fluid level
Einsatz im Gefahrenbereich

Portamess
Portamess 913
913 XXpH
pH
in Hazardous Area
Zone
Zone
0 0

Measurement in Hazardous Area Zone 0

53
5 General Information on Measurement
Note The chapter “General Information on Measurement”
provides a summary of the most important points to
be observed during pH measurement. You can skip this
chapter if you are sufficiently familiar with the practice of
pH measurement.

Notes on pH measurement
General Two electrodes, a glass electrode and a reference elec-
­information trode, are required for electrometric pH measurement.
They are usually offered combined in a glass or plastic
body as a so-called combination electrode.

During pH measurement, simultaneous temperature

detection is required. For a correct pH value, you must
always specify the respective measurement temperature,
e.g. pH25°C = 7.15.
Using a temperature detector together with the elec-
trode allows to optimally use the advantages of the
microprocessor-controlled pH meter. Combination elec-
trodes with integrated temperature detector, e.g. Model
SE 101N or SE 102N, are particularly advantageous.
Calibration and The measuring characteristics of pH electrodes are dif-
­measurement ferent for each electrode, are variable and temperature-
dependent. Therefore, the meter must be adjusted to the
characteristics of the current electrode. This process is
called calibration.

For calibration, you take measurements of buffer solu-

tions. These are solutions with exactly defined pH values.
The Portamess® 913 (X) pH provides two calibration
modes: automatic calibration using Calimatic® and
manual ­calibration.

Information on Measurement
54
Calimatic® In the Portamess® 913 (X) pH, the table values of various
automatic buffer sets are stored for the correct temperatures. Simply
­calibration select and enter the buffer set once during initial start-up
(see page 20). Then, the patented Calimatic® will cali-
brate the meter at the press of a key.
Calibration is conducted with two different buffer
­solutions from the selected buffer set. The sequence of
­buffers is irrelevant. The pH meter measures the electrode
voltages and the temperatures and compares them with
the programmed pH temperature tables for the buffer
solutions. From the measured values, the meter calcu-
lates the zero point and slope of the electrode. This type
of calibration with two buffer solutions is a two-point
­calibration.
For a one-point calibration, only one buffer solution is
used and the calibration process is discontinued after the
first calibration step. Only zero point is adjusted.
The previous slope value is retained.
The Portamess® 913 (X) pH also allows performing a
three-point calibration. Here, three buffer solutions are
required. Zero point and slope are calculated using a
mean straight line (to DIN 19268).
Note The buffer solutions used for calibration must always
­correspond to the buffer set selected in the meter.

Manual If you want to work with special buffer solutions not

­calibration included in the stored buffer sets, select manual calibra-
tion (see page 19). Here, you enter your individual
buffer value at the correct temperature (pH at calibration
temperature). Values entered once remain stored. During
the next calibration the meter will suggest these values.
That means you do not have to enter the values once
more provided that the sequence of the last calibration
is retained.
Note Make sure that the buffer values are entered for the
proper temperature. Do not enter the nominal buffer
value but instead the pH of the buffer solution at the
­calibration temperature.

Information on Measurement
55
Calibration The calibration interval is highly dependent on the condi-
intervals tions under which measurements are taken. As a result,
no generally valid interval can be given here.
However, the calibration can be repeated frequently at
the beginning. If the calibration values (electrode zero
and slope) show only minor differences, the time between
calibrations can be increased.
For measurements under constant conditions, weekly
calibration may be sufficient. On the other hand, calibra-
tion may be necessary prior to each measurement when
measuring in media with large temperature or pH differ-
ences. For monitoring the calibration interval, you should
configure the calibration timer (see page 19).
Observe the • For electrodes with liquid electrolyte, open the KCl fill-
following: ing hole for calibration, measurement and cleaning.
• Immerse the electrode in the buffer solution ensuring
that the junction is completely immersed.
• Electrode response time is considerably reduced if you
first move the electrode in the buffer solution and then
keep it still to read the values.
• Always rinse the electrode with deionized water before
immersing it in the buffer solution.
• If you calibrate without a temperature detector, make
sure that the manually set temperature matches the
actual temperature of the buffer solutions and the
­substance to be measured.
Note For additional information, refer to the electrode
­instruction manual.

Information on Measurement
56
 Design of a combination electrode with liquid electrolyte:

filling hole

reference electrolyte

junction

glass membrane

Buffer Two buffer solutions are required for a two-point calibra-

­solutions tion. The pH values of the buffer solutions should differ by
at least two pH units and bracket the expected measured
value.

Note To ensure measurement accuracy, the buffer solutions

should be fresh.
• Therefore, never pour used buffer solution back into the
storage container. Never use used buffer solution.
• Never immerse the electrode directly in the storage
container.
• Always keep the storage container closed. The carbon
dioxide from the air can lead to incorrect buffer solution
values.

Note The problems described above can be avoided by using

buffer bags (see Accessories on page 43).

Note Make sure that the buffer values are entered for the
­proper temperature. Do not enter the nominal buffer
value but instead the pH of the buffer solution at the
­calibration temperature.

Information on Measurement
57
Electrodes Today, combination electrodes are commonly used due
to the simpler handling involved. When using individual
electrodes, make sure that they are connected to form a
symmetrical system:
• The dissipation systems of glass and reference elec-
trodes have the same potential (e.g. both Ag/AgCl, KCl
3 mol/l, AgCl saturated or both “calomel“, KCl saturated).
• Only combine Thalamide glass electrodes with
Thalamide reference electrodes.
The nominal zero point of commercially available
­electrodes is pH 7.

Note For additional information, refer to the appropriate

­electrode instruction manual.

Electrode care Proper cleaning and care increases electrode service

life and measurement accuracy. Therefore, you should
observe the following points:
• When not in use, store electrodes in KCl solution (refer-
ence electrolyte). Never store them dry. For a few hours
the electrode can also remain in the sensor quiver,
­without liquid.
• Soak dry electrodes in KCl solution for up to 12 hours
prior to initial use.
• For electrodes with liquid electrolyte, open the KCl
­filling hole for calibration, measurement and cleaning.
• Make sure the electrolyte in the electrode is always at
least 2 cm (1”) higher than the medium to be measured.
Top up the KCl solution if necessary. Use the KCl solu-
tion specified by the manufacturer. For example, for
the SE 102N electrode use only KCl solution 3 mol/l
­(contained in calibration buffer set).
To remove grease or oil, you can use hot water and a
household dishwashing liquid; strong pollutions can
­carefully be removed using household scouring agent.

Information on Measurement
58
 Protein contaminations can be removed by soaking the
electrode in a pepsin-hydrochloric acid solution (elec-
trode cleaner) for one hour.
• Do not rub the electrode dry with a cloth or fleece, as
this will cause electric charging which may later result in
incorrect measurements or even make them impossible.

Temperature The temperature compensation takes the tempera-

compensation ture dependency of the electrode slope into account.
Reference temperature for zero and slope of the meter
is 25 °C. The pH of the medium to be measured is also
temperature-dependent. This temperature dependence
is unknown and depends on the composition of the mea-
sured medium. As a result, this temperature dependence
cannot be compensated. Therefore, always indicate the
measuring temperature together with the pH (observe
when comparing measured pH values!).

Note In the case of a major temperature difference between

the calibration and measuring temperature, an additional
temperature effect on the electrode zero may affect the
electrode performance. These effects are not subject to
any general rules (in contrast to the temperature depen-
dence of the slope). To achieve a particularly high degree
of measurement accuracy, this error can be eliminated by
calibrating at the measuring temperature (recommended
by DIN 19268). The temperature dependence of the
­calibration buffer pH values is automatically taken into
consideration during calibration with Calimatic®.

Information on Measurement
59
Glossary
Auto ­switch-off To protect the batteries, the meter switches off automati-
cally when not operated for a longer period. Switch-off
can take place after either one hour or twelve hours.
When data logger or remote interface are active, the auto
switch-off feature is disabled.
Buffer set Contains selected buffer solutions which can be used for
automatic calibration with the Knick Calimatic®.
The buffer set must be selected prior to initial calibration.
Buffer ­solution Solution with an exactly defined pH for calibrating a pH
measuring instrument.
cal Key for activating calibration.
Calibration Adjustment of the pH measuring unit to the current
electrode characteristics. The zero point and slope are
adjusted. Either a one or two-point calibration can be
­carried out. With one-point calibration only the zero
point is adjusted.
Calibration See buffer set.
buffer set
Calimatic® Automatic buffer recognition. Before the first calibration,
the buffer set used must be activated once. The patented
Calimatic® then automatically recognizes the buffer
­solution used during calibration.
Combination Combination of glass and reference electrode in one
electrode body.
Data logger The data logger records up to 100 measured values (pH
or mV) together with the temperature, date and time
in the data memory. Recording takes place either inter-
val- or event-controlled (measured-value difference) or
­manually at the press of a key.
Data memory Up to 100 measured values (pH or mV) can be stored in
the data memory together with temperature, time and
date.
Electrode slope Is indicated in % of the theoretical slope (59.2 mV/pH at
25 °C). The electrode slope is different for every electrode
and changes with age and wear.

Glossary
60
Electrode zero The voltage which a pH electrode gives off at a pH of 7.
point The electrode zero point is different for every electrode
and changes with age and wear.
GLP Good Laboratory Practice: Rules for conducting and
documenting measurements in the laboratory.
meas This key is used to return to measurement mode from all
other levels. In measuring mode it switches between mV
and pH.
NAMUR German committee for measurement and control
­standards in the chemical industry…
One-point Calibration with which only the electrode zero point is
­calibration taken into consideration. The previous slope value is
retained. Only one buffer solution is required for a one-
point calibration.
pH electrode A pH electrode system consists of glass and reference
system electrode. If they are combined in one body, they are
referred to as combination electrode.
Response time Time from the start of a calibration step to the
­stabilization of the electrode potential.
Sensoface® Automatic electrode monitoring. The Sensoface® indica-
tors provide information on the status of the electrode
and the meter. Calibration interval, zero, slope and
response time of the electrode are evaluated.
Slope See electrode slope.
Three-point Calibration in which the electrode zero and slope are
calibration taken into consideration. Three buffer solutions are
required for three-point calibration.
Zero point and slope are calculated using a mean straight
line (to DIN 19268).
Two-point Calibration in which the electrode zero and slope are
­calibration taken into consideration. Two buffer solutions are
required for two-point calibration.
Zero point See electrode zero point

Glossary
61
Index Connecting the sensors 16
Connections, overview 13
35
Converting the slope values 26
A D
Accessories 43 Data logger 29
Approvals 45 Data logger, configuration 30
Automatic calibration 22 Data memory 28
Automatic calibration, Data memory, printout 33
configuration 19
Date format 21
Automatic switch-off, configuration
21 Date, setting 31
Declaration of Conformity 50
B
Batteries for hazardous-area Diagnostics, Sensoface 35
­applications 5 Display 14
Battery replacement 41 Disposal 2
Baud rate, setting 21 E
Buffer handling 57 EC Declaration of Conformity 50
Buffer selection 19 EC-Type-Examination Certificate 46
Buffer sets 19 Electrode care 58
C Electrode connection 16
Calibration error messages 38 Electrode monitoring in brief 16
Calibration, general information 54 Electrode monitoring, smileys 35
Calibration mode 22 Electrodes, general 58
Calibration timer, configuration 19 Error messages 37
Calimatic automatic calibration 22 Event-controlled logging 30
Certificate of Conformity 46 Explosion protection 5
Changing the batteries 41 G
Cleaning the electrode 58 General information on measurement
Cleaning the meter 42 54
Clear memory 28 Glossary 60
Clock mode 31 H
Combination electrode 57 Hazardous-area application 5
Computer cable 33 Hazardous-area application, Zone 0 53
Configuration 18
Index
62
I Printing measured values 33
Icons 14 Printing the memory 33
Intended use 11 Printing the record 34
Interface cable 33
R
Interface conflicts 21 Read memory 28
Interface parameters 32 Record printout 34
Interval-controlled logging 30 Remote interface 32
K S
Keypad 14 Safety precautions 4
M Safety precautions for hazardous areas
Maintenance 41 5
Manual calibration 24 Saving measured values 28
Manual calibration, configuration Sensoface electrode monitoring in
19 brief 16
Manual data logging 30 Sensoface messages 35
Manual temperature specification Sensor connection 16
27 Sensor problems 37
Measuring mode 27 Sensor references 43
Memory function 28 Serial interface 32
mV measurement 27 Short description 11
O Slope values 26
One-point calibration, automatic 23 Socket assignment 16
One-point calibration, manual 25 Specifications 44
Operation 13 Start-up 17
Order information 43 Statement of Conformity 49
P Storing the meter 42
Package contents 11
T
Paraly software 12 Technical data 44
pH measurement, general 54 Technical terms 60
Plugs 16 Temperature compensation 59
Printer cable 33 Temperature display °C / °F 21
Printer settings 33 Temperature, manual 27
Printer specifications 45 Temperature probe connection 16

Index
63
Three-point calibration, automatic
23
Three-point calibration,
­configuration 20
Three-point calibration, manual 25
Time format 21
Time, setting 31
Troubleshooting 35
Two-point calibration, automatic 23
Two-point calibration, manual 25
W
Warranty 2
Write memory 28
Z
Zone 0 connection 53
Zone 0, precautions 6

Index
64
65
66
 TA–193.104–KNE06 20160623 Software version: 3.x
091400