Solution of Model Test Paper-1 Chemistry (Class XI)

Solutions AY2021-22

of
Model Test Paper-1
For School/Board Exams (Term-II)

CHEMISTRY
Topics: States of Matter: Gases and Liquids, Chemical Thermodynamics, Equilibrium, s-Block Elements, Some p-Block
Elements, Hydrocarbons

SECTION-A

Ans. 1. (a) [OH]= 2 × 10 −2 M

pOH = – log(2 × 10–2) [½]
= 2 –log2 = 1.7
pH = 14 – 1.7 = 12.3 [½]
(b) • Species which accepts electron pair is called Lewis acid. [½]
• BF3 is a Lewis acid [½]
(c) Species Conjugate acid Conjugate base
HCO −
3 H2 CO3 CO32 −

PM
Ans. 2. d= [½]
RT
0.82 × 32
d= [1]
0.082 × 300
d = 1.07 g/L [½]
Ans. 3. (a) Sn + 2H2 O → SnO2 + 2H2
∆
[1]

(b) 2Al + 3O2 

∆
→ 2Al2 O3 [1]

SECTION-B
Ans. 4. (a) LiCl is deliquescent and crystallises as a hydrate, LiCl·2H2O. [1]
(b) 2Na + 2H2 O 
→ 2NaOH + H2 ↑ [1]
(c) Beryllium chloride has a chain structure in solid state.

OR

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Chemistry (Class XI) Solution of Model Test Paper-1

Ans. 5. (a) From the first law of thermodynamics

∆U = q + w [½]
∆U = 550 – 285 [½]
= 265 J [1]
(b) • An extensive property is a property whose value depends on the quantity or size of matter present
in the system. [½]
• Enthalpy is an extensive property. [½]
OR
28
(a) Mole of N
=2 = 1 [½]
28

8
Mole of He= = 2 [½]
4
Partial pressure = mole fraction × total pressure

2
Partial pressure of He= × 12 [½]
3
= 8 atm [½]
(b) Boyle’s law: At constant temperature, the pressure of a fixed amount of gas varies inversely with its
volume.

1
P∝ (at constant T and n) [1]
V
Ans. 6. (a) Bromine is reddish brown in colour. It is added to the double bond leading to discharge in colour of
bromine. [½]
Br2
R −=
CH CH2 
CCl4
→ R − CH − CH2 [½]
| |
Br Br
(b) Propyne contains acidic hydrogen. It reacts with sodium liberating H2 gas [½]

1
CH3 − C ≡ CH + Na 
→ CH3 − C ≡ C−Na + + H2 [½]
2

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Solution of Model Test Paper-1 Chemistry (Class XI)
vf
Ans. 7. Work done in the isothermal and reversible process = −2.303nRT log [½]
vi
20
w rev =−2.303 × 2 × 8.314 × 300 log [½]
1
= – 2.303 × 2 × 8.314 × 300 × 1.3 [1]
= – 14.93 kJ [1]

• B(CH3 – CH = CH2) is propene [½]

 
• C  CH3 − CH − C H2  is propane-1, 2-diol [½]
 | | 
 OH OH 
• D(CH3CHO) is acetaldehyde [½]
• E(HCHO) is formaldehyde [½]
Ans. 9. (a) PbI4 does not exist because Pb-I bond initially formed during the reaction does not release enough
energy to unpair 6s2 electrons and excite one of them to higher energy orbital to have four unpaired
electrons around lead atom. [1]
(b) The main reasons are
• Six large chloride ions cannot be accommodated around Si4+ due to limitation of its size. [½]
• Interaction between lone pair of chloride ion and Si4+ is not very strong. [½]
(c) Down the group of carbon family, size increases and electronegativity decreases and thereby
tendency to show catenation decrease. [1]
OR
(a) The presence of 10d-electrons offer poor screening effect for the outer electrons from the increased
nuclear charge in gallium. As a result, the atomic radius of gallium is less than that of aluminium. [1]
(b) In graphite carbon is sp2 hybridised. [1]
(c) In 13 family, down the group +1-oxidation state increases due to inert pair effect hence TlCl3 is less
stable than BCl3. [1]
[C]3
Ans. 10. K C = [½]
[A][B]2
(0.5)3
= = 2 [1]
0.25 × (0.5)2
∆G° = – 2.303 RT log Kc [½]
= – 2.303 × 8.314 × 300 log 2 [½]
= – 1.7 kJ mol–1 [½]

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Chemistry (Class XI) Solution of Model Test Paper-1
Ans. 11. (a) 

AgCl(s) 
 Ag (aq) + Cl (aq)
+ −
[½]
Initially : 1 0 0
At Equilibrium: s (s + 0.2)
Ksp = [Ag+] [Cl–] [½]
s(s + 0.2) = 1.8 × 10–10
s2 + 0.2s = 1.8 × 10–10 [½]
−10
1.8 × 10
s= (s2 is neglected as s is very small)
0.2
= 9 × 10–10 [½]

(b) 

A 2B3  3+
 2A + 3B
2−

K sp = [A 3 + ]2 [B2 − ]3 [½]
= (2s)2 (3s)3
Ksp = 108 s5 [½]
OR
(a) PV = nRT [½]
nRT
P= [½]
V
128 0.082 × 400
P
= × [½]
64 10
P = 6.56 atm [½]
(b) van der Waals gas equation for n mole of gas is
 an2 
 P + 2  (V − nb) =
nRT [½]
 V 
van der Waals gas equation for 1 mole of gas will be
 a 
 P + 2  (V − b) =
RT [½]
 V 

SECTION-C

Ans. 12. (a) Alkali metals are low melting solids because of weak metallic bonding due to the presence of only a
single valence electron in them [1]
(b) Caesium show blue colour to the flame test. [1]
(c) • Because of high lattice enthalpy LiF is less soluble in water [1]
• CsI is less soluble in water because of smaller hydration enthalpy of the two ions. [1]
1
(d) KO2 is potassium superoxide. Oxidation state of oxygen is − . [1]
2
OR
Alkali metals and their salts show colour to the flame because the heat from the flame excites the
outermost orbital electron to a higher energy level. When the excited electron comes back to the
ground state, there is emission of radiation in the visible region.
  
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 Solutions of Model Test Paper-2 Chemistry (Class XI)

Solutions AY2021-22

of
Model Test Paper-2
For School/Board Exams (Term-II)
CHEMISTRY
Topics: States of Matter: Gases and Liquids, Chemical Thermodynamics, Equilibrium, s-Block Elements, Some p-Block
Elements, Hydrocarbons

SECTION-A
Ans. 1. (a) Extensive properties are the properties whose value depend on the quantity or size of matter present
in the system. [½]
Example: mass, volume. [½]
(b) The change in enthalpy during a process depends only upon the initial and final state of the system,
therefore, it is a state function. But the work depends upon the path followed, therefore it is a path
function, not a state function. [1]
Ans. 2. (a) Melting Point: C > Si > Ge > Sn [1]
(b) Density: In > Ga > Al > B [1]
(c) Hydration Enthalpy: Li+ > Na+ > K+ > Cs+ [1]
Ans. 3. (a) Geometrical isomers are the cis-trans isomers. [½ + ½]

(b) Cis form of but-2-ene is more polar than trans-form, because the net dipole moment of trans form is
almost zero whereas cis form has a dipole moment of 0.33 Debye. [1]

SECTION-B

Ans. 4. (a) Relation between ∆G and Qc can be derived as [1]

∆G = ∆G° + RTlnQc …(i)

where,

∆G° = Standard Gibbs free energy.

∆G = Gibbs energy change

R = Gas constant
T = Temperature
Qc = Reaction quotient
(b) Kc (Equilibrium constant) is the ratio of concentration of products to that of reactants each raise to
their stoichiometric coefficients at equilibrium. [½]
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Chemistry (Class XI) Solutions of Model Test Paper-2
Qc (Reaction quotient) is the ratio of concentration of products to that of reactants each raise to their
stoichiometric, coefficients at any time during the reaction. [½]
(c) If Qc > Kc, it means reaction concentration of products is to be decreased as to reach equilibrium
concentration, thus, the net reaction proceeds in the backward direction. [1]
OR
(a) For the given reaction, [1]

(p )
2
NH3
KP =
(p )(p )
3
N2 H2

(b) (i) According to Le Chatelier principle, if the pressure is increased, the equilibrium will shift in a
direction where the number of gas molecules are less. [1]
No. of moles of reactants = 1 + 3 = 4
No. of moles of products = 2
∴ Increase in pressure will shift the equilibrium in forward direction i.e., conc. of NH3 will be
increased.
(ii) Addition of inert gas at constant volume will not affect the equilibrium as it does not cause any
change in partial pressures of gases in the container. [1]
Ans. 5. (a) Markovnikov Rule states that the negative part of the addendum gets attached to that carbon atom
which possess less number of hydrogen atoms in an unsymmetrical alkene. [½]
For example:

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Solutions of Model Test Paper-2 Chemistry (Class XI)
OR

Ans. 6. According to combined gas law,

P1V1 P2 V2
= [½]
T1 T2

P1 = 760 mm Hg
P2 = ?
V1 = 400 mL
V2 = 440 mL
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 Chemistry (Class XI) Solutions of Model Test Paper-2
T1 = 27 + 273 = 300 K [½]
T2 = 17 + 273 = 290 K [½]

P1V1T2
P2 = [½]
T1V2

760 × 400 × 290

=
300 × 440

= 667.87 mm Hg  667.9 mm Hg [1]

Ans. 7. Ksp = 4 × 10–9


 2+ −
BaCl2 
 Ba (aq) + 2Cl (aq) [½]

Ksp = (s) (2s)2

Ksp = 4s3 [½]

4 × 10−9
s3 = = 10–9 [½]
4
s = (10–9)1/3 = 10–3 M
Molar mass of BaCl2 = 208 g mol–1 [½]
No. of moles of BaCl2
s of BaCl2 =
Volume of solution (in L)

0.2
10−3 = [½]
208x
0.2
x= = 0.96 L [½]
208 × 10−3
The volume of water required is 0.96 L
Ans. 8. (a) CH3 – CH = CH – CH2 – C ≡ C – CH3
Hept-2-en-5-yne [1]

Mo2O3
(ii) CH4 + O2 
∆
→ HCHO+ H2O [1]
Methane Methanal

Ans. 9. (a) In BCl3, the central atom has only six electrons after sharing electrons with that of Cl. It is an electron
deficient compound and thus behave as a Lewis acid. [1]
(b) The presence of additional 10d-electrons offer poor screening effect for the outer electrons from the
increased nuclear charge in gallium. Consequently, atomic radius of gallium is less than that of
aluminium. [1]
(c) Graphite is very soft and slippery and can be easily cleaved between the layers. [1]

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Solutions of Model Test Paper-2 Chemistry (Class XI)
OR
(a) Due to the property of catenation and tendency to form pπ – pπ multiple bonds with itself, carbon
exhibits many allotropic forms. [1]
(b) The stability of dihalides of group 14 elements increases down the group due to inert pair effect.
Therefore, PbCl2 is more stable than PbCl4. [1]
(c) Carbon cannot expand its covalency more than 4 while other elements of the group can do so due to
the presence of d orbitals in them. [1]
Ans. 10. (a) Boiling Point: 2, 4-dinitrobromobenzene < 2-Methylbutane < Pentane. [1]
(b) Acidic character: Propane < Propene < Propyne. [1]
(c) Electrophilic substitution: 2, 4-dnitrobromobenzene < p-nitrobromobenzene < Bromobenzene [1]
Ans. 11. According to first law of thermodynamics,
∆U = q + w [½]
where, ∆U = Change in internal energy [½]
q = Heat absorbed by the system = +620 J [½]
w = Work done by the system = –294 J [½]
∆U = +620 – 294
= 326 J [1]
OR
∆rG° = – 2.303 RTlogKp [½]
= – 2.303 × 8.314 × 300 log[20] [½]
= – 2.303 × 8.314 × 300 log [2 × 10] [½]
= – 2.303 × 8.314 × 300 × 1.3010 [½]
= – 7473 J mol–1 [½]
= – 7.47 kJ mol–1 [½]
SECTION-C

Ans. 12. (a) (i) It is due to the exceptionally small size of its atom or ion. [½]
(ii) High polarising power (Charge/radius ratio). [½]
(b) On moving from sodium to potassium, the increase in volume is greater than increase in mass.
Therefore, potassium has a lower density than sodium. [1]
(c) Alkali metals have low boiling point because of weak metallic bonding due to the presence of single
valence electrons in them. [1]
(d) • Due to the heat of flame, the electrons are excited to higher energy levels and when they drop
back to the ground state, energy is emitted in the form of visible light. [1]
• Sodium gives yellow colour to the flame test. [1]
OR
The diagonal relationship occurs due to the similarity in atomic sizes of elements. Boron is in diagonal
relationship with silicon. [1 + 1]

  

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 Chemistry (Class XI) Solutions of Model Test Paper-3

Solutions AY2021-22

of
Model Test Paper-3
For School/Board Exams (Term-II)
CHEMISTRY
Topics: States of Matter: Gases and Liquids, Chemical Thermodynamics, Equilibrium, s-Block Elements, Some p-Block
Elements, Hydrocarbons

SECTION-A

Ans. 1. (a) Intensive properties are those which are independent of the quantity or size of matter present in the
system example temperature and density. [1]

(b) According to first law of thermodynamics, energy can neither be created nor be destroyed although
it may be changed from one form to another. [1]

(c) ∆U = q + w

= –100 + 210

= 110 J [1]

Ans. 2. (a) Alkali metals and their salts impart colour to flame. It is because their loosely held valence electrons
get excited to higher energy level. When they return back they release visible light of characteristics
colour to flame. [1]

(b) Smaller the size of ion, more easily it will be hydrated. Li+ is smallest, therefore more hydrated hence,
it has least ionic mobility in aqueous solution whereas Cs+ being large in size, is least hydrated, so
its mobility is highest. [1]

Ans. 3. NaCl → Na+ + Cl− [½]

0.01 M 0.01 M

Let the solubility of AgCl be s mol L–1

AgCl  Ag+ + Cl−

[½]
s s + 0.01

Ksp = [Ag+][Cl–]

= s (s + 0.01)

1.8 × 10–10 = s × 0.01 [s + 0.01  0.01 ( s << 0.01)] [½]

1.8 × 10−10
s=
10 −2

= 1.8 × 10–8 mol L–1 [½]

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 Solutions of Model Test Paper-3 Chemistry (Class XI)
SECTION-B

Ans. 4. (a) The thermal stability of hydroxides of alkaline earth metals increases on increasing atomic number.
∴ Order of thermal stability is [½]
Ba(OH)2 > Sr(OH)2 > Ca(OH)2 > Mg(OH)2 [½]
∆
(b) (i) 4LiNO3  → 2Li2O + 4NO2 + O2 [1]
∆
(ii) 2NaNO3  → 2NaNO2 + O2 [1]

Ans. 6. (a) Due to small size of F, six fluorine atoms can be accommodated around silicon but six chlorine atoms
cannot, due to large size of Cl atoms. [1]
(b) Carbon shows remarkably catenation property due to its small size and high strength of carbon-
carbon bond. [1]
(c) In PbCl4 the oxidation state of Pb is +4. Due to inert pair effect, Pb2+ is more stable than Pb4+. Hence
Pb4+ is easily reduced to Pb2+, thereby acting as a good oxidising agent. [1]
OR

(a) In SiCl4, silicon has empty d-orbitals and gets readily hydrolysed whereas in CCl4, carbon does not
have empty d-orbitals so it does not undergo hydrolysis. [1]
(b) [2]

Criterion Diamond Graphite

Hybridization of C sp3 sp2

Structure of C Tetrahedral carbon which Planar trigonal which gives

gives rise to a 3-dimensional rise to a 2-dimensional
structure sheet like structure

C-C bond length 154 pm 141.5 pm

Electrical Diamond is an insulator Graphite is a good

conductivity conductor of electricity due
to presence of delocalised
π-electrons

Ans. 7. Wurtz reaction,

Dry ether
CH3Br + 2Na + BrCH3  → CH3 − CH3 + 2NaBr [1]

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 Chemistry (Class XI) Solutions of Model Test Paper-3
When we prepare heptane, there are the chances of the formation of side products, eg by starting with
1-bromobutane and 1-bromopropane, besides the main product heptane, hexane and octane are formed
as side products. [1]
Dry Ether
CH3 CH2CH2Br + BrCH2CH2CH2CH3  → C7H16 + C6H14 + C8H18 [1]
heptane 
hexane
octane
side products

Ans. 8. (a) Boyle’s Law [1]

(b) T1 < T2 < T3 [1]
(c) According to Boyle’s law P1V1 = P2V2 [½]
1 × 2.27 = 0.2 × V2
V2 = 11.35 L
since balloon burst at 0.2 bar pressure, the volume of balloon should be less than 11.35 L. [½]
Ans. 9. N2 (g) + 2H2 (g) → N2H4 (l); ∆H =−50.4 kJ/mol ...(i) [½]

H2 (g) + O2 (g) → H2O2 (l); ∆H =−193.2 kJ/mol ...(ii) [½]

1
H2 (g) + O2 (g) → H2O(l); ∆H =−242.7 kJ/mol ...(iii) [½]
2
For the reaction,

N2H4 (g) + 2H2O2 (l) → N2 (g) + 4H2O(l) [½]

By applying, 4 × (iii) – (i) –2 × (ii)

∆rH = 4 × (–242.7) – (–50.4) –2 × (–193.2) [½]

= –534 kJ/mol [½]

OR
(a) According to this law, the standard enthalpy of reaction is the algebraic sum of the standard
enthalpies of reaction into which the overall reaction may be divided at constant temperature. [1]
(b) Standard enthalpy of combustion: Enthalpy change at 298 K and 1 bar pressure accompanying
complete combustion of one mole of the compound is known as standard enthalpy of
combustion. [1]
(c) Standard enthalpy of formation: Enthalpy change accompanying the formation of one mole of a
compound from its elements at 298 K and 1 bar pressure, when all the substances are in their
standard states is called standard enthalpy of formation (∆fH°) [1]
Ans. 10. (a) Atomic size: Atomic radii of group 13 elements increase down the group with the exception that
atomic radius of Ga is less than that of Al due to presence of 10 d-electrons which offer poor shielding
effect for the outer electrons from the increased nuclear charge in Ga. [1]
(b) Ionisation enthalpy: For group 13 elements, the trend of ionisation enthalpy is
B > Al < Ga > In < Tl. This is due to increase in size and low screening effect of d and f electrons. [1]
(c) Oxidation states: For group 13, both +1 and +3 oxidation states are observed. The +1 oxidation state
becomes more stable as we move down the group due to inert pair effect. [1]

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 Solutions of Model Test Paper-3 Chemistry (Class XI)
alc KOH
Ans. 11. (a) CH3 CH2Br → CH
=2 CH2 + HBr [1]

OR

2,3-Dimethylhept-3-ene

(c) Friedel-Crafts alkylation reaction

SECTION-C

[H2 ]4
Ans. 12. (a) KC = [1]
[H2O]4

1 1 1
(b) K=
C = = 0.1 [1]
K C 10
(c) Increase in pressure and decrease in temperature will yield maximum amount of AB3 [1]
(d) The equilibrium constant for the reaction:
N2 (g) + O2 (g)  2NO(g) is [½]

[NO]2
KC = [½]
[N2 ][O2 ]

(2.8 × 10−4 )2
∴ KC = [½]
(3.0 × 10−4 )(4.2 × 10−4 )

= 0.622 [½]

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Chemistry (Class XI) Solutions of Model Test Paper-3
OR
aA + bB  cC + dD

(pC )c (pD )d
KP = [½]
(p A )a (pB )b

[C]c [D]d [RT](c + d)

= [½]
[A]a [B]b [RT](a +b)

[C]c [D]d
= (RT)(c + d)−(a +b)
[A]a [B]b

[C]c [D]d ∆n ∆n
= = (RT) g K C (RT) g [½]
[A]a [B]b

where ∆ng = (number of moles of gaseous products) – (number of moles of gaseous reactants) in the
balanced chemical equation. [½]
  

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