THE FIRST

COMPARATIVE EXAMINATION 2022-23

Class XII (SC)
CHEMISTRY
Paper 1 (Theory)
95
(Maximum marks: 70)
Time allowed:
(Candidates are allowed additional 15 Three hours)
They must NOT
minutes for only reading the paper.
start writing during this time.)
All questions are
All working inchuding rough work, should be done compulsory.
on the same sheetas, and adjacent to the rest
of the answer
Question 1 is of 20 marks having four sub parts, all of which are
Question numbers 2 to 8 carry 2 marks each, with compulsory.
two questions having internal choice
Question numbers 9 to 15 carry 3 marks each, with two questions
Question numbers 16 to 18 cary 5 marks each. Each question has having internal choice.
an internal choice.
The intended marks for
questions or parts of
questions given [].
are in
Balanced equations must be given wherever
possible and diagrams where they are helpful. When
solving
numerical problems, all essential working must be shown.
n working out the problems, use the following data:
Gas constant R =
1.987 cal deg mor =8.314
IL atm =l dm'atm JK mor 0.0821 L atm Kmo
=

101.3J Avogadro's mumber =

6.023 x 10, 1 Faraday 96500 Coulombs.

Question 1
4x1]
(a) Fill in the blanks by choosing the appropriate word/words from those given in the
brackets:
[Raoult's, Henry's, Ideal, Non ideal, carboxylic acid, aldehyde, ketone, 4, 6,
+3, +2, but-1-ene, but-2-ene, elimination, substitution]

) The oxidation number and coordination number of central metal ion in

[Cr{en)Cl;] are 2 and respectively
Gi) Solutions which strictly obeykaow law are called Ide solutions.
en
(ii) 2-Chlorobutane on heating with alcoholic KOH solution gives but as
major product. It is an example of jain teaction.
SE
Giv) The primary alcohols are easily oxidised first to aklabaand then to
Enkeead,

Q-4 This paper consists of Seven printed pages. Turn oveer

 3 HCHO D CMCHo.
(iv) ldentify A, B, C and D in the following: CMaCh OH
Conc. 1,So, (A) O, CHMg (C) K.CrO,/H
KC,o,/H
C,H,OH
443 K HO/Zn (B)HO/H K,Cr,0,/H(D)

Question 2 2
(a) Give reasons:

fizzes on opening. Henrys las

(1) Sodawater bottle kept at room temperature
pressure is the most suitable method for
determination of
(2) Osmotic
molecular weight of proteins and polymers. does not reqwire teann or coling
OR

Himalaya's
in a Valley was found to be -10°C.
(b) In winter the normal temperature
If a 30% by mass of aqueous of Ethylene glycol (Molecular ight= 62) is AT= lovx x
1.86 K kg/mol)
prepared, is it suitable for car radiator in that region? (Kr= Sxm
Ye Sutadle. ATea1'06xyI 12.35
Question 3
7 O 70 622 12
How will you bring about the following conversions? le Kom
) 1-Chloropropane to 2-Chloropropane.

(ii) Ethanol to Ethyl fluoride.

Question4 (21
Define CFSE value. e derene b/w eg a tg 4a
)
(i) Draw a
sketch to show splitting ofd-orbital in an octahedral crystal field and 6
show d Ao> p.
do>P
21
Question 5
(t2e
Calculate the boiling point ofUrea solution when 6 g ofUrea is dissolved în 200 g of
Water (K=0.52 Kkg mol"), boiling point of pure water is 373K, molecular weight

ofUrea-60). Ts 13.26K &T- looxka ¥ > 'ov2 ax0s2x6

A 6So
.2
Question 6
Using IUPAC noms write the formulae for the following:

G) tetraamminechloridonitrito-N-platinum (IV) Sulphate PE(M, C (onto)]soy

) Sodium tetrahydroxozincate (11)
[znlou)a

(3) Turn over

Q-4
 Question 12

(a) Write IUPAC names of following coordination compounds:

()
) K [Fe(CN).1 potamiumm htma Cano ernh
i) Ni(co)u] tehncanbanyl nichl()
(ii) [Pt (NH) ONO () Con
Cu Pentnammine nitnei-o-phhun
OR
Hzo.
b) Give reasons for following:
Nickel does not form low spin octahedral complex. duG dohs
(i) Sc (H;0)%]* is colourless while [Ti(H;0)%]" is coloured. [Atomic'mumber:
Sc 21, Ti - 22] wwpised e d dfonuter
(ii). [Ni(Co)] is diamagnetic but [NiCl] is paramagnetic although both are
tetrahedral complexes.
>no
unpired elosh has nbaiede-/ci=seat lij
Question 13 13
How will you convert:
) Benzene to Phenol (eH 1 63
i) Chlorobenzene to Toluene
Gii) Methanol to Ethanol Cy
3i 1+2n

cyo Cny eM eMzO n

Question 14 13
Complete and balance the following equations:

CHBr+ AgCN (alc) GHs NC+gKr

*
t KSr *20
Cii) CH-CH-CH,+ KOH (alc)A, eu-mecu,
Br
Steenfidte

CH,CI+CH,CI+ Na dry ether

(ii) A CMat
Question 15
'>2'23° 13
() Which will react faster towards SN reaction 1-bromopéntane or 2-bromopentane
and why? 2
fakr
ii) Racemisation occurs in SN reactions. Why?

Cabocahion har þlaner J hus

attoakad ehon beth sile,
Cqunly

Q-4 (5) Turn over

Question 18
(51

) Give balanced equations for the following:

(a)
(1) Dow's Process
(2) Coupling Reaction
3) Rcimmer Tiemann Reaction.
2
ro la c H2 o
between the following compounds:
(ii) Give one chemical test to distinguish
-vjolet
colern rt
(1) Phenol and Diethyl ether
ehe Fec
(2) Propan-l-ol and Propan-2-o
Ne t u h a h
OR td y-to i
reactions:
(b) ) Complete the following

(1) CH-CH-OH+SOCl PyridineG Hs Clt502t HY

CH
(2) H,C-C-OCH,+ HI -1 CuO
CH

ONa
(3) O +CHI> Nal

(ii) Arange thefollowing asdirected u 2-od butan

2medP
(1) Butan-1-ol, Butan-2-o1, 2-methyl-propan-1-ol (Increasing order of
Boiling Point)

OH OH OH (Increasing order of
NO CH, Acidic Strength)
(2)

Q-4 (7)