Test - 4A (Paper-2) (Code-B)_(Answers) All India Aakash Test Series for JEE (Advanced)-2024

All India Aakash Test Series for JEE (Advanced)-2024

TEST - 4A (Paper-2) - Code-B
Test Date : 02/04/2023

ANSWERS
PHYSICS CHEMISTRY MATHEMATICS

1. (5) 19. (7) 37. (4)

2. (4) 20. (8) 38. (2)

3. (2) 21. (7) 39. (7)

4. (2) 22. (3) 40. (8)

5. (6) 23. (1) 41. (2)

6. (5) 24. (6) 42. (7)

7. (8) 25. (4) 43. (6)

8. (6) 26. (8) 44. (2)

9. (B, C) 27. (A, B, D) 45. (A, B)

10. (B) 28. (A, B, C, D) 46. (A, D)

11. (B, D) 29. (A, B, C) 47. (A, B, C)

12. (A, C, D) 30. (C) 48. (A, B, D)

13. (A, B) 31. (A, C) 49. (A, B, C)

14. (B) 32. (A, B, C, D) 50. (A, C)

15. (B) 33. (D) 51. (A)

16. (C) 34. (B) 52. (A)

17. (D) 35. (C) 53. (D)

18. (C) 36. (A) 54. (A)

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All India Aakash Test Series for JEE (Advanced)-2024 Test - 4A (Paper-2) (Code-B)_(Hints & Solutions)

HINTS & SOLUTIONS

PART - I (PHYSICS) 3. Answer (2)

Hint : Apply energy conservation.
1. Answer (5)
Sol. :
m
M+
Hint : T = 2 3
K

m
M+
Sol. : T = 2 3
K Energy Equation
l 1 1
T = 2
( 20 + 5 )  10–3 mg (1– sin ) = mv 2 + icm 2
2 2 2
(1)
10

= 2 25  10–2 second s

T = 10 × 10–2 seconds

10  11 Equation (1) can be written as

= = = seconds
100 10 35 L 1  1 2L2  3 1 1
 mg  1–  = m +  mL2 2
2 2 2 44 2 12
2. Answer (4)
3 1
v = mL2 2  + 
Hint : f =  32 24 
2(length)
9 + 4
= mL22  
 v  96 
Sol. : Length = =
2 2f
24 g
=
v 13 L
f =
2(length) 4. Answer (2)

 v  v
f1 =  1  ; f2 = 2 
Hint : E x = dE cos 
 2  2L  2L
Sol. :
f1 v
= 1
f2 2v 2

Also, v =
T

( )
1 =   r 2 = r 2

  r 2
2 =
4 
E x = dE cos 

Gdm 4Gdm cos2 

v1 2 1 1 dE = =
= = =  3L 
2
3L2
v2 1 4 2  
 2cos  
f1  1 
=
f2  4 
3L
y= tan 
2
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Test - 4A (Paper-2) (Code-B)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2024

3L 6. Answer (5)
dy = sec 2 d 
2 gx 2
Hint : y = x tan  –
m  3L  2v 2 cos2 
dm = dm =   sec d 
2
L  2 
Sol. : y = 4x – x2

=
3m
sec 2 d  gx 2
 y = x tan  –
2 2v cos2 
2

4G cos2  3m x = 1, y = 3
dE = 2
 sec 2 d 
3L 2
[tan = 4]
 2 3Gm 
= d
 3L2 
 

+
 8 
6
2 3Gm 2 3Gm 1 2sin  · cos  =  
Ex =  
3L2
cos d  =
3L2
 2
2
 17 
–
6

 2 3Gm 
=
 3L2 
 
5. Answer (6)
v 2 sin2
Hint : VBA = VB – VA =4
g
Sol. :
v 2  17 
= =
g  2 
u2 = v2 – 2g × 3
17g
– 6g
2
VBA = VB – VA 5g
u2 =
2
VBA = 202 + 102
u = 25 = 5 m/s
= 10 5 km/hr
7. Answer (8)
 V  10 1 n
tan  =  A  = = x
 VB  20 2 Hint : X mean =
n
 1  10
tan  = 2  cos  =   Sol. : X mean = m
 5 4
BP = 5 cos = 2.50 m

1 0.08
=5× Mean absolute error =
5 4
= 0.02 m
= 5 km
Percentage error in measurement
BP 5 1
time = = = hr 0.02
VBA 10 5 10 =  100
2.50
time = 6 min  0.8%
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All India Aakash Test Series for JEE (Advanced)-2024 Test - 4A (Paper-2) (Code-B)_(Hints & Solutions)

8. Answer (6) 13. Answer (A, B)

Hint : T V = 0 Hint : Apply linear momentum conservation.

Sol. : VA = VB = 6 m/s Sol. :

as 3TVA – 3TVB = 0
VA = VB
VA = 6 m/s
9. Answer (B, C)
Fx Fy
Hint : =
y x

Fx Fy
Sol. : = = (2 xy )
y x
Force is conservative in nature.
R 1
10. Answer (B) sin  = =
3R 3
Hint : Normal reaction is independent of frame of
reference R 1
tan  = =
2 2R 2 2
Sol. : Normal reaction is independent of frame of
reference. 2 2
cos  =
Acceleration of block in case-I is zero. 3
11. Answer (B, D) MQ = M

T MS = M
Hint : = constant
Rth MP = 8M
Sol. : Momentum conservation
v1 = v2 = v0
Final velocity of P is v

2 2
 8Mu = 2Mv 0  + 8MV
3

4 2
8u = v 0 + 8v
3
90 – T T – 40 T – 60
= + 2
 2L  L L  2u = v 0 + 2v (1)
 KA  3
  2KA 2KA
v 0v cos 
90 – T e= =1
= (T – 40 + T – 60 )  2 u cos 
2
 90 – T = 8T – 100 × 4 v2 2 u  2 2
v0 – =
3 3
 9T = 490
3·v 0
 490   –u =v (2)
T =  C 2 2
 9 
On solving (1) and (2),
12. Answer (A, C, D)
 12 2 
Hint : Temperature first increases then decreases. v0 =   u
 11
Sol. : So, W > 0  

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Test - 4A (Paper-2) (Code-B)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2024

14. Answer (B) 17. Answer (D)

F  0, x  0  Hint : I =  x dm
2
Hint :  stable equilibrium
F  0, x  0
F  0, x  0 Sol. : I =  x dm =  x dx
2 2
Sol. :  stable equilibrium
F  0, x  0 
F  0, x  0 
= x 2  0 x 2dx
 unstable equilibrium
F  0, x  0 2
15. Answer (B) 
=  0 x 4 dx
0
1
Hint : l1  2
nd  0 x (2)5
=
1 5
Sol. : l1 
nd 2
32
= 0
n = number density per unit volume 5
d = diameter of molecule 18. Answer (C)
2
l1 n2  d2  Hint : aP = aP, com + acom, A
=  
l 2 n1  d1 
Sol. : aP = 2R + 2 × (2R)
2
l1  3   4  3 16  8  = 32R
=    =  =
l2  2   3  2 9  3 

16. Answer (C) PART - II (CHEMISTRY)

V V 19. Answer (7)
dv
Hint : 
0
2–v
= dt 
0
Hint : NaCl + HCl → No reaction

Na2CO3 + 2HCl → 2NaCl + H2O + CO2

dv
Sol. : = 2–v
dt Sol. : Since, 1 mole of Na2CO3  1 mole of CO2

V V Let the mass of Na2CO3 be w gm

dv 2–v 

0
2–v
= dt 
0
 – ln 
 2 
=t

w
=
4.8
106 44
v 4.8
 1– = e–t w=  106 = 11.56 g
2 44
11.56
 v = 2(1– e – t ) % Na2CO3 =  100 = 58%
20
dx 20. Answer (8)
= 2(1– e – t )
dt
1
ln 4 Hint : PV = mnC2

 dx = 2  (1– e ) dt
–t 3
−3 1
0 Sol. : P  10 =  10−25  1024  (102 )2
3
ln 4  1 
x = 2 t + e – t  = 2 ln4 + = 1 106
 0  4  = N / m2
3
 3 106
= 2 ln 4 –  x =P= bar = 3.33 bar
 4 105  3
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All India Aakash Test Series for JEE (Advanced)-2024 Test - 4A (Paper-2) (Code-B)_(Hints & Solutions)

3 23. Answer (1)

Kinetic energy of 1 molecule = kBT
2
Hint : e–Zr/na0
3 1
kBT = mC2 −r −r
2 2 =
3a0 na0
mC2 10−25  (102 )2
y=T= = Sol. : n = 3
3 kB 3  1.38  10−23
Maximum power of r = 1
xy
8
10 Hence,  = 1
21. Answer (7)
No. of radial nodes = n –  – 1 = 3 – 1 – 1 = 1
Hint : meq of O.A = meq of R.A
24. Answer (6)
Sol. : H2O2 + KI + H2SO4 → I2 + H2O + K2SO4
Hint : Sodium tetraborate decahydrate is Borax.
I2 + 2Na2S2O3 → 2NaI + Na2S4O6
Na2[B4O5(OH)4]8H2O has following
Since, meq of I2 = meq of Na2S4O6 structure.
meq of I2 = 25 × 0.1 = 2.5

meq of H2O2 = meq of I2

(N  V)H2O2 = 2.5 Sol. :

2.5 25
N= =
100 1000

25
Volume strength of H2O2 =  5.6 Hence x = 2, y = 2 and z = 2
1000
25. Answer (4)
x = 0.14 V
Hint : NH+4 + H2O NH4OH + H+
22. Answer (3) C−Ch Ch Ch

[H+] = 10–pH

Hint : is more stable, since negative charge Sol. : [H+] = 10–5

kw 10 –14
is more stable on more electronegative Kh = Ch2 = = = 0.5  10−9
kb 2  10−5
atom.
Kh K 5  10−10
+ + h= = +h = = 5  10−5
Sol. : CH3 – C  O and CH3 – O = CH2 are more Ch [H ] 10−5
stable due to complete octet. [H+ ] 10 −5
C= = = 0.2
h 5  10 −5
is more stable due to
1 litre contains → 0.2 moles
complete octet. 0.2
800 ml contains →  800
1000
 0.16 mole
In –I effect is operating at Meta
Mass (in g) = 0.16 × 53.5 = 8.56 g
,
position, leads to stabilisation of carbanion. x = 8.56 g

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Test - 4A (Paper-2) (Code-B)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2024

26. Answer (8) 31. Answer (A, C)

Hint : Work done by the system = –pV Hint : N2 = 1s2, *1s2, 2s2, 2s2, 2px2 = 2py2,
W = –nRT 2pz2
O2 = 1s2, *s2, 2s2, 2s2, 2pz2, 2px2,
Sol. : Ca + 2HCl → CaCl2 + H2
= 2py2, 2px1, 2py1
−m −10
w= RT =  0.0821 400 1
M 40 B.O = [Nb − Na ]
2
= –8.21 L atm
1
27. Answer (A, B, D) Sol. : N2 (B.O) = [6] = 3
2
Hint : Li+ Be+ B+ C+
1
1s2 1s22s1 1s22s2 1s22s22p1 N2+ (B.O) = [5] = 2.5
2
Sol. : I– is more stable than other halide ions
1
SiO2 < P2O5 < SO3 < Cl2O7 (acidic strength) O2+ , B.O. = [6 − 1] = 2.5
2
As we move from left to right, acidic strength of
C2− = 1s 2 , * 1s 2 , 2s 2 , * 2s 2, 2 px2,
oxides increases.
2 py2 , 2 p1z
Although Ne+ and F are iso-electronic, due to
greater nuclear charge, the electron attracting 1
Bond order 
tendency or electron affinity of Ne+ ion is more than Bond length
that of F.
In F2 molecule, HOMO is Anti bonding
28. Answer (A, B, C, D) molecular orbital.
All statements are correct 32. Answer (A, B, C, D)
29. Answer (A, B, C) 12−
Hint : Beryl contain Si6O18 unit, hence a cyclic
silicate.
Hint : Sol. : Pyroxenes are formed by sharing of O-
atoms at two corners of each tetrahedron with
other tetrahedra.
Two tetrahedral units are joined by sharing the O
at one corner, thus giving the unit (Si2O7)6–.
Sol. : 33. Answer (D)
Hint : Beryllium halides are essentially covalent
and soluble in organic solvents.
Sol. : Among alkaline earth metal hydroxides, the
anion being common the cationic radius will
influence lattice enthalpy. Since lattice enthalpy
decreases much more than the hydration enthalpy
30. Answer (C) with increasing ionic size, the solubility increases
Hint : For exothermic reaction, increasing as we go down the group.
temperature moves the reaction in backward 34. Answer (B)
direction. Hint : HC  CH ⎯⎯⎯⎯⎯⎯
2 3
→
NaNH , liq NH
1eq
Sol. : Addition of inert gas at constant volume has
no effect. HC  CNa ⎯⎯⎯⎯⎯
Ph−CH −Br
→HC  C − CH2 − Ph
(P) 2 (Q)
According to Le-Chatelier’s principle,
On decreasing pressure, reaction moves in Sol.:
backward direction.

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All India Aakash Test Series for JEE (Advanced)-2024 Test - 4A (Paper-2) (Code-B)_(Hints & Solutions)

35. Answer (C) 38. Answer (2)

28  V  100 Hint : Use relation between roots and coefficients.
Hint : Percentage of nitrogen =
22400  m

V is volume of N2 in mL (at STP) Sol. :

m is weight of organic compound.

Sol. : Actual pressure = 725 – 15 = 710 mm
Volume of nitrogen at STP
r + s = –p …(i)
273  710  80
= p + q = –r …(iii)
300  760
= 68 mL rs = q …(ii)

Since, 22400 ml of N2 at STP weighs 28 g pq = s …(iv)

28  68 Equation (i) × (ii),

68 mL of nitrogen weighs = g
22400 pqrs = qs  pr = 1 …(v)

28  68  100 Equation (i) + (iii),

Percentage of nitrogen =
22400  0.8 p + q + r + s = –p – r
= 10.6%  2(p + r) + q + s = 0
36. Answer (A) p2 + rp + s = 0 [ p is root of equation]
Hint : Mg2C3 ⎯⎯⎯
→ CH3 – C  CH
H2O
r2 + pr + q = 0 [ r is root of equation]
Sol. : CH3 – C  CH ⎯⎯⎯⎯⎯
→ 2 mole HCl

(P) ( p + r )2 − 2( p + r ) = 0  p + r = 0, p + r = 2
CH3 – CCl2 − CH3
(Q)
Also, pr = 1  p = 1, r = 1
From equation (iv),

PART - III (MATHEMATICS) pq = s  q = s

37. Answer (4)  q + s = –2(p + r)

Hint : Remove modulus sign for different intervals  q + s = –4  q = s = –2

and solve.  4×1–2+2–2=2
Sol. : 39. Answer (7)
Case I : sinx  0 0<x n

|sinx| siny = sinx siny

Hint : Use  [(r + 1)p+1 − r p+1]
r=1

1 n n n
= [cos( x − y ) − cos( x + y )] Sol. : C1  r p +
p +1
C2  r p −1 + ... +  (1)
p +1
2
r=1 r=1 r=1
1
cos( x − y ) − cos( x + y ) = −
2 1
 a0 =
3 p +1
cos( x + y ) + cos( x − y ) =
2 1 1
=
1 8 p +1
cos( x − y ) =   5 7    11 
2   ,  and  , 
 6 6  6 6  p+1=8
cos( x + y ) = 1 

 p=7
 Four ordered pairs.

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Test - 4A (Paper-2) (Code-B)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2024

40. Answer (8) Sol. : Similarly, m2 = t2 + t3 and m3 = t3 + t1

m1 + m2 + m3
 t1 =
Hint : While applying summation on k, take i and j
as constant. 2
   m−2
Sol. : S = 208 
1 Now, tan60 =
  3i 3 j 3k 1 + 2m
i= 0 j= 0 k= 0
i  j k

     
S 1 1 1
=    i j k − 3   i k + 2 i
208 i = 0 j = 0 k = 0 3 3 3 i= 0 k= 0 9 3 i = 0 27

3
3  9  3   27 
=   − 3    + 2  
 
2   
8 2  26 
S 81
= − (2 + 3) 2− 3
208 208  m1 = m2 = m3 = 2
2 3 −1 2 3 +1
S = 81 = 3a/2
3
a
 t1 = 11
=4
2 43. Answer (6)
 a=8 m
Hint : Use logak (b)m = loga b
k
41. Answer (2)
1
Hint : Make different cases and count. log1/ 5 4 1
Sol. : 5 2 + log + log1/2
2
7+ 3 10 + 2 21
Sol. : Case I : When we use 6, 7 or 8 at ten
4
thousand place, then number of numbers = 5log5 2 + 2log2 + log2 (10 + 2 21)
4P
7+ 3
=3× 4 = 72
= 2 + 2 log2 ( 7 − 3) + log2 (10 + 2 21)
Case II : When we use 5 at ten thousand place
and 6, 7 or 8 at thousand place, then number of = 2 + log2 (10 − 2 21) + log2 (10 + 2 21)
numbers is = 2 + log2 (102 − (2 21)2 )
= 1 × 3 × 3P3 = 18
= 2 + log2(100 – 84)
Hence, required number of numbers is = 2 + log216
72 + 18 = 90 =2+4=6
Now, 2 × 10C
r = 90 44. Answer (2)

 r=2 Hint : Use transformation formula to simplify and

use standard limits.
42. Answer (7)
Sol. :
Hint :  1 
 − cos5 x + cos x  (5 sin5 x − 1 sin x )
lim  
x →0+  1 
 sin x  cos x
 
1
(5 sin5 x − sin x )
lim 2sin3 x sin2 x
x →0 cos x
sin x
t22 − t12 sin x (5 sin5 x − sin x )
m1 = = t1 + t2 lim
t2 − t1 x →0 2 sin3 x sin 2 x cos x

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All India Aakash Test Series for JEE (Advanced)-2024 Test - 4A (Paper-2) (Code-B)_(Hints & Solutions)

45. Answer (A, B) a2 − 2

−1  1
Hint : Put z = x + iy and simplify. 2
Sol. : |z – iRe(z)| = |z – Im(z)| 0  a2  4
Let x = x + iy a  [–2, 2]

|x + iy – ix| = |x + iy – y| 48. Answer (A, B, D)

i.e., x2 + (y – x)2 = (x – y)2 + y2 Hint : Try to represent as different of 2 terms.

i.e., x2 = y2 n2 + n − 1
Sol. : Tn =
x = ±y (n + 2)!
 x=y (n 2 + 2n ) − (n + 1)
=
x = –y (n + 2)!
46. Answer (A, D) n n +1
= −
Hint : Use parametric point as diametrically end (n + 1)! (n + 2)!
points.
1002 + 100 − 1 10099
 T100 = =
 2 2 102! 102!
Sol. : The circles with  2t1,  and  2t2 ,  as
 t1   t2 
1 2 2 3
Sn =  −  +  −  +
diameter.  2! 3!   3! 4! 
 2  2  n n +1 
( x − 2t1 )( x − 2t2 ) +  y −  y −  = 0 ... +  − 
 t1  t2   (n + 1)! (n + 2)! 
1 1 n +1
Also, slope − = 1  t1t2 = −1  Sn = −
t1t2 2 (n + 2)!
So, equation of circle 1 2010
S2009 = −
( x 2 + y 2 − 8) − (t1 + t2 )( x − y ) = 0 2 (2011)!
+ L=0
S 1 1 1
= − 
Fixed point 2 2011 2009!
x−y =0 
 (2, 2) 1
S =
 2
 (−2, − 2)
x + y = 8
2 2

49. Answer (A, B, C)

47. Answer (A, B, C)
Hint : Sum of roots = Product of roots and roots
Hint : Express cos2x in terms of a. are real
    Sol. :
Sol. : 4 sin  x +  cos  x − 
 3  6 b 1
sec 2  + cosec 2  = − = …(i)
= a + 3 sin2x − cos2x
2 a sin  cos2 
2

 sin x  3 c 1
3 sin x  sec 2  + cosec 2  = = …(ii)
4 + cos x  cos+  a cos  sin 
2
 2 2  2 
  2
4a
sin2 2 =  1  c  4a
= a2 + 3 sin2x − cos2x c
3 sin2x + 3 cos2 x + sin2 x Combining equations (i) and (ii),
b+c=0
= a2 + 3 sin2x − cos2x
50. Answer (A, C)
cos2x + 2 = a2 – cos2x Hint : 3p = (4 – 1)p = 4l + (–1)p
a −2
2
5q = (4 + 1)q = 4m + 1
cos2x =
2 7r = (7 – 1)r = 8m + (–1)r
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Test - 4A (Paper-2) (Code-B)_(Hints & Solutions) All India Aakash Test Series for JEE (Advanced)-2024

Sol. : Any positive power of 5 will be of form 53. Answer (D)

4l + 1.
x 2 −3 x + 2
 1
Even power of 3 and 7 will form 4l + 1 and odd Hint :  x 2 − x +  1
power of 3 and 7 will be 4l – 1.  2
Sol. :
Hence, both p and r must be even.
1
Thus, p + r is always even. (i) x2 − x +
2
Also, p + q + r can be odd or even. 2
 1 1
51. Answer (A) x − 2 + 4 =1
 
Hint :
1 3
 x= 
2 2

(ii) x2 – 3x + 2

The line can be written y = mx and curve as

x2 + y2 = 4.

Sol. : Let C(h, k) be a point on circles and A( 3, 1) 1

(iii) | x − 1| − | x + 1| −
be given point, then 2
 Set X can be
h+2 3
=  1  3
3  − , − 4  − − 4 
   
 h = 3 − 2 3
1 1
− 2x  − 2x −
=1
k +2 2 2
= m
3 −1 −3
 x  x=
 k = 3m – 2 4 4
Now, this point (h, k) lie on circle.

 (3 − 2 3)2 + (3m − 2)2 = 4

= 3(1 + m2 ) 2 − 4( 3 + m) + 4 = 0
D>0 54. Answer (A)
16( 3 + m)2 − 4  3(1 + m2 )(4)  0 Hint : Im(z) = 4
Sol. : z = |z| – 2 + 4i
( 3 + m)2 − 3(1 + m2 )  0
 Im( z ) = 4
3 + m + 2 3m − 3 − 3m  0
2 2
z = a + 4i
 2m − 2 3m  0
2
 a = a2 + 16 − 2
m  (0, 3)  (a + 2)2 = a2 + 16  a = 3
52. Answer (A)  z = 3 + 4i
Hint : Squaring and adding. 4
Amp( z ) = tan−1  
Sol. : x2 + y2 = a2 + b2 3

❑ ❑ ❑
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