Energy Cycle Diagram of Hess Law.

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Energy cycle diagram of Hess Law.

Determine ΔH of NH3(g) + HCl(g) NH4Cl(s) ….

A. -452 kJ
B. -158 kJ
C. -176 kJ
D. -462 kJ
E. -137 kJ

The silicon(IV) oxide, SiO2, found in the mineral quartz, has a structure similar
to diamond. Each silicon atom is bonded to X oxygen atoms but each oxygen
atom is bonded to only Y silicon atoms. Determine the number of X and Y ….

A. X = 4 and Y = 2
B. X = 4 and Y = 3
C. X = 1 and Y = 2
D. X = 2 and Y = 4
E. X = 2 and Y = 2

Which of the following is not a redox reaction ….

A. C(s) + O2(g) → CO2(g)


B. 2CuO(aq) + N2(g) → 2Cu(s) + 2NO(aq)
C. SO3(g) + H2O(l) → H2SO4(aq)
D. 2H2(g) + O2(g) → 2H2O(l)
E. Fe2O3(aq) + 2Al(s) → Al2O3(aq) + 2Fe(s)

Chlorine gas can be made from the reaction of kawi stone, sodium chloride, and
sulfuric acid, according to the equation:

MnO2(s) + 2NaCl(s) + 2H2SO4(aq) → MnSO4(s) + Na2SO4(s) + Cl2(g) +


2H2O(g)

The oxidising agent is ….

A. NaCl
B. H2SO4
C. MnSO4
D. Cl2
E. MnO2

Allotropes are different crystalline or molecular forms of the same element.


Allotropes of Carbon are ….

A. graphite, diamond, and aluminum


B. graphite, diamond, and buckminsterfullerene
C. graphite, diamond, and steel
D. graphite, alloy, and buckminsterfullerene
E. brass, diamond, and buckminsterfullerene

The naming compound for FeCl2 is ….

A. Iron (IV) chloride


B. Iron (II) chloride
C. Iron (V) chloride
D. Iron (I) chloride
E. Iron (III) chloride

Calculate the volume occupied by 0.5 mol of carbon dioxide at a pressure of


150 kPa and a temperature of 19 °C … (8.31 J mol-1 K-1)

A. 12.12 dm3
B. 9.12 dm3
C. 11.73 dm3
D. 8.09 dm3
E. 10.23 dm3

The equation for the complete combustion of propane is:

C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(g)

ΔH°f C3H8(g) = -231 kJ mol-1


ΔH°f CO2(g) = -146 kJ mol-1
ΔH°f H2O(g) = -101 kJ mol-1

Calculate enthalpy change, ΔH, of this reaction ….

A. -511 kJ mol-1
B. -598 kJ mol-1
C. -611 kJ mol-1
D. -483 kJ mol–
E. -542 kJ mol-1
In thermodynamics,
the ideal gas law is the equation of state of a hypothetical ideal gas. It is a good
approximation of the behavior of many gases under many conditions, although
it has several limitations.
The properties of an ideal gas, except ….

A. all collisions between particles are elastic


B. distance between the gas molecules is less than the diameter of the
molecules
C. the volume of the molecules is negligible
D. no intermolecular forces of attraction or repulsion
E. the gas molecules move rapidly and randomly

The following reaction:

Ag(s) + 1/2N2(g) + 3/2O2(g) → AgNO3(s)

Type of ΔH from the reaction above is ….

A. ΔH°c (combustion)
B. ΔH°n (neutralisation)
C. ΔH°d (dissociation)
D. ΔH°f (formation)
E. ΔH°s (solvation)

Caffeine is a drug that stimulates (increases the activity of) your brain and
nervous system. Caffeine is found in many drinks such as coffee, tea, soft
drinks and energy drinks. Determine the number of sigma (σ) bonds of caffeine.

A. 27
B. 26
C. 24
D. 23
E. 25

Vanadium with an oxidation number +4 is found in the compound ….

A. VCl3
B. VSO4
C. NaVO2
D. V2O5
E. VO2

Nitrogen with an oxidation number -2 is found in the compound ….

A. NH3
B. NO
C. N2
D. N2H4
E. NO3–

Zinc carbonate, ZnCO3, is soluble in water. A student dissolved 14.3 g of zinc


carbonate in 200 cm3 of water in a polystyrene beaker stirring. The
temperature of the water fell by 3.4 °C. Calculate the enthalpy change of
solution of zinc carbonate …. (c = 4.18 J g-1 °C-1)

A. +27 kJ mol-1
B. +25 kJ mol-1
C. +23 kJ mol-1
D. +29 kJ mol-1
E. +31 kJ mol-1

Potassium permanganate is an oxidising agent with disinfectant, deodorising,


and astringent properties. Its chemical formula is KMnO4. It is sometimes called
by Condy’s crystals. The oxidation number of Mn in KMnO4 is ….

A. +7
B. +5
C. +6
D. +3
E. +4

Which of the following reaction is a redox reaction ….

A. KOH(aq) + HF(aq) → KF(aq) + H2O(l)


B. 2NaCl(aq) + MgSO4(aq) Na2SO4(aq) + MgCl2(aq)
C. All False
D. S(s) + O2(g) → SO2(g)
E. AgNO3(aq) + HI(aq) → AgI(s) + HNO3(aq)

50 cm3 of 1.0 mol dm-3 hydrochloric acid in the cup. Then add 50 cm3 of 1.0
mol dm-3 sodium hydroxide, the temperature rise from 21.3 °C to 27.8 °C.
(specific heat capacity = 4.18 J g-1 °C-1). Calculate enthalpy change, ΔH, of
this reaction ….

A. -61.85 kJ mol-1
B. -54.34 kJ mol-1
C. -21.38 kJ mol-1
D. -34.56 kJ mol-1
E. -42.34 kJ mol-1

Determine the number of phi (π) bonds of this compound.

A. 2
B. 5
C. 4
D. 3
E. 6

The equation for the complete combustion of but-2-ene is:

C4H8(g) + 6O2(g) → 4CO2(g) + 4H2O(l)

Calculate a value for the standard enthalpy change ….

E(C═C) = +608 E(O─H) = +465 E(O═O) = +496

E(C─C) = +347 E(C═O) = +805 E(C─H) = +413

A. +2785 kJ mol-1
B. -2875 kJ mol-1
C. +2578 kJ mol-1
D. -2578 kJ mol-1
E. -2785 kJ mol-1

The standard enthalpy change of combustion, ΔH°c, is when one mole of a


substance is burnt in excess oxygen under standard conditions. The following
reaction of standard enthalpy change of combustion ….

A. NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)


B. CH4(g) → C(s) + 2H2(g)
C. Mg(s) + C(s) + 3/2O2(g) → MgCO3(s)
D. CaSO4(s) + aq → CaSO4(aq)
E. CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)

In the stratosphere, nitrogen dioxide reacts with excess water to produce NO


and nitric acid, contributing to acid rain, with the equation:

3NO2(g) + H2O(l) 2HNO3(aq) + NO(g)

The oxidation number of nitrogen (N) changes from ….

A. +3 becomes -1 and +2
B. +2 becomes -1 and 0
C. +3 becomes +5 and +2
D. +4 becomes +5 and +2
E. +4 becomes +5 and +3

Sodium hydrogen carbonate decomposes on heating.

2NaHCO3(s) → Na2CO3(s) + H2O(l) + CO2(g)

Calculate the enthalpy change for this reaction using enthalpy changes of
formation ….

ΔH°f NaHCO3(s) = -302 kJ mol-1

ΔH°f H2O(l) = -393.5 kJ mol-1

ΔH°f Na2CO3(s) = -174.5 kJ mol-1

ΔH°f CO2(g) = +45 kJ mol-1

A. +125 kJ mol-1
B. -34 kJ mol-1
C. +81 kJ mol-1
D. +34 kJ mol-1
E. -81 kJ mol-1
In the reaction:

Cl2(g) + 2KOH(aq) → KCl(aq) + KClO(aq) + H2O(l)

The oxidation number of chlorine changes from ….

A. 0 becomes -1 dan +1
B. +1 becomes 0 dan -1
C. -1 becomes +1 dan 0
D. 0 becomes -1 dan -2
E. +1 becomes -1 dan 0

A flask of volume 5 dm3 contained 4 g of oxygen (O2). Calculate the pressure


exerted by the gas at a temperature of 127 °C … (R = 8.31 J mol-1 K-1)

A. 8.31 x 107 Pa
B. 8.31 x 108 Pa
C. 8.31 x 104 Pa
D. 8.31 x 106 Pa
E. 8.31 x 105 Pa

The following reaction:

CuCNS(aq) + KIO3(aq) + H3PO4(aq) → Cu3(PO4)2(s) + KH2PO4(aq) +


HCN(aq) + I2(s) + KHSO4(aq) + H2O(l)

Which element has a decreasing oxidation number ….

A. Cu and S
B. Only I
C. S and I
D C and I
C and I
E. Cu and C

The compound with the name potassium nitrate(V) is ….

A. KNO3
B. Ca(NO3)2
C. NaNO2
D. NaNO3
E. KNO2

Which of the following is a reduction reaction ….

A. Na(s) → Na+(aq) + e–
B.Zn(s) → Zn2+(aq) + 2e–
C. H2(g) → 2H+(aq) + 2e–
D. Fe2+(aq) → Fe3+(aq) + e–
E. Cu2+(aq) + 2e– → Cu(s)

A flask of volume 2 dm3 was found to contain 5.28 g of a gas. The pressure in
the flask was 200 kPa and the temperature was 20 °C. Calculate the relative
molecular mass of the gas … (8.31 J mol-1 K-1)

A. 33.26
B. 32.14
C. 34.65
D. 35.62
E. 36.21

Endothermic reaction is chemical reactions that absorb heat energy from the
surroundings. The temperature of the surroundings decreases. Which
statement is an endothermic reaction ….

1. photosynthesis
2. the combustion of fuels
3. the evaporation of seawater
4. the reaction of water with calcium oxide

A. 1 and 2
B. 2 and 4
C. 1 and 3
D. 1 and 4
E. 2 and 3

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