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SET-3

Series HFG1E/4 Q.P. Code 56/4/3

Roll No.
Candidates must write the Q.P. Code
on the title page of the answer-book.

THT faTa (grf-aa)

CHEMISTRY (Theory)
etfRa H7:3 v2 T4A4 3/5:70
Time allowed: 3 hours Maximum Marks: 70

10.15 a fT IZTI 10.15 a H 10.30 a 7 a T7-77 T

ia
Please check that this question paper contains 23 printed pages
.Q.P. Code given on the right hand side of the question paper should be
written on the title page of the answer-book by the candidate.
Please check that this question paper contains 35 questions.
Please write down the serial number of the question in the
answer-book before attempting it.
1 5 minute time has been allotted to read this question paper. The question

paper distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m.,

will bewill
the students read the question paper only and will not write anny
answer on the answer-book during this period.
AAIIAIAIIIIIIUIAIIIASGJAIAIAIAIIGSAIAIASANNANANANAddddss
P.T.O.
56/4/3
General Instructions: and strictly follow them:
Read the following instructions carefully
35 questions. All questions compulsory are
i) This paper contains
question
Sections A, B, C, D and E.
paper is divided into five
-

(i) This question

choice (MCY type questions,
Questions 1 to 18 are multiple
(iii) In Section A no.

carryingl mark each.

19 to 25 very short answer (VSA) type questions,
(iw) In Section B
-

Questions no.

marks each.
carrying 2
26 to 30 are short answer (SA) type questions,
(v) In Section C Questions - no.

carrying 3 marks each.

31 and 32 are case-based questions carrying
(vi) In Section D
-

Questions no.

4 marks each.
33 to 35 are long answer (LA) type questions
(vii) In Section E Questions - no.

carrying 5 marks each. in

internal choice has been provided
There is overall choice. However, an
(vii) no
in Section D and
in Section C, 2 questions
2 questions in Section B, questions
2
E.
2 questions in Section
allowed.
ix) Use of calculators is not
SECTION A
carrying
Multiple Choice (MC) type Questions,
Questions no. 1 to 18 are 18x1-18

I mark each.
dissociation in water. The
undergoes complete
1. A compound CaCl2. 6H,0
Van't Hoff factor f is:
9
(b) 6
(a) 4
(d)
(c) 3
of the type A products, the rate equation
For a zero order reaction
2.
as
may be expressed k - A - A

a) k-4h-[A] (b) t
t
k-A-A).
k-4-A] (d) 2
(c) 2t
Cu* halide is not known?
8. Which of the following (b) Culg
(a) CuBr2
(d) Cul2
(c) CuCl2 P.T.O
56/4/3
3
 a-D-glucose ?
4. Which of the following structures represents
CH,OH CH,OH
H H H 0 QH
(a)
(b)
QH
HO O H H OH OH

H OH H OH

H
H
CHOH H 0 QH
H (d) N
(c) OHMOH OH
OH H OH CHOH
OH Å OH H

5. The compounds [CrtH,0)ICI3. [ICr{H20),CIJCl2. H,0 and

ICrH,0),ClICl. 2H,0 exhibit:

(a) Linkage isomerism (b) Geometrical isomerism

Ionization isomerismn (d) Hydrate isomerism

(c)
6. Which of the following alkenes on acid catalysed hydration gives a

tertiaryalcohol?
(a) 2-Butene (b) 2-Methylpropene
(c) Propene (d) 1-Butene
When nitrobenzene is heated with tin and concentrated HCl, the product
7.
formedis

(a) NH2
(b) -NH3 C

(_N-N
(d)

56/4/3 5 P.T.O
 with alcoholic KOH gives mainly:
1-phenyl-2-chloropropane
8.
Reaction of (b) 3-phenylpropene
(a) 1-phenylpropene

1-phenylpropan-3-ol
d) 1-phenylypropan-2-ol
(c)

9.
Corrosion of iron is
a decomposition process
(a)
photochemical process
(b) a

an electrochemical process
(c)
( d ) a reduction process

molecules that react with each

other in an elementary
10. The number of
reaction is a measure of the:

(a) activation energy of the reaction

(b) order of the reaction

(c) stoichiometry of the reaction

(d) molecularity of the reaction
and
11. On hydrolysis, which of the following carbohydrates gives glucose
galactose?
(b) Lactose
(a) Sucrose
(d) Cellulose
(c) Maltose
'Rickets'?
12. The deficiency of which of the following vitamins causes
Vitamin A (b) Vitamin DD
(a)
Vitamin B (d) Vitamin C
(c)
13. Which ofthe following is an 'Acetal'?

(a) CHgCH2-OCH3
HC 0-CH
(b) H.C ~0- H2

OCH3
(eCH-CH~oCH3
OH
(d)
CH-CH~OCH3 P.T.O
56/4/3
 in tetralhedral erystal field (A,) is equal to:
field splitting energy
14. The crystal
(b)
(a)
(d) 2Ao
(c)
labelled as
are given-
one
statements
15 to 18, two
number
(R). Select the
correet
For Questions as
Reason
other labelled
and the below.
Assertion (A)
the codes (a), (b), (e) and (d) a s given
to these questions from
and Reason (R) is the
answer

and Reason (K) a r e true

Both Assertion
(A)
(a)
of the Assertion (A).
correct explanation
but Reason (R) is not
and Reason (R) a r e true,
Both Assertion (A)
(b) of the Assertion (A).
the correct explanation
is false.
Assertion is true, but Reason (R)
(A)
(c)
Reason (R) is true.
(d) Assertion (A) is false, but
a depression in freezing
NaCl is added to
water,
Assertion (A): When
15. point is observed.
increased which causes

of solution is
Reason (R): The vapour pressure
point.
depression in freezing
done by
be conveniently
Monobromination of aniline can
Assertion (A) :
16. amino group by acetylation.
protecting the the amino
decreases the activating
effect of
Acetylation
Reason (R):
group.
obtained by the
molar conductivity
(Am) is
Assertion (A): Limiting /2 of strong
17. versus C curve

extrapolation of the Am
electrolyte. using
is obtained by
for weak electrolytes
Reason (R): Am
Kohlrausch's law.

V).
Assertion (A): E2+ 1 is positive (+ 0-34
18.
Copper has high A,H and low AhyaH.
Reason (R): P.T.O

56/4/3
 SECTION B

2x1-2
19. Write IUPAC names of the following:
(a)(a) Co(en),(H,OxCN)J"
(bNi(NH3)gCla

4x=2
20. Name the cell which
used in Apollo SLace
programme.
(a) was

automobiles and inverters.

(b)is used in
aids and watches.
(c)
(c) is suitable for hearing
and is used in transistors.
d) does not give a steady potential
mixture of
from Raoult's law
is shown by a
of deviation 2
(a) What type
21. ? Give reason.
ethanol and acetone

OR
is formed by negative
What type of azeotrope 2
Define Azeotrope.
(b)
from Raoult's law
? Give an example.
deviation
2x1=2
reactions:

22. (a) Write the products of the following

CHO Conc. NaOH

(i) A

H
H2NNH-CO-- NH2
(ii)

OR 2x1-2
than two steps
conversions in not
more

(b) Do the following

acid
Toluene to Benzoic
i)
1-Phenylethanol
Benzaldehyde to
(ii) P.T.O.

11
56/4/3
 first order decomposition of NgO is given by
23. The rate constant for the
the following equatiom:
2x10 K
log k 23-6-.
T
2
Calculate E for this reaction.

[R 8-314JK mol
treatment wit
An alkyl halide (A)
of molecular formula CgHy13Cl on
24. molecular
two isomeric alkenes (B) and (C) of
alcoholic KOH gives
give 2,3-dimethylbutane.
Both alkenes on hydrogenation
formula C6H2. 2
and (C).
Write the structures of (A), (B)

acid dehydration of ethanol to yield ethene.

25. Write the mechanism of

SECTION c

3x1-3
26. Account for the following:
reactive towards Sy1 reaction.
(a) Benzyl chloride is highly
it contains a chiral
b) -Butan-2-ol is optically inactive, though
carbon atom.
coloured bottles.
(c) Chloroform is stored in closed dark

order thermal
27. The following data were obtained during the first
constant volume:
decomposition of CgHsCl at a
CaHCl (g) C,H4(g)+HCl(g)
Experiment Time (s) Total pressure
(atm)
0.4
2 100 0-6
3
Calculate the rate constant.
0-6021)
log 2 0-3010, log 3 0-4771, log 4
= =
(Given: =

P.T.O
66/4/3 13
 122 g mol *) is associated into a dimer when
If benzoic acid (M
=

28. of a solution of 6-1 g of

dissolved in benzene and the osmotic pressure
is 6-5 atm at 27°C, then what is the
benzoic acid in 100 mL benzene
3
association of benzoic acid ?
percentage
(Given: R =0-0821 L atm Kmol)

Write hydroboration-oxidation
reaction with an example.
29. (a) )
(ii) Write the products of the following reaction:
OCH3
+HBr

more acidic than phenol ? 3x1-3

(i) Why is p-nitrophenol

OR

b) (i) What happens when phenol reacts with

(1) Conc. HNO3, and
of aqueous NaOH followed by
(2) CHCl3 in presence

acidification ?
Write equations only.
Br give
(i) Why does the reaction of CHgONa with (CH3),C
2-methylpropene ànd not (CH3),C-OCHg? 2+1-3

3x1-3
30. Answer any three of the following questions
3 basis of
(a) Explain the type [Fe(CN)Glon the
of hybridization in

valence bond theory. (Given: Atomic number of Fe 26)

=

(b) Draw the geometrical isomers of [PtCl,(en)," ion.

(c)
(c) [NiCIis paramagnetic while (Ni(CO),] is diamagnetic though
both are tetrahedral. Why ?
Name the type of isomerism when ambidentate ligands are
(d)
attached to central metal ion. Give one example of ambidentate
ligand.
15 P.T.O.
56/4/3
 SECTION D

case-based questions. Read the carefully and

The follouing questions are case

answer the questions that follow.

various complex biomolecules like

31. Living systems are made up of
carbohydrates, proteins, nucleic acids, lipids, etc. Carbohydrates
are

or ketones o r molecules which

optically active polyhydroxy aldehydes
three
provide hydrolysis. They are broadly classified into
such units on

groups monosaccharides, oligosaccharides and polysaccharides.

to form
Monosaccharides are held together by glycosidic linkages

disaccharides like sucrose, maltose or polysaccharides like starch and

cellulose.
which
polymers of a-amino acids
aare
Another biomolecule proteins are

bonds. Ten amino acids are called essential amino

linked by peptide
at four different
acids. Structure and shape of proteins can be studied
and quaternary, each level being
levels i.e. primary, secondary, tertiary
complex than the previous
one.
more

Answer the following questions:

(i) What is the difference between a glycosidic linkage and peptide

1
linkage?
1
(1i) Which amino acids are called essential amino acids ?

structures of proteins ?
(111) What are the common types of secondary
and tertiary
Write any two forces which stabilise the secondary
2
structures of protein.

OR

(iii) Define denaturation of protein with an example. During

denaturation which structures of protein lose their biological
2
activity?
P.T.O.
6/4/3 17
 32. Amines are usually formed from nitro compounds, halides, amides,
imides, etc. They exhibit hydrogen bonding which influences their
physical properties. In alkyl amines, a combination of electron releasing,
steric and hydrogen bonding factors influence the stability of the
substituted ammonium cations in protic polar solvents and thus affect
the basic nature of amines. In aromatic amines, electron releasing and
withdrawing groups, respectively increase and decrease their basic
character. Influence of the number of hydrogen atoms at nitrogen atom
on the type of reactions and nature of products is responsible for
identification and distinction between primary, secondary and tertiary
of
amines. Prasence of amino group in aromatic ring enhanc s reactivity
the aronmatic amines. Aryl diazonium salts provide advantageous
methods for producing aryl halides, cyanides, phenols and arenes by
reductive removal of the diazo group.

Answer the following questions:

values in
(i) Arrange the following in the increasing order of their pK,
aqueous solution
CaH,NH2, (C2H,)NH, (C,Hs)3N
(ii)
i) Aniline on gives a substantial amount of m-nitroaniline,
nitration
1
though amino group is o/p directing. Why?
formula CH%O2 on
(ii) An aromatic compound 'A' of molecular
B.
treatment with aqueous ammonia and heating forms compound
Compound B' on heating with Br2 and aqueous KOH gives a

Write the structures of

compound 'C' of molecular formula CH,N.
A, B and C.
2
OR
2x1-2
Complete the following reactions giving main products
:
(iii)
NH2

(1) +Bra (aq)

Ng C
i) HBF4
(2)
(ii) NaNO/Cu, A

56/4/3 19 P.T.O.
 SECTION E

(a) i) Account for the following:

33.
coloured.
(1) Zn" salts are colourless while Ni" salts are
(2) Cr is a strong reducing agent.
show catalytic
(3) Transition metals and their compounds
activities.
of MnO4 in
(ii) Write the ionic equations for the oxidizing action
acidic redium with
(1) Iion, and
3+2-5
(2) Fes" ion.

OR
transition
3d series of the
) Name two oxometal anions of the
b) exhibits the oxidation state equal
metals in which the metal
to its group number.
solution of KgCrgO, ?
What is the effect of increasing pH
on a
(ii)
solution ?
stable in aqueous
(ii) Why is Cu' not well-known to
which is
Name a member of Lanthanoid series
(iv) state.
exhibit +4 oxidation
show anomalous
Name two elements
of 3d series which 5x1=5
(v)
electronic configuration.

2,4-dinitrophenylhydrazone
of benzaldehyde.
34.
34. (a) Draw structure of the
stronger acid ?
(b) Which acid of the following pair is a

-COOH
COOH or HgC:
FC
reduction.
involved in Rosenmund's
(c) Write the chemical equation
ketones acidic in
a-hydrogen atoms of aldehydes and
(d)
(d) Why are
nature?
and
distinguish between Benzaldehyde
(e) Write a chemical test to 5x1-5
Benzoic acid.

P.T.O.
56/4/3 21
35. (a) ) Calculate the emf of the following cell at 298 K

Al(s) A* (0-001 M) ll Ni (0-1 M)|Ni(s)

Given E'A3,A-1-66 V, E -0-25 V, log 10 = 1]
ASAI Ni2t /Ni

(i) With the help of a graph explain why it is not possible to

determine Am for a weak electrolyte by extrapolating the
molar conductivity (Am) versus C/2 curve as for strong
3+2-5
electrolyte.
OR
(b)6) The molar conductivities of NH and CI ion are

73-8 S cm2 mol and 762 S em2 mol respectively. The

conductivity of 0-1 M NH,CI is 1-29 x 10 S cm. Calculate

its molar conductivity and degree of dissociation.

(ii) Calculate the haf-cell potential at 298 K for the reaction

Zn2+2e Zn
if (Zn] = 0-1 M and EZn2t /Zn - 0-76 V. 3+2-5

56/4/3 23