Topic 4. STIOCHIOMETRY [Formulae, Equations and Calculations]
Valency or Combining Power
The valency of an element is the number which shows its ability to combine with
other elements.
In molecules (covalent compounds) it gives the num
the atoms can forin.
In ionic compoun.is the val
ber of covalent bonds which
lency gives the charge on the ions of the element.
>The valency (combining power) increases with the group till group 4, then
decreases.
Group number | 1 2 3 4 5 6 7 8
Valency 1 2 3 4 3 2 1 oO
Valency can be used to predict the formulae of compounds.
Here is a list of most of the ions that you are likely to meet and will need
to know:
OH™ hydroxide ion »
CI> chloride ion
Br~ _ bromide ion
te iodide ion
F fluoride ion
NO,” nitrateion «
H* hydrogen ion
Li* lithium ion
Na* — sodium ion
K* potassium ion
Ag* _ silver ion
NH,* ammonium ion «
Ca?* calcium ion
Mg?* magnesium ion
Ba?* — barium ion
Pb?* — Jead(I) ion
Cu?+ * copper(II) ion
zinc ion
iron(II) ion
Fe?* * iron(II) ion N3- nitride ion
AP* aluminium ion PO,)” phosphate ion *
Valency
oxide ion
si sulfide lon
sulfate lon
AIP cn {f
nN
aI.
CO,?" carbonate ion «
a ie
Scanned with CamScannerPredicting the formula of ionic compounds
In an ionic compound, the ions are attracted to each other by their opposite
charges.
The number of positive charges Is always equal to tho number of negative
charges. Knowing this, the formulae of ionic compounds can be written down.
‘aluminium oxide
Examples :
aie — alo,
magnesium oxide
mg@e® -- Mg20.
Remember;
i)
Ni
ammonium sulfate
Hse —(nH,),S0,
this is then waitten
——_—_+ MgO
Compounds ending in ‘ide’ are made of just 2 elements only.
ii) Compounds ending in ‘ate’ have a third element, ‘oxygen’.
Question ; Write down the formula for each of these ionic compounds:
1. Sodium chloride ... 9. Lead(Il) nitrate ..
2. Zinc chloride .. 10. Calcium hydroxide ...
3. Sodium sulfate .. 11. Iron(IIl) oxide
4. Copper(Il) sulfate. 12. Sodium carbonate ....
5. Zinc carbonate .. 13. Zinc sulfide te
6, Aluminium carbonate .. . | 14. Magnesium nitride
7, Potassium iodide .. 15. Aluminium hydroxide ..
8. Copper(Il) oxide... 16. Silver nitrate ..
Scanned with CamScanner