GE Water & Process Technologies. Protecting Public Health With ZeeWeed Membranes
GE Water & Process Technologies. Protecting Public Health With ZeeWeed Membranes
GE Water & Process Technologies. Protecting Public Health With ZeeWeed Membranes
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Clean, Safe Drinking Water is a Basic Right
Increasingly stringent
regulatory requirements to
provide pathogen free
drinking water 100% of time Gastro-intestinal
Illness
Inadequate turbidity
removal is directly
correlated to increased
gastro-intestinal illness. UF
provides <0.1 NTU, 99% of
time.
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Membrane Technology Provides the
Ultimate Level of Security
Positive barrier - Parasites are removed
by size exclusion (>0.1 um), not
inactivation
Superior treated water quality
• California Department of Health
Services Testing
– > 9 log removal of Giardia Cryptosporidium Parvum (4-7 µm)
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ZeeWeed is the Trusted Membrane
Platform
Introduced in 1993
Immersed hollow fiber membrane
configuration
Outside-in mode of operation
PVDF chemistry that is resistant to
chlorine, oxidants and wide pH range
Compatible with coagulants/PAC
NSF 61 Certified ultrafilter
Over 1.8 BGD* of treatment
capacity makes ZeeWeed the world’s
most trusted and experienced
immersed membrane platform!
* Installed or under design as of December, 2006
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Membranes are the Key to Superior
Drinking Water Quality
Hollow strands of porous plastic fibers
with billions of microscopic pores on
the surface
The pores are thousands of times
smaller in diameter than a human hair 7 ft
Typical
Size Range (mm)
Microorganism
Enteric Viruses 0.03 – 1.0
Fecal Coliform 1-4 Giardia Lamblia
(10-12 µm)
Cryptosporidium 3-7
Giardia 7 - 15
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Achievable ZeeWeed Treated Water
Quality
< 0.1 NTU 95% of the time
Turbidity
< 0.3 NTU 100% of the time
Cryptosporidiu
m removal > 4 log 100% of the time
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Treated Water Quality Exceeds the
World’s Toughest Standards – Current
and Future
United States:
– CDHS, LT2,
USEPA
United Kingdom:
– Drinking Water
Inspector (DWi)
US EPA Turbidity Limit for
Drinking Water is 0.15 NTU
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Source Water Cryptosporidium Bins
Bin Average Additional treatment
Number Cryptosporidium beyond conventional
Concentration filtration
(per L)
1 < 0.075 No Action
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LT2 Technology Toolbox
Toolbox Technologies Additional Log Credit
0.5 1.0 2.0 >2.5
Watershed control program X
Off-stream raw water storage X X
Pre-settling basin with coagulant X
Lime Softening X
In-bank filtration X X
Filter effluent turbidity <0.15 NTU 95% X
Slow sand filters X
Roughing filters X
Membranes (MF, UF, NF, RO) X X X >>>
Cartridge Filters X
Chlorine Dioxide X X
Ozone X X X
UV X X X >>>
Peer Review Program X
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LT2 New Plant Example
LRV Values
Conventional UF filtration UF filtration and
filtration with UV UV disinfection
Bin 2 (0.75 to <1 Bin 2 (0.75 to Bin 3 (1 to <3
cyst/L) <1 cyst/L) cysts/L)
4.0 LRV required 4.0 LRV 5.0 LRV required
Coagulation, 0.5 required
flocculation,
sedimentation
Dual Media Filtration 2.5
UV 1.5 1.0
Residual Disinfection 0.0
UF 4.0 4.0
Total LRV 4.5 4.0 5.0
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Reliable Turbidity Removal
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Smaller Footprint
UF is uniquely suited for
spatially constrained facility
sites
Additional Minimum
• High tank intensity Footprint of Conventional
Pretreatment
• Smaller flocculation zones
• Elimination of clarification
• Minimization of treatment
chemicals
Minimization or elimination of
treatment processes reduces
cost
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Simple, Cost Effective Media Filter
Retrofits
Existing rapid sand filter ZeeWeed 1000 Retrofit
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Drinking Water Installations
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Proven Solutions for Plants of All
Sizes
GE has the proven experience to deliver
drinking water plants of any size, from
small pre-engineered, quick delivery
systems to the world’s largest operating
plants.
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Total Installed ZeeWeed
Drinking Water Capacity*
1400
1200
MGD (Cumulative)
1000
800
600
400
200
0
1998 1999 2000 2001 2002 2003 2004 2005 2006
1400
1200
1000
800
600
400
200
0
1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006
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Largest Awarded* DW Installations use
ZeeWeed
Twin Oaks, CA, USA 100 mgd
Lakeview, ON, Canada 95 mgd
Fridley, MN, USA – P 90 mgd
Moscow, Russia - A 73 mgd
Chestnut Avenue, Singapore 72 mgd
Columbia Hts, MN, USA - N 70 mgd
Racine, WI, USA 50 mgd
Thornton, CO, USA 50 mgd
CCK, Singapore 48 mgd
Clay Lane, UK - N 42.8 mgd
Kamloops, BC, Canada 42.3 mgd Lakeview, ON, Canada
Forest Park, PA, USA – USF 40 mgd
Roetgen, Germany - N 38 mgd
Escombreras, Spain 37 mgd
San Joaquin, CA, USA 36 mgd
Modesto, CA – USF 36 mgd
Olivenhain, CA, USA 34 mgd
Coliban, Bendigo, AU – USF 33 mgd
Sweetwater, CA 30 mgd
Scottsdale, AZ 30 mgd Racine, WI, USA
Thunder Bay Bare Point 30 mgd
*As of January 2007 22 /
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Largest Operating UF/MF for DW use ZeeWeed
Chestnut Avenue, Singapore 72 mgd
Columbia Hts., MN, USA - N 70 mgd
Racine, WI, USA 50 mgd
Thornton, CO, USA 50 mgd
Clay Lane, UK - N 42.8 mgd
Kamloops, BC, Canada 42.3 mgdChestnut Avenue, Singapore
Roetgen, Germany - N 38 mgd
San Joaquin, CA, USA 36 mgd
Olivenhain, CA, USA 34 mgd
Scottsdale AZ 30 mgd
Coliban Water, Australia - USF 33 mgd
Appleton, WI - K 24 mgd
Thornton, CO, USA
Keldgate, UK - N 23.8 mgd
*As of January 2007, in order of peak daily flow
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Membranes – The Basics
What is a membrane?
Membranes are engineered thin barriers or films
of material that allow certain substances to pass
by a size exclusion mechanism related to the
size of the pores on the membrane surface
Rejected
Matter
Support
Material
Membrane
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Membranes for Water Treatment
Conventional Pretreatment
0.035 µm
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Membrane Configurations
Reverse Osmosis Ultrafiltration Sand filtration
Nanofiltration Microfiltration
Reverse
Osmosis
ZeeWeed membrane
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Hollow Fiber Configurations
Immersed Pressurized
Backpulse Valves
Process Permeate
pump discharge
Membrane valve
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Automatic Backpulse
•Permeate flow periodically reversed through the membrane, removing
solids from fiber surface
•Can backpulse with or without chemicals
Backpulse
Valves
Process Permeate
pump discharge
Membrane
valve
Feed Cleaning
Chemical
C.I.P
Cleaning
Air Reject
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ZeeWeed Membrane Cleaning
Maintenance clean
Membranes contacted with either 50 - 100 mg/L sodium
hypochlorite (NaOCl) or citric acid at pH 2.2-2.5
Cleaning interval: Daily-Weekly
Duration : Approx. 25 minutes & scheduled through the PLC
Recovery Clean
High strength chemical clean to return membranes back to
full efficiency with 500 mg/L NaOCl or 2 g/L citric acid
Initiated when a train reaches maximum TMP (typically 12-13
psig or 83-90 kPa)
Typical frequency: 1-6 months
Typical duration: 6 hours
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Evolution of ZeeWeed
1993 2004
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The ZeeWeed Hollow Fibres
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ZeeWeed Family of Immersed
Membranes
ZeeWeed 500 Series ZeeWeed 1000 Series
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ZeeWeed 500 - The Most Robust
Membrane on the Market
Reinforced inner structure ensures a long
and trouble free membrane life
ZeeWeed membranes have the highest
solids tolerance of any HF membrane
system, offering more reliability over the
plant’s lifecycle
Produces a high quality water at all times
regardless of water quality change or
upset
Does not require pre-clarification thereby
reducing capital/operating costs and
simplifying the system
Conservative design and the unique
operator tools ensure that the system
works through any unexpected situation
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ZeeWeed 500: Precise Fiber
Placement
High solids tolerance
• Routine operation in drinking
water up to 5,000 mg/L
• Process flexibility
Proven design details
• Efficient aeration minimizes
resistance of cake layer
• Shell-less design and spacing
between modules and fibers
eliminates solids accumulation
• Optimum fiber slack prevents
solids build-up Defined spatial
distribution of
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Fully Integrated Cassettes
Simplify Plant Design & Operation
Compact
• High packing density
= smaller footprint
Accessible
• Easy to remove modules and
cassettes
Simple to Operate
• Fewer connections,
valves = higher reliability
Easy to Maintain
• Larger building block design with
less equipment and fewer
connections
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ZeeWeed 1000 – Setting the
Standards for High Efficiency
Membranes
Ultrafiltration membrane – high quality
permeate with provides extra public
health protection
Extremely compact design – smaller
plant footprint reduces capital costs
Operator friendly – streamlined design
makes it simple to operate and maintain
Conservative design and the unique
operator tools ensure that the system
works through any unexpected situation
Open tank operations provide a more
robust system and is ideal for large scale
plants and retrofits
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ZeeWeed 1000
Immersed Membranes for Low Solids Water
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ZeeWeed 1000 Membranes
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Reduced Footprint
Comparison for a 50 MGD DW plant
Conventional High Rate
Membrane
Flocculation
HDT: 45 min
Compare size to 12,000 ft2
2 football fields HDT: 10 min
(each 360 ft 35,000 ft2
long)
Sedimentation
Filtration
120,000 ft2
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ZeeWeed 1000:Virus Rejection
Superior virus removal
Better removal of colloidal particles
Improved protection against emerging pathogens
Pore Size (microns)
Nominal Maximum
ZeeWeed Others ZeeWeed Others
0.02 0.1 0.1 0.2
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ZeeWeed 1000:
Setting the Industry Standard
Cost effective
Modular platform
• 60 or 96 module cassettes
• 2 or 3 stack configurations
• 8 or 10 in. permeate headers
Suitable for different module areas and
water quality and applications
• 450 ft2, 500 ft2, and 600 ft2 modules
•Large system configuration typically
employed for large drinking water
plants
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Typical ZeeWeed Plant Layout
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Drinking Water Treatment Options
North American Distribution
Settled Water
EC + Fe/Mn
DF
Other
Fe/Mn
EC
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Membrane Integrity Monitoring
Indirect monitoring:
• Turbidity monitoring on each train
• Optional particle counting on each train
Direct monitoring: Pressure decay testing
• Typically automated offline test
• Detects 3 micron leaks (69 kPa test
pressure)
• Decay can be correlated to a log removal
value across the membranes (ASTM,
LT2ESWTR)
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Treatment Options
Turbidity
and
Pathogen
Removal UF
Coagulant
Organics
Removal
UF
Oxidant
Fe & Mn
Remova
l UF
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Turbidity Removal –
ZeeWeed UF vs. Conventional Treatment
Cost
RW TW
CONVENTIONAL TREATMENT
RW TW
UF DISINFECTIO
N
ZeeWeed UF
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Feed & Permeate Turbidity
100.00
Turbidity (NTU)
10.00
1.00
0.10
0.01
21-Jul 28-Jul 4-Aug 11-Aug 18-Aug 25-Aug 1-Sep 8-Sep 15-Sep
Raw Permeate
Turbidity
and
Pathogen
UF
Removal
Coagulant
Organics
Removal
UF
Oxidant
Fe & Mn
Remova
l UF
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Organics Removal –
ZeeWeed UF vs. Conventional Treatment
Raw Treated
Water Water
FLASH FLOCCULATIO CLARIFICATI FILTRATI
MIX N ON ON
CONVENTIONAL TREATMENT
Raw Treated
Water Water
FLASH FLOCCULATIO ULTRAFILTRATI
MIX N ON
IMMERSED MEMBRANE
ULTRAFILTRATION WITH
ENHANCED COAGULATION
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Organics Removal
Color and DOC removal & DBP Pin sized floc sufficient
reduction
• Lower coagulant dose
• Up to 95% color removal
possible • Shorter HRT in flocculation tank
• Up to 75% TOC removal • Reduced sludge formation
possible
Footprint for a membrane plant is
Minimize colloidal and organic smaller since:
fouling
• Clarification not required
Effective pre-treatment required
• Lower HRT needed for
• coagulant mixing and dosing flocculation allows for smaller
• pH control tank
– minimize membrane
fouling
– reduce dissolved metals
• PAC if taste and odor control
also required
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Color Removal Example –
Anthony Henday WTP
Mountain View Regional Water - Anthony Henday WTP
Raw Water and Permeate Colour
140
120
100
Colour (PCU)
80
60 Target value
per Canadian
40 guidelines
20
0
31-Dec-02 1-Mar-03 30-Apr-03 29-Jun-03 28-Aug-03 27-Oct-03 26-Dec-03
Date
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Feed and Permeate TOC
Turbidity
and
Pathogen
UF
Removal
Coagulant
Organics
Removal
UF
Oxidant
Fe & Mn
Remova
l UF
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Iron and Manganese Removal
pH
Adjustmen ClO2, HOCl,
t KMnO4
(optional) Permeate
Flash Mixer Pump
Fee
d
Mn 2+
Fe2+
Air
Contact Chamber
(optional)
Reject
Air
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Manganese Removal – Seekonk
WTP
10
Total Manganese (mg/L)
0.1
Removal Objective: 0.03 mg/L
0.01
0.001
26-Mar 31-Mar 5-Apr 10-Apr 15-Apr 20-Apr 25-Apr 30-Apr 5-May
Raw Water Permeate
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Iron Removal – Seekonk WTP
0.12
Removal Objective: 0.1 mg/L
0.1
Total Iron (mg/L)
0.08
0.06
0.04
0.02
0
26-Mar 31-Mar 5-Apr 10-Apr 15-Apr 20-Apr 25-Apr 30-Apr 5-May
Raw Water Permeate
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Drinking Water Installations
Rothesay Water Treatment Plant
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Collingwood Water Treatment Plant
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Kamloops Treatment Plant
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Lakeview Water Treatment Plant
When commissioned, will be
the largest UF drinking water
plant in the world
Location: Mississauga, Ontario,
Canada
Peak Capacity: 96 MGD (363,000
m3/d)
Commissioning:Raw
June 2006
Water Treated Water
Quality Quality
Cryptosporidium N/A > 4 log
removal
Giardia N/A > 4 log
removal
Turbidity (NTU) 5 < 0.1
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Burloak Water Purification Plant
ZeeWeed 1000 system expandable in
four phases
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Hamlet of Smith Water Treatment Plant
Emergency treatment required
after suspected
Cryptosporidium outbreak
Location: Hamlet of Smith, Alberta,
Canada
Peak Capacity: 0.19 MGD (8.5 l/s)
Commissioned: June 2003
Raw Water Treated Water
Quality Quality
TOC 3 – 3.7 50-60%
mg/l Removal
Cryptosporidium N/A > 4 log
removal
Giardia N/A > 4 log
removal
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Sudbury Treatment Plant
ZeeWeed 1000 system with a
ZeeWeed 500 second stage
for 99% plant recovery
Location: Sudbury, Ontario, Canada
Peak Capacity: 13 MGD (49,400
m3/d)
Commissioned: May 2004
Raw Water Treated Water
Quality Quality
Cryptosporidium N/A > 4 log
removal
Giardia N/A > 4 log
removal
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Drinking Water Retrofit Installations
Location Operational Size (m3/d) Membrane
Anthony Henday, AB, Ph1: Feb 02 Ph1: ZW 500
Canada 11,000
Ph2: Nov 02
Cold Lake, AB, Canada Feb 05 Ph2:
9,463 ZW 1000
21,200
Picture Butte, AB, Canada Nov 01 4,500 ZW 500
Fenelon Falls, ON, Canada Oct 00 4,100 ZW 500
Saugeen Shores, ON, Jul 05 14,990 ZW 1000
Canada
Thornton, CO, USA Jun 05 136,260 ZW 500 / RO
Duck River, TN, USA Jul 04 35,960 ZW 1000
Draper, UT, USA Feb 04 25,000 ZW 1000
Marmagen, Germany Feb 01 1,200 ZW 1000
Osan Air Base, Korea Aug 04 10,200 ZW 1000
Southampton WTP Aug 06 14,990 ZW 1000
St Saviours, Guernsey, UK Mar 04 14 ZW 500
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Anthony Henday
Membrane Cassette Layout
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Cold Lake Water Treatment Plant
Retrofit of existing media
filters doubles plant capacity
in the same plant footprint
Location: Cold Lake, Alberta, Canada
Peak Capacity: 22-33 MLD
Commissioned: April 2005
Raw Water Treated
Quality Water
Quality
Turbidity (NTU) 0.2-1.0 < 0.05
Particle Counts 2,000-6,000 < 20
(counts/mL)
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WaterPro Water Treatment Plant
Draper, UT, United States
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