Mole Reactions and Stoichiometry Multiple
Mole Reactions and Stoichiometry Multiple
Mole Reactions and Stoichiometry Multiple
1. How many of phosphate ions are present in 3.01 x 1023 formula units of copper (II)
phosphate?
(A) 2
(B) 3
(C) 6.02 x 1023
(D) 1.2 x 1024
(E) 3.01 x 1023
2. A gas sample contains 16.0 g of CH4, 16.0 g of O2, 16.0 g of SO2, and 33.0 g of CO2.
What is the total number of moles of gas in the sample?
(A) 39 grams
(B) 78 grams
(C) 38 grams
(D) 57 grams
(E) 59 grams
4. How many mL of SO2 gas are present at STP in a 100 gram sample that is 6.4% SO2
by mass
(A) 2.24 mL
(B) 22.4 mL
(C) 2240 mL
(D) 1120 mL
(E) 11.2 mL
5. How many moles of chloride ions are present in a 66.7 gram sample of AlCl3?
7. The empirical formula for an oxide of nitrogen that is 30.4% by mass nitrogen is
(A) NO
(B) NO2
(C) N2O
(D) NO4
(E) NO3
8. Rubbing alcohol was found to contain 47.0 % carbon, 10.0 % hydrogen, and the
remaining mass was due to oxygen. What is the empirical formula of rubbing alcohol?
(A) C3H8O
(B) C2H6O
(C) CH3O
(D) C2H4O
(E) CHO
9. Potassium metal (3.91 g) is allowed to react with excess oxygen (O2). The reaction
yields 7.11 g of an explosive, yellow solid called a “superoxide.” What is the empirical
formula of the compound?
(A) KO
(B) KO2
(C) K2O
(D) K2O3
(E) K3O2
10. Hydrated salts are very common. If you heat 2.374 g of CoCl2 • x H2O, and find that
1.294 g of CoCl2 remains, what is the value of x?
(A) 2
(B) 3
(C) 4
(D) 5
(E) 6
11. When a hydrate of Na2CO3 is heated until all the water is removed, it loses 33.8
percent of its mass. The formula of the hydrate is
(A) C4H4O5
(B) C10H12
(C) C7O3
(D)C6H12O3
(E) C4H8O5
13. A 54 gram sample of an unknown hydrocarbon was burned in the presence of excess
oxygen to produce 44.0 grams of carbon dioxide and 27.0 grams of water. A mass
spectrometry analysis produced a molecular ion peak with an mass of 30.08 u. What
is the molecular formula of the hydrocarbon?
(A) CH3
(B) C2H3
(C) CH6
(D) C2H8
(E) C2H6
(A) CH2O
(B) CH3O
(C) CH4O
(D) C2H4O
(E) C4H2O
15. To find the formula of a compound composed of iron and carbon monoxide, Fex(CO)y,
you burn the compound in pure oxygen according to the following, unbalanced
equation.
If you burn 1.959 g of Fex(CO)y and find 0.860 g of Fe2O3 and 2.133 g of CO2, what is
the empirical formula of Fex(CO)y?
(A) Fe(CO)4
(B) Fe2(CO)9
(C) Fe(CO)5
(D) Fe(CO)6
(E) Fe2(CO)3
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Chemical Reactions and Stoiciometry
3 A + 2 B → A3B2
(A) I only
(B) II only
(C) III only
(D) II and III
(E) I, II, and III
(A) 1
(B) 2
(C) 3
(D) 4
(E) 6
18. When the following equation is balanced, the coefficients are __________.
(A) 2, 3, 4, 4
(B) 1, 4, 8, 9
(C) 2, 12, 8, 9
(D) 4, 4, 32, 36
(E) 2, 25, 16, 18
19. When the following equation is balanced, the coefficients are __________.
(A) 2, 3, 1, 6
(B) 2, 1, 3, 2
(C) 1, 1, 1, 1
(D) 4, 6, 3, 2
(E) 2, 3, 2, 3
(A) you need 2.2 moles of O2 for complete reaction and produce 2.2 moles of NO2.
(B) you need 1.1 moles of O2 for complete reaction and produce 2.2 moles of NO2.
(C) you need 1.1 moles of O2 for complete reaction and produce 3.3 moles of NO2.
(D) you need 1.0 moles of O2 for complete reaction and produce 2.0 moles of NO2.
(E) you need 2.0 moles of O2 for complete reaction and produce 1.0 moles of NO2.
22. The very stable compound SF6 is made by burning sulfur in an atmosphere of fluorine.
3 Mg + N2 → Mg3N2
(A) 8.04
(B) 24.1
(C) 16.1
(D) 0.92
(E) 13.9
(A) 101 L
(B) 11.2 L
(C) 44.8 L
(D) 89.6 L
(E) 67.2 L
25. Propane burns in the presence of oxygen to produce carbon dioxide and water vapor.
How many total moles of gas are produced when 50% of a 88.2 gram sample of
propane combusts?
(A) 3 mol
(B) 6 mol
(C) 7 mol
(D) 10 mol
(E) 15 mol
26. An aqueous solution of NaCl gives H2(g), Cl2(g), and NaOH when an electrical current
is passed through the solution.
If you begin with 10. liters of 0.15 M NaCl, how many grams of NaOH can be formed?
(A) 60. g
(B) 120 g
(C) 30. g
(D) 6.0 g
(E) 40. g
27. How many total liters of gas can be produced @STP if 9.0 grams of aluminum metal
react with 200 mL of 10.0 M HCl?
28. Pentacarbonyliron (Fe(CO)5) reacts with phosphorous trifluoride (PF3) and hydrogen,
releasing carbon monoxide:
(A) 15
(B) 5.0
(C) 24
(D) 6.0
(E) 12
29. Consider the following redox reaction. What is the amount of Cr3+ formed If 100.0 mL
of 0.200M Cr2O7 is mixed with 100.0 mL of 0.300M Cl- solution that contains a large
excess of H+?
31. Sulfur and oxygen react to produce sulfur trioxide. In a particular experiment, 7.9
grams of SO3 are produced by the reaction of 5.0 grams of O2 with 6.0 grams of S.
What is the % yield of SO3 in this experiment?
(A) 32
(B) 63
(C) 75
(D) 95
(E) 99
32. GeF3H is formed from GeH4 and GeF4 in the combination reaction:
(A) 3.24
(B) 5.56
(C) 6.48
(D) 2.78
(E) 2.16
33. Sulfur and fluorine react in a combination reaction to produce sulfur hexafluoride:
In a particular experiment, the percent yield is 79.0%. This means that in this
experiment, a 7.90-g sample of fluorine yields __________ g of SF6.
(A) 30.3
(B) 10.1
(C) 7.99
(D) 24.0
(E) 0.110
Precipitation Reactions
36. The equation for the reaction, BaCl2(aq) + K2CrO4(aq) → BaCrO4(s) + KCl(aq),
can be written as an ionic equation. In the ionic equation, the spectator ions are
37. Aqueous potassium chloride will react with which one of the following in an exchange
(metathesis) reaction?
38. With which of the following will the ammonium ion form an insoluble salt?
(A) chloride
(B) sulfate
(C) carbonate
(D) sulfate and carbonate
(E) none of the above
39. If aqueous solutions of barium iodide are sodium sulfate are mixed and the resulting
solution filtered, what ions would be present dissolved in the filtrate?
40. In a qualitative analysis for the presence of Pb2+, Mg2+, and Zn2+ ions in a aqueous
solution, which of the following will allow the separation of Pb2+ from the other ions at
room temperature?
41. The net ionic equation for formation of an aqueous solution of Al(NO3)3 via mixing solid
Al(OH)3 and aqueous nitric acid is __________.
43. Two aqueous solutions are mixed forming a blue precipitate. Which of the following
could be the correct identity of the two aqueous solutions?
44. A yellow precipitate forms when 0.10 M NaI(aq) is added to a 0.10 M solution of which
of the following ions?
(A) Pb2+(aq)
(B) Zn2+(aq)
(C) CrO42¯(aq)
(D) SO42¯(aq)
(E) OH¯(aq)
(A) 0.150 M
(B) 0.160 M
(C) 0.200 M
(D) 0.240 M
(E) 0.267 M
46. A 1.0 M sample of an aqueous solution contains 0.10 mol of NaI and 0.10 mol of CaI2.
What is the minimum number of moles of PbNO3 that must be added to the solution in
order to precipitate all of the I¯ as PbI(s) ?
47. What would be the correct order of ions from highest to lowest concentration in the
solution after 100 mL of 0.2 M Na3PO4 is mixed with 100 mL of 0.2 M AgNO3 (aq)?
49. Which statement below states a fact? (Hint: Remember the difference between
dissociation and ionization).
(A) All acids are strong electrolytes and dissociate completely when dissolved in water.
(B) Some acids are strong electrolytes and ionize completely when dissolved in water.
(C) Some acids are strong electrolytes and dissociate completely when dissolved in
water.
(D) Some acids are weak electrolytes and ionize completely when dissolved in water.
(E) Some acids are weak electrolytes and dissociate partially when dissolved in water.
51. Which one of the equations below represents what happens when NH3 is dissolved in
water?
HCl(aq) + NaCH3COO(aq) → ?
53. The following reactants are mixed in equal molar portions. Predict if the resulting
solution will be acidic,basic, neutral, or if there is not enough information given to tell
for sure.
HCl(aq) + NaHCO3(aq) → ?
(A) acidic
(B) basic
(C) neutral
(D) cannot be determined from information given
54. In the reaction, HClO3 + N2H4 ClO3- + N2H5+, which species are a conjugate
acid-base pair?
(A) PO4-3
(B) H2PO4
(C) H3PO4
(D) HPO4-2
(E) none of the above
(A) SO42-
(B) H2SO4
(C) HSO4+
(D) H+
(E) HSO3+
(A) H2O(l)
(B) HCO3– ion
(C) NH4+ ion
(D) H2PO4– ion
(E) NH3(aq)
(A) HNO3(aq)
59. Aqueous solutions of a compound did not form precipitates with Cl-, Br-, I-, SO42- ,
CO32-, PO43-, OH-, or S2-. This highly water-soluble compound produced the foul-
smelling gas H2S when the solution was acidified. This compound is __________.
(A) Pb(NO3)2
(B) (NH4)2S
(C) KBr
(D) Li2CO3
(E) AgNO3
60. The reaction between strontium hydroxide and chloric acid produces __________.
61. The balanced molecular equation for complete neutralization of H2SO4 by KOH in
aqueous solution is __________.
62. The balanced reaction between aqueous nitric acid and aqueous strontium hydroxide
is __________.
63. The net ionic equation for the reaction between aqueous nitric acid and aqueous
sodium hydroxide is __________.
(A) H+ (aq) + HNO3 (aq) + 2OH- (aq) → 2 H2O (l) + NO3- (aq)
(B) HNO3 (aq) + NaOH (aq) → NaNO3 (aq) + H2O (l)
(C) H+ (aq) + OH- (aq) → H2O (l)
(D) HNO3 (aq) + OH- (aq) → NO3- (aq) + H2O (l)
(E) H+ (aq) + Na+ (aq) +OH- (aq) → H2O (l) + Na+ (aq)
I. HI
II. HNO3
III. HF
IV. HBr
(A) III, IV
(B) I, II, III, IV
(C) I, III, IV
(D) II, III, IV
(E) I, II, IV
67. Classify the following compounds as weak acids (W) or strong acids (S):
69. Which of the following would you predict to be basic when dissolved in water?
(A) I only
(B) II, and III
(C) II, III, and IV
(D) III, IV, and V
(E) IV and V
70. What is the molarity of a NaOH solution if 28.2 mL of a 0.355 M H2SO4 solution is
required to neutralize a 25.0-mL sample of the NaOH solution?
(A) 0.801
(B) 0.315
(C) 0.629
(D) 125
(E) 0.400
71. Oxalic acid is a diprotic acid. If a solid material contains 53.66 percent of oxalic acid
(H2C2O4), by mass, then a 0.6543-g sample of that solid will require __________ mL of
0.3483 M NaOH for neutralization.
(A) 11.20
(B) 97.78
(C) 28.59
(D) 1.119
(E) 22.40p
72. A 25.5 mL aliquot of HCl (aq) of unknown concentration was titrated with 0.113 M
NaOH (aq). It took 51.2 mL of the base to reach the endpoint of the titration. The
concentration (M) of the acid was __________.
(A) 1.02
(B) 0.114
(C) 0.454
(D) 0.113
(E) 0.227
73. A 13.8 mL aliquot of 0.176 M H3PO4 (aq) is to be titrated with 0.110 M NaOH (aq).
What volume (mL) of base will it take to reach the equivalence point?
(A) 7.29
(B) 22.1
(C) 199
(D) 66.2
(E) 20.9
75. What is the identity of a monoprotic acid if after 1.26 gram sample of it is dissolved in
water, 50 mL of 0.4 M NaOH is needed to titrate it completely?
(A) HClO3
(B) HCl
(C) HBr
(D) HC3H6O3
(E) HNO3
What is the molarity of the base if 32.75 mL is required to titrate 1.732 g of the primary
standard?
(A) 0.5189 M
(B) 0.2590 M
(C) 1.732 M
(D) 3.861 M
(E) 3.275 M
Redox Reactions
(A) 0
(B) +1
(C) +2
(D) -1
(E) +3
(A) -1
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(B) +1
(C) +3
(D) +5
(E) +7
(A) -1
(B) +1
(C) +3
(D) +5
(E) +7
(A) +3
(B) +6
(C) +7
(D) +12
(E) +14
Which reaction below does not occur spontaneously upon mixing the reagents shown?
(A) Cr6+
(B) S2+
(C) H+
(D) O2-
(E) S4O62-
(A) Cr2O72-
(B) S2O32-
(C) H+
(D) Cr3+
(E) S4O62-
86. Which substance is serving as the reducing agent in the following reaction?
(A) H+
(B) Cr2O72-
(C) Ni
(D) H2O
(E) Ni2+
(A) Pb
(B) H2SO4
(C) PbO2
(D) PbSO4
(E) H2O
(A) Fe
(B) Cr
(C) O
(D) H
(A) I
(B) Mn
(C) O
(D) H
(A) I
(B) Mn
(C) O
(D) H
(A) Fe
(B) C
(C) O
(D) H
(E) I
(A) Fe
(B) C
(C) O
(D) H
(E) I
(A) HNO3
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(B) S
(C) NO2
(D) Fe2S3
(E) H2O
95. Zinc metal reacts with perchloric acid solution to produce zinc perchlorate (in solution)
and hydrogen gas, which escapes. The species being oxidized in this reaction is
(A) HClO4(aq)
(B) H2(g)
(C) Zn2+(aq)
(D) Zn(s)
(E) Zn(ClO4)2(aq)
96. Which of the following statements is true about oxidizing and reducing agents?
(A) Good reducing agent must lose electrons easily. Neutral metals or substances with
low ionization energies
(B) Good reducing agent must gain electrons easily. Neutral metals or substances with
low ionization energies
(C) Good oxidizing agents must lose electrons easily. Neutral or positive nonmetals or
highly positive metals
(D) Good oxidizing agents must gain electrons easily. Neutral or negative nonmetals or
highly negative metals
I. Na
II. MnO4-
III. F2
IV. I-
V. Fe+2
(A) I and II
(B) II and III
(C) II and III
(D) III and IV
(E) I and IV
I. HNO3 (concentrated)
II. K
III. Cr2O72-
IV. Fe2+
V. F-
(A) I, II and IV
(B) II and V
(C) II, III and V
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(D) II, IV and V
(E) III, IV, and V
99. What is the coefficient of the permanganate ion when the following equation is
balanced?
(A) 1
(B) 2
(C) 3
(D) 5
(E) 4
100. What is the coefficient of the dichromate ion when the following equation is
balanced?
(A) 1
(B) 2
(C) 3
(D) 5
(E) 6
101. What is the coefficient of Fe3+ when the following equation is balanced?
(A) 1
(B) 2
(C) 3
(D) 4
(E) 5
102. Balance the half-reaction, H2S → S8, taking place in acidic media. How many
electrons are needed to balance the half reaction?
103. Balance the half-reaction, C8H10 → C8H4O42, taking place in basic media. How
many electrons are needed to balance the half reaction?
104. Complete the balancing of the following half-reaction, taking place in basic media,
Cr(OH)4(aq) → CrO42(aq)
(A) 7
(B) 9
(C) 13
(D) 15
(E) 19
106. What is the balanced net ionic equation for the following reaction in an acidic
solution?
109. The reaction of Cl2 with itself can be carried out in basic solutions.
110. The following is the balanced net ionic equation for an oxidation-reduction reaction.
If you use 1.234 g of MnO2 (molar mass = 86.937g/mol), how many milliliters of
0.730M HCl solution are required for complete reaction?
(A) 2.5 mL
(B) 77.8 mL
(C) 4.86 mL
(D) 25.7 mL
(E) 38.9 mL
(A) 0.14 M
(B) 0.18 M
(C) 0.35 M
(D) 0.62 M
(E) 0.88 M
What color changes would you expect for the following redox processes
117. What would be the expected color change in the analyte given the following titration?
Answers
11. D 22. A
1. C 12. D 23. B
2. B 13. E 24. A
3. B 14. B 25. C
4. C 15. B 26. A
5. C 16. D 27. B
6. B 17. B 28. A
7. B 18. E 29. B
8. A 19. A 30. B
9. B 20. B 31. D
10. E 21. B 32. C
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33. C 62. D 91. D
34. A 63. C 92. A
35. D 64. B 93. D
36. C 65. E 94. D
37. C 66. A 95. D
38. E 67. E 96. A
39. C 68. E 97. C
40. B 69. D 98. D
41. D 70. A 99. B
42. A 71. E 100. A
43. C 72. E 101. B
44. A 73. D 102. B
45. B 74. A 103. E
46. C 75. E 104. D
47. A 76. B 105. C
48. B 77. B 106. B
49. B 78. D 107. C
50. D 79. D 108. D
51. C 80. B 109. D
52. C 81. B 110. B
53. A 82. A 111. E
54. D 83. D 112. D
55. D 84. A 113. C
56. B 85. A 114. E
57. C 86. C 115. A
58. D 87. A 116. B
59. B 88. B 117. C
60. D 89. A
61. E 90. B