Class 12 Chemistry Chapter 11 Alcohols, Phenols, andEthers MCQs
1. To get carboxylic acids directly from alcohol, which of the following oxidising agents is used?a) Alkaline KMnO
4
b) Aqueous KMnO
4
c) Acidified KMnO
4
d) Anhydrous CrO
3
Answer
: c
Explanation
: Strong oxidizers, such as acidified potassiumpermanganate or acidified potassiumdichromate, convert alcohol to carboxylic acid immediately. Using CrO
3
as the oxidising agent in ananhydrous media, however, only aldehyde can be produced.2. When phenol reacts with bromine water, what is the result?a) Brown liquidb) Colourless gasc) White precipitated) No reaction
Answer
: c
Explanation
: When phenol is treated with bromine water,a white precipitate is formed, which is2,4,6-Tribromophenol.3. The Lucas test was carried out on three different compounds: A, B, and C. Compounds A and Bwere turbid at ambient temperature, while compound C did not become turbid until it was heated.Which one of the compounds is tertiary in structure?a) Ab) Cannot be determined
c) Cd) A and B
Answer
: b
Explanation
: It is stated that A and B exhibit turbidityat room temperature, however it is not statedwhether the turbidity appears immediately or over a period of time. So compounds A and B may betertiary or secondary depending on whether turbidity appears immediately or after 5 minutesrespectively. Compound C may be primary.4. Which of the following compounds is formed when secondary alcohols are oxidised by [O]?a) Ether b) Aldehydec) Ketoned) Amine
Answer
: c
Explanation
: The oxidation of secondary alcohols bya nascent oxygen atom [O] yields the ketonemolecule.5. Which of the following processes does not result in the production of alcohol?a) Acid catalysed hydration of alkenesb) Free radical halogenation of alkanesc) Reduction of aldehydesd) Hydroboration-oxidation of alkenes
Answer
: b
Explanation
: When alkanes are halogenated by freeradicals, they form a mixture of haloalkanesrather than alcohols. Alcohols can be made from alkenes through acid catalysed hydration andhydroboration-oxidation, or from aldehyde reduction.6. The conversion of trialkyl borane to an alcohol does not require which of the following?
a) Sodium hydroxideb) Water c) Diboraned) Hydrogen peroxide
Answer
: c
Explanation
: In the presence of aqueous NaOH, trialkylboranes are oxidised by hydrogen peroxide toproduce alcohol. This conversion does not require diborane, although it is required for the creation of trialkyl boranes.7. Ethers may be used as solvents because they react only with which of the following reactants?a) Oxidising agentb) Basesc) Acidsd) Reducing agents
Answer
: c
Explanation
: Nucleophiles and bases cannot attackether. However, because of their capacity to solvecations by giving an electron pair from an oxygen atom, they are excellent solvents in many chemicalreactions. Ethers are less reactive than alcohols and react only with acids.8. An aryl carbon can be found in which of the following compounds?a) Ethanolb) Phenolc) Vinyl alcohold) Benzyl alcohol
Answer
: b
Explanation
: An aryl carbon is the sp
2
hybridisedcarbon of an aromatic ring to which the hydroxylgroup is connected. The OH group is connected to an aryl carbon in phenol.
9. It's called ether when the alkyl groups connected to either side of the oxygen atom in an ether aredifferent.a) mixedb) symmetricalc) simpled) diethyl
Answer
: a
Explanation
: A mixed or unsymmetrical ether is onein which the alkyl or aryl groups on either side of the O atom differ.10. Which of the following alcohols is not polyhydric?a) Propylene glycolb) Ethylene glycolc) Cyclohexanold) Benzene-1,2-diol
Answer
: c
Explanation
: Polyhydric alcohols include two or morehydroxyl groups and are classified as glycols inthe common system or diols and triols in the IUPAC system.