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Sec: SR.IIT_*CO-SC(MODEL-A) Date: 17-09-2023

Time: 3HRS CAT-5 Max. Marks: 186

17-09-23_SR.IIT_STAR CO-SC(MODEL-A) _JEE ADV_CAT-5_SYLLABUS

MATHEMATICS: PT-1 TO PT-7 SYLLABUS ONLY

PHYSICS: PT-1 TO PT-7 SYLLABUS +RAY & WAVE OPTICS

CHEMISTRY: PT-1 TO PT-7 SYLLABUS ONLY

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Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
TIME:3HRS IMPORTANT INSTRUCTIONS Max Marks: 186

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 1 – 8) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 9 – 14) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +3 0 6 18
27.30)
Matrix Matching Type
Sec – III (Q.N : 15 – 18) +3 -1 4 12
(Each match consist of 2 questions)
Total 18 62

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 19 – 26) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 27 – 32) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Matrix Matching Type
Sec – III (Q.N : 33 – 36) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
One of More Correct Options Type
Sec – I (Q.N : 37 – 44) +4 -1 8 32
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – II (Q.N : 45 – 50) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +3 0 6 18
127.30)
Matrix Matching Type
Sec – III (Q.N : 51 – 54) (Each match consist of 2 questions)
+3 -1 4 12
Total 18 62

SR.IIT_*CO-SC Page. No. 2

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MATHEMATICS
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
1. A is a set containing 8n9 elements. A subset 8P9 of 8A9 is chosen at random. The set A is
reconstructed by replacing the elements of 8P9. A subset Q is again chosen at random.
Then the number of ways of selecting P & Q so that

A) The number of ways of choosing P, Q such that P = Q is 2 n

B) The number of ways of choosing P, Q such that P ÷ Q contains just

one element is n.3n 1

C) The number of ways of choosing P, Q such that P ø Q contains just

one element is 3n

D) The number of ways of choosing P, Q such that P, Q contains same number of

2n
elements Cn

2. Triangles are formed by joining vertices of a convex octagon then number of triangles

A) In which exactly one side common with the side of octagon is 32

B) In which atmost one side common with the side of octagon is 48

C) In which atleast one side common with the side of octagon are 50

D) Total number of triangles is 56

  
3. If a , b , c be non coplanar unit vectors equally inclined to one another at an angle ñ and if
      
a  b  b  c ý pa  qb  rc then which of the following is /are true

1 1
A) p = B) r ý
1  2 cos ñ 1  2 cos ñ

2 cos ñ 1
C) q ý D) r ý
1  2 cos ñ 1  2 cos ñ

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4.
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Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
A bag initially contains one red ball and two blue balls. An experiment consists of
selecting a ball at random, noting its colour and replacing it together with an additional
ball of the same colour. If three such trials are made then

A) Probability that at least one blue ball is drawn is 0.9

B) Probability that exactly one blue ball is drawn is 0.2

C) Probability that all the drawn balls are red given that all the drawn balls are of the
same colour is 0.2

D) Probability that at least one red ball is drawn is 0.6

5. Cards are drawn one by one from a pack of well shuffled cards with out replacement
until all the cards are drawn then

A) Chance of getting a spade at the 13th trail is 1/13.

B) Chance of getting a spade at the 13th trail is ¼.

C) Chance of getting last card as a spade is 1/4.

D) Chance of getting king at the 5th trail and queen at the 10th trail is 4/663.

6. The letters of the word PROBABILITY are written down at random in row. Let E1
denotes the event that two I9s are together and E2 denotes the event that two B9s are
together, then
3 2
A) P ø E1 ù ý P ø E 2 ù ý B) P ø E1 ÷ E 2 ù ý
11 55
18 1
C) P ø E1 ø E 2 ù ý D) P ø E1 / E 2 ù ý
55 5
7. Consider the set of eight vectors V ý {ai  bj  ck ; a, b, c þ{1,1}} . No of ways of selecting
three non- coplanar vectors from V is pand the number of ways selecting three co-planar
vectors from V is q then
A) p  q ý 56
B) No of positive integral divisors of p is 6
C) No of positive integral divisors of q is 6
D) p-q=6

SR.IIT_*CO-SC Page. No. 4

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8. A line with direction cosines proportional to 2, 1, 2 meets the line x  y  a  z at P and
the line x  a  2 y  2 z at Q. If the mid point R of line segment joining P and Q lies on
x  2 y  z  14 then

A) R  ø4,3, 4ù B) Q is nearer to origin than P

C) PQ  6 D) OQ  3

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
9. Govindam has 8x9 children by his 1st wife. Geethas has 8x+19 children by his 1st husband.
They marry and have children of their own. The whole family has 24 children.
Assuming that two children of the same parents do not fight, then the maximum number
of fights that can take place is
 
10. In a triangle ABC, CAB ý 90Ā , AB ý 1, AC ý 3 and a point P inside the ABC satisfies
    
PA PB PC  PC  PB
     ý 0 , then  is equal to………..
PA PB PC PA

11. There are two die A and B both having six faces. Die A has three faces marked with 1,
two faces with 2, and one faces marked with 3. Die B has one face marked with 1, two
faces marked with 2 and three faces marked with 3. Both dies are thrown randomly
once. If E be the event of getting sum of the numbers appearing on top faces equal to x,
P(E) is maximum if x is _____

12. If the papers of 4 students can be checked by any one of the 7 teachers. If the probability
that all the 4 papers are checked by exactly 2 teachers is A, then the value of 49 A must
be

13. Let L1 : x ý y ý z and the line L2 : 2x  y  z 1 ý 0 ý 3x  y  2z  2 and if the shortest distance

between the lines L1 and L2 is d then the value of 2d2 =

SR.IIT_*CO-SC Page. No. 5

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Narayana IIT Academy

17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
14. The vector OA ý i  2 j  2k turns through a right angle while passing through the positive
 
x-axis on the way, the vector in the new position is OB . If the vector OA is turned
through a right angle while passing through the positive y-axis on the way, the vector in
   
the new position is OC . If the volume of tetrahedron formed by OA, OB, OC as
coterminous edges is V then [V] equals ([ ] is GIF)

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.15 and Q.16 by appropriately matching the lists based on the information
given in the paragraph
Triangle is formed by joining the vertices of a cube

Column – I Column – II
a) Probability that the triangle is isosceles or p) 3
14
equilateral is greater than
b) Probability that the triangle is isosceles but q) 2
7
not equilateral is smaller than
c) Probability that the triangle is scalene is r) 3
7
greater than
d) Probability that the triangle is right angled is s) 4
7
greater than or equal to
t) 6
7

15. Which of the following is the only CORRECT combination?

A) a þ s B) a þ q C) b þ p D) c þ t

16. Which of the following is the only INCORRECT combination?

A) a þ p B) d þ p C) c þ s D) c þ q

SR.IIT_*CO-SC Page. No. 6

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Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Answer Q.17 and Q.18 by appropriately matching the lists based on the information
given in the paragraph
Let X ý 1, 2,3....,10. A, B, C are three sets such that A ý X , B ý X and C ý X .

Column-1: Contains types of three subsets of X.

öEö ö Eö
Column-2: Contains conditional probabilities P ÷ ÷ or P ÷ ÷ where
ø E1 ø ø E2 ø

E: Selecting three subsets of X according to column-1

E1 : Selecting three subsets of X such that n ø A ÷ B ù ý 5

E2 : Selecting three subsets of X such that n ø A ø B ù ý 5

Column – I Column – II
öEö
A) A ÷ B ÷ C  2,3, 4,5,6 and A = B = C P) P÷ ÷ ý 0
ø E1 ø
öEö 1
B) A ø B ø C ý 3, 4,5 Q) P ÷ ÷ ý 10
ø E1 ø C5 .125
ö Eö 31
C) A ÷ B ÷ C ý 3, 4,5,6,7 and A ý B  C R) P ÷ ÷ ý 10
ø E2 ø C5 .125
öEö
D) A ø B ø C ý 6,7,8,9,10 and A ý B  C S) P÷ ÷ ý 0
ø E2 ø
öEö 1
T) P ÷ ÷ ý 10
ø E1 ø C5 .35
[Note: S  T denotes Sa superset of T, means S contains all elements of T]

17. Which of the following options is the only correct combination?

A) A – P B) B–S C) C–Q D) D–P

18. Which of the following options is the only incorrect combination?

A) A–Q B) B–P C) B–S D) D–S

SR.IIT_*CO-SC Page. No. 7

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Narayana IIT Academy
PHYSICS
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
19. In a Young9s double slit experiment, the slit separation d is 0.3 mm and the screen
distance D is 1 m. A parallel beam of light of wavelength 600 nm is incident on the slits
at angle ñ as shown in figure. On the screen, the point O is equidistant from the slits
and distance PO is 11.0 mm. Which of the following statement(s) is/are correct?

0.36
A) For ñ ý degree, there will be destructive interference at point O.
ð

B) Fringe spacing depends on ñ

0.36
C) For ñ ý degree, there will be destructive interference at point P.
ð

D) For ñ ý 0 , there will be constructive interference at point P.

20. A free hydrogen atom after absorbing a photon of wavelength ü a gets excited from the
state n = 1 to the state n = 4. Immediately after that the electron jumps to n = m state by
emitting a photon of wavelength ü e . Let the change in momentum of atom due to the
absorption and the emission are pa and pe respectively.

üa 1
If ý , which of the option(s) is/are correct?
üe 5

[Use hc = 1242 eV nm; 1 nm = 10-9m, h and c are Planck9s constant and speed of light,
respectively]

SR.IIT_*CO-SC Page. No. 8

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Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
pa 1
A) ý
pe 2

B) The ratio of kinetic energy of the electron in the state n = m to the state n = 1
1
is
4

C) üe ý 418 nm

D) m = 2

21. A thin convex lens is made of two materials with refractive indices n1 and n2, as shown
in figure. The radius of curvature of the left and right spherical surfaces are equal. f is
the focal length of the lens when n1 = n2 = n. The focal length is f  f when n1 = n and
n2 = n  n . Assuming n üü (n 1) and 1 < n < 2. The correct statement(s) is/are.

f n
A) ü
f n

n f
B) If ü 0 then þ0
n f

C) For n = 1.5, n ý 103 and f = 20 cm, the value of | f | will be 0.02 cm (round
off to 2nd decimal place).
f n
D) The relation between and remains unchanged if both the convex
f n
surfaces are replaced by concave surfaces of the same radius of curvature.

SR.IIT_*CO-SC Page. No. 9

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22.
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
The circular scale of a screw gauge consists of 50 divisions and the linear distance
travelled by screw in one complete rotation is equal to 0.5mm and it is equal to the value
of one pitch scale division. When nothing is placed between the studs, 46th division of
circular scale coincides with the index line of pitch scale and zero of the pitch scale is
just inside the circular scale. Now a thin plate of thickness 4.68mm is inserted between
the studs by unscrewing the circular scale and fit it just tight to measure its thickness.
Choose the correct option(s)

A) The minimum number of rotations to be done by the ratchet in order to insert the
plate during unscrewing is 5

B) If Mth circular scale division of screw gauge coincides with the index line while
taking the reading, then M is 14

C) The minimum number of rotations to be done by the ratchet in order to insert the
9
plate during unscrewing is
2

D) If Mth circular scale division of screw gauge coincides with the index line while
taking the reading, then M is 7

1
23. For an experiment of photoelectric effect, a graph between and stopping potential
ü
(V) of three metals A, B and C whose work functions are ö A ,öB & öC respectively, is
plotted as shown in the figure.
Which of the following statement(s) is/are correct? [Here ü is the wavelength of
incident light]

A) ñ A ü ñ B ü ñC B) ñ A ý ñ B ý ñC C) ö A ü öB ü öC D) ö A ý öB ý öC

SR.IIT_*CO-SC Page. No. 10

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24.
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Interference pattern experiment is done on the surface of water by using a slit in an
opaque plate AB and screen is placed at 50 cm from slit. Slit is 1 cm above water surface
o
and light of wavelength ü ý 6000 A is falling over it. The plate is oscillating according
to equation x ý (50cm  Asin t ) along the BO, where A = 1 cm,  ý 100 rad / s . Point
O is just above the water surface and another point P is 5 cm above the water surface.
Plate AB is just above the water surface.

A) Maximum speed of fringe at point P is 10 cm/s nearly

B) Maximum speed of fringe at point P is 5 cm/s

C) Intensity at point O is minimum

D) Intensity at point O is maximum

25. A solid glass cylinder of radius R and refractive index ý ý 2 is cut and a quarter
portion is carved and kept in vaccum as shown. A horizontal ray of light falls normally
on the vertical surface as shown.

SR.IIT_*CO-SC Page. No. 11

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Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
ð
A) For ñ ü , TIR takes place on curved surface.
4
B) If a ray suffers TIR only from the curved surface 8n9 times before hitting the
nð
corner B(R,O), then ñ for the ray follows ñ ý
2n  1

2R
C) For very small value of ñ , the ray intersects the x-axis at x ý
2 1
R
D) For very small value of ñ , the ray intersects the x-axis at x ý .
2 1
ð
26. The figure shows a ray incident at an angle i ý . If the plot drawn shown in the
3
ý1
variation of | r  i | versus ý k , (r = angle of refraction)
ý2

2 ð
A) the value of k1 is B) the value of ñ1 ý
3 6
ð
C) the value of ñ 2 ý D) the value of k2 is 1
3
SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
27. Suppose a 88 226
Ra nucleus at rest and in ground state undergoes ñ -decay to a 86
222
Rn
nucleus in its excited state. The kinetic energy of the emitted ñ particle is found to be
4.44 MeV. 86222
Rn nucleus then goes to its ground state by ÷ -decay. The energy of the
emitted ÷ photon is _______ keV.
226 222
[Given: atomic mass of 88 Ra = 226.005 u, atomic mass of 86 Rn = 222.000 u, atomic
mass of ñ particle = 4.000 u, 1 u = 931 MeV/c , c is speed of the light]
2

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28.
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
A perfectly reflecting mirror of mass M mounted on a spring constitutes a spring-mas
4ð M 
system of angular frequency  such that ý 1024 m 2 with h as Planck9s constant.
h
N photons of wavelength ü ý 8ð 10 m strike the mirror simultaneously at normal
6

incidence such that the mirror gets displaced by 1 ým . If the value of N is

x 1012 , then the value of x is ______.
[Consider the spring as massless]

29. A composite lens is made by filling the two half of the lens by medium of refractive
3
index n1 ý and n2 ý 2 as shown. The radius of curvature of both sides of lens is R1 &
2
R2 of 30 cm & 45 cm respectively. What should be the refractive index of a liquid
medium in which if this lens is dipped completely, the effective power of the lens
becomes zero.

30. On the 8+y9 axis, two identical coherent sources S1 & S2 separated by distance 8d9 emits
light wave each of wavelength 8 ü 9. Plane x ý 0 serves as an imaginary boundary
between two medium of ref index ý ý 1 & ý ý 1.125 .
If a maxima is observed just on the left of origin and a minima is observe just on the
right of origin, then the minimum non-zero value of d (in ým ) is ( ü ý 4000 nm in air)

SR.IIT_*CO-SC Page. No. 13

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40 40
31. In a radioactive sample 19 K nuclei either decay into stable 20 Ca nuclei with decay

constant 4.5 1010 per year or into stable 40

18 Ar nuclei with decay constant 0.5 1010
40 40
per year. Given that in this sample all the stable Ca and
20 18 Ar nuclei are produced by

the 40
19 K nuclei only. In time t 109 years, if the ratio of the sum of stable 40
20Ca and 40
18 Ar
40
nuclei to the radioactive 19 K nuclei is 99, the value of t will be

[Given : ln 10 = 2.3]

32. The figure shown below is a picture of Vernier screw gauge. Main scale or pitch is 0.5
mm. There are 50 divisions on circular scale. 9 circular scale divisions correspond to 10
vernier scale divisions. What is the reading R (in mm)? Fill 10R in the OMR.

(In figure, 2nd vernier scale division coincides with 30th screwgauge division. 11th
division of main scale is just visible).

SR.IIT_*CO-SC Page. No. 14

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SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.33 and Q.34 by appropriately matching the lists based on the information
given in the paragraph
Consider a linear extended object that could be real or virtual with its length at right angles to
the optic axis of a lens. With regard to image formation by lenses, match Column – I
with Column – II for all possible cases: Assume medium outside the lens to be air.

Column – I Column – II
Image of the same size as the
P) 1) Concave lens
object
Virtual image of a size greater
Q) 2) Convex lens
than the object
Real image of a size smaller than
R) 3) Not possible
the object
S) Real and erect image

33. If the object is real then

A) P-2, Q-2, R-2, S-3 B) P-2, Q-2, R-1, S-2

C) P-1, Q-1, R-1, S-2 D) P-1, Q-1, R-2, S-3

34. If the object is virtual then

A) P-1, Q-2, R-1, S-2 B) P-1, Q-1, R-2, S-1,2

C) P-2, Q-2, R-1, S-1 D) P-1, Q-1, R-2, S-2

Answer Q.35 and Q.36 by appropriately matching the lists based on the information
given in the paragraph
Four combinations of two thin lenses are given in List – I. The radius of curvature of all curved
surfaces is r and the refractive index of all the lenses is 1.5. Match lens combinations in
List – I with their focal length in List – II and select the correct answer using the code
given below the lists.

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LIST – I LIST – II

P) 1) 2r

r
Q) 2)
2

R) 3) r

S) 4) r

35. If the combination is kept in air, then

A) P-1, Q-2, R-3, S-4 B) P-2, Q-4, R-3, S-1

C) P-4, Q-1, R-2, S-3 D) P-2, Q-1, R-3, S-4

36. If the combination is kept in a medium of refractive index = 3, then the correct match of
magnitude of focal length is

A) P-1, Q-2, R-4, S-4 B) P-2, Q-4, R-4, S-1

C) P-4, Q-1, R-2, S-4 D) P-2, Q-1, R-4, S-4

SR.IIT_*CO-SC Page. No. 16

 Yashpatil TG~ @bohring_bot
Narayana IIT Academy
CHEMISTRY
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
37. Which of the following acids will decompose dissolved carbonates on warming
( Ka1 of H 2CO3 ý 4.3 107 )

A) 1M CH3COOHøaqù ø Ka1 ý 1.76 105 ù B) 1M BoricAcidøaqù ø Ka1 ý 5.8 1010 ù

C) 1M HCNøaqù ø Ka1 ý 4.79 1010 ù D) 1M HCOOHøaqù

38. 1) A ø aq ù  S2 ø aq ù þ Ag 2S ÿ  oxoAnion ø Xo nm  ù

black ppt

2)Xo mn   H 2SO 4  Cu þ Reddish brown fumes and solution acquires blue colour
ø con.ù ø copper throwings ù

3) B+Aøaqù þ C  D  E
ø metalù

B, D are oxoacids of Phosphorus, E is oxoacid of Nitrogen

Correct match (or) statement is /are
A) 8A9 is AgNO3øaqù
B) Reddish brown gas in reaction (2) is NO2 and blue colour solution is due to Cu II
ions
C) If 8B9 is H3PO2 , 8D9 is H3PO4
D) C  PCl5 þ AgCl  PCl3
39.

Correct statement
A) Fig-(a) represents heating in upper reducing flame
B) Fig-(a) represents heating in luminous flame
C) Fig-(b) represents heating in upper oxidising flame
D) Fig-(b) represents heating in non-luminous flame
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Narayana IIT Academy
40.
17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Tailing of Mercury is due to MO. The chloride of same metal (M) is 8X9. The 15 th group
hydride 8Y9
Decomposes in water and in the presence of light gives red phosphorus and H 2 .
Correct statement(s) is/are
A) Ozone with Hg gives MO B) X is HgCl2
C) Y is PH3 D) X  Y þ Hg3P2  HCl

41. Precipitate of SO 32 decomposes acidified KMnO4 solution as follows:

BaSO3  H2SO4 þ BaSO4  H2O  A

2KMnO4  3H2SO4 þ K 2SO4  2MnSO4  3H2O  5 ø O ù

A  H2O  ø O ù þ H2SO4

If 8A9 reacts with Cl2 in the presence of charcoal catalyst 8B9 is formed
B  P4 þ C  A (C is a chloride of Phosphorus)

Correct statement(s) is/are

A) 8A9 is SO2
B) Industrially 8A9 is produced as a by product of following reaction
D  O2 þ Fe2O3  'A'
MetalSulphide

8n9 factor of 8D9 is 11

C) 8C9 reacts with acetic acid and gives CH3COCl
D) 8B9 is SO2Cl2

42. HX  O2 
CuCl2
þ X 2  H 2 O ø Deacon`s process ù
ø Halogen ù

CaY2  H2SO4 þ CaSO4  HY

ø Calcium
halide ù ø con.ù ùHalogen Acid,ù
ûúHBonding ûú

HZ  P4O10 þ HPO3  A

[8HZ9 is oxo acid of nitrogen, A is oxide of central atom of Z with +5 oxidation state]
Correct statement(s) / reaction(s)
A) A is N2O5
B) S8  HZ þ H2SO4  NO2  H2O
øcon.ù

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C) The possibility of 8B9 (oxide of nitrogen) emitted from the exhaust systems of
supersonic jet aeroplanes might be slowly depleting the concentration of 8 O3 9 in upper
atmosphere due to B  O3 þ NO2  O2
D) Sulphuric acid because of its low volatility can be used to manufacture more volatile
acids like HX, HY & HZ from their corresponding salts
43. Pb ø NO3 ù2 øaqù  H2SO4 þ A ÿ HNO3
Whiteppt

Correct statement(s) regarding 8A9

A) precipitate 8A9 dissolves in CH3COONH4 on boiling
B) precipitate 8A9 dissolves in CH3COOH  K2CrO4 solution completely and forms clear
solution without any precipitate
C) precipitate 8A9 dissolves completely in very dilution KIøaqù and forms clear solution
without any precipitate
D) To PbS(lead sulphide), dil.HNO3  dil.H2SO4 and a few drops of alcohol is added then
it gives white precipitate 8A9
44. Which of the following is correct order of the property given below.

N
A) N ü ü
N N

(Nucleophilicity order on reaction with methyl Iodide)

N
ü N ü
B) N
N

(Basic strength order)

O NH

<
C)
N
NH

H (Basic strength order)

O2 N  CH 2  COOH þ CCl3  COOH
D)
ø Acidic strength order ù

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SECTION – II
Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of positive or
negative decimal numbers (place value ranging from Thousands Place to Hundredths place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
45. How many of the following represents correct order / statement(s)
a) IE1 Phosphorous þ Sulphur
b) IE1 F þ N þ O
c) IE1 Sb ü Te
d) S0 of òsulphur þ ñ sulphur
e) G0 is zero for the following species
white phosphorous, ñ Sulphur, F2 ø g ù ,Cl2 ø g ù ,Br2 ø  ù ,I2 øSù
f) H 0f is zero for the following species
white phosphorous, ñ Sulphur, F2 ø g ù ,Cl2 ø g ù ,Br2 ø g ù ,I2 ø g ù
[ IE1 = 1st Ionisation energy, S0 = Absolute entropy, G0 = Standard free energy charge,
H 0f = Standard enthalpy of formation]
46. Z Br, Z1 X are consecutive elements [Z is atomic number of Bromine]

Z1 At, Z1 1 Y are consecutive elements [ Z1 is atomic number of Astatine]

Z
If fluoride of Y is identified as YF , find value
n n
47. C10 H16  Cl2 þ A  C ø carbon ù

Br2  F2 þ B [Arrangement of valence electron pairs is trigonal bipyramidal]

ø Diluted with N2 ù

Br2  F2 þ D[Colourless liquid]

ø excess ù

The number of halogen atoms in each molecule of 8A9, in each molecule of B and in
ö n3 ö
each molecule of D are n1,n2 and n3 respectively, then find ÷ ÷ value
n
ø 1  n 2 ø

48. UøSù  ClF3øù þ UF6øgù  Xøgù

98 Cf 249  ZY48 þ 116 Og294  3øø neutron ù

önö
Sum of the atomic numbers of constituent atoms in one molecule of 8X9 is 8n9, find ÷ ÷
øZø
value

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49.
Yashpatil TG~ @bohring_bot
Narayana IIT Academy 17-09-23_SR.IIT_*CO-SC(MODEL-A)_JEE-Adv_CAT-5_Q’P
Among the following, how many non-metal oxides are acidic.
SO2 ,CO2 ,Cl2O7 , N2O5 ,Mn2O7 ,CrO3 ,V2O5 ,P4O10

50. On theoritical basis, considering the carbocation stability, the number of 1,2-shifts
during the following conversion is

SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.51 and Q.52 by appropriately matching the lists based on the information
given in the paragraph
G0 values of reactants and products are as follows :
CaOøsù  CO2øg ù þ CaCO3 G0 ý 134kJ / mole
G0  602  393  1129
kJ / mole

CaOøs ù  N 2O5ø g ù þ Ca ø NO ù2øs ù G 0 ý 272 kJ / mole

G 0  602  134  740
kJ / mole

CaOøsù  SO3øg ù þ CaSO4øsù G0 ý 372kJ / mole

G0  602  368  1317
kJ / mole

LIST – I LIST – II
I) CaCO3 ø s ù P) Strongly acidic
II) CO 2 ø g ù Q) Weakest acidic oxide
III) N 2O5 ø g ù R) Less stable
IV) SO3 ø g ù S) Most stable
V) Ca ø NO3 ù2 ø s ù T) Most reactive
VI) CaSO4 ø s ù U) Least reactive

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51. Which of the following is correct combination (from G0 values)

A) VI – S,U B) I – S,U C) V – Q,S D) VI – S,U,Q

52. Which of the following is correct combination (from G0 values)

A) IV – P, V – R B) V – T, IV – Q C) II – P, I – T D) III – Q, II - P

Answer Q.53 and Q.54 by appropriately matching the lists based on the information
given in the paragraph

LIST – I LIST – II
CH 3 Cl

Cl & CH 3 H
P) H I) Enantiomers
C2 H5
C2 H5

Br
Cl
Q) II) Identical
& Cl
Br

CH 3 CH 3

& Geometrical
R) III)
Isomers

CH 3 CH 3

S) IV) Diastereomers
&

53. Which of the following match is correct?

A) P – I B) R- I C) Q – I D) S- III
54. Which of the following match is correct?
A) Q – IV B) R- III C) S- II D) P – IV

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SPACE FOR ROUGH WORK

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SPACE FOR ROUGH WORK

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