SANDEEP GANIGA ,HOD CHEMISTRY ,SRI VENKATRAMANA PU COLLEGE KUNDAPURA
SRI VENKATRAMANA PU COLLEGE KUNDAPURA
Important Questions(
For average and below average students) PASSING PACKAGE
SUBJECT: II PU CHEMISTRY (2023-2024)
Prepared By:
Sandeep Ganiga
M.Sc (Organic Chemistry)
HOD of Chemistry Sri Venkatramana PU College Kundapura, Udupi Dist. Mob. 9902628785 Email: sganiga21@gmail.com
1.Solutions
1. Problems on Colligative properties. Relative lowering of vapourpressure:
°−°
=
×
×
Elevation of boiling point:
∆
=
××
×
Depression in freezing point:
∆
=
××
×
Osmotic pressure:
=
×
×
2. Write any two differences between ideal and non-ideal solutions. Ans: Ideal Non-ideal 1. They obey Raoults law 1. They obey Raoults law 2.
∆
=0
2.
∆
≠0
3. .
∆
=0
3.
∆
≠0
SANDEEP GANIGA ,HOD CHEMISTRY ,SRI VENKATRAMANA PU COLLEGE KUNDAPURA
3.Write any two differences between positive and negative deviation. Ans: 4. What is reverse osmosis ?Mention any one of its use. Ans: Flow of solvent out of a solution, through a semipermeable membrane, when pressure larger than the osmotic pressure is applied to the solution side. Use: Desalination of sea water
5. State Raoult’s law.
Ans: In a solution of volatile liquids, the partial pressure of each component of the solution is directly proportional to its mole fraction.
6. State Henry’s law.Write its mathematical form.
Ans: “ Mole fraction of gas in the solution is proportional to the partial pressure of t
he gas over the solution P=K
H
X 7. What do you expect to happen when RBC is placed in (i) 1% NaCl solution and (ii) 0.5% NaCl solution. Ans: (i) In 1% NaCl solution RBC will Shrink. (ii) In 0.5% NaCl solution RBC will Swell 8. What are azeotropes? Ans: Binary liquid mixtures having the same composition in liquid and vapour phase and boil at a constant temperature are called azeotropic mixtures. Minimum boiling azeotropes: Mixture of ethanol(95%) and water(5%) Maximum boiling azeotropes: Mixture of nitric acid(68%) and water (32%) 9. What are isotonic solutions? Ans: Two solutions having a same osmotic pressure at a given temperature. 10.What is the value of vantHoff factor (i) for K
2
SO
4
(ii) MgSO
4
(iii) Ethanoic acid in benzene ? Ans: (i) 3 (ii) 2 (iii) 0.5 11. Define molarity? How does it vary with temperature? Ans: Number of moles of solutes present in one litre of solutions. Inversly or as temperature increases, molarity decreases 12. How solubility of gas in liquid varies with (i) Temperature (ii) Pressure Ans: (i) Temperature increases solubility of gas in liquid decreases. (ii) Pressure increases solubility of gas in liquid increases Positive Negative 1.
∆
>0
1.
∆
<0
2.
∆
>0
2.
∆
<0
3. Solvent
–
solute interaction is weaker than solvent-solvent and solute
–
solute interaction 3. Solvent
–
solute interaction is stronger than solvent-solvent and solute
–
solute interaction
SANDEEP GANIGA ,HOD CHEMISTRY ,SRI VENKATRAMANA PU COLLEGE KUNDAPURA
2.Chemical Kinetics
1.
Derive an integrated rate equation for the rate 2. Derive an integrated rate equation for the rate constant for a zero order reaction rate constant for a first order reaction
.
3. What is pseudo first order reaction ? Give an example.
Ans: Reactions of higher order which are made first order by taking the relative concentration of all the reactants very high except one called pseudo first order reaction. Example: Inversion of cane sugar
C
12
H
22
O
11
+ H
2
O C
6
H
12
O
6
+ C
6
H
12
O
6
H
+
SANDEEP GANIGA ,HOD CHEMISTRY ,SRI VENKATRAMANA PU COLLEGE KUNDAPURA
4. Write any two differences between order and Molecularity. Ans: 5. What are two criteria for effective collision according to the collision theory? Ans: (i) proper orientation of reactant (ii) Activation energy. 6. Draw a graph of potential energy versus reaction co ordinate to show the effect of a catalyst on activation energy. 7. Problems on: 1.
12⁄
=
.693
2.
=
2.33×
−
8. Write the Arrhenius equation and mention what each term stands for. Ans:
=.
−
k- rate const , T- temperature A- Arrhenius const, Ea
–
Activation energy 9. Unit of rate constant of a reaction is the same as unit of rate of reaction . What is the order of the reaction ? Ans: Zero order 10. What happens to the half life period of a first order reaction, if the initial concentration of the reaction increased ? Ans: Half life period of a first order reaction independent of initial concentration (or remains same). Order Molecularity 1.It may be whole number , fraction or zero 1. It cannot be fraction or zero 2. May or may not depends on the balanced equation 2. Depends on balanced equation