Real XI Chemistry Session Ending Papers

1 AA-1105
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Roll No.:
TERM END (I|) EXAMINATION 2021-22

SUBJECT : CHEMISTRY THEORY
CLASS: XI
Time:2 Hours MM:35
GENERAL INSTRUCTIONS:
Read the following instructions carefully.

1. There are 12 questions in this question paper with internal choice.
2. SECTION A: Q. No.1 to 3 are very short answer questions
carrying 2 marks each.
3. SECTION B -Q. No. 4 to 11 are short answer questions carrying
3 marks each.
4. SECTION C- Q. No. 12 is a case based question carrying 5 marks.
5. All questions are compulsory.
6. Use of log tables and calculators is not allowed
SECTION A
1 a) Calculate the temperature of 4.0 moles of a gas occupying 5
dm at 3.32 bar. (R= 0.083 bar dm K-1 moll) 1x2
b) Which type of intermolecular forces exist among the following

molecules?
(i) N, molecules (ii) HCI molecules 1x2
2 a) What will be the sign of 'AS' for the following reaction?

CaCO3 (s) ’ CaO (s) +
COz (9) 1x2
b) Define Hess's law of constant summation

3 a According to Le-Chatelier's Principle. What is the effect of:
(i addition of H, (ü) removal of CO on the equilibrium: 1x2
2 (9) + CO
(g) CH,oH (9)
[P.T.O.]
XI-Chemistry
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b) What will be the conjugate bases for the Bronsted acids: HF and
H,SO4 1x2
SECTION B
4 a) What is common ion effect? 1 x3

b) Write the Ksp expressions for Ag,CrO,.
c) Calculate the pH of 0.005 M HCI solution (Given;log 5= 0.6990)
OR
c) At 473 K, equilibrium constant, K, for decomposition of PCI, is

8.3 x 10, If decomposition is depicted as:
PCls (g) PCI, (g) + Clz (g) AHO = 124.0 kJ mo1
a) Write an expression for K, for the reaction. 1 X3
b) What is the value of K. for the reverse reaction at same
temperature?
c) What would be the effect on K, if
(i) the pressure is increased (ii) the temperature is increased?
5 a) If water vapour is assumed to be a perfect gas, molar enthalpy change
for vaporisation of 1 mol of water at 1bar and 100°C is 41kJ mot",
Calculate the internal energy. change when 1 mol of water is vaporised
at 1 bar pressure and 100°C. 2
b) For an isolated system, U =0, what will be S? 1
OR
a) Define third law of thermodynamics. 1
b) Enthalpy of combustion of carbon to CO, is -393.5 kJ mo1.
What amount of heat will be released upon formation of,35.2 g
of CO, from carbon and oxygen gas. 2
Pressure versus volume graph for a real gas and an ideal gas are
shown in the figure. 1x3
Pressure
6-Real Gas
tldeal Gas
Volume
XI Chemistry [P.T.O.]
3 AA-1105
(i) Answer the following guestions on the basis of this graph.
(i) Interpret the behaviour of real gas with respect to ideal gas ()
at low pressure and () at high pressure.
(ii) Mark the pressure and volume by drawing a line at the point
where real gas behaves as an ideal gas.
7 Give reasons:
1x3
i) Conc. HNO, can be transported in aluminium container.
ii) A mixture of dilute NaOH and aluminium pieces is
used to open drain.
ii) Graphite is used as lubricant.
8. Give reason 1x3
(a) Why CCI, is immiscible in water, whereas SiCI, is easily
hydrolysed
(b) Carbon shows catenation property but lead does not.
(c) Lead does not form Pbl,
9 (a) CH,-CH(Br)-CH,-CH,. Write IUPAC name 1x3
(b) Write IUPAC names of the products obtained by addition
reactions of HBr to hex-1-ene_in peroxide's
() absence (i) presence.
OR
(a) Which of the cofirmers of butane will be more stable and why
(b) Write an equation in case of Wurtz reaction(stating all conditions)
(c) How will you convert benzene into p- nitrobromobenzene.
10 (a) An alkene 'A' on ozonolysis gives a mixture of ethanal and
pentan-3-one. Write structure and IUPAC name of A 1x3
(b) Benzene is highly unsaturated but undergoes substitution
reactions easily
(c) rather than addition.
Explain Friedel-Crafts alkylation reaction with chemical equation.
11 An organic compound 'A' with molecular formula C,H,0 reacts with conc.
H,SO, to give 'B' which on reaction with HCI gives 'C'. Compound C
reacts with metallic sodium to give D. ldentify compounds A, B, C and
D.
1x3
XI-Chemistry [P.T.O.]
2
22 -A
23
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OR
An alkene A' contains three C -C, eight C-H bonds and one
C- C pi ( ) bond. 'A on ozonolysis gives two moles of an aldehyde
of molar mass 44 u. Write the structure and IUPAC name of 'A. 2
(b) Draw the Newman projections of the eclipsed and staggered

conformers of ethane. 1
SECTION C
Read the passage given below and answer the questions that follow:5
The first element of each group, lithium in the first group and beryllium
in the second group differs from the rest of the elements but have
similar properties to diagonally situated elements. Lithium resembles
Mg and Be resembles Aluminium. Boron resembles with Silicon. The
compounds of alkali metals are predominantly ionic. The oxides and
hydroxides are soluble in water forming strong alkalis. Important
compounds of sodium include sodium carbonate, sodium chloride,
sodium hydroxide, and NaHCO,. Sodium hydroxide is manufactured by
the Castner-Kellner process and sodium carbonate by the Solvay
process. The oxides and hydroxides of group 2 elements are less
basic than group 1, oxides, and hydroxides. CaO, Ca(OH),, CaSO,.1/
2 H,O, CaCO, and cement are industrially important compounds.
Portland cement is an important constructional material. It is manufactured
by heating limestone and clay in a rotary kiln. The clinker obtained is mixed
with 2 to 3% gypsum. Nat, K*, Mg and Ca are found in large amounts
in biological fluids. These ions perform important biological functions such
as maintenance of ion balance and nerve impulse conductions.
(a) What is the cause of the diagonal relationship?
(b) Why does the first element of each group differ from the rest of
the elenments?
(c) Why is BeSO, soluble in water but BaSO, is not ?
(d) Which of the folowing alkali metals gives hydrated salts? ()
Li (ü) Na (ii) K (iv) Cs
OR
The hydroxide, which is best soluble in water, is

() Sr(OH), () Ba(OH)), (ii) Ca(OH), (iv) Mg(OH),
XI Chemistry

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1 AA-1105

Please check total printed pages before start 4

TERM END (I|) EXAMINATION 2021-22

Read the following instructions carefully.

b) Which type of intermolecular forces exist among the following

2 a) What will be the sign of 'AS' for the following reaction?

b) Define Hess's law of constant summation

4 a) What is common ion effect? 1 x3

c) At 473 K, equilibrium constant, K, for decomposition of PCI, is

(b) Draw the Newman projections of the eclipsed and staggered

The hydroxide, which is best soluble in water, is

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