SDS8

ventós
SAFETY DATA SHEET

Conforms to the requirements of the Global Harmonized System (GHS)
LEADERS
BERGAMOTE L FIRMENICH 631
IN ESSENCE
Revision date: 28-02-2019 Print Date: 06-05-2022
Version: 3.2/GHS/EN Page: 1 / 6
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING
1.1. Identification of the substance/mixture

Trade name: BERGAMOTE L FIRMENICH 631
CAS Number: —
CE Number: —
1.2. Relevant identified uses of the substance or mixture and uses advised against
Raw material for the manufacture of fragrances and/or flavourings.
1.3. Details of the supplier of the safety data sheet

Company: Ernesto Ventós SA
Address: Carretera Real, 120 B
08960 Sant Just Desvern – Barcelona – SPAIN
Telephone: (00 34) 934 706 210
Fax: (00 34) 934 733 010
E-mail: [email protected]
1.4. Emergency telephone number

NCEC (+44) 1865 407333 (24h)
NCEC (+34) 91 114 2520 (24h) (ES)
NCEC (+1) 202 464 2554 (24h) (USA, Canada)
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture

Flammable Liquids - Category 3 - H226
Skin Irritant - Category 2 - H315
Eye Irritant - Category 2 - H319
Skin sensitizer - Category 1 - H317
Aspiration hazard - Category 1 - H304
Hazardous to the aquatic environment, short-term (acute) - Category 1 - H400
Hazardous to the aquatic environment, long-term (chronic) - Category 1 - H410
2.2. Label Elements

Hazard pictograms:
Signal Word:
Danger
Hazard statements:
H226 – Flammable liquid and vapour.
H304 – May be fatal if swallowed and enters airways.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H319 – Causes serious eye irritation.
H410 – Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P210 – Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 – Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 – Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310+P331 – IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting.
P302+P352+P333+P313 – IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention.
P305+P351+P338+P337+P313 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
2.3. Other hazards

No Information available
BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

ventós
SAFETY DATA SHEET
LEADERS
IN ESSENCE
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
Not applicable
3.2. Mixtures
MIXTURE OF AROMATIC SUBSTANCES
Hazardous constituents:
CAS No
Chemical Name % (w/w) Classification according to GHS
EC No
115-95-7
LINALYL ACETATE ≥25; <50 Eye Irritant - Category 2B - H320
204-116-4
Skin sensitizer - Category 1 - H317
Acute Toxicity - Category 5 (oral) - H303
78-70-6 Skin Irritant - Category 2 - H315
LINALOOL ≥10; <25
201-134-4 Eye Irritant - Category 2A - H319
Skin sensitizer - Category 1B - H317
138-86-3 Skin sensitizer - Category 1B - H317
LIMONENE ≥10; <25
205-341-0 Aspiration hazard - Category 1 - H304
BETA-PINENE ≥1; <10
204-872-5 Aspiration hazard - Category 1 - H304
GAMMA-TERPINENE ≥1; <10
202-794-6 Toxic to reproduction - Category 2 - H361
495-62-5
GAMMA-BISABOLENE ≥1; <10 Skin sensitizer - Category 1B - H317
207-805-8
Acute Toxicity - Category 5 (dermal) - H313
5392-40-5
CITRAL ≥1; <10 Eye Irritant - Category 2A - H319
226-394-6
586-62-9
TERPINOLENE ≥0.1; <1 Skin sensitizer - Category 1B - H317
209-578-0
GERANYL ACETATE ≥0.1; <1
203-341-5 Hazardous to the aquatic environment, short-term (acute) - Category 2 - H401
106-25-2
NEROL ≥0.1; <1 Eye Irritant - Category 2A - H319
203-378-7
... ... ... ...

ventós
SAFETY DATA SHEET
LEADERS
IN ESSENCE
... ... ... ...

106-24-1
GERANIOL ≥0.1; <1 Serious eye damage - Category 1 - H318
203-377-1
Acute Toxicity - Category 5 (dermal) - H313
CITRONELLOL ≥0.1; <1
203-375-0 Eye Irritant - Category 2A - H319
80-56-8
ALPHA-PINENE ≥0.1; <1 Skin sensitizer - Category 1B - H317
201-291-9
See the full text of the hazard statements in section 16.
4. FIRST-AID MEASURES
4.1. Description of necessary first aid measures

Ingestion: Rinse mouth with water.
Obtain medical advice.
Keep at rest. Do not induce vomiting.
Eye contact: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes and seek medical advice.
Inhalation: Remove person to fresh air and keep at rest.
Seek immediate medical advice.
Skin contact: Take off immediately all contaminated clothing.
Thoroughly wash affected skin with soap and water.
Seek medical attention if symptoms persist.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing Media

Water spray, carbon dioxide, dry chemical powder or appropriate foam.
For safety reasons do not use full water jet.
5.2. Special hazards arising from the substance or mixture

Known or Anticipated Hazardous Products of Combustion: Emits toxic fumes under fire conditions.
5.3. Advice for firefighters

High temperatures can lead to high pressures inside closed containers.
Avoid inhalation of vapors that are created. Use appropriate respiratory protection.
Do not allow spillage of fire to be poured into drains or watercourses.
Wear self-contained breathing apparatus and protective clothing.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures

Evacuate surronding areas. Ensure adequate ventilation. Keep unnecessary and unprotected personnel from entering.
Do not breathe vapor/spray. Avoid contact with skin and eyes. Information regarding personal protective measures: see section 8.
6.2. Environmental precautions

To avoid possible contamination of the environment, do not discharge into any drains, surface waters or groundwaters.

ventós
SAFETY DATA SHEET
LEADERS
IN ESSENCE
6.3. Methods and materials for containment and cleaning up

Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime, sand, soda ash).
Place in covered containers using non-sparking tools and transport outdoors.
Avoid open flames or sources of ignition (e.g. pilot lights on gas hot water heater).
Ventilate area and wash spill site after material pickup is complete.
6.4. Reference to other sections

Information regarding exposure controls, personal protection and disposal considerations can be found in sections 8 and 13.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling

Do not store or handle this material near food or drinking water. Do not smoke.
Avoid contact with the eyes, skin and clothing. Wear protective clothing and use glasses.
Observe the rules of safety and hygiene at work.
Keep in the original container or an alternative made from a compatible material.
7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed and preferably full containers in a cool, dry and ventilated area, protected from light.
Keep away from sources of ignition (e.g. hot surfaces, sparks, flame and static discharges).
Keep away from incompatible materials (see section 10).
7.3. Specific end use(s)

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1. Control parameters
Components with occupational exposure limits:
Chemical Name CAS No Norm. 8 hr. 15 min.

ppm mg/m³ ppm mg/m³
ES (España) 1 VLA-ED 5 VLA-EC
CITRAL 5392-40-5
PL (Polska) NDS 27 NDSCh 54
1 Possibility of significant uptake though the skin.
8.2. Exposure controls

Measures should be taken to prevent materials from being splashed into the body.
Provide adequate ventilation, according to the conditions of use. Use a mechanical exhaust if required.
8.3. Individual protection measures, such as personal protective equipment

Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated goggles before reuse.
Hand Protection: Chemical-resistant gloves are recommended. Wash contaminated gloves before reuse.
Body protection: Personal protective equipment for the body should be selected based on the task being performed and the risks
involved.
Respiratory Protection: In case of insufficient ventilation, use suitable respiratory equipment.
Environmental exposure controls: Emissions from ventilation or process equipment should be checked to ensure they comply with environmental
protection legislation.
In some cases, filters or engineering modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties

Appearance: Liquid
Colour: Conforms to standard
Odour: Conforms to standard
Odour theshold: Not determined
pH: Not determined
Melting point/freezing point: Not determined
Boling point/boiling range: Not determined
Flash point: 57 ºC
Evaporation rate: Not determined
Flammability: Not determined

ventós
SAFETY DATA SHEET
LEADERS
IN ESSENCE
Lower flammability/Explosive limit: Not determined

Upper flammability/Explosive limit: Not determined
Vapour pressure: Not determined
Vapour Density: Not determined
Density: 0,869−0,879 g/mL (20ºC)
Relative density: 0,869−0,879 (20ºC)
Water solubility: Not determined
Solubility in other solvents: SOLUBLE EN ETHANOL
Partition coefficient n-octanol/water: Not determined
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity, dynamic: Not determined
Viscosity, kinematic: Not determined
Explosive properties: Not determined
Oxidising properties: Not determined
10. STABILITY AND REACTIVITY
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.
10.4. Conditions to Avoid

Conditions to Avoid: Excessive heat, flame or other ignition sources.
10.5. Incompatible materials

Avoid contact with strong acids and bases and oxidizing agents.
10.6. Hazardous decomposition products

During combustion may form carbon monoxide and unidentified organic compounds.
11. TOXICOLOGICAL INFORMATION
Acute toxicity Based on the data available, the criteria for classification are not met.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/irritation Causes serious eye irritation.
Respiratory or skin sensitisation May cause an allergic skin reaction.
Germ cell mutagenicity Based on the data available, the criteria for classification are not met.
Carcinogenicity Based on the data available, the criteria for classification are not met.
Reproductive toxicity Based on the data available, the criteria for classification are not met.
STOT-single exposure Based on the data available, the criteria for classification are not met.
STOT-repeated exposure Based on the data available, the criteria for classification are not met.
Aspiration hazard May be fatal if swallowed and enters airways.
12. ECOLOGICAL INFORMATION
12.1. Toxicity
Assessment:
Very toxic to aquatic life with long lasting effects.
Experimental/calculated data:
12.2. Degradability
12.3. Bioaccumulative potential

12.4. Soil mobility


ventós
SAFETY DATA SHEET
LEADERS
IN ESSENCE
12.5. Other adverse effects

See also sections 6, 7, 13 and 15
Do not allow to get into waste water or waterways.
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods

Dispose of in accordance with national and local environmental regulations.
14. TRANSPORT INFORMATION
ADR/RID/ADN IMDG IATA-ICAO

14.1. UN Number UN1169 UN1169 UN1169
14.2. UN Proper Shipping Name EXTRACTS, AROMATIC, LIQUID EXTRACTS, AROMATIC, LIQUID EXTRACTS, AROMATIC, LIQUID
(LIMONENE)
14.3. Transport Hazard Class(es) 3 3 3
14.4. Packing Group III III III
14.5. Environmental hazards Yes Yes Yes
Additional information
14.6 Special precautions for user

None known
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No information available
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
No information available
16. OTHER INFORMATION

Full text of the R-phrases, hazard statements and precautionary statements mentioned in section 3:
H226 – Flammable liquid and vapour.
H227 – Combustible liquid.
H302 – Harmful if swallowed.
H303 – May be harmful if swallowed.
H304 – May be fatal if swallowed and enters airways.
H313 – May ne harmful in contact with skin.
H315 – Causes skin irritation.
H316 – Causes mild skin irritation.
H317 – May cause an allergic skin reaction.
H318 – Causes serious eye damage.
H319 – Causes serious eye irritation.
H320 – Causes eye irritation.
H361 – Suspected of damaging fertility or the unborn child.
H400 – Very toxic to aquatic life.
H401 – Toxic to aquatic life.
H402 – Harmful to aquatic life.
H410 – Very toxic to aquatic life with long lasting effects.
H411 – Toxic to aquatic life with long lasting effects.
H412 – Harmful to aquatic life with long lasting effects.
The information included in this safety data sheet is based on the available data at the moment this document is issued. It is meant to be a description of safety
requirements for our product and does not stand for a guarantee of its properties. The user is responsible for taking all necessary steps leading to compliance
with local rules and legislation.

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ventós

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND THE COMPANY/UNDERTAKING

1.1. Identification of the substance/mixture

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

2.1. Classification of the substance or mixture

2.2. Label Elements

2.3. Other hazards

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

... ... ... ...

4.1. Description of necessary first aid measures

5.1. Extinguishing Media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

6.3. Methods and materials for containment and cleaning up

6.4. Reference to other sections

7. HANDLING AND STORAGE

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1. Control parameters

Components with occupational exposure limits:

Chemical Name CAS No Norm. 8 hr. 15 min.

8.2. Exposure controls

8.3. Individual protection measures, such as personal protective equipment

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

Lower flammability/Explosive limit: Not determined

10. STABILITY AND REACTIVITY

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to Avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

11. TOXICOLOGICAL INFORMATION

12. ECOLOGICAL INFORMATION

12.3. Bioaccumulative potential

12.4. Soil mobility

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

12.5. Other adverse effects

13. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

14. TRANSPORT INFORMATION

ADR/RID/ADN IMDG IATA-ICAO

14.6 Special precautions for user

15. REGULATORY INFORMATION

16. OTHER INFORMATION

BRAZIL • CHINA • COLOMBIA • MEXICO • SINGAPORE • SPAIN • USA • http://www.ventos.com

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