Use of Recycled Concrete Aggregate in Fly-Ash Concrete
Use of Recycled Concrete Aggregate in Fly-Ash Concrete
Use of Recycled Concrete Aggregate in Fly-Ash Concrete
a r t i c l e i n f o a b s t r a c t
Article history: Nowadays, environmentally friendly building is becoming a crucial issue in construction industry. The
Received 15 October 2010 course towards sustainable concrete involves mainly minimizing the environmental impact of concrete
Received in revised form 28 June 2011 production by substituting virgin mineral materials by recycled ones as well as reducing the global
Accepted 18 July 2011
CO2 emissions. The approach adopted here includes a large substitution of natural coarse aggregates
Available online 9 September 2011
(NA) by recycled concrete aggregates (RCA) obtained from crushed concrete debris, as well as the use
of 30% fly ash (FA) as a partial substitute of Portland cement for FA concrete production.
Keywords:
Previous study by the authors has revealed the potential of using coarse RCA to produce concrete with a
Carbonation
Drying shrinkage
similar 28-day design strength to that obtained when using natural aggregates. This paper discusses the
Durability effect of both partial and full replacement of natural coarse aggregates by coarse RCA in a fly ash concrete.
Fly ash Engineering properties and durability performance have been examined on both concrete types (Portland
Mechanical properties cement and fly ash) for mixes designed with various proportions of the RCA (0%, 30%, 50% and 100%) by
Portland cement mass. The results obtained showed that while embedding high amount of the RCA could lower the resis-
Permeability tance to chloride penetration and carbonation of concrete still comparable design strength to that of the
Recycled concrete aggregates control mix might be achieved.
Sustainable concrete
Ó 2011 Elsevier Ltd. All rights reserved.
0950-0618/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.conbuildmat.2011.07.023
440 M. Limbachiya et al. / Construction and Building Materials 27 (2012) 439–449
and quality; the properties of concrete made with RCA are strongly Table 1
dependent on the quality of the recycled materials used as well as Chemical composition of Portland cement and fly ash used in this study.
supplementary cementitious materials to enhance sustainability Mix code RCA (%) Component (kg/m3)
and durability of concrete material; whereas, most of the existing PC FA Water Aggregates w/c
work is mainly carried out on concrete with natural aggregates.
NA RCA Sand
The current investigation attempts to strengthen the concept of sus-
tainability in concrete industry by combining the use of FA with var- PC20 0 275 0 180 1260 0 625 0.66
30 275 0 180 882 378 625 0.66
ious proportions of coarse RCA in concrete. 50 295 0 180 635 635 595 0.61
Previous research by the authors [16,17] has proven that RCA 100 310 0 180 0 1240 610 0.58
could successfully be used as substitute of natural aggregates to pro- PCFA20 0 215 90 160 1311 0 589 0.52
duce normal and high strength concrete, meeting required design 30 215 90 160 918 393 589 0.52
strength and desire durability performance. The results led to a gen- 50 230 100 160 657 657 562 0.48
eral conclusion that up to 30% coarse RCA, used as natural aggregate 100 245 105 160 0 1280 575 0.45
replacement, has no negative effect on fresh and hardened concrete PC30 0 330 0 180 1245 0 585 0.55
properties of Portland cement and silica fume concretes. 30 330 0 180 872 373 585 0.55
50 355 0 180 623 623 560 0.51
The reported study was undertaken to examine suitability of
100 372 0 180 0 1252 536 0.48
coarse RCA for use in fly ash concrete, produced using a single
PCFA30 0 260 110 160 1285 0 550 0.43
batch FA conforming to BS EN 450-2; 2005 as PC replacement.
30 260 110 160 900 386 550 0.43
The fly ash cement concrete used in this research therefore was a 50 280 120 160 641 641 523 0.40
combination of PC and 30% FA by mass, as PC replacement, com- 100 295 126 160 0 1267 517 0.38
bined in the concrete mixer as per BS 8500-2; 2002. RCA concrete PC35 0 355 0 180 1245 0 560 0.50
mixes were proportioned using natural (gravel and sand) and recy- 30 355 0 180 872 373 560 0.50
cled aggregate blends with 30%, 50% and 100% coarse RCA. The PC 50 385 0 180 613 613 550 0.47
concrete mixes were proportioned for 28 day design cube strength 100 409 0 180 0 1226 525 0.44
of 20, 30 and 35 MPa. The mixes were tested for basic mechanical PCFA35 0 280 120 160 1282 0 523 0.40
and engineering properties (compressive and flexural strengths, 30 280 120 160 898 384 523 0.40
50 300 130 160 631 631 514 0.37
elastic modulus and drying shrinkage) as well as durability perfor- 100 322 138 160 0 1257 488 0.34
mance in aggressive environments (sulphate attack, carbonation
and chloride ions).
strength of 20, 30 and 35 MPa, respectively. For identification, PC denotes mixes reported. The specimens were coated with a bituminous coating on five of the six
made with Portland cement and mixes containing FA were labelled as PCFA. The faces, leaving only the top face uncoated to simulate unidirectional chloride ingress.
first numerical value after ‘PC’ and ‘PCFA’ represents the 28 day design strength. The top side of the cube was exposed to 1 mol of sodium chloride solution (58.4 g of
Depending on test procedure, three main curing regimes were adopted in this NaCl per litre of distilled water). Following exposure period of 42 days, the specimens
study. A conventional curing in water at 20 ± 2 °C for 28 days, curing under 95% were dried and drilled from the top side to the inner section at different depths. The
of RH at 20 ± 2 °C; and a standard dry conditions curing under 20 ± 2 °C and concrete specimen powder was collected from the exposed surface to chloride at
60 ± 5% of RH. regular intervals of 5 mm by drilling. The powder samples obtained was analysed
for acid soluble chloride by potentiometric titration as described in BS 1881-124.
2.3. Testing procedures Chloride concentrations are quoted in terms of percent by mass of cement.
Mechanical properties investigated included compressive and flexural strengths, 2.3.4. Carbonation
and elastic modulus. Compressive strength was determined on 100 mm cubes at 3, 7, Cubic specimens measuring 100 mm were used for carbonation test. The spec-
14, 28, 56, 91 and 365 days in accordance to EN 12390-3. Flexural strength under four- imens were first cured in water for 28 days and then conditioned under dry air for
point loading was measured at 28 days using beams of 100 100 500 mm, while 14 days. Thereafter, specimens were coated on all except the top side using a bitu-
elastic modulus was determined at 28 days on 150 300 mm cylinders according minous coating. The specimens were stored in a carbonation chamber at 20 ± 2 °C
to EN 1390-5 and BS EN 13412:2006, respectively. The ends of the cylinders were and 60 ± 5% of RH and 3.5% of CO2. Thus, top surface of test specimens was exposed
capped with a sulphur compound to ensure a flat and parallel surface and a better con- to a CO2 enriched atmosphere. After exposure periods of 2, 4, 8, 12 and 20 weeks,
tact with the loading device. All specimens (cubes, beams and cylinders) were cured in carbonation depth in concrete was measured by spraying a phenolphthalein indica-
water tank at 20 ± 2 °C until the time of testing which is carried out on three samples tor solution onto the surface of a split of freshly broken pieces of the concrete spec-
per mix and the average values were reported. imens. This turns pink when the concrete is alkaline (pH about 9) but remains
Drying shrinkage was measured on 75 75 300 mm prism specimens in one colourless where the concrete is carbonated. The carbonation depth indicated by
direction; using stainless steel pins fixed over 200 mm gauge length on two oppo- the colourless zone of the concrete, was then measured at five points along the ex-
site long sides. Test samples were stored in upright position under dry conditions posed surface and the average carbonation depth of the five measurements is
(20 ± 2 °C and 60 ± 5% of RH) and measurements were taken up to 90 days. The reported.
length change of the specimens was then measured using a comparator and peri-
odic measurements were taken.
To establish durability performance, a range of tests that include sulphate 3. Results and discussion
attack, initial surface absorption, chloride ions penetration, and carbonation were
carried out, as briefly described in the following section.
3.1. Workability
2.3.1. Sulphate attack
The resistance of concrete with and without the coarse RCA to sulphate attack
As abovementioned, embedding various industrial by-products
was determined by submerging concrete beams measuring 75 75 300 mm in a in cement paste as a partial replacement of Portland cement com-
0.3 g/l solution of Na2SO4 at 20 ± 2 °C cured under water for 28 days prior to expo- bined with a partial and/or full replacement of natural coarse
sure to the sulphate solution. The sodium sulphate solution was renewed on a aggregates by the RCA could affect the fresh concrete properties
monthly basis and the total test duration was 2 months. The length change mea-
of the concrete mix.
surements of specimens were taken throughout the whole period of exposure to
the sulphate solution (60 days). Slump and compacting factor values of each mix investigated
are given in Table 3. Whilst for both concretes (PC and PCFA), the
2.3.2. Initial surface absorption average slump values were generally within the limits specified
This test consists of the measurement of the rate at which water flows into the by the EN 206-1 for the designated concrete grade, the slump of
capillary pore network of concrete through a known surface area. Estimation of the fly ash concretes was generally lower than that of the PC concretes.
volume flow is obtained by measurement of the length of flow along a capillary of
This is due to the fact that fly ash concretes had higher binder con-
known dimension. The initial surface absorption of the various mixes was deter-
mined on 150 mm cubes after the concrete was water-cured for 28 days as per tent (approximately 10%) and lower water content (11%) compared
BS 1881-208. The specimens were oven-dried to constant weight prior to the test to the PC concretes.
and left to cool to the laboratory temperature. The contact area is defined by a plas- It can be observed that, increasing the amount of the coarse RCA
tic cell sealed onto the concrete surface and should not be less than 5000 mm2. in the PC mixes has generally resulted in quite a significant in-
Water is introduced into the cell via a connecting point and maintained at a head
of 200 mm using a filter funnel. A second connection point to the cap leads to a
crease of the slump value. A similar trend was also observed with
horizontal capillary tube. The connection to the reservoir is closed and the absorp- fly ash concrete mixes. This could be explained by the moisture
tion is measured by observing the movement of the end of the water line in the provided by the RCA added to the mix as these aggregates are more
capillary tube with an affixed scale at 10 min. The setup used is shown in Fig. 1. porous and have a higher water absorption capacity compared to
the natural coarse aggregate (NA). This initial moisture of the
2.3.3. Chloride ions penetration
Cubes of 150 150 150 mm cured, for 3 days, under wet curing regime (95% of
coarse RCA has contributed in the improvement of the initial val-
RH at 20 ± 2 °C) and then exposed to dry conditions for 14 days. Chloride ions pene- ues of the slump for the mixes made with the RCA compared to
tration was measured on three specimens per mix and the average values were the mixes made with the NA.
Table 3
Fresh concrete properties.
3.2. Mechanical performance While the general trend suggest that, compressive strength of
both concrete types (PC and PCFA) decreases as the replacement le-
Compressive strength and elastic modulus of concrete are vel of natural aggregates by the RCA increases, still this tendency is
commonly considered in structural design, but for some purposes influenced by the w/c and the design strength of concrete. The
and specific project, the flexural or tensile strength is of interest, PC35 has showed quite a unique tendency with the highest com-
particularly to enhance resistance to cracking. Substituting natural pressive strength achieved by the concrete made with a solely
aggregates, at different replacement levels, by recycled aggregates RCA, whereas the lowest compressive strength was obtained by
would have influence on the mechanical behaviour of the concrete. the mix containing 30% of the RCA (Fig. 4). This inconsistency in
The results of the compressive and flexural strengths and modulus the behaviour of concrete mixes designed with the RCA could
of elasticity are presented in Figs. 2–9. It could be seen, as pointed mainly be attributed to the various intrinsic parameters of the
out above, that the targeted design strength was achieved for all RCA that are of a great influence on the concrete properties. The
the concrete mixes made with coarse RCA. amount and thickness of old mortar attached on the RCA are one
60
40 0% PCFA20
50
35
30% 50%
30 50% 40 100%
25 100%
30
20
15 20
10 10
5
0
0 3 7 14 28 56 90 180 365
3 7 14 28 56 90 180 365 Age (days)
Age (days)
Fig. 5. Compressive strength versus time for PCFA20 concrete.
Fig. 2. Compressive strength versus time for PC20 concrete.
70
60
0% PCFA30
Compressive strength (MPa)
0% PC30 60
Compressive strength (MPa)
30%
50 30% 50%
50
50% 100%
40 100% 40
30 30
20 20
10 10
0 0
3 7 14 28 56 90 180 365 3 7 14 28 56 90 180 365
Age (days) Age (days)
Fig. 3. Compressive strength versus time for PC30 concrete. Fig. 6. Compressive strength versus time for PCFA30 concrete.
70
0% PCFA35
Compressive strength (MPa)
70 60 30%
Compressive strength (MPa)
0% PC35
60 50%
30% 50
100%
50 50%
40
100%
40
30
30
20
20
10 10
0 0
3 7 14 28 56 90 180 365 3 7 14 28 56 90 180 365
Age (days) Age (days)
Fig. 4. Compressive strength versus time for PC35 concrete. Fig. 7. Compressive strength versus time for PCFA35 concrete.
M. Limbachiya et al. / Construction and Building Materials 27 (2012) 439–449 443
3
3.3. Drying shrinkage
the incorporation of FA in concrete made with RCA may subse- due to the presence of pozzolan compared to the PC concretes.
quently reduce the cracking tendency of such a concrete. Replacing 30% of PC by FA would decrease the reactive aluminates
(C3A) content in the PCFA concretes and hence, less ettringite
3.4. Sulphate attack formed which enhances the resistance to sulphate attack.
The use of FA could also bind the free lime of the hydrated
It is generally recognized that some chemicals inherent in the cement paste and prevent reaction with the sodium sulphate solu-
environment could be detrimental for the integrity and durability tion. Previous studies [2–4,21–23] have also pointed out a reduction
of concrete structures. Under sulphate environment, cement paste in the expansion exhibited due to sodium sulphate immersion when
undergoes deterioration resulting from destructive expansion, using blended cement with FA. Furthermore, while the incorpora-
spalling and softening. Soluble sulphates in soils, ground water, tion of 30% and 50% of RCA showed a slight effect on the expansion
and sewage can lead to severe deterioration of concrete unless it induced by sulphate attack, a solely use of RCA instead of natural
is properly designed to provide sulphate resistance commensurate aggregates has led to an accelerating expansion pattern for both
with the severity of the attack. concretes PC and PCFA, especially from the first week of exposure
Figs. 10 and 11 present the patterns of expansion induced by sul- and onward. It has also been reported that sulphate attack resis-
phate solution for the PC and PCFA concretes, respectively. It could tance of concrete containing FA depends on various parameters
be seen that while both concretes have shown a quite similar trend, related mainly to FA type used such as the content of reactive alu-
the PCFA mix with and without RCA performs slightly better than mina and lime. Obviously, longer term exposure to sulphate attack
the PC mix in terms of resistance to sulphate attack. Generally speak- is necessary to establish more realistic prediction of durability of
ing, for a given concrete mix containing FA, the total expansion concrete with coarse RCA while 2 months of exposure showed the
exhibited by sulphate attack was more or less 10 microstrains lower superior performance of the PCFA mixes compared to the PC mixes.
than that of the PC mixes. The fact that fly ash concrete induces less
internal pressure and destructive expansion than plain concrete was 3.5. Initial surface absorption (ISA)
reported in earlier research by several authors [2–4,20].
In fact, as is well known, sulphate attack mechanism includes The initial surface absorption test was basically designed to
mainly two-phased process. Sulphates combine with calcium evaluate the porosity of cement-based composite materials. For a
hydroxide generated during cement hydration to form calcium sul- given concrete mix at a given age, the ISA test could roughly indi-
phate (gypsum). Meanwhile, aluminates compound (C3A) from cate the degree of porosity as well as the connectivity of its pore
Portland cement reacts chemically with sulphates and calcium to system.
form ettringite. Both the formation of gypsum and ettringite expand The test results of the ISA of the concrete to water after ten min-
concrete mixture which generates internal pressure and lead to utes are shown in Fig. 12. It can be seen that the partial replacement
cracks formation and disruption in hardened cement paste. The of Portland cement by pozzolanic materials (FA) can effectively
lower expansion recorded in the PCFA concrete is essentially attrib- reduce the initial surface absorption. For the same concrete design
uted to the relatively low volume of monosulphate and portlandite strength, the fly ash concrete has shown lower ISA compared to
the PC concrete, especially for mixtures made with solely RCA. The
use of coarse RCA as a partial or full replacement of the NA has
90 resulted in significant increase of the ISA. The higher the replace-
PC20 ment levels of RCA, the more perceptible the increasing effect on ISA.
80
Generally, for both concrete types, the use of up to 30% coarse
70
Expansion ( x 10-6)
Fig. 10. Length change of PC20 concrete mixes exposed to sulphate solution.
1.2
1.0
80
PCFA20
ISA-10 ( ml/m 2/s)
70 PC20
0.8
Expansion ( x 10-6)
PC30
60
PC35
50 0.6
PCFA20
40 PCFA30
0.4
PCFA35
30
NA
20 0.2
30% RCA
10 50% RCA
100% RCA 0.0
0 0 20 40 60 80 100 120
0 10 20 30 40 50 60 RCA content (%)
Immersion time (days)
Fig. 12. Initial surface absorption (10 min) versus the RCA content for the various
Fig. 11. Length change of PCFA20 concrete mixes exposed to sulphate solution. mixes investigated.
M. Limbachiya et al. / Construction and Building Materials 27 (2012) 439–449 445
3.6. Carbonation the carbonation process of the mixes made with the RCA compared
to the control mixes. Moreover, it is well recognized that carbon-
Carbonation is the process that leads to the formation of calcium ation of concrete occurs at a relative humidity from about 40% to
carbonate through the reaction of CO2 (atmospheric carbon dioxide 70%. Due to the high water absorption of the coarse RCA, the con-
or artificial) with some constituents of the concrete, (calcium trol concretes have generally lower moisture content compared to
hydroxide, silicates and aluminates), resulting in a reduction of their corresponding concretes designed with RCA. This may also
the pH of concrete from around 12 to below 9. Under such a value explain the low resistance to carbonation of concretes containing
of pH, the steel rebar become active and the corrosion process is coarse RCA.
initiated which affects the interface steel/concrete and the loading As the progress of carbonation process is governed by the pore
carrying capacity of reinforced concrete element. network characteristics, the results presented in Fig. 13 showed
The results of carbonation depth are presented in Fig. 13. It is that the carbonation becomes limited beyond 20 mm because of
clear that the depth of carbonation is proportional to the duration the increasing difficulty for carbon dioxide to penetrate into the
of exposure. The higher the exposure period, the higher the depth depth of the concrete pore network.
of carbonation is. The results have revealed that adding various For a given design strength, the carbonation depth of all the fly
proportions of coarse RCA as a partial replacement of natural ash concrete mixes was quite greater than the one of the PC con-
aggregates has resulted in a lower resistance to carbonation, espe- crete mixes. These results are in agreement with those reported
cially for the C30 and C35 concrete grades. While no significant in previous works [24–27]. Earlier researches have also found that
difference was observed in the carbonation depth of the C20 series increasing FA content in cementitious system results in a higher
between mixes with and without RCA, the gap between the control rate of carbonation compared to a plain cement mix [28,29]. Due
mix and the mixes containing various proportions of RCA is con- to the pozzolanic reaction between FA and portlandite, and the
siderable for the C30 and C35 series, particularly for the PCFA consumption of CH, the pH of the concrete decreased and leads
mixes. to a higher carbonation as compared to the PC concretes. On
It is also believed that the water stored in the pore system of the the other hand, as hydration proceeds in FA concrete, and due to
RCA and released throughout hydration process may contribute in the secondary C–S–H formed, both the total porosity as well as
25
30
Carbonation depth (mm)
C20 PC
Carbonation depth (mm)
C20 FA
20 25
20
15
15
10
NA
10 NA
30% RCA
5 30% RCA
50% RCA 5 50% RCA
100% RCA 100% RCA
0 0
0 4 8 12 16 20 0 4 8 12 16 20
Period of exposure (weeks) Period of exposure (Weeks)
20 20
Carbonation depth (mm)
C30 PC
Carbonation depth (mm)
C30 FA
15 15
10 10
NA NA
5 30% RCA 5 30% RCA
50% RCA 50% RCA
100% RCA 100% RCA
0 0
0 4 8 12 16 20 0 4 8 12 16 20
Period of exposure (weeks) Period of exposure (Weeks)
20
25
Carbonation depth (mm)
C35 FA
C35 PC
20 15
15
10
10
NA
NA
30% RCA 5 30% RCA
5 50% RCA
50% RCA
100% RCA 100% RCA
0 0
0 4 8 12 16 20 0 4 8 12 16 20
Period of exposure (weeks) Period of exposure (Weeks)
Fig. 13. Carbonation depth versus exposure period for the investigated concretes.
446 M. Limbachiya et al. / Construction and Building Materials 27 (2012) 439–449
where Xc is the tested carbonation depth (mm), t is the exposure Fig. 14. Relationship carbonation coefficient-exposure period for the investigated
duration (week) and K is the corresponding carbonation coefficient concretes.
(mm/week0.5).
Generally, it was observed that for a given RCA replacement le-
vel, the coefficient of carbonation tends to increase for both the PC 30
PC
and PCFA concretes following the same trend of the carbonation Xc = -0.7fc + 43.4
depth discussed above. The carbonation coefficient seems to be R² = 0.90 PCFA
25
Carbonation depth (mm)
1.0 30% concretes compared to the control concrete. At the same depth, the
50% higher the replacement level of the NA by the RCA, the higher the
0.8
100% chloride concentration found. Meanwhile, it seems that for all mixes
0.6 investigated, substituting 30% of natural aggregates by the RCA has
shown no significant effect on the chloride ions content compared
0.4
to the control mix and beyond this limit, concrete produced with
0.2 RCA become more vulnerable to chloride ions ingress.
On the other hand, for the same concrete design strength and at
0.0 the same penetration depth, fly ash concrete tends generally, to
0-5 5-10 10-15 15-20
slightly increase the chloride content. This effect might be attrib-
Depth (mm) uted to the relative changes in intrinsic diffusivity and chloride
binding capacity exhibited by the binder compositions used
Fig. 16. Chloride content versus depth penetration for the PC30 (a) and PC35 (b).
(PCFA). As pointed out above, part of the chlorides ions in the solu-
tion can react with some component of the cement such as the C3A,
while blended cement contains less C3A than the PC concrete.
PCFA30
(a) 1.0 RCA Therefore, the binding capacity of the fly ash concrete to chloride
0.9 0% tends to decrease and consequently, more free chloride ions re-
Chloride content (%)
0.8 30% main in the pore solution as also reported by Kayyali and Qasrawi
0.7 50% [35]. Nevertheless, it is also worth mentioning that FA contains
0.6 100% higher proportions of active alumina compared to Portland cement
0.5
(around 30% by weight of Al2O3 in FA cf. 5% in PC), which is capable
0.4
of binding and immobilizing chloride ions in solution.
0.3
Moreover, FA is characterized by a slow reaction with portlan-
0.2
0.1
dite to produce a secondary C–S–H that fill the coarser capillary
0.0 pores and refine the pore network which leads to a low porosity
0-5 5-10 10-15 15-20 and a disconnected pore network and hence, improve resistance
Depth (mm) to permeability characteristic. As a result, it is expected that at long
term, the fly ash concretes with and without RCA may perform
(b) 1.8 RCA
PCFA35 0%
1.6
Chloride content (%)
30%
1.4
50%
1.2 100% Durability performance
1.0
ASTM limit
Concrete properties
0.8
0.6
0.4
0.2 Drying shrinkage
0.0
0-5 5-10 10-15 15-20
Mechanical properties
Depth (mm)
Fig. 17. Chloride content versus depth penetration for the PCFA30 (a) and PCFA35
(b).
0 30 50 100
Proportions of RCA
The chloride concentration–penetration depth profiles of the PC
and blended cement with FA produced with natural aggregates are Fig. 18. General relationships between concrete properties and the content of the
compared with those containing various proportions of the RCA. RCA.
448 M. Limbachiya et al. / Construction and Building Materials 27 (2012) 439–449
much better than the PC concretes in terms of resistance to chlo- and recycled concrete aggregate using a proper binder type and
ride ions penetration. This was also confirmed in earlier researches w/c could significantly promote sustainability and enhance
by several authors [1,36]. durability in concrete industry.
In the practical use of cement-based materials, not all concrete
Acknowledgement
mixes are designed to be used in reinforced concrete structural
elements. A large part of concrete, especially normal strength
The authors would like to acknowledge the Day Group Ltd., UK
concretes are usually used in nonaggressive environment under
for partial funding of the reported work and supplying recycled
normal exposure conditions for which resistance to aggressive
concrete aggregate sample for the test programme.
environment is not required.
Fig. 18 summarizes the relationship between concrete proper-
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