NARAYANA IIT ACADEMY

INDIA
Sec: Sr.IIT-IZ-CO-SPARK Date: 20-06-15
Time: 9:00 AM to 12:00 Noon WTM-10 Max.Marks: 360
KEY SHEET

PHYSICS CHEMISTRY MATHS

Q.NO ANSWER Q.NO ANSWER Q.NO ANSWER
1 1 31 2 61 1
2 2 32 3 62 3
3 1 33 3 63 4
4 2 34 1 64 3
5 1 35 4 65 4
6 4 36 2 66 2
7 4 37 3 67 4
8 3 38 4 68 2
9 4 39 4 69 1
10 2 40 3 70 2
11 3 41 4 71 3
12 2 42 2 72 3
13 2 43 2 73 1
14 3 44 4 74 4
15 2 45 3 75 3
16 3 46 1 76 2
17 3 47 2 77 1
18 2 48 4 78 2
19 2 49 2 79 1
20 2 50 4 80 2
21 1 51 1 81 1
22 1 52 4 82 3
23 4 53 2 83 1
24 4 54 3 84 3
25 1 55 4 85 2
26 2 56 4 86 1
27 1 57 3 87 4
28 4 58 1 88 2
29 3 59 3 89 1
30 1 60 4 90 2
Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
PHYSICS - HINTS
1. Conceptual

2. Conceptual

3. Wavelength of K X- ray depends on atomic number of target.

4. Conceptual

5. As the accelerating voltage is increased C decreases but K remains same.

6. As cutoff wavelength of A is less than that of B. VA  VB .

1
K   2
hence Z A  Z B .
 Z  1
7. As bomarded electrons havee sufficient energy to knock out inner shell electrons of
target, characteristic X-rays are observed along with continuous X – ray.

1
8. K   2
 Z  1
1
9. Cut off 
V

50 2
10. 2
 4  Z  26
 Z  1
E2
11. Conservation of momentum. KE 
2mc 2

12.  UB   UE 

1
  o Eo 2
4

= 8.86 x 10-12 J/m3

13. Power of electron beam is V  i = 200W

0.5
So power of X – ray beam is 200   1W
100

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
14. Conceptual

15. Conceptual

16. Conceptual

17. Conceptual

18. Conceptual
2
Cu  Z Mb  1 
19.  
Mb  ZCu  1 

20. Conceptual

21. Conceptual

22. Conceptual

23. Conceptual

E0
24. B0 
C

25. Conceptual

26. Use dimensional analysis

P 1
27. 2
 C 0 E 2
4 r 2
1/2
 1  2 P 
 E    
 4 0  C 

28. Conceptual

1
29.  
KE

30. Conceptual

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
CHEMISTRY - HINTS
31. Odd configuration 2s 2 2 p 2 so even oxidation numbers are paramagnetic.
32. White P4 exhibits phosphorescence but Red does not.
34. NH 4 NO3 

 N 2O  2H 2O . (A) gives N2O .
35. Explosive
36. For ships in dark,
Ca3 P2  H 2O  PH 3 CaC2  H 2O  C2 H 2
PH 3 catches fire and allows C2 H 2 burn for longer time.
37. H 3PO3 

 H 3PO4  PH 3  A
39. 4 Zn  10 HNO3  4 Zn  NO3 2  NH 4 NO3  3H 2O
44. P4O10  4HClO4  2Cl2O7  4HPO3
45. Others react with NH3 . CaO and NH3 are basic and so do not react. CaO is good for drying NH3
gas.
46. NO2  1800   NO2 132 0   NO2  120 0 

47. NH 4 NO3 

 N 2O  H 2O, others give red brown gas.
3
49. PO
3 9 See the structure.

50. H 4 P2O6  Hypo phosphoric acid

51. See the structures.
52. Ca3 P2 with water vapour in the atmosphere becomes PH 3 and burns to give PO
4 10 which forms a
smokes screen. Used in the war fare.
I2
53. P4  20 HNO3   4 H 3 PO4  20 NO2  4 H 2O
54. PCl3  3H 2O  H3 PO3  3HCl , others give H 3PO4 .

55.  PCl4    PCl6 
57. See the structures. P is in +3 oxidation state.
59. NH 3  3Cl2  NCl3  3HCl
60. Stable at 0  50 C (Diazodization Reaction)
Undergoes autooxidation / Self disproportionation.

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
MATHS - HINTS
61. n  S   25  32
5
E   2 2 2 3 3  can appear in  10
3 2
10 5
Pe  
32 16
62. P  E   P   HH  HTHH  HTHTHH  ......   

 1  1 2  1 3 
P TT  THTT  THTHTT  ........   2         ...... 
 4  4   4  
 1 
  2
 2 4  
1
1   3
 4
63. n  S   5  5 C5 10 C5
n  E   6 C5  6
P  E   6 /10 C5
1
64. E1  Event of getting sum 5  P  E1  
9
1
E2  Event of getting sum 7  P  E2  
6
P  E1  E2   1  P  E1  E2 

= 1   P  E1   P  E2  

5 13
1 
18 18
E be the event that 5 comes before 7.
P  E   P  E1   P  E1  E2  .P  E1   P  E1  E2  .P  E1  E2  P ……+ 
1 13 1 13 13 1
  .  . .  .......
9 18 9 18 18 9
 
1  1 
  2/5
9  1  13 
 18 

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
8 7  6
65. n  S  8 C5 8 C3   56
6
E   5 5 3   2 6 5   3 6 4  1 6 6   4 4 5 
5
P E 
56
66.
67. n  S  52 C4 , n  E   4 Since

E  s A sK sQ s J   D A DK DJ   C A C k C q C g   H A H k H r H j 
68. After every week repeated 52 times 2 days left then can be
(S,M) (M T ) (T W) (W Th) (Th F) (F SAT) (SAT S)
n(S) = 7
n(E) = 2 P(E) = 2/7
69. B, G, BG BG BG  4 4
G B G B GBGB  4 4
n  E   2. 4 4
n s  8
2. 4 4 2  24 1
PE   
8 5  7  6  8 35
70. 5 boys can be arranged in a circle is 4 ways.
There are 5 gaps in between boys
5
 3 girls can sit in P3 ways

n  E   4 5 P3
n S   7
5 4  3 2
 
765 7
A B
71.
1 2 3 4 5 6 7 8 9 10 11 12
A and B can be place in position n(1,5), (2,6),(3,7), (4,8), (5,9, (6, 10), (7, 11), (8, 12)  8 ways
n  E   2  8  10
n  S   12

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
28 4
P E  
11 12 33
72. n  S   m C3 .
Let the stopping stations be S1, S2 , S3
S1 S2 S3


 

 

 


   

x y z w
Let x – Number of stations before S1  x  0
y – Number of stations between S1 and S2  y  1
z – Number of stations between S2 and S3  z  1
w – Number of stations after S3.  w  0
x y z  w m3 give 1  to y

x  y1  z1  w  m  5 1  to z
Number of non negative Integral solution
m 53
C3 m2 C3
m  2C3
PE   m
C3
n  n  4  n  5 
73. PE  6 
 n  4  n  5
n  n  1 n  2   n  1 n  2 
6
74. n  S   95
n  E   53

53
PE  5
9
75. n  S   74
7
2 – teachers can be selected is C2 .
4
These two teachers check 4 papers in 2  2 ways.
 n  E  7 C2  14
21 14 6
P E   .
74 49

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
76. n  S   5  120
n  E   1 2  3  3  1 2  3  1  24 ways.
24
P E  1/ 5
120
77. Consider 15, 30, 45, 60, 75, 90, 105,120, 135,150
10
10 C6
n  E   C6 , P  E   150
.
C6
78. E1 = Event that A gets success.
9
C 21 34
P  E1   1  12 3  1  
C3 55 55
E2  Event that B – gets success.
6
C2 15 13
P  E2   1  8
1 
C5 28 28
34 13
P  E1  : P  E2   :  952 : 715
55 25
n  S  
2 n 1
79. C3 .
E = Event that 3 – numbers are in AP. with common.
d = 1  (1, 2,3) (2 3 4)……..  2n  1, 2n, 2n  1  2n  1
d = 2  (1 3 5) (2, 4, 6)……(2n-3 2n-1 (2n+1)  2n-3
d=n 1, n  1, 2n  1 
n  E   1  3  5  .....  2n  1  n 2

6n2 3n
PE  
 2n  1 2n  2n  1  4n 2  1
80. The units digit of any integer can be 0,1, 2,3,……9  10 ways.
Last digit in the product is 1, 3, 7, 9
4n 2 n
P ( required event )=  .
10 n 5n
3 n C2   n C1.n C1 5n  3
81. P(required event ) =  3n 

C2 3  3n  1

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Narayana IIT Academy 20-06-15_ Sr.IIT-IZ-CO-SPARK _JEE-MAIN_WTM-10 _Key & Sol’s
3n 
82. nS   C3

R1  1 3 6 ........ 3n  3
R2  1 4 7 ........ 3n  2 
R3  2 5 8 ........ 3n  1

3
n  E   3 n C3    n C1 

3
3  n C3    n C1 
P E 
 3n
C3 

83. n  S  9 P7

7 – digit number divisible by 9  n E  4  2 7

1
PE 
9

84. p 2  4q  0

Select  p, q  such that above inequality satisfied.

85. a 5,  4,  3,  2,  1, 0,1, 2, 3.....30

n  S   36
2
graph of y  x  2  a  4  x  5a  64

strictly lies above the x-axis

Disc < 0
2
 4  a  4   4  5a  64   0

 16  a  3

2
n  E   8  P  E   8 / 36 
9

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7 8
 C4
4 2
86. P E   7 / 33
11
4. 4 2

87. Conceptual

88. He should perform 6 forward steps and 5 backward steps or reverse.

6 5 6 5
P  E  11 C6 . 0.4  .  0.6  . 11 C6  06  .  0.4 

5
11 C6 . 0.24 

89. n  S   n1 Cr 1

n  E  
n 3 
x [A] x ___ ___
Cr 1 ___ ___ ____ ____

n 3
Cr 1
P E  n 1
.
Cr 1

90. When A – contains only one element say a1

Then a1  P a1  Q

a1  P a1  Q

a1  P a1  Q

a1  P a1  Q

Then P  Q   in 3 – ways

Probability that P  Q   is ¾

n
When A – contains n elements =  3 / 4 

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