Teixidor 1987
Teixidor 1987
Teixidor 1987
-
them. The cation trans-CrFz(en)2+ is of particular interest
because of the large splitting of the (AQ (Tzg and 'Azg
'TI, bands (2).
- bv charae-transfer bands. The cis and trans octahedral di-
sibstituied complexes belong to CPUandD4hsymmetry point
croups,
- . respectively, but, from the view of the electronic
environmedt around the metal ion, both symmetry groups
are in practice the tetragonal one, Ddh. This fact is not gener-
ally recognized and is neglected in almost all textbooks, but
it is well explained in Ballhausen's classic Introduction to
' Author to whom correspondence should be addressed. Ligand Field Theory (6).