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    UNIROL 3 PCT English

    Uploaded by

    German Kodzhebash

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    UNIROL 3 PCT English

    Uploaded by

    German Kodzhebash
    11 views6 pages

    Original Title

    UNIROL_3_PCT_English

    Copyright

    © © All Rights Reserved

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    Copyright:

    © All Rights Reserved
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    11 views6 pages

    UNIROL 3 PCT English

    Uploaded by

    German Kodzhebash

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 6

    UNIROL 3 PCT

    SAFETY DATA SHEET

    1 Identification of the substance or preparation and of the company/undertaking

    1.1 Product identifier


    Product Name:
    Datasheet Number: 556084-r 1. 0. 0
    Product Part Number: 592204 (20 liter), 556084 (200 liter)
    Head Office:: Wilhelmsen Ships Service AS
    Address: Strandveien 20, N1324 Lysaker, Norway, Tel:+47 67 584550
    1.2 Relevant identified uses of the substance or mixture and uses advised against
    Fire fighting foam concentrate
    1.3 Details of the supplier of the safety data sheet
    Name of Supplier: Wilhelmsen Ships Service AS
    Address of Supplier: Willem Barentszstraat 50
    3165AB Rotterdam
    The Netherlands
    Telephone: +31 10 4877 777
    Fax: +31 10 4877 888
    Responsible Person: Patrick Rijsdijk, Product HSE Manager, Tel.:+31 6 349 440 35
    Email: [email protected]
    1.4 Emergency telephone number
    **ONL TO BE USED IN CASE OF AN INCIDENT**
    NCEC: +44 1865 407333, CHEMTREC (800) 424 9300
    American Chemistry Council +1 703 527 3887,
    Greece +30 210 7793777
    Australia: +61 3 9630 0998

    2 Hazards identification

    2.1 Classification of the substance or mixture


    - Not classified as hazardous for users
    2.2 Label elements
    - Not Classified
    Risk Phrases
    - Not applicable
    Safety Phrases
    - Not applicable
    2.3 Other hazards
    - Odour: Slight smell of solvent
    - Appearance: Liquid, dark, brown
    - Contact with eyes: Causes redness and irritation
    - Contact with skin: May cause redness and irritation
    - Inhalation: Vapours or aerosols may cause irritation of eyes, nose and respiratory tract

    Date of Last Change 06/12/2011 1


    UNIROL 3 PCT
    2 Hazards identification (....)
    - Ingestion: May cause gastro-intestinal disturbances

    3 Composition/information on ingredients

    3.1 Mixtures

    Chemical Name Concentration CAS Number EC Number R/H Phrases* Symbols


    Zinc chloride <1.5% 7646-85-7 231-592-0 R34 C
    Non classified ingredients >98.5% - - - -

    *See Section 16

    4 First aid measures

    4.1 Description of first aid measures


    - IF ON SKIN: Wash with plenty of soap and water.
    -
    - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
    do. Continue rinsing.
    - If substance has got into eyes, immediately wash out with plenty of water for at least 15 minutes
    - Irrigate eyes thoroughly whilst lifting eyelids
    -
    - Inhalation is unlikely to occur
    - Remove patient to fresh air
    -
    - IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
    - Give plenty of water to drink
    - Never give anything by mouth to an unconscious person
    - Never make an unconscious person vomit or drink fluids
    - Obtain immediate medical attention
    -
    - When in doubt or symptoms persist, seek medical attention
    4.2 Most important symptoms and effects, both acute and delayed
    - Possible redness and irritation of affected areas
    4.3 Indication of immediate medical attention and special treatment needed

    5 Fire-fighting measures

    5.1 Extinguishing media


    - Not flammable. In case of fire use extinguishing media appropriate to surrounding conditions
    5.2 Special hazards arising from the substance or mixture
    - Not applicable
    5.3 Advice for firefighters
    - Prevent run off water from entering drains if possible

    Date of Last Change 06/12/2011 2


    UNIROL 3 PCT

    6 Accidental release measures

    6.1 Personal precautions, protective equipment and emergency procedures


    - Wear protective clothing as per section 8
    6.2 Environmental Precautions
    - Do not flush spilt material into any public water system
    6.3 Methods and material for containment and cleaning up
    - Absorb spillage in suitable inert material
    - Sweep or shovel-up spillage and remove to a safe place
    - Ventilate the area and wash spill site after material pick-up is complete
    6.4 Reference to other sections
    - None

    7 Handling and storage

    7.1 Precautions for safe handling


    - See Section 8
    7.2 Conditions for safe storage, including any incompatibilities
    - Protect from frost
    - Do not store above 50 °C
    7.3 Specific end use(s)

    8 Exposure controls/personal protection

    8.1 Control parameters


    - Zinc chloride
    TLV (TWA) 1 mg/m3 ( )
    8.2 Exposure controls
    - No special precautions are required for this product
    Occupational exposure controls
    - Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber are
    recommended)

    Goggles Gloves Suit

    9 Physical and chemical properties

    9.1 Information on basic physical and chemical properties


    - Odour: Slight smell of solvent
    - Appearance: Liquid, dark, brown
    - pH 6.5 - 7.5 at 100 % concentration
    - Boiling point >100 °C at 760 mm /Hg
    Date of Last Change 06/12/2011 3
    UNIROL 3 PCT
    9 Physical and chemical properties (....)
    - Freezing point - 10 °C at 760 mm/Hg
    - Completely soluble in water
    - Specific gravity (water=1) 1.16
    9.2 Other information

    10 Stability and reactivity

    10.1 Reactivity
    - This article is considered stable under normal conditions
    10.2 Chemical stability
    - Considered stable under normal conditions
    10.3 Possibility of hazardous reactions
    - No hazardous reactions known if used for its intended purpose
    10.4 Conditions to avoid
    - No special precautions are required for this product
    10.5 Incompatible materials
    - None
    10.6 Hazardous Decomposition Products
    - No hazardous decomposition products known

    11 Toxicological information

    11.1 Information on toxicological effects


    - LD50 (oral,rat) >2000 mg/kg
    Inhalation
    - Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
    Contact with skin
    - In cases of severe exposure, redness and irritation may develop
    Contact with eyes
    - May cause redness and irritation
    Ingestion
    - May cause gastro-intestinal disturbances
    - The ingestion of significant quantities may cause diarrhoea
    Carcinogenicity
    - No evidence of carcinogenic effects

    12 Ecological information

    12.1 Toxicity
    - LC50 (fish) >1000 mg/l (# hr)

    Date of Last Change 06/12/2011 4


    UNIROL 3 PCT
    12 Ecological information (....)

    12.2 Persistence and degradability


    - Its main ingredients will either dissolve rapidly and dissociate in water or are readily/inherently
    biodegradable.
    12.3 Bioaccumulation Potential
    - Bioaccumulation of the components in this product is insignificant.
    12.4 Mobility in soil
    - Completely soluble in water
    12.5 Results of PBT and vPvB assessment
    12.6 Other Adverse Effects
    - No environmental problems are expected when the product is used / handled correctly.

    13 Disposal considerations

    13.1 Waste treatment methods


    - Disposal should be in accordance with local, state or national legislation
    - Do not discharge into drains or the environment, dispose to an authorised waste collection point
    Classification
    - EU Waste class: -

    14 Transport information

    14.1 UN Number
    - n/a
    14.2 UN Proper Shipping Name
    - n/a
    14.3 Transport hazard class(es)
    - n/a
    14.4 Packing group
    - n/a
    14.5 Environmental hazards
    - On available data, substance is not harmful to the environment
    14.6 Special precautions for user
    - Not classified as hazardous for transport
    14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code
    - Not applicable
    Other information

    15 Regulatory information

    15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
    - This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and
    Directive 453/2010/EU.

    Date of Last Change 06/12/2011 5


    UNIROL 3 PCT
    15 Regulatory information (....)
    - This Safety Data Sheet is provided in compliance with The Dangerous Substances Directive
    (67/548/EEC)
    - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations.
    15.2 Chemical Safety Assessment

    None

    16 Other information

    Text of R and S phrase codes used in this safety data sheet:- R34: Causes burns.
    The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the
    individual constituents
    The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in
    terms of safety requirements and does not signify any warranty with regard to the product's properties
    The data given here only applies when product used for proper application(s). The product is not sold as suitable for
    other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s)
    without seeking advice from manufacturer

    OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES


    For addresses of other Wilhelmsen Ships Service offices, please refer to www.wilhelmsen.com/shipsservice

    Wilhelmsen Ships Service Level 1, 39 Park Street South Melbourn, Vic 3205 Australian Tel:+61 3 9630 0900
    Emergency 24hrs: +61 3 9630 0998
    Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States Telephone
    daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
    Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United States
    Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
    Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft Pennsylvania
    United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
    Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States Telephone
    daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
    Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United Kingdom Tel
    (+44) 1322 282 412 Fax (+44) 1322 284 774
    Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro Brazil Tel
    (+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
    Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
    Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002, Japan Tel
    (+81) 45 775 0012 Fax (+81) 45 775 0070
    Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece Tel (+ 30)
    210 4239100 Fax (+ 30) 210 4212480
    WMS AS U.A.E. Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East) Dubai United Arab Emirates Tel
    (+971) 4 382 3888

    Date of Last Change 06/12/2011 6

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