ass 11 - Chemistry Sample Paper - 01 (2023-24) Maximum Marks: 70 Time Allowed: : 3 hours General

Instructions: a. There are 33 questions in this question paper with internal choice. b. SECTION A
consists of 16 multiple-choice questions carrying 1 mark each. c. SECTION B consists of 5 very short
answer questions carrying 2 marks each. d. SECTION C consists of 7 short answer questions carrying
3 marks each. e. SECTION D consists of 2 case-based questions carrying 4 marks each. f. SECTION E
consists of 3 long answer questions carrying 5 marks each. g. All questions are compulsory. h. The
use of log tables and calculators is not allowed. Section A 1. If the density of a solution is 3.12 g mL–1
, the mass of 1.5 mL solution in significant figures is _______. a) 4680 × 10–3g b) 4.7g c) 47.80g d)
4.680g 2. Oil drop experiment is for determining the: a) deviation of the electron. b) mass of the
electron c) number of electrons d) charge on the electrons 3. The enthalpies of elements in their
standard states are taken as zero. The enthalpy of formation of a compound is: a) is never negative.
b) may be positive or negative. c) is always negative. d) is always positive. 4. If nucleon (mass) and
proton (atomic) number is 40 and 20 respectively, element is a) chlorine b) phosphorus c) potassium
d) calcium 5. Enthalpies of formation of CO(g), CO2 (g), N2O(g), and N2O4 (g) are -110, –393, 81, and
9.7 kJ mol-1 respectively. Find the value of ΔrH for the reaction:N2O4 (g) + 3CO(g) → N2O(g) + 3CO2
(g) a) - 850 kJ b) -600 kJ c) -778 kJ d) -802 kJ myCBSEguide Copyright © myCBSEguide.com. Mass
distribution in any mode is strictly prohibited. 2 / 13 6. de-Broglie equation is a) λ = hv m b) λ = mv h
c) λ = hmv d) λ = h mv To practice more questions & prepare well for exams, download myCBSEguide
App. It provides complete study material for CBSE, NCERT, JEE (main), NEET-UG and NDA exams.
Teachers can use Examin8 App to create similar papers with their own name and logo. 7. In which of
the following compounds, an element exhibits two different oxidation states. a) NH4NO3 b) N3H c)
N2H4 d) NH2OH 8. Which of the following carbocation is most stable? a) (CH3 )3 ⊕ C b) (CH3 )3C ⊕
CH2 c) CH3 ⊕ CHCH2CH3 d) CH3CH2 ⊕ CH2 9. Baeyer's reagent is: a) K2MnO4 b) alkaline KMnO4 c)
bromine water d) acidified KMnO4 10. Which of the following compounds is/are amphoteric in
nature? a) As2O3 b) Both AI2O3 and As2O3 c) CI2O7 d) AI2O3 11. Which of the following conditions
is/are applied for the measurement made in calorimeter? a) Both Constant volume, qv or Constant
pressure, qp b) Constant temperature, qT c) Constant pressure, qp d) Constant volume, qv 12. An
aqeous solution of compound A gives ethane on electrolysis. The compound A is .....? a) Sodium
propionate b) Sodium acetate c) Sodium ethoxide d) Ethyl acetate 13. Assertion (A): The resonance
structure is hypothetical and individually represents any real molecules. Reason (R): According to the
resonance theory the actual structure of benzene cannot be adequately represented by any
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3 / 13 of these structures. a) Both A and R are true and R is the correct explanation of A. b) Both A
and R are true but R is not the correct explanation of A. c) A is true but R is false. d) A is false but R is
true. 14. Assertion (A): Addition of HBr on in presence of peroxide give as major product. Reason (R):
Addition of HBr on alkene proceed by carbocation intermediate. a) Both A and R are true and R is the
correct explanation of A. b) Both A and R are true but R is not the correct explanation of A. c) A is
true but R is false. d) A is false but R is true. 15. Assertion (A): All isotopes of a given element show
the same type of chemical behaviour. Reason (R): The chemical properties of an atom are controlled
by the number of electrons in the atom. a) Both A and R are true and R is the correct explanation of
A. b) Both A and R are true but R is not the correct explanation of A. c) A is true but R is false. d) A is
false but R is true. 16. Assertion (A): Both 44g CO2 and 16g CH4 have same number of carbon atoms.
Reason (R): Both contain 1 g atom of carbon which contains 6.023 × 1023 carbon atoms. a) Both A
and R are true and R is the correct explanation of A. b) Both A and R are true but R is not the correct
explanation of A. c) A is true but R is false. d) A is false but R is true. Section B 17. Calculate the molar
solubility of Ni(OH)2 in 0.10M NaOH. The ionic product of Ni(OH)2 is 2.0 × 10-15 . 18. What do you
understand by exothermic reaction and endothermic reaction? Give one example of each type. 19.
Calculate: Number of gram atoms in 1.4 grams of nitrogen. (Atomic mass, N = 14) 20. Draw the
structure of the following compounds all showing C and H atoms. a. 2-methyl -3-isopropyl heptane b.
Dicyclopropyl methane. OR Write equations for the preparation of i. HC ≡ CD and ii. DC ≡ CD 21.
What is the mass (me ) of an electron? Section C 22. Explain with the help of suitable example polar
covalent bond. 23. Answer the following: 1. Two liters of an ideal gas at a pressure of 10 atm expands
isothermally at 25 °C into a vacuum until its total volume is 10 liters. How much heat is absorbed and
how much work is done in the expansion? 2. Identify the state functions and path functions out of
the following. Enthalpy, entropy, heat, temperature, work, free energy. 3. If enthalpy of fusion and
enthalpy of vaporisation of sodium metals are 2.6 and 98.2 kJ mol-1 respectively, what is the
enthalpy of sublimation of sodium? myCBSEguide Copyright © myCBSEguide.com. Mass distribution
in any mode is strictly prohibited. 4 / 13 24. Calculate the standard Gibbs energy change for the
formation of propane at 298 K. 3C (graphite) + 4H2 (g) → C3H8 (g) ΔfH o for propane, C3H8 (g) is -
103.8 kJ mol-1 Given, s ∘ m C3H8 (g) = 270.2 JK-1mol-1 s ∘ mC (graphite) = 5.70 JK-1mol-1 and s ∘
mH2 (g) = 130.7JK-1mol-1 25. In the reactions given below, identify the species undergoing oxidation
and reduction. i. H2S(g) + CI2 (g) → 2HCl(g) + S(s) ii. 3Fe3O4 (s) + 8 AI(s) → 9 Fe(s) + 4Al2O3 (s) iii.
2Na (s) + H2 (g) → 2NaH(s) 26. Calculate the energy required for the process: He+ (g) ⟶ He2+ (g) +
eThe ionization energy for the H atom in the ground state is 2.18 × 10-18 J atom. 27. An element 'X'
with atomic number 112 has been recently predicted. Its electronic configuration is : [Rn]
5f146d107s2 . Predict i. its group ii. block in which this element would be placed iii. IUPAC name and
symbol. 28. Commercially available concentrated hydrochloric acid(HCl) contains 38% HCI by mass. i.
What is the molarity (M) of the solution (density of solution = 1.19 g mL-1 ) ii. What volume required
of concentrated HCI is required to make 1.0 L of an 0.10 M HCI? Section D 29. Read the text carefully
and answer the questions: IUPAC (International Union of Pure and Applied Chemistry) system of
nomenclature. Common names are useful and in many cases indispensable, particularly when the
alternative systematic names are lengthy and complicated. A systematic name of an organic
compound is generally derived by identifying the parent hydrocarbon and the functional group(s)
attached to it. By using prefixes and suffixes, the parent name can be modified to obtain the actual
name. In a branchedchain compound, small chains of carbon atoms are attached at one or more
carbon atoms of the parent chain. The small carbon chains (branches) are called alkyl groups. An
alkyl group is derived from a saturated hydrocarbon by removing a hydrogen atom from carbon.
Abbreviations are used for some alkyl groups. For example, methyl is abbreviated as Me, ethyl as Et,
propyl as Pr and butyl as Bu. i. Draw the structure of 3-Ethyl-4,4-dimethylheptane. OR Why CH4 after
becoming-CH3 called a methyl group? ii. How is the numbering in branched chain hydrocarbon
done? iii. Derive the structure of 2-Chlorohexane. 30. Read the text carefully and answer the
questions: When anions and cations approach each other, the valence shell of anions are pulled
towards the cation nucleus and thus, the shape of the anion is deformed. The phenomenon of
deformation of anion by a cation is known as polarization and the ability of the cation to polarize the
anion is called as polarizing power of cation. Due to polarization, sharing of electrons occurs between
two ions to some extent and the bond shows some covalent character. The magnitude of polarization
depends upon a number of factors. myCBSEguide Copyright © myCBSEguide.com. Mass distribution
in any mode is strictly prohibited. 5 / 13 i. Out of AlCl3 and AlI3 which halides show maximum
polarization? ii. Out of AlCl3 and CaCl2 which one is more covalent in nature? iii. The non-aqueous
solvent like ether is added to the mixture of LiCl, NaCl and KCl. Which will be extracted into the
ether? OR Out of CaF2 and CaI2 which one has a minimum melting point? To practice more questions
& prepare well for exams, download myCBSEguide App. It provides complete study material for CBSE,
NCERT, JEE (main), NEET-UG and NDA exams. Teachers can use Examin8 App to create similar papers
with their own name and logo. Section E 31. Attempt any five of the following: 1. What happens to
equilibrium constant when temperature increases for a reaction? 2. Explain why alkynes are less
reactive than alkenes towards addition of Br2 . 3. What is a Lindlars’ catalyst? 4. Why do alkynes not
show geometrical isomerism? 5. Which conformation of ethane is more stable? 6. State Le chatelier’s
principle. 7. How is alkene produced by vicinal dihalide? 32. Write a relation between △G and Q and
define the meaning of each term and answer the following: a. Why a reaction proceeds forward
when Q < K and no net reaction occurs when Q = K. b. Explain the effect of an increase in pressure in
terms of reaction quotient Q for the reaction: CO(g) + 3H2 (g) ⇌ CH4 (g) + H2O(g) OR Ethyl acetate is
formed by the reaction of ethanol and acetic acid and the equilibrium is represented as: CH3COOH(l)
+ C5H5OH(l) ⇌ CH3COOC2H5 (l) + H2O(l) a. Write the concentration ratio (reaction quotient), Qc , for
this reaction (note: water is not in excess and is not a solvent in this reaction) b. At 293 K, if one
starts with 1.00 mol of acetic acid and 0.18 mol of ethanol, there is 0.171 mol of ethyl acetate in the
final equilibrium mixture. Calculate the equilibrium constant. c. Starting with 0.5 mol of ethanol and
1.0 mol of acetic acid and maintaining it at 293 K, 0.214 mol of ethyl acetate is found after some
time. Has equilibrium been reached? 33. Answer the following: i. Give the IUPAC name of the
following compound CH3 − CH | Br − C | | O − CH | CH3 − CH3 ii. 0.12 g of an organic compound
containing phosphorous gave 0.22 g of Mg2P2O7 by usual analysis. Calculate the percentage of
phosphorous in the compound. OR i. Which of the two structures CH3COOH and CH3COOis more
stabilized by resonance? Explain. ii. Will CCl4 give a white precipitate of AgCl on heating it with
AgNO3?