"Marine Growth Preventing Device"

"CHLORINE ATTACKER-DS"
CAPABILITIES
TYPE: CL- 850 DS
Sea Water Treatment of Flow: 850 M3/H
Source: AC 440V,60 Hz 7A 1 φ
Max. Electrolytic Current: DC 150A
Residual Chlorine Density: 0.05 ppm (Standard), 0.1ppm (Max.)
Injective Chlorine Density ( In sea Chest ) 0.19 ppm
Amount of Flow in Electolytic Cell: 6. 0 M3/H
Note:
Residual chlorine density changes with the condition of sea water.

Specifications
1.General
This device will produce chlorine and hypochloride by electrolyzing sea water. This electrolyzed sea
water including them will be injected into sea chest and sucked in ship by pumps,that will protect
the equipments using sea water against being fouled by marine growth.

2.Principal Items
1) Type / Quantity CL - 850 DS / L Set
2) Dimension & Weight
Dimension 650 mm(W) x 1200mm(H) x 400mm(D)
Weight abt. 200Kg
3) Max. Sea Water Flow 850 M3/H
*Based on keeping 0.05 ppm residual chlorine density on the average, measured on s.w. pump's
outlet.
4) Sea Water Flow into Electrolytic Cell 6.0 M3/H
5) Max. Electrolytic Current 150 Amps.
6) Electrolytic Cell
a) Type Double Spiral Flow (DS)
b) Quantity 1 Set
c) Testing Pressure 0.49 MPa(5Kg/cm2)
d) Designing Life of Anode Coating abt. 2 years.
7) Rectifier Unit
a) Type Drip Proof,Self-Support.
b) Rating Continuous
c) Input AC 440 Volt,l Phase, 60Hz, ab 7 Amps.
d) Output DC 7.8 Volt, 150 Amps.
e) Electrolytic Current Adjustment Continuously Variable
8) Color of Painting
a) Cabinet(outside Surface) Munsell 10 GY 8/4
b) Cabinet(Inside Board of Electric Parts) Munsell 10 GY 8/4
c) Spare Parts Box Munsell 10 GY 8/4

3.Scope of Work
1) Following work is to be conducted by Shipyard.
a) piping (Supply and Installation ) 1 Lot
b) Wiring ( ---- Do ---- ) 1 Lot
2) Following materials are to be supplied by YOKOHAMA DENKO Co.,LTD.
a) Electrolytic Cell (Cathode) 1 Unit
b) Anode 1 Unit
c) Rectifier Unit 1 Unit
d) Flow Meter ( for Inlet with Switch) 1 Unit
e) Flow Meter ( for outlet ) 0 Unit
f) Injection Nozzle (SUS316LTP) 2 Unit
g) Chlorine Comparator 1 Unit
h) Spare Parts & Tool ( mentioned in spare parts list) 1 Set
*** g) & h) are to be packed in spare parts box

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
INSTRUCTION
1. General description
Marine growth will often causes the equipments such as condenser to become blockaded in the
case of using sea water as cooling water at ships, thermal power stations and etc..
YDK marine growth prevention device CHLORINE ATTACKER-DS will produce chlorine and
hypochloride by electrolyzing sea water and protect the equipments from marine growth by
blending them to cooling sea water.
Even if residual chlorine in cooling sea water is at very small density, 0.05ppm as standard, it will be
effective well, so it will not corrode the equipments and nor pollute the sea water.
When sea water is electrolyzed with non-solube anode chlorine (Cl2) and sodium hypochloride
(NaCIO) will be produced as follows.
( At anode ) 2C1- ------------------- Cl2 + 2e- ( FORM - I )
( At cathode) 2Na+ + 2H2O + 2e- ----- 2NaOH + H2 ( FORM - 2 )
( At mixing) Cl2 + 2NaOH ------------ NaCIO + NaCl + H2O ( FORM - 3 )
According to FORM-3, most of chlorine (Cl2) changes to sodium hypochloride (NaClO), sodium
hypochloride attackes marine growth as follows.
NaCIO ------------------ NaCl + [O] ( FORM - 4 )
[O] in FORM-4 means oxygen in condition of atom. It kills marine growth pactically. In case sea
water is dirty, a great quantity of sodium hypochloride will be used up according to FORM-4.
In practical electrolysis of sea water, following reactions will happen secondarily.
( At anode ) 4OH- ------------------- O2 + 2H2O + 4e- ( FORM - 5 )
( At cathode) Mg + 2H20 + 2e
2 - ---- Mg(OH)2 + H2 ( FORM - 6)
The reaction of FORM-5 makes efficiency of producing chlorine decrease and that of FORM-6
causes scale of magnesium hydroxide to adhere to cathode. For the purpose of high
efficiency,that is obtained by controling the reaction of FORM-5 and promoting that of
FORM-1,chlorine ion (Cl-) has to be supplied continuously to anode. Therefor it increases effiency to
mix enough sea water electrolysed.
Then adhesion of the scale causes sea water flow to be abnormal,that results in decrease of
effiency. Still more that causes strong-alkaline solution produced partly, resulting in corrosion of cell
and anode. YDK marine growth prevention device 'CHLORINE ATTACKER-DS' clear up the problems
by using unique cell making DOUBLE SPIRAL FLOW.
2. Construction and features
2-1. Electrolytic cell
1) Double spiral flow
In YDK marine growth prevention device 'CHLORINE ATTACKER-DS', scale of magnesium hydroxide
produced on cathode secondarily dose not adhere practically, because it has unique double
spiral flow. It mixes well sea water electrolyzed, that results in high efficiency of producing chlorine.
In this cell a high density of sodium hypochloride can be produced, because sea water has a fully
long time in contact with electrodend chlorine ion in sea water can be made use of effiently.
In the following figure, sea water injected into the cylindrical cell from tangent direction flows
making double spiral in such a way illustrated with arrow marks and runs out from axial pipe. It is the
reason that in only whirling of water rate of flow drops at the center but in double spiral flow it dose
not drop largely even near center because circling momentum is held there.

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
2) Easy maintenance
Draining or cleaning with reverse flow is not necessary because of little adhesion of magnesium
hydoxide. The anode can be easily pulled out by loosening only four bolt-nuts.

3) Easy exchange of anode

After anode is pulled out from the electrolyzer with anode holding-board, it can be easily
detached by loosening bolt-nut in following figure.

4) Body of electrolyzer is cathode

As body electrolyzer is cathode, it has a long life due to the same law with cathodic protection.

2-2. Electric part

1) DC power supply
It takes small and light switching power supply unit,and is able to operate in safty depend on
protection device.(over current,over voltage)
2) Protective device for electrode
a. When level of sea water flow electrolyzed drops,electrolysis automatically stops according to
interlocking with flow switch.
b. When electrode has been over-load, over current protector operate and the system stop.
c. In case of Item a, when sea water flow became normal,system restart automatically.
In case ob Item b,the system does not start automatically so please off run switch and NFB,after
check the system and confirm no problem,restart by hand-operation.
d. In case of short-circuit due to electric accident,No-Fuse-Breaker tripps and stops operation.
3. Adjustment and operation procedure
1) Open fully the electrolyte injection valves, which are equipped with sea chest.
2) Operate the pump and let the sea water flow into the electrolyzer. Then make certain that
setting of flow switch is correct. (Settig value is the red index of inlet flow meter)
3) Making certain whether the given amount of sea water is flowing, turn the No-FuseBreaker on.
Then make certain that source lamp turns on.
4) Next, turn the A-regulator clockwise, and set electrolytic current to usual value. (Refer to Fig.1
Treated amount-Electrolytic current-Chlorine density)
5) Check whether or not the electrolyzed sea water is distributed properly to each cooling system
by taking the sea water from the air vent,which is fixed to sea water pumps to suck the sea
water from each sea chest.
If the residual chlorine dosage is 0.05ppm, it will be good.
If it is not within the allowance,adjust the injection valve of each sea chest.
In case of the redidual chlorine dosage is low as a whole, increase the electrolytic current. And
in case of high,decrease it.
Note;
1) If the sea water is turbid, residual chlorine dosage is decreased and may not appear. Therefore,
the measurement must be made where sea water is clean.
2) Make the data of electrolytic current and residual chlorine dosage both at times of the ship is
sailing and anchoring. According to the data, set the electrolytic current and electrolyte
injection valves.
3) The opening degree of the injection valves often varies by vibration, so check it periodically .

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
4) In areas where sea water has higher density of salt or higher temperature, readjustment of
electrolytic current is necessary, because larger current flows in such a place.
In areas where sea water and fresh water are mixed, stop electrolys is because it is difficult for
current to flow there.
5) Even if electrolysis has been stopped, electrolytic voltage meter does not become on zero
point.
It is not due to breakdown of the meter but due to formation of electrolyzer. To make certain of
zero point of the meter, it is necessary to cut off electrically the voltage meter from the electric
circuit.
4. Determination of residual chlorine density
1) Open the air vent valve of sea water pump and let the sea water flow out for one minute, then
proceed for determination in according to the instruction of chlorinedeter mination apparatus,
which is provided with the device.
2) Wash test tube thoroughly before determination. If it is dirty the correct value can not be
obtained.
5. Operation note
1) First, make certain that the given sea water flow is followed. If it is satisfactory, apply a current.
Also when you close the inlet and outlet valves of sea water, you must, first, stop its operation.
2) Don't let flow electrolytic current more over reguler value. Under operation,if electrolytic current
become on zero point, check following order.
* Electric part
1) Have each fuse been normal ?
* Electrolyzer
1) Have flow amount kept on normal ?
2) Have electrode and lead wire been short-circuit ?
3) Have coating of electrode been used up completly ?
3) Electrolytic current may be varied by the resistance of sea water depends on the place or the
season of the year. In case the current is varied exceedingly, readjust it to a proper value.
4) Check residual chlorine density to be 0.05ppm about once a month.
5) Check electrode every three months by pilling out it together with anode holding board. In case
that the clay-like white substance (magnesium hydroxide) is found in the electrelyzer, wipe it off
thoroughly with cloth.
The magnesium hydroxide adheres in abundance when the flow in the electrolyzer is small and
large amount of it will cause the current to become decreased and will damage the electrode.
Therefore, given sea water flow must be maintained when the device Is under operation. Anode
is coating platinum on the base material titanium plated.
So, pay attention to handle and do not knock or damage it. Life of anode is about two years.
Anode is possible to use.even if coating fall off somewhat, but if the appointed electrolytic
current is not again in spite of normal electrolytic voltage, please exchange new one. And,
anode is also possible to refresh by recoating.
In time of checking, clean through the air vent tube with the tool provided.
6) In case operation to be stopped for a long time, let sea water out of electrolytic cell from drain
valve.

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
RESIDUAL CHLORINE TESTER (0-TOLIDINE METHOD)
OPERATION MANUAL
1 . COMPONENTS AND NAME Of PARTS:
Items NAME Of PARTS DESCRIPTION Qty
I Colorimeter body with standard colored glasses (0.05-2.0ppm) 1
2 Colorimetric tubes with graduations (10ml, 20ml) 3
3 Dropping bottle with pipet and rabber bulb 1
4 Vinyl case 1
5 Reagent O-Tolidine Ilydrochloride solution (100ml) 1

2.MEASURING:
1) Take sampling sea water from air vent valve of sea water pump after ten (10) minutes operation
and let the sea water flow out for one (1) minute.
2) Take out two (2) colorimetric tubes from the colorimeter body, put sampling sea water in each
tube up to about 8/10 height (about 25ml) of them.(Fig-1)
*SAMPLING SEA WATER TO BE TESTED SOONESTLY OTHERWISE CORRECT CAN NOT BE MEASURED.
3) Set these two (2) tubes in pocket of both side with colorod glass windows of the colorimeter
body.(Fig-2)

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

4) Put reagent of 0.5ml in the other tube with pipet first, socondly, add sample sea water to it up to
the markline of 10ml, then set the tube In pocket of center immediately.(Fig-3)

5) By the reaction between reagent and sample sea water, it is colored.

compare the color with standard colored glass windows In the both sides and read the
concentration of residual chlorine (Free chlorine) In ppm from the value of corres ponding
color(Fig-4)
* At this time, direct the rear side of the body to a light side of the room In order to make an easy
color comparison. But avoid the direct sunbeam.

NOTE:
1) Measurement to be carried out accroding to the above mentioned steps sirictly.
2) Keep the reagent at cool dark place always.
3) Avoid to store the reagent in the dropping bottle.
4) Wash the colorimetric tubes and pipet thoroughly after use, let it dried and then return to the
vinyl case.
5) Don't touch the reagent (0-Toidine Hydrochloride Solution) by hand.

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
SPECIAL DIAPHRAGM DIFFERENTIAL PRESSURE FLOW METER
INSTRUCTION MANUAL
MODEL; ODM-300&300S

1. Piping procedure
1) See Fig-A As shown, fasten the flow meter together with the packing between two flanges with
bolts and nuts.
Note:
i) Piping may be made In either direction of flow provided that the flow meter should be Installed
with the arrow on its body aligned to the direction of flow.
ii) The flow meter, model ODM 300 or 300S, has an Interface spacing of 80 mm with two sheets of
packing Included (one sheet being 2mm thick).
iii) A length of straight pipe should be provided before as well as after the flow meter (for 10 to 15D
*D representing the Inner diameter of the pipe).
2. Caution for flow meter of liquid (See Fig-A)
1) After completion of the piping work, run the system for a while with the stop valves (two) kept In
a state of "shut" In order to flow off any foreign matters In the piping system.
2) With the equalizing valve kept In a state of "open", open the stop valves (two) to the full. After
elapse of about 20 seconds, close the equalizing valve. Measurement Is now possible.
Note:
i) In the case of field Indication, the normal operation may be entered Immediately after the
procedure of subparagraph 2).
ii) The procedure of subparagraph 2) Is performed for the purpose of purging air In the pressure
pipe and pressure receiving unit.
iii) Where the flow has a considerable amount of pulsating and It Is difficult to read the Indicating,
reduce the stop valves appropriately for adjustment. (It Is possible to Interfere the swing of
pointer)

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"
3. Adjustment of the contact position for the model provided with contact (OOM-3005)
1) The contact Is of Internally adjustable type and can be set at any flow position within the range
of scale.
2) Remove the front cover shown In Fig-A. Then, unfasten the screws + at the corners For the Inside,
see Fig-B.

Note:
i) In setting the contacts, OFF the power before any work is made.
ii) For the microswitch the circuit A or B should be used.
C Red - White = Circuit A, C Red - Black or Green = Circuit 0
4. Maintenance and Inspection
1) When the operation Is slopped or otherwise the flow Is suspended, see that the pointer Indicates
the zero point.
2) For the sake of safety, be sure to use the Instrument within the specified pressure and
temperature.
Note:
i) The Indicator pointer has a stopper provided within the Indicator so that If It swings over the
range of scale, there will be no problem.
ii) In order for the Ilquld pressure to Lie tested by the Indicator, It must be 0.05 MPa (G) (0.5
kg/cm2 (G)) or more.
5. Cleaning method
The cleaning Is to be made with the stop valve closed, two cleaning valves opened and equalizing
valve opened (for about 5 minutes).
Upon complectlon of the cleaning, close the cleaning valves and equalizing valve.

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]

 "Marine Growth Preventing Device"
"CHLORINE ATTACKER-DS"

YOKOHAMA DENKO CO.,LTD [email protected]