1. The oxide of an element contains 67.67% oxygen and the (a) 1.2 × 10–20 g (b) 5.

025 × 1023 g
vapour density of its volatile chloride is 79. Equivalent weight (c) 1.4 × 10 g–21 (d) 6.023 × 10–20 g
of the element is: 14. Among the following pairs of compounds, the one that
(a) 2.46 (b) 3.82 (c) 4.36 (d) 4.96 illustrates the law of multiple proportions is
2. The empirical formula of a compound is CH2O. Its molecular (a) NH3 and NCl3 (b) H2S and SO2
weight is 180. The molecular formula of compound is : (c) CS2 and FeSO4 (d) CuO and Cu2O
(a) C 4 HO4 (b) C 3 H 6 O 3 15. Irrespective of the source, pure sample, of water always yields
88.89% mass of oxygen and 11.11% mass of hydrogen. This is
(c) C 6 H12O 6 (d) C 5 H10 O 5
explained by the law of
3. 0.4 moles of HCl and 0.2 moles of CaCl 2 were dissolved in (a) conservation of mass (b) multiple proportions
water to have 500 mL of solution, the molarity of Cl – ion is: (c) constant composition (d) constant volume
(a) 0.8 M (b) 1.6 M (c) 1.2 M (d) 10.0 M 16. The volume of 20 volume H2O2 required to get 5 litres of O2 at
4. 1021 molecules are removed from 200 mg of CO2. The moles of STP is
CO2 left are : (a) 250 ml (b) 125 ml (c) 100 ml (d) 50 ml.
17. Given P = 0.0030m, Q = 2.40m, R = 3000m, Significant figures
(a) 2.88 ´ 10 - 3 (b) 28.8 ´10 -3
in P, Q and R are respectively
(c) 288 ´ 10 -3 (d) 28.8 ´ 10 3 (a) 2, 2, 1 (b) 2, 3, 4 (c) 4, 2, 1 (d) 4, 2, 3
5. The weight of NaCl decomposed by 4.9g of H2SO4, if 6 g of 18. The prefix zepto stands for (in m)
sodium hydrogen sulphate and 1.825 g of HCl, were produced (a) 109 (b) 10–12
in the reaction is: (c) 10–15 (d) 10–21
(a) 6.921 g (b) 4.65 g (c) 2.925 g (d) 1.4 g 19. Two samples of lead oxide were separately reduced to metallic
6. Which one of the following pairs of compounds illustrate the lead by heating in a current of hydrogen. The weight of lead
law of multiple proportions ? from one oxide was half the weight of lead obtained from the
(a) H2O and Na2O (b) MgO and Na2O other oxide. The data illustrates
(c) Na2O and BaO (d) SnCl2 and SnCl4 (a) law of reciprocal proportions
7. The molecular weight of O2 and SO2 are 32 and 64 respectively. (b) law of constant proportions
At 15°C and 150 mm Hg pressure, one litre of O2 contains ‘N’ (c) law of multiple proportions
molecules. The number of molecules in two litres of SO2 under (d) law of equivalent proportions
the same conditions of temperature and pressure will be : 20. Number of valency electrons in 4.2 gram of N3– ion is
(a) N/2 (b) 1N (c) 2N (d) 4N (a) 4.2 NA (b) 0.1 NA (c) 1.6 NA (d) 3.2 NA
8. In the final answer of the expression 21. 100 ml of solution of H2O2 on decomposition gives 1500 ml of
O2 at N.T.P. The H2O2 has the volume strength
( 29.2 - 20.2) (1.79 ´ 10 5 ) (a) 8.6 volume (b) 10 volume
1.37 (c) 15 volume (d) 25 volume
the number of significant figures is : 22. Which of the following is the best example of law of
(a) 1 (b) 2 (c) 3 (d) 4 conservation of mass?
9. The number of significant figures for the three numbers (a) 12 g of carbon combines with 32 g of oxygen to form 44 g
161 cm, 0.161 cm, 0.0161 cm are of CO2
(a) 3,4 and 5 respectively (b) 3,4 and 4 respectively (b) When 12 g of carbon is heated in a vacuum there is no
(c) 3,3 and 4 respectively (d) 3,3 and 3 respectively change in mass
10. A gas occupies a volume of 300 cc at 27°C and 620 mm (c) A sample of air increases in volume when heated at
pressure. The volume of gas at 47°C and 640 mm pressure is: constant pressure but its mass remains unaltered
(a) 260 cc (b) 310 cc (c) 390 cc (d) 450 cc (d) The weight of a piece of platinum is the same before and
11. The prefix 1018 is after heating in air
(a) giga (b) kilo (c) exa (d) nano 23. With increase of temperature, which of these changes?
12. A sample was weighted using two different balances. The (a) Molality (b) Weight fraction of solute
results were (c) Molarity (d) Mole fraction
(i) 3.929 g (ii) 4.0 g 24. A gas is found to have formula (CO)n. If its vapour density is
How would the weight of the sample be reported? 56, the value of n will be:
(a) 3.93 g (b) 3g (c) 3.9 g (d) 3.929 g (a) 7 (b) 5 (c) 4 (d) 3
25. The least count of an instrument is 0.01 cm. Taking all precautions,
13. The weight of one molecule of a compound of molecular
the most possible error in the measurement can be :
formula C60H122 is (a) 0.005 cm (b) 0.01 cm (c) 0.0001 cm (d) 0.1 cm
26. A metallic chloride contain 47.22% metal. Calculate the 37. What is the molarity of 0.2N Na 2 CO 3 solution?
equivalent weight of metal.
(a) 0.1 M (b) 0 M (c) 0.4 M (d) 0.2 M
(a) 39.68 (b) 31.76 (c) 36.35 (d) 33.46
2+
27. One litre hard water contains 12.00 mg Mg . Milli-equivalents 38. The molar solution of H 2SO 4 is equal to :
of washing soda required to remove its hardness is : (a) N/2 solution (b) N solution
(a) 1 (b) 12. 16 (c) 2N solution (d) 3N solution
(c) 1 × 10 –3 (d) 12. 16 × 10–3 39. The equivalent weight of a solid element is found to be 9. If
the specific heat of this element is 1.05 Jg–1 K–1, then its
28. The percentage weight of Zn in white vitriol [ZnSO4.7H2O] is
atomic weight is :
approximately equal to ( Zn = 65, S = 32, O = 16 and H = 1) (a) 17 (b) 21 (c) 25 (d) 27
(a) 33.65 % (b) 32.56 % (c) 23.65 % (d) 22.65 % 40. The maximum number of molecules are present in
29. 25ml of a solution of barium hydroxide on titration with a 0.1 (a) 15 L of H2 gas at STP
molar solution of hydrochloric acid gave a litre value of 35ml. (b) 5 L of N2 gas at STP
The molarity of barium hydroxide solution was (c) 0.5 g of H2 gas
(a) 0.14 (b) 0.28 (c) 0.35 (d) 0.07 (d) 10 g of O2 gas
30. 20
6.02 × 10 molecules of urea are present in 100 ml of its 41. The vapour density of a gas is 11.2, then 11.2 g of this gas at
solution. The concentration of urea solution is N.T.P. will occupy a volume-
(a) 0.02 M (b) 0.01 M (c) 0.001 M (d) 0.1 M (a) 11.2 L (b) 22.4 L (c) 11.2 mL (d) 22.4 mL
42. What is the mass of 1 molecule of CO.
(Avogadro constant, NA = 6.02 × 1023 mol–1)
(a) 2.325 × 10–23 (b) 4.65 × 10–23
31. Two solutions of a substance (non electrolyte) are mixed in –23
(c) 3.732 × 10 (d) 2.895 × 10–23
the following manner. 480 ml of 1.5 M first solution + 520 ml of
43. Calculate the volume at STP occupied by 240 gm of SO2.
1.2 M second solution. What is the molarity of the final
mixture? (a) 64 (b) 84 (c) 59 (d) 73
44. The number of gram molecules of oxygen in 6.02 × 1024
(a) 2.70 M (b) 1.344 M (c) 1.50 M (d) 1.20 M
CO molecules is
32. What volume of hydrogen will be liberated at NTP by the
(a) 10 gm molecules (b) 5 gm molecules
reaction of Zn on 50 ml dilute H2SO4 of specific gravity 1.3
(c) 1 gm molecules (d) 0.5 gm molelcules
and having purity 40%?
45. Which has maximum number of molecules?
(a) 3.5 litre (b) 8.25 litre (c) 6.74 litre (d) 5.94 litre
(a) 7 gm N2 (b) 2 gm H2
33. Following is the composition of a washing soda sample :
(c) 16 gm NO2 (d) 16 gm O2
46. Number of atoms in 558.5 gram Fe (at. wt. of Fe = 55.85 g mol–1)
Substance Molecular Wt. Mass percent
is
Na2CO3 106.0 84.8 (a) twice that in 60 g carbon (b) 6.023 ´ 1022
NaHCO3 84.0 8.4
(c) half that in 8 g He (d) 558.5 ´ 6.023 ´ 1023
NaCl 58.5 6.8
47. How many moles of magnesium phosphate, Mg3(PO4)2 will
On complete reaction with excess HCl, one kilogram of the contain 0.25 mole of oxygen atoms?
washing soda will evolve:
(a) 1.25 × 10–2 (b) 2.5 × 10–2
(a) 9 mol of CO2 (b) 16 mol of CO2
(c) 0.02 (d) 3.125 × 10–2
(c) 17 mol of CO2 (d) 18 mol of CO2
48. 7.5 grams of a gas occupy 5.6 litres of volume at STP. The gas
34. To neutralise completely 20 mL of 0.1 M aqueous solution of is
phosphorous acid (H3PO3), the value of 0.1 M aqueous KOH
(a) N2O (b) NO (c) CO (d) CO2
solution required is
49. 3 g of an oxide of a metal is converted to chloride completely
(a) 40 mL (b) 20 mL (c) 10 mL (d) 60 mL and it yielded 5 g of chloride. The equivalent weight of the
35. Density of a 2.05M solution of acetic acid in water is metal is
1.02 g/mL. The molality of the solution is (a) 3.325 (b) 33.25 (c) 12 (d) 20
(a) 2.28 mol kg–1 (b) 0.44 mol kg–1 50. The number of molecules in 16 g of methane is
(c) 1.14 mol kg–1 (d) 3.28 mol kg–1
16
36. The equivalent weight of MnSO4 is half of its molecular weight (a) 3.0 × 1023 (b) ´ 10 23
when it is converted to : 6.02

(d) MnO42-
-
(a) Mn 2O3 (b) MnO2 (c) MnO4 16
(c) 6.023 × 1023 (d) ´ 10 23
3.0
51. Number of g of oxygen in 32.2 g Na2SO4.10 H2O is (c) all the oxygen will be consumed
(a) 20.8 (b) 2.24 (d) all the ammonia will be consumed
(c) 22.4 (d) 2.08 65. Assuming fully decomposed, the volume of CO2 released at
52. The number of water molecules present in a drop of water STP on heating 9.85 g of BaCO3 (Atomic mass, Ba = 137) will
(volume 0.0018 ml) at room temperature is be
(a) 1.084 × 1018 (b) 6.023 × 1019 (a) 2.24 L (b) 4.96 L (c) 1.12 L (d) 0.84 L
(c) 4.84 × 10 17 (d) 6.023 × 1023 66. In a compound C, H and N atoms are present in 9 : 1 : 3.5 by
53. The number of moles of oxygen in one litre of air containing weight. Molecular weight of compound is 108. Molecular
21% oxygen by volume, under standard conditions are formula of compound is
(a) 0.0093 mole (b) 0.21 mole (a) C2H6N2 (b) C3H4N
(c) 2.10 mole (d) 0.186 mole (c) C6H8N2 (d) C9H12N3.
54. The number of molecules in 8.96 litre of a gas at 0ºC and 1 atm. 67. The simplest formula of a compound containing 50% of
pressure is approximately element X (atomic mass 10) and 50% of element Y (atomic
(a) 6.023 × 1023 (b) 12.04 × 1023 mass 20) is
(c) 18.06 × 1023 (d) 24.08 × 1022 (a) XY (b) XY3 (c) X2Y (d) X2Y3
55. The mass of a molecule of water is 68. The empirical formula of an acid is CH2O2, the probable
(a) 3 × 10–25 kg (b) 3 × 10–26 kg molecular formula of acid may be :
–26
(c) 1.5 × 10 kg (d) 2.5 × 10–26 kg (a) C3H6O4 (b) CH2O (c) CH2O2 (d) C2H4O2
56. How many atoms are contained in one mole of sucrose 69. An organic compound contains 49.3% carbon, 6.84%
(C12 H22O11)? hydrogen and its vapour density is 73. Molecular formula of
(a) 20 × 6.02 × 1023 atoms/mol the compound is :
(b) 45 × 6.02 × 1023 atoms/mol (a) C 3 H 5 O 2 (b) C 4 H10 O 2
(c) 5 × 6.02 × 1023 atoms/mol
(c) C 6 H10 O 4 (d) C 3 H10 O 2
(d) None of these
70. The number of atoms in 4.25 g of NH3 is approximately
57. How many moles of helium gas occupy 22.4 litre at 0°C and 1
atm pressure ? (a) 6 × 1023 (b) 2 × 1023 (c) 4 × 1023 (d) 1 × 1023
(a) 0.11 (b) 1.11 (c) 0.90 (d) 1.0 71. 30 g of magnesium and 30 g of oxygen are reacted, then the
residual mixture contains
58. Number of moles of NaOH present in 2 litre of 0.5 M NaOH is :
(a) 50 g of Magnesium oxide and 10 g of oxygen
(a) 1.5 (b) 2.0 (c) 1.0 (d) 2.5
(b) 40 g of Magnesium oxide and 20 g of oxygen
59. O2, N2 are present in the ratio of 1 : 4 by weight. The ratio of
number of molecules is : (c) 45 g of Magnesium oxide and 15 g of oxygen
(a) 7 : 32 (b) 1 : 4 (c) 2 : 1 (d) 4 : 1 (d) 60 g of Magnesium oxide only
60. The hydrogen phosphate of certain metal has formula 72. The mass of BaCO3 produced when excess CO2 is bubbled
MHPO4. The formula of metal chloride would be through a solution of 0.205 mol Ba(OH)2 is :
(a) MCl (b) M2Cl2 (c) MCl2 (d) MCl3 (a) 81 g (b) 40.5 g (c) 20.25 g (d) 162 g
61. Number of moles of KMnO4 required to oxidize one mole of 73. A compound contains 54.55 % carbon, 9.09% hydrogen ,
Fe(C2O4) in acidic medium is 36.36% oxygen. The empirical formula of this compound is :
(a) 0.167 (b) 0.6 (c) 0.2 (d) 0.4 (a) C3H 5O (b) C 4 H 8O 2
62. 10 g CaCO3 gives on strong heating CO2. It gives quicklime
(c) C 2 H 4O 2 (d) C 2 H 4O
(in grams)
(a) 5g (b) 4.4 g (c) 5.6 g (d) 4 g 74. In the reaction
63. What is the weight of oxygen required for the complete ® 4NO(g) + 6H 2 O(l ) ,when 1 mole
4NH 3 (g) + 5O 2 (g) ¾¾
combustion of 2.8 kg of ethylene ? of ammonia and 1 mole of O2 are made to react to completion
(a) 2.8 kg (b) 6.4 kg (c) 9.6 kg (d) 96 kg (a) 1.0 mole of H2O is produced
64. In the reaction (b) 1.0 mole of NO will be produced
4 NH3 ( g ) + 5O2 ( g ) ® 4 NO( g ) + 6H2 O(l ) (c) all the ammonia will be consumed
When 1 mole of ammonia and 1 mole of O2 are made to react (d) all the oxygen will be consumed
to completion, 75. A gas is found to have a formula [CO]x. If its vapour density
(a) 1.0 mole of H2O is produced is 70, the value of x is :
(b) 1.0 mole of NO will be produced (a) 2.5 (b) 3.0 (c) 5.0 (d) 6.0
1. 0.5400 g of a metal X yields 1.020 g of its oxide X 2O3. The 11. The specific heat of a metal is 0.16 cal g–1. The equivalent
mass of the metal is 20.04, the correct atomic mass of the metal
number of moles of X is : is :
(a) 0.01 (b) 0.02 (c) 0.04 (d) 0.05 (a) 40 (b) 20.04 (c) 40.08 g (d) 80.16 g
2. 12 L of H2 and 11.2 L of Cl2 are mixed and exploded. Find the 12. A metal oxide has the formula Z2O3. It can be reduced by
composition by volume of mixture. hydrogen to give free metal and water. 0.1596 g of the metal
(a) 11.2, 11.2, 22.4 (b) 0.8, 0, 22.4 oxide requires 6 mg of hydrogen for complete reduction. The
(c) 0.8, 0.8, 22.4 (d) 0.8, 11.2, 22.4 atomic weight of the metal is
(a) 27.9 (b) 159.6 (c) 79.8 (d) 55.8
3. The hydrated salt Na 2 CO3 .x H 2 O undergoes 63% loss in 13. Ratio of Cp and Cv of a gas ‘X’ is 1.4. The number of atoms of
mass on heating and becomes anhydrous. The value of x is the gas ‘X’ present in 11.2 litres of it at NTP will be
(a) 3 (b) 5 (c) 7 (d) 10 (a) 6.02 ×1023 (b) 1.2 × 1023
(c) 3.01 × 10 23 (d) 2.01 × 1023
4. On adding excess of CaCl2 to a solution containing Na2CO3
14. Percent by mass of a solute (molar mass = 28 g) in its aqueous
and NaHCO3, x g of precipitate was obtained. On adding in
solution is 28. Calculate the mole fraction (X) and molality (m)
drops to the filtrate, a further y g of precipitate was obtained.
of the solute in the solution.
In another experiment to the same amount of solution excess (a) X = 0.2, m = 10 (b) X = 0.2, m = 125/9
of CaCl2 was added, boiled and filtered. The amount of the (c) X = 0.8, m = 125/9 (d) X = 0.8, m = 10
precipitate in the second experiment would be 15. The density of 0.5 M glucose solution is 1.0900g ml–1. The
y molality of the solution is
(a) x + y (b) x + (a) 0.1000 (b) 0.2000 (c) 0.2500 (d) 0.5000
2
16. Haemoglobin contains 0.334% of iron by weight. The
x+ y molecular weight of haemoglobin is approximately 67200. The
(c) (d) none of these number of iron atoms (at. wt. of Fe is 56) present in one
2
molecule of haemoglobin are
5. 10 moles SO2 and 15 moles O2 were allowed to react over a (a) 1 (b) 6
suitable catalyst. 8 moles of SO3 were formed. The remaining (c) 4 (d) 2
moles of SO2 and O2 respectively are - 17. Specific volume of cylindrical virus particle is 6.02 × 10–2 cc/gm.
(a) 2 moles, 11 moles (b) 2 moles, 8 moles whose radius and length 7 Å & 10 Å respectively.
(c) 4 moles, 5 moles (d) 8 moles, 2 moles If NA = 6.02 × 1023, find molecular weight of virus
(a) 3.08 × 103 kg/mol (b) 3.08 × 104 kg/mol
6. If 0.5 mol of BaCl2 is mixed with 0.2 mole of Na3PO4, find the 4
(c) 1.54 × 10 kg/mol (d) 15.4 kg/mol
maximum amount of Ba3(PO4)2 that can be formed.
18. Percentage of Se in peroxidase anhydrase enzyme is 0.5% by
(a) 1 mole (b) 0.5 mole weight (at. wt. of Se = 78.4) then minimum molecular weight
(c) 0.1 mole (d) 0.01 mole of peroxidase anhydrase enzyme is
7. On reduction 1.644 gm of hot iron oxide give 1.15 gm of iron. (a) 1.568 × 103 (b) 15.68
Evaluate the equivalent weight of iron. (c) 2.136 × 104 (d) 1.568 × 104
(a) 18.62 (b) 19.13 19. In Haber process 30 litres of dihydrogen and 30 litres of
dinitrogen were taken for reaction which yielded only 50% of
(c) 18.95 (d) 12.95
the expected product. What will be the composition of
8. The volume of chlorine at STP required to liberate all the gaseous mixture under the aforesaid condition in the end?
bromine and iodine in 100 ml of 0.1 M each of KI and MBr2 will (a) 20 litres ammonia, 25 litres nitrogen, 15 litres hydrogen
be: (b) 20 litres ammonia, 20 litres nitrogen, 20 litres hydrogen
(a) 0.224 L (b) 0.336 L (c) 0.448 L (d) 0.560 L (c) 10 litres ammonia, 25 litres nitrogen, 15 litres hydrogen
9. 6.8 gm H2O2 present in 100 ml of its solution. What is the (d) 20 litres ammonia, 10 litres nitrogen, 30 litres hydrogen
molarity of solution? 20. Malachite has the formula Cu2CO3(OH)2. What percentage
(a) 1 M (b) 2 M (c) 3 M (d) 0.5 M by mass of malachite is copper?
(a) 25% (b) 50.9% (c) 57.5% (d) 63.5%
10. 1 c.c. N2O at NTP contains :
21. What volume of hydrogen gas, at 273 K and 1 atm. pressure
6.02
(a) 1.8 ´ 10 22 atoms (b) ´ 10 23 molecules will be consumed in obtaining 21.6 g of elemental boron
224 22400 (atomic mass = 10.8) from the reduction of boron trichloride
by hydrogen ?
(c) 1.32 ´ 10 23 electrons (d) All of these
224 (a) 67.2 L (b) 44.8 L (c) 22.4 L (d) 89.6 L
22. The number of atoms of Cr and O are 4.8 × 1010 and 9.6 × 1010 (a) decrease twice
respectively. Its empirical formula is (b) increase two fold
(a) Cr2O3 (b) CrO2 (c) remain unchanged
(c) Cr2O4 (d) None of these (d) be a function of the molecular mass of the substance
23. The unit J Pa–1 is equivalent to 36. The density (in g mL–1) of a 3.60 M sulphuric acid solution
(a) m3 (b) cm3 that is 29% H2SO4 (molar mass = 98 g mol–1) by mass will be
(c) dm 3 (d) None of these (a) 1.45 (b) 1.64 (c) 1.88 (d) 1.22
24. Sulphur forms the chlorides S2Cl2 and SCl2. The equivalent 37. The molality of a urea solution in which 0.0100 g of urea,
mass of sulphur in SCl2 is [(NH2)2CO] is added to 0.3000 dm3 of water at STP is :
(a) 8 g/mol (b) 16 g/mol
(a) 5.55 ´ 10 -4 m (b) 33.3 m
(c) 64.8 g/mol (d) 32 g/mol
(c) 3.33 × 10–2 m (d) 0.555 m
25. How many moles of KI are required to produce 0.4 moles of
38. Consider a titration of potassium dichromate solution with
K2HgI4 ?
acidified Mohr's salt solution using diphenylamine as
(a) 0.4 (b) 0.8
indicator. The number of moles of Mohr's salt required per
(c) 3.2 (d) 1.6
mole of dichromate is
26. 100 ml O2 and H2 kept at same temperature and pressure.
(a) 3 (b) 4 (c) 5 (d) 6
What is true about their number of molecules
39. A gaseous hydrocarbon gives upon combustion 0.72 g of
(a) NO > NH (b) NO < NH
2 2 2 2 water and 3.08 g. of CO2. The empirical formula of the
(c) NO = NH (d) NO + NH = 1 mole
2 2 2 2 hydrocarbon is :
27. The percentage of P2O5 in diammonium hydrogen phosphate
(a) C2H4 (b) C3H4 (c) C6H5 (d) C7H8
(NH4)2HPO4 is
40. Experimentally it was found that a metal oxide has formula
(a) 23.48 (b) 46.96 (c) 53.78 (d) 71.00
M0.98O. Metal M, present as M2+ and M3+ in its oxide. Frac-
28. Under similar conditions of pressure and temperature, 40 ml
tion of the metal which exists as M3+ would be :
of slightly moist hydrogen chloride gas is mixed with 20 ml of
(a) 7.01% (b) 4.08% (c) 6.05% (d) 5.08%
ammonia gas, the final volume of gas at the same temperature
41. Liquid benzene (C6H6) burns in oxygen according to the
and pressure will be
(a) 100 ml (b) 20 ml equation 2C 6 H 6 (l ) + 15O 2 ( g ) ¾¾® 12CO 2 ( g ) + 6 H 2 O( g )
(c) 40 ml (d) 60 ml How many litres of O2 at STP are needed to complete the
29. How many gram of sulphur can be obtained by the reaction of combustion of 39 g of liquid benzene?(Mol. wt. of O2 = 32,
1 mol of SO 2 with 22.4 L of H 2S at STP? C6H6 = 78)
(a) 96 g (b) 48 g (a) 74 L (b) 11.2 L (c) 22.4 L (d) 84 L
(c) 32 g (d) None of these 42. An organic compound whose empirical and molecular formula
30. 3 g of Mg is burnt in a closed vessel containing 3 g of oxygen. are same, contains 20% carbon, 6.7% hydrogen, 46.7%
The weight of excess reactant left is nitrogen and the rest oxygen. On heating it yields ammonia,
(a) 0.5 g of oxygen (b) 1.0 g of oxygen leaving a solid residue. The solid residue gives a violet colour
(c) 1.0 g of Mg (d) 0.5 g of Mg with dilute solution of alkaline copper sulphate. The organic
31. The mass of carbon an ode consumed (giving only compound is
carbondioxide) in the production of 270 kg of aluminium (a) NH2COONH4 (b) HCOONH4
metal from bauxite by the Hall process is (Atomic mass: (c) NH2NHCHO (d) NH2CONH2
Al = 27) 43. In order to prepare one litre normal solution of KMnO4, how
(a) 270 kg (b) 540 kg (c) 90 kg (d) 180 kg many grams of KMnO4 are required if the solution is to be
32. Volume occupied by one molecule of water used in acid medium for oxidation?
(density = 1 g cm–3) is : (a) 158 g (b) 62.0 g (c) 31.6 g (d) 790 g
(a) 9.0 × 10–23 cm3 (b) 6.023 × 10– 23 cm3 1
44. If 1 moles of oxygen combine with Al to form Al2O3 the
(c) 3.0 × 10–23 cm3 (d) 5.5 × 10– 23 cm3 2
33. How many moles of lead (II) chloride will be formed from a weight of Al used in the reaction is (Al = 27)
reaction between 6.5 g of PbO and 3.2 g of HCl ? (a) 27 g (b) 54 g (c) 49.5 g (d) 31 g
(a) 0.044 (b) 0.333 (c) 0.011 (d) 0.029 45. Number of moles of MnO-4 required to oxidize one mole of
34. Which has the maximum number of molecules among the ferrous oxalate completely in acidic medium will be :
following ? (a) 0.6 moles (b) 0.4 moles
(a) 44 g CO2 (b) 48 g O3 (c) 7.5 moles (d) 0.2 moles
(c) 8 g H2 (d) 64 g SO2 46. 10 g of hydrogen and 64 g of oxygen were filled in a steel
35. If we consider that 1/6, in place of 1/12, mass of carbon atom vessel and exploded. Amount of water produced in this
is taken to be the relative atomic mass unit, the mass of one reaction will be:
mole of a substance will (a) 3 mol (b) 4 mol (c) 1 mol (d) 2 mol
47. In the reaction, (b) Statement -1 is True, Statement -2 is True ; Statement-2 is
2Al( s ) + 6HCl( aq ) ® 2Al3+ (aq) + 6Cl- (aq) + 3H2 ( g ) NOT a correct explanation for Statement - 1
(a) 11.2 L H2(g) at STP is produced for every mole HCl(aq) (c) Statement - 1 is True, Statement- 2 is False
(d) Statement -1 is False, Statement -2 is True
consumed
48. Statement-1 : Volume of a gas is inversely proportional to
(b) 6 L HCl(aq) is consumed for every 3 L H2(g) produced
(c) 33.6 L H2(g) is produced regardless of temperature and the number of moles of gas.
Statement-2 : The ratio by volume of gaseous reactants and
pressure for every mole Al that reacts
products is in agreement with their mole ratio.
(d) 67.2 H2(g) at STP is produced for every mole Al that reacts.
49. Statement-1 : One mole of SO2 contains double the number
DIRECTIONS for Qs. 48 to 50 : These are Assertion-Reason of molecules present in one mole of O2.
type questions. Each of these question contains two statements: Statement-2 : Molecular weight of SO2 is double to that of
Statement-1 (Assertion) and Statement-2 (Reason). Answer these O2.
questions from the following four options. 50. Statement-1 : 1.231 has three significant figures.
(a) Statement- 1 is True, Statement-2 is True, Statement-2 is a Statement-2 : All numbers right to the decimal point are
correct explanation for Statement -1 significant.

Exemplar Questions 6. If the concentration of glucose (C 6H12 O6) in blood is

1. Two students performed the same experiment separately and 0.9 g L–1, what will be the molarity of glucose in blood?
each one of them recorded two readings of mass which are (a) 5 M (b) 50 M
given below. Correct reading of mass is 3.0 g. On the basis (c) 0.005 M (d) 0.5 M
of given data, mark the correct option out of the following 7. What will be the molality of the solution containing 18.25 g
statements. of HCl gas in 500 g of water?
(a) 0.1 m (b) 1 M
Students Readings (c) 0.5 m (d) 1 m
8. One mole of any substance contains 6.022 × 10 23
(i) (ii)
atoms/molecules. Number of molecules of H2SO4 present in
A 3.01 2.99 100 mL of 0.02 M H2SO4 solution is........
(a) 12.044 × 1020 molecules (b) 6.022 × 1023 molecules
B 3.05 2.95
(c) 1 × 1023 molecules (d) 12.044 × 1023 molecules
(a) Results of both the students are neither accurate nor 9. What is the mass percent of carbon in carbon dioxide?
precise. (a) 0.034% (b) 27.27%
(b) Results of student A are both precise and accurate. (c) 3.4% (d) 28.7%
(c) Results of student B are neither precise nor accurate. 10. The empirical formula and molecular mass of a compound
(d) Results of student B are both precise and accurate. are CH2O and 180 g respectively .What will be the molecular
2. A measured temperature on Fahrenheit scale is 200°F. What formula of the compound?
will this reading be on celsius scale? (a) C9H18O9 (b) CH2O
(a) 40 °C (b) 94 °C (c) C6H12O6 (d) C2H4O2
(d) 93.3 °C (d) 30 °C 11. If the density of a solution is 3.12 g mL–1, the mass of
3. What will be the molarity of a solution, which contains 5.85 g 1.5 mL solution in significant figures is......
of NaCl(s) per 500 mL? (a) 4.7 g (b ) 4680 ×10–3 g
(a) 4 mol L–1 (b) 20 mol L–1 (c) 4.680 g (d) 46.80 g
(c) 0.2 mol L –1 (d) 2 mol L–1 12. Which of the following statements about a compound is
4. If 500 mL of a 5 M solution is diluted to 1500 mL, what will be incorrect?
the molarity of the solution obtained? (a) A molecule of a compound has atoms of different
(a) 1.5 M (b ) 1.66 M elements.
(c) 0.017 M (d) 1.59 M (b) A compound cannot be separated into its constituent
5. The number of atoms present in one mole of an element is elements by physical methods of separation.
equal to Avogadro number. Which of the following element (c) A compound retains the physical properties of its
contains the greatest number of atoms? constituent elements.
(a) 4 g He (b) 46 g Na (d) The ratio of atoms of different elements in a compound
(c) 0.40 g Ca (d) 12 g He is fixed.
13. Which of the following statements is correct about the 17. 6.02 × 1020 molecules of urea are present in 100 mL of its
reaction given below? solution. The concentration of solution is : [2013]
(a) 0.01 M (b) 0.001 M
4Fe (s) + 3O2 (g) ¾¾
® 2Fe2O3 (g) (c) 0.1 M (d) 0.02 M
(a) Total mass of iron and oxygen in reactants = total mass 18. When 22.4 litres of H2(g) is mixed with 11.2 litres of Cl2(g),
of iron and oxygen in product therefore it follows law each at S.T.P., the moles of HCl(g) formed is equal to : [2014]
of conservation of mass. (a) 1 mole of HCl(g) (b) 2 moles of HCl(g)
(b) Total mass of reactants = total mass of product, (c) 0.5 moles of HCl(g) (d) 1.5 moles of HCl(g)
therefore, law of multiple proportions is followed. 19. 1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel.
(c) Amount of Fe2O3 can be increased by taking any one Which reactant is left in excess and how much ? [2014]
of the reactants (iron or oxygen) in excess. (At. wt. Mg = 24 ; O = 16)
(d) Amount of Fe2O3 produced will decrease if the amount (a) Mg, 0.16 g (b) O2, 0.16 g
of any one of the reactants (iron or oxygen) is taken in (c) Mg, 0.44 g (d) O2, 0.28 g
excess. 20. IfAvogadro number NA, is changed from 6.022 × 1023 mol –1 to
14. Which of the following reactions is not correct according to 6.022 × 1020 mol–1 this would change : [2015 RS]
the law of conservation of mass? (a) the definition of mass in units of grams
(a) 2Mg (s) + O2 (g) ¾¾ ® 2MgO (s) (b) the mass of one mole of carbon
(b) C3H8 (g) + O2 (g) ¾¾ ® CO2 (g) + H2O (g) (c) the ratio of chemical species to each other in a balanced
(c) P4 (s) + 5O2 (g) ¾¾ ® P4O10 (s) equation.
(d) CH4 (g) + 2O2 (g) ¾¾ ® CO2 (g) + 2H2O (g) (d) the ratio of elements to each other in a compound
15. Which of the following statements indicates that law of 21. What is the mass of precipitate formed when 50 mL of
multiple proportion is being followed? 16.9% solution of AgNO3 is mixed with 50 mL of 5.8% NaCl
(a) Sample of carbon dioxide taken from any source will solution ? [2015 RS]
always have carbon and oxygen in the ratio 1 : 2. (Ag = 107.8, N = 14, O = 16, Na = 23, Cl = 35.5)
(b) Carbon forms two oxides namely CO2 and CO, where (a) 28 g (b) 3.5 g
masses of oxygen which combine with fixed mass of (c) 7 g (d) 14 g
carbon are in the simple ratio 2 : 1. 22. A mixture of gases contains H2 and O2 gases in the ratio of 1
(c) When magnesium burns in oxygen, the amount of : 4 (w/w). What is the molar ratio of the two gases in the
magnesium taken for the reaction is equal to the mixture ? [2015]
amount of magnesium in magnesium oxide formed. (a) 4 : 1 (b) 16 : 1
(c) 2 : 1 (d) 1 : 4
(d) At constant temperature and pressure 200 mL of
23. 20.0 g of a magnesium carbonate sample decomposes on
hydrogen will combine with 100 mL oxygen to produce
heating to give carbon dioxide and 8.0 g magnesium oxide.
200 mL of water vapour.
What will be the percentage purity of magnesium carbonate
NEET/AIPMT (2013-2017) Questions in the sample ? [2015 RS]
16. In an experiment it showed that 10 mL of 0.05 M solution of (a) 75 (b) 96
chloride required 10 mL of 0.1 M solution of AgNO3, which (c) 60 (d) 84
of the following will be the formula of the chloride (X stands 24. The number of water molecules is maximum in : [2015 RS]
for the symbol of the element other than chlorine): (a) 18 molecules of water
[NEET Kar. 2013] (b) 1.8 gram of water
(a) X2Cl (b) X2Cl2 (c) 18 gram of water
(c) XCl2 (d) XCl4 (d) 18 moles of water