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1.2. Relevant identified uses of the substance or mixture and uses advised against
Chemical Product
PC37 Water treatment chemicals
Category
Sectors of Use SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)
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Other emergency
+31-10-4877700 +1 800 424 9300 + 31 10 4877700
telephone numbers
Emergency telephone
+ 31 30 274 88 88
numbers
Other emergency
+ 31-10-4877700
telephone numbers
Hazard pictogram(s)
Hazard statement(s)
H302 Harmful if swallowed.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
Supplementary statement(s)
Not Applicable
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3.1.Substances
See 'Composition on ingredients' in Section 3.2
3.2.Mixtures
1.CAS No
2.EC No Classification according to regulation (EC) SCL / Nanoform Particle
%[weight] Name
3.Index No No 1272/2008 [CLP] and amendments M-Factor Characteristics
4.REACH No
1.107-21-1*
Specific Target Organ Toxicity - Repeated
2.203-473-3 Not
80-98% ethylene glycol * Exposure Category 2, Acute Toxicity (Oral) Not Available
3.603-027-00-1 Available
Category 4; H373, H302 [1]
4.Not Available
1.19766-89-3*
2.243-283-8|406-150-7 2-ethylhexanoic acid, Not
3-5% Reproductive Toxicity Category 2; H361d [1] Not Available
3.Not Available sodium salt Available
4.Not Available
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties
Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or
unless instructed otherwise:
INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side
(head-down position, if possible) to maintain open airway and prevent aspiration.
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4.2 Most important symptoms and effects, both acute and delayed
See Section 11
4.3. Indication of any immediate medical attention and special treatment needed
As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the ABCDEs of
toxicology (antidotes, basics, change absorption, change distribution, change elimination).
For poisons (where specific treatment regime is absent):
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BASIC TREATMENT
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Establish a patent airway with suction where necessary.
Watch for signs of respiratory insufficiency and assist ventilation as necessary.
Administer oxygen by non-rebreather mask at 10 to 15 L/min.
Monitor and treat, where necessary, for pulmonary oedema.
Monitor and treat, where necessary, for shock.
Anticipate seizures.
DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to
swallow, has a strong gag reflex and does not drool.
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ADVANCED TREATMENT
--------------------------------------------------------------
Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
Positive-pressure ventilation using a bag-valve mask might be of use.
Monitor and treat, where necessary, for arrhythmias.
Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
Drug therapy should be considered for pulmonary oedema.
Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
Treat seizures with diazepam.
Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994
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Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Major Spills Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.
+ x + o + + +
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Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.
INGREDIENT DATA
Emergency Limits
MATERIAL DATA
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Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
8.2.1. Appropriate
Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.
Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
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Material CPI
NATURAL RUBBER A
NATURAL+NEOPRENE A
NEOPRENE A
NEOPRENE/NATURAL A
NITRILE A
NITRILE+PVC A
PE/EVAL/PE A
PVC A
TEFLON A
PVA B
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gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
Partition coefficient
Odour Not Available Not Available
n-octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Applicable
(°C)
Decomposition
pH (as supplied) 8.7 Not Applicable
temperature
Melting point / freezing
Not Applicable Viscosity (cSt) Not Available
point (°C)
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products
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exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and that
suitable control measures be used in an occupational setting.
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be
Ingestion
fatal or may produce serious damage to the health of the individual.
Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models). Systemic
harm, however, has been identified following exposure of animals by at least one other route and the material may still produce
health damage following entry through wounds, lesions or abrasions. Good hygiene practice requires that exposure be kept to a
Skin Contact
minimum and that suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
Eye Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
transient discomfort characterised by tearing or conjunctival redness (as with windburn).
Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical
systems.
Chronic Exposure to the material may cause concerns for humans owing to possible developmental toxic effects, generally on the basis
that results in appropriate animal studies provide strong suspicion of developmental toxicity in the absence of signs of marked
maternal toxicity, or at around the same dose levels as other toxic effects but which are not a secondary non-specific
consequence of other toxic effects.
TOXICITY IRRITATION
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Oral (Rat) LD50; 1720 mg/kg[2] Not Available
TOXICITY IRRITATION
Dermal (rabbit) LD50: 9530 mg/kg[2] Eye (rabbit): 100 mg/1h - mild
Oral (Human)LDLo: 398 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]
TOXICITY IRRITATION
2-ethylhexanoic acid,
dermal (rat) LD50: >2000 mg/kg[1] Not Available
sodium salt
Oral (Rat) LD50; 2043 mg/kg[1]
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a
non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high
levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease,
in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented
2-ethylhexanoic acid,
exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial
sodium salt
hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have
also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent
disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the
other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in
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nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus
production.
No significant acute toxicological data identified in literature search. Substance has been investigated as a mutagen in rodents.
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
12.1. Toxicity
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
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P B T
PBT
vPvB
vPvB No
Labels Required
Marine Pollutant NO
14.5. Environmental
Not Applicable
hazard
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Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.5. Environmental
Not Applicable
hazard
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14.7. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable
14.8. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture
This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.
ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
ethylene glycol 107-21-1* 603-027-00-1 Not Available
Acute Tox. 4; STOT RE 1; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; H302; H372; H336; H319; H335;
2 STOT SE 1; STOT RE 1; STOT SE 1; STOT RE 1; Aquatic Chronic GHS08; Dgr H370; H332; H340; H360; H412;
3; STOT SE 1; STOT RE 1; STOT RE 1 H315
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
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Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 10 4877775
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.
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The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.
For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices
end of SDS