Cooltreat ELC

Wilhelmsen Ships Service AS

Part Number: 779030 Issue Date: 06/07/2017
Version No: 2.11 Print Date: 02/02/2022
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) L.REACH.NOR.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name Cooltreat ELC

Chemical Name Not Applicable

Synonyms Not Available
Chemical formula Not Applicable
Other means of
779030
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Chemical Product
PC37 Water treatment chemicals
Category

Sectors of Use SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen)

Relevant identified uses Use according to manufacturer's directions.

Uses advised against Not Applicable

1.3. Details of the supplier of the safety data sheet

Outback (M)SDS portal:
Wilhelmsen Ships Service AS*
Registered company name Wilhelmsen Ships Service AS http://jr.chemwatch.net/outb/account
Central Warehouse
/autologin?login=wilhelmsen
--------Use our Outback portal to obtain our
(M)SDSs in other languages and/or
Strandveien 20 Lysaker 1366 format.--------- For questions relating to our Willem Barentszstraat 50 Rotterdam
Address
Norway SDSs please use Email: Netherlands
[email protected]
--------- Norway
Telephone +47 67 58 40 00 Not Available +31 10 4877 777

Fax Not Available Not Available Not Available

Website http://www.wilhelmsen.com/ http://www.wilhelmsen.com http://www.wilhelmsen.com
Email [email protected] [email protected] [email protected]

Registered company name Wilhelmsen Ships Service AS* Central Warehouse

Address Willem Barentszstraat 50 Rotterdam Netherlands
Telephone +31 10 4877 777
Fax Not Available
Website http://www.wilhelmsen.com
Email [email protected]

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1.4. Emergency telephone number

Association / Organisation Giftinformasjonssentralen - 24 timer 24hrs - Chemtrec Dutch nat. poison centre
Emergency telephone
+47 22591300 +31-10-4877700 + 31 88 7558561
numbers

Other emergency
+31-10-4877700 +1 800 424 9300 + 31 10 4877700
telephone numbers

Association / Organisation Dutch nat. poison centre

Emergency telephone
+ 31 30 274 88 88
numbers

Other emergency
+ 31-10-4877700
telephone numbers

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Classification according to
regulation (EC) No H302 - Acute Toxicity (Oral) Category 4, H361d - Reproductive Toxicity Category 2, H373 - Specific Target Organ Toxicity -
1272/2008 [CLP] and Repeated Exposure Category 2
amendments [1]
Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI

2.2. Label elements

Hazard pictogram(s)

Signal word Warning

Hazard statement(s)
H302 Harmful if swallowed.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.

Supplementary statement(s)
Not Applicable

Precautionary statement(s) General

P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read carefully and follow all instructions.

Precautionary statement(s) Prevention

P201 Obtain special instructions before use.
P260 Do not breathe mist/vapours/spray.
P280 Wear protective gloves and protective clothing.
P264 Wash all exposed external body areas thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.

Precautionary statement(s) Response

P308+P313 IF exposed or concerned: Get medical advice/ attention.
P314 Get medical advice/attention if you feel unwell.

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P301+P312 IF SWALLOWED: Call a POISON CENTER/doctor/physician/first aider if you feel unwell.

P330 Rinse mouth.

Precautionary statement(s) Storage

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container to authorised hazardous or special waste collection point in accordance with any local regulation.

2.3. Other hazards

REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 Composition / information on ingredients

3.1.Substances
See 'Composition on ingredients' in Section 3.2

3.2.Mixtures
1.CAS No
2.EC No Classification according to regulation (EC) SCL / Nanoform Particle
%[weight] Name
3.Index No No 1272/2008 [CLP] and amendments M-Factor Characteristics
4.REACH No

1.107-21-1*
Specific Target Organ Toxicity - Repeated
2.203-473-3 Not
80-98% ethylene glycol * Exposure Category 2, Acute Toxicity (Oral) Not Available
3.603-027-00-1 Available
Category 4; H373, H302 [1]
4.Not Available

1.19766-89-3*
2.243-283-8|406-150-7 2-ethylhexanoic acid, Not
3-5% Reproductive Toxicity Category 2; H361d [1] Not Available
3.Not Available sodium salt Available
4.Not Available

Legend: 1. Classified by Chemwatch; 2. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 3. Classification drawn from
C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with the eyes:
Wash out immediately with fresh running water.
Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally
Eye Contact
lifting the upper and lower lids.
Seek medical attention without delay; if pain persists or recurs seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

If skin or hair contact occurs:

Skin Contact Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
For advice, contact a Poisons Information Centre or a doctor.
Urgent hospital treatment is likely to be needed.
In the mean time, qualified first-aid personnel should treat the patient following observation and employing supportive
measures as indicated by the patient's condition.
If the services of a medical officer or medical doctor are readily available, the patient should be placed in his/her care and a
copy of the SDS should be provided. Further action will be the responsibility of the medical specialist.
Ingestion If medical attention is not available on the worksite or surroundings send the patient to a hospital together with a copy of the
SDS.

Where medical attention is not immediately available or where the patient is more than 15 minutes from a hospital or
unless instructed otherwise:
INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS. Lean patient forward or place on left side
(head-down position, if possible) to maintain open airway and prevent aspiration.

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NOTE: Wear a protective glove when inducing vomiting by mechanical means.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
As in all cases of suspected poisoning, follow the ABCDEs of emergency medicine (airway, breathing, circulation, disability, exposure), then the ABCDEs of
toxicology (antidotes, basics, change absorption, change distribution, change elimination).
For poisons (where specific treatment regime is absent):
--------------------------------------------------------------
BASIC TREATMENT
--------------------------------------------------------------
Establish a patent airway with suction where necessary.
Watch for signs of respiratory insufficiency and assist ventilation as necessary.
Administer oxygen by non-rebreather mask at 10 to 15 L/min.
Monitor and treat, where necessary, for pulmonary oedema.
Monitor and treat, where necessary, for shock.
Anticipate seizures.
DO NOT use emetics. Where ingestion is suspected rinse mouth and give up to 200 ml water (5 ml/kg recommended) for dilution where patient is able to
swallow, has a strong gag reflex and does not drool.
--------------------------------------------------------------
ADVANCED TREATMENT
--------------------------------------------------------------
Consider orotracheal or nasotracheal intubation for airway control in unconscious patient or where respiratory arrest has occurred.
Positive-pressure ventilation using a bag-valve mask might be of use.
Monitor and treat, where necessary, for arrhythmias.
Start an IV D5W TKO. If signs of hypovolaemia are present use lactated Ringers solution. Fluid overload might create complications.
Drug therapy should be considered for pulmonary oedema.
Hypotension with signs of hypovolaemia requires the cautious administration of fluids. Fluid overload might create complications.
Treat seizures with diazepam.
Proparacaine hydrochloride should be used to assist eye irrigation.
BRONSTEIN, A.C. and CURRANCE, P.L.
EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed. 1994

SECTION 5 Firefighting measures

5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

5.2. Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear full body protective clothing with breathing apparatus.
Prevent, by any means available, spillage from entering drains or water course.
Fire Fighting Use water delivered as a fine spray to control fire and cool adjacent area.
Avoid spraying water onto liquid pools.
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
Combustible.
Slight fire hazard when exposed to heat or flame.
Heating may cause expansion or decomposition leading to violent rupture of containers.
Fire/Explosion Hazard On combustion, may emit irritating/ toxic fumes.
May emit acrid smoke.
Mists containing combustible materials may be explosive.
May emit poisonous fumes.

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SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Remove all ignition sources.
Clean up all spills immediately.
Avoid breathing vapours and contact with skin and eyes.
Minor Spills Control personal contact with the substance, by using protective equipment.
Contain and absorb spill with sand, earth, inert material or vermiculite.
Wipe up.
Place in a suitable, labelled container for waste disposal.

Moderate hazard.
Clear area of personnel and move upwind.
Alert Fire Brigade and tell them location and nature of hazard.
Major Spills Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water course.
No smoking, naked lights or ignition sources.
Increase ventilation.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Safe handling Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or food utensils.
Avoid contact with incompatible materials.
Fire and explosion
See section 5
protection

Consider storage under inert gas.

Material is hygroscopic, i.e. absorbs moisture from the air. Keep containers well sealed in storage.
Store in original containers.
Keep containers securely sealed.
Other information No smoking, naked lights or ignition sources.
Store in a cool, dry, well-ventilated area.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Observe manufacturer's storage and handling recommendations contained within this SDS.

7.2. Conditions for safe storage, including any incompatibilities

Metal can or drum
Suitable container Packaging as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Storage incompatibility None known

+ x + o + + +

X — Must not be stored together

0 — May be stored together with specific preventions
+ — May be stored together

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Note: Depending on other risk factors, compatibility assessment based on the table above may not be relevant to storage situations, particularly where large volumes
of dangerous goods are stored and handled. Reference should be made to the Safety Data Sheets for each substance or article and risks assessed accordingly.

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment
10 mg/L (Water (Fresh))
1 mg/L (Water - Intermittent release)
Dermal 106 mg/kg bw/day (Systemic, Chronic)
10 mg/L (Water (Marine))
Inhalation 35 mg/m³ (Local, Chronic)
ethylene glycol 37 mg/kg sediment dw (Sediment (Fresh Water))
Dermal 53 mg/kg bw/day (Systemic, Chronic) *
3.7 mg/kg sediment dw (Sediment (Marine))
Inhalation 7 mg/m³ (Local, Chronic) *
1.53 mg/kg soil dw (Soil)
199.5 mg/L (STP)
0.36 mg/L (Water (Fresh))
Dermal 2 mg/kg bw/day (Systemic, Chronic) 0.036 mg/L (Water - Intermittent release)
Inhalation 14 mg/m³ (Systemic, Chronic) 0.493 mg/L (Water (Marine))
2-ethylhexanoic acid, sodium
Dermal 1 mg/kg bw/day (Systemic, Chronic) * 0.301 mg/kg sediment dw (Sediment (Fresh Water))
salt
Inhalation 3.5 mg/m³ (Systemic, Chronic) * 0.03 mg/kg sediment dw (Sediment (Marine))
Oral 1 mg/kg bw/day (Systemic, Chronic) * 0.058 mg/kg soil dw (Soil)
71.7 mg/L (STP)

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

EU Consolidated List of
Indicative Occupational
ethylene glycol Ethylene glycol 20 ppm / 52 mg/m3 104 mg/m3 / 40 ppm Not Available Skin
Exposure Limit Values
(IOELVs)
Norway regulations on action
rvalues o​ a nd limitf values ​
physical and chemical
factors in the work ethylene glycol 1,2-etandiol 20 ppm / 52 mg/m3 104 mg/m3 / 40 ppm Not Available HE​5
environment and infection
risk groups for biological
factors

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

ethylene glycol 30 ppm 150 ppm 900 ppm

Ingredient Original IDLH Revised IDLH

ethylene glycol Not Available Not Available

2-ethylhexanoic acid, sodium
Not Available Not Available
salt

Occupational Exposure Banding

Ingredient Occupational Exposure Band Rating Occupational Exposure Band Limit

2-ethylhexanoic acid, sodium
E ≤ 0.01 mg/m³
salt
Notes: Occupational exposure banding is a process of assigning chemicals into specific categories or bands based on a chemical's
potency and the adverse health outcomes associated with exposure. The output of this process is an occupational exposure
band (OEB), which corresponds to a range of exposure concentrations that are expected to protect worker health.

MATERIAL DATA

8.2. Exposure controls

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Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
8.2.1. Appropriate
Process controls which involve changing the way a job activity or process is done to reduce the risk.
engineering controls
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.

8.2.2. Personal protection

Safety glasses with side shields

Chemical goggles.
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should
be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly.

Skin protection See Hand protection below

Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
Hands/feet protection can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.

Body protection See Other protection below

Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

Recommended material(s)
GLOVE SELECTION INDEX
Glove selection is based on a modified presentation of the:
"Forsberg Clothing Performance Index".
The effect(s) of the following substance(s) are taken into account in the computer-generated selection:
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Material CPI

NATURAL RUBBER A

NATURAL+NEOPRENE A

NEOPRENE A

NEOPRENE/NATURAL A
NITRILE A

NITRILE+PVC A

PE/EVAL/PE A

PVC A

TEFLON A

PVA B

* CPI - Chemwatch Performance Index

A: Best Selection
B: Satisfactory; may degrade after 4 hours continuous immersion
C: Poor to Dangerous Choice for other than short term immersion
NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. -
* Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of

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gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Red

Relative density (Water =

Physical state Liquid 1.113
1)

Partition coefficient
Odour Not Available Not Available
n-octanol / water

Auto-ignition temperature
Odour threshold Not Available Not Applicable
(°C)
Decomposition
pH (as supplied) 8.7 Not Applicable
temperature
Melting point / freezing
Not Applicable Viscosity (cSt) Not Available
point (°C)

Initial boiling point and

175 Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) 122 Taste Not Available

Evaporation rate Not Available BuAC = 1 Explosive properties Not Available

Flammability Not Applicable Oxidising properties Not Available
Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Applicable Not Available
or mN/m)
Lower Explosive Limit (%) Not Applicable Volatile Component (%vol) Not Applicable

Vapour pressure (kPa) Not Applicable Gas group Not Available

pH as a solution (Not
Solubility in water Miscible Not Available
Available%)
Vapour density (Air = 1) Not Applicable VOC g/L Not Available
Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

10.1.Reactivity See section 7.2

Unstable in the presence of incompatible materials.
10.2. Chemical stability Product is considered stable.
Hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2

10.5. Incompatible
See section 7.2
materials

10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on toxicological effects

The material is not thought to produce either adverse health effects or irritation of the respiratory tract following inhalation (as
Inhaled
classified by EC Directives using animal models). Nevertheless, adverse systemic effects have been produced following

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exposure of animals by at least one other route and good hygiene practice requires that exposure be kept to a minimum and that
suitable control measures be used in an occupational setting.
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be
Ingestion
fatal or may produce serious damage to the health of the individual.

Skin contact is not thought to produce harmful health effects (as classified under EC Directives using animal models). Systemic
harm, however, has been identified following exposure of animals by at least one other route and the material may still produce
health damage following entry through wounds, lesions or abrasions. Good hygiene practice requires that exposure be kept to a
Skin Contact
minimum and that suitable gloves be used in an occupational setting.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with
harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.

Eye Although the liquid is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may produce
transient discomfort characterised by tearing or conjunctival redness (as with windburn).

Repeated or long-term occupational exposure is likely to produce cumulative health effects involving organs or biochemical
systems.

Chronic Exposure to the material may cause concerns for humans owing to possible developmental toxic effects, generally on the basis
that results in appropriate animal studies provide strong suspicion of developmental toxicity in the absence of signs of marked
maternal toxicity, or at around the same dose levels as other toxic effects but which are not a secondary non-specific
consequence of other toxic effects.

TOXICITY IRRITATION
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Oral (Rat) LD50; 1720 mg/kg[2] Not Available

TOXICITY IRRITATION
Dermal (rabbit) LD50: 9530 mg/kg[2] Eye (rabbit): 100 mg/1h - mild

Inhalation (Human) TCLo: 10000 mg/m3[2] Eye (rabbit): 12 mg/m3/3D

Inhalation(Rat) LC50; 50100 mg/m3/8 hr[2] Eye (rabbit): 1440mg/6h-moderate

ethylene glycol
Oral (child) TDLo: 5500 mg/kg[2] Eye (rabbit): 500 mg/24h - mild

Oral (Human)LDLo: 398 mg/kg[2] Eye: no adverse effect observed (not irritating)[1]

Oral (Rat) LD50; 4700 mg/kg[2] Skin (rabbit): 555 mg(open)-mild

Skin: no adverse effect observed (not irritating)[1]

TOXICITY IRRITATION
2-ethylhexanoic acid,
dermal (rat) LD50: >2000 mg/kg[1] Not Available
sodium salt
Oral (Rat) LD50; 2043 mg/kg[1]

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

For ethylene glycol:

Ethylene glycol is quickly and extensively absorbed through the gastrointestinal tract. Limited information suggests that it is also
absorbed through the respiratory tract; dermal absorption is apparently slow. Following absorption, ethylene glycol is distributed
throughout the body according to total body water. In most mammalian species, including humans, ethylene glycol is initially
metabolised by alcohol.
ethylene glycol dehydrogenase to form glycolaldehyde, which is rapidly converted to glycolic acid and glyoxal by aldehyde oxidase and aldehyde
dehydrogenase. These metabolites are oxidised to glyoxylate; glyoxylate may be further metabolised to formic acid, oxalic acid,
and glycine. Breakdown of both glycine and formic acid can generate CO2, which is one of the major elimination products of
ethylene glycol. In addition to exhaled CO2, ethylene glycol is eliminated in the urine as both the parent compound and glycolic
acid. [Estimated Lethal Dose (human) 100 ml; RTECS quoted by Orica] Substance is reproductive effector in rats (birth defects).
Mutagenic to rat cells.

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a
non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high
levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease,
in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented
2-ethylhexanoic acid,
exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial
sodium salt
hyperreactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have
also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent
disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the
other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in

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nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus
production.
No significant acute toxicological data identified in literature search. Substance has been investigated as a mutagen in rodents.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2.1. Endocrine Disruption Properties

Not Available

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value Source

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EC50 48 Crustacea Daphnia magna >100mg/L 8

Endpoint Test Duration (hr) Species Value Source

EC50(ECx) Not Available Algae or other aquatic plants 6500-7500mg/l 1

ethylene glycol LC50 96h Fish >10000mg/l 1

EC50 48h Crustacea >100mg/l 2

EC50 96h Algae or other aquatic plants 6500-13000mg/l 1

Endpoint Test Duration (hr) Species Value Source

NOEC(ECx) 504h Crustacea 18mg/l 2
2-ethylhexanoic acid,
LC50 96h Fish >100mg/l 2
sodium salt
EC50 72h Algae or other aquatic plants 49.3mg/l 2
EC50 48h Crustacea 85.4mg/l 2

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Harmful to aquatic organisms.

DO NOT discharge into sewer or waterways.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
ethylene glycol LOW (Half-life = 24 days) LOW (Half-life = 3.46 days)

12.3. Bioaccumulative potential

Ingredient Bioaccumulation

ethylene glycol LOW (BCF = 200)

12.4. Mobility in soil

Ingredient Mobility

ethylene glycol HIGH (KOC = 1)

12.5. Results of PBT and vPvB assessment

P B T
Relevant available data Not Available Not Available Not Available

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P B T
PBT
vPvB

PBT Criteria fulfilled? No

vPvB No

12.6. Endocrine Disruption Properties

Not Available

12.7. Other adverse effects

Not Available

SECTION 13 Disposal considerations

13.1. Waste treatment methods

Containers may still present a chemical hazard/ danger when empty.
Return to supplier for reuse/ recycling if possible.
Otherwise:
If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
Where possible retain label warnings and SDS and observe all notices pertaining to the product.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Product / Packaging
Disposal (if all else fails)
disposal
This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it
has been contaminated, it may be possible to reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that properties of a material may change in use, and
recycling or reuse may not always be appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Recycle wherever possible or consult manufacturer for recycling options.
Consult State Land Waste Management Authority for disposal.
Bury residue in an authorised landfill.
Recycle containers if possible, or dispose of in an authorised landfill.

Waste treatment options Not Available

Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required
Marine Pollutant NO

Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard Class Not Applicable

class(es) Subrisk Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

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Hazard identification (Kemler) Not Applicable

Classification code Not Applicable

14.6. Special precautions Hazard Label Not Applicable

for user Special provisions Not Applicable

Limited quantity Not Applicable

Tunnel Restriction Code Not Applicable

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

ICAO/IATA Class Not Applicable

14.3. Transport hazard
ICAO / IATA Subrisk Not Applicable
class(es)
ERG Code Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Special provisions Not Applicable

Cargo Only Packing Instructions Not Applicable

Cargo Only Maximum Qty / Pack Not Applicable

14.6. Special precautions
Passenger and Cargo Packing Instructions Not Applicable
for user
Passenger and Cargo Maximum Qty / Pack Not Applicable

Passenger and Cargo Limited Quantity Packing Instructions Not Applicable

Passenger and Cargo Limited Maximum Qty / Pack Not Applicable

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name

14.3. Transport hazard IMDG Class Not Applicable

class(es) IMDG Subrisk Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

EMS Number Not Applicable

14.6. Special precautions
Special provisions Not Applicable
for user
Limited Quantities Not Applicable

Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable

14.2. UN proper shipping

Not Applicable
name

14.3. Transport hazard

Not Applicable Not Applicable
class(es)

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Classification code Not Applicable

14.6. Special precautions
Special provisions Not Applicable
for user
Limited quantity Not Applicable

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Equipment required Not Applicable

Fire cones number Not Applicable

14.7. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.8. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group

ethylene glycol Not Available

2-ethylhexanoic acid, sodium
Not Available
salt

14.9. Transport in bulk in accordance with the ICG Code

Product name Ship Type

ethylene glycol Not Available

2-ethylhexanoic acid, sodium

Not Available
salt

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

ethylene glycol is found on the following regulatory lists

Chemical Footprint Project - Chemicals of High Concern List European Union - European Inventory of Existing Commercial Chemical
EU Consolidated List of Indicative Occupational Exposure Limit Values Substances (EINECS)
(IOELVs) European Union (EU) Regulation (EC) No 1272/2008 on Classification,
Europe EC Inventory Labelling and Packaging of Substances and Mixtures - Annex VI
dNorway regulations on n action values ​ and limit
a values ​ for physical
chemical factors in the work environment and infection risk groups for
biological factors

2-ethylhexanoic acid, sodium salt is found on the following regulatory lists

Europe EC Inventory European Union - European Inventory of Existing Commercial Chemical
Substances (EINECS)

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

15.2. Chemical safety assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
ethylene glycol 107-21-1* 603-027-00-1 Not Available

Harmonisation (C&L Pictograms Signal

Hazard Class and Category Code(s) Hazard Statement Code(s)
Inventory) Word Code(s)
1 Acute Tox. 4 GHS07; Wng H302

Acute Tox. 4; STOT RE 1; STOT SE 3; Skin Irrit. 2; Eye Irrit. 2; H302; H372; H336; H319; H335;
2 STOT SE 1; STOT RE 1; STOT SE 1; STOT RE 1; Aquatic Chronic GHS08; Dgr H370; H332; H340; H360; H412;
3; STOT SE 1; STOT RE 1; STOT RE 1 H315
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.

Ingredient CAS number Index No ECHA Dossier

2-ethylhexanoic acid, sodium

19766-89-3* Not Available Not Available
salt

Harmonisation (C&L Pictograms Signal Word

Hazard Class and Category Code(s) Hazard Statement Code(s)
Inventory) Code(s)

Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.

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Harmonisation (C&L Pictograms Signal Word

Hazard Class and Category Code(s) Hazard Statement Code(s)
Inventory) Code(s)
1 Skin Irrit. 2; Eye Irrit. 2 GHS07; Wng H315; H318
Repr. 2; Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; STOT SE 3; H361; H361d; H315; H318;
2 GHS08; Wng; GHS05
STOT SE 3 H335

Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.

National Inventory Status

National Inventory Status

Australia - AIIC / Australia

No (2-ethylhexanoic acid, sodium salt)
Non-Industrial Use
Canada - DSL Yes

Canada - NDSL No (ethylene glycol; 2-ethylhexanoic acid, sodium salt)

China - IECSC Yes

Europe - EINEC / ELINCS /
Yes
NLP

Japan - ENCS Yes

Korea - KECI Yes

New Zealand - NZIoC Yes

Philippines - PICCS Yes

USA - TSCA Yes

Taiwan - TCSI Yes

Mexico - INSQ Yes
Vietnam - NCI Yes

Russia - FBEPH Yes

Yes = All CAS declared ingredients are on the inventory
Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 06/07/2017

Initial Date 06/07/2017

CONTACT POINT
- For quotations contact your local Customer Services - http://wssdirectory.wilhelmsen.com/#/customerservices - - Responsible for safety data sheet Wilhelmsen
Ships Service AS - Prepared by: Product HSE Manager, - Email: Email: [email protected] - Telephone: Tel.: +31 10 4877775

Full text Risk and Hazard codes

H315 Causes skin irritation.

H318 Causes serious eye damage.

H319 Causes serious eye irritation.

H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H336 May cause drowsiness or dizziness.

H340 May cause genetic defects.

H360 May damage fertility or the unborn child.

H361 Suspected of damaging fertility or the unborn child.

H370 Causes damage to organs.

H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

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The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
AIIC: Australian Inventory of Industrial Chemicals
DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory
NZIoC: New Zealand Inventory of Chemicals
PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

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end of SDS