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    Haloalkane & Haloarene - DPP 05

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    shaanmukherjee2020

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    Haloalkane & Haloarene - DPP 05

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    shaanmukherjee2020
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    Haloalkane & Haloarene _ DPP 05

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    3 views3 pages

    Haloalkane & Haloarene - DPP 05

    Uploaded by

    shaanmukherjee2020

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    1

    LAKSHYA JEE 2023


    Haloalkane & Haloarene DPP-05

    5. Aryl halides can be prepared by


    Fe/Br
    1.  2
    → (1) Sand mayer’s method
    Dark
    (2) Friedel-craft reaction
    (3) Gattermann’s reaction
    (1) (2) (4) 1 and 3

    6. The conditions that is necessary in the preparation


    of Aryl halides from benzene
    (1) Low temperature
    (3) (4) Both (2) & (3) (2) Absence of sunlight
    (3) Presence of halogen carrier
    (4) All of the above

    2. 7. In Gattermann reaction, a diazonium group is


    replaced by X using Y, X, Y are:
    X Y
    −

    Set of reagents for above conversion is/are (1) Cl Cu/HCl
    (1) (i) Conc ⋅ HNO3 + conc ⋅ H 2SO 4 ⊕
    (2) Cl CuCl2/HCl
    (ii) Cl2, sunlight −

    (2) (i) Cl2, fe, dark (3) Cl CuCl2/HCl
    (ii) Conc ⋅ HNO3 + conc ⋅ H 2SO 4 (4) Cl2 Cu2O/HCl
    (3) (i) Conc ⋅ HNO3 + conc ⋅ H 2SO 4
    8. Chlorobenzene can be prepared by reacting aniline
    (ii) Cl2/fe/dark with
    (4) (i) HNO2 (ii) Cu/HCl (1) Hydrochloric acid
    (2) Cuprous chloride
    NaNO + HCl Kl
    3. C6 H5 − NH 2 →
    2
    o A → B + C ↑ (3) Chlorine in presence of anhydrous aluminium
    0 −5 C
    chloride
    Here B and C are (4) Nitrous acid followed by heating with
    (1) C6 H5 I, N 2 (2) C6 H5 l,O 2 cuprous chloride
    (3) C6 H 6 ,l2 (4) C6 H5 CH 2 l, N 2

    4. Aryl fluoride may be prepared from arene 9.


    diazonium chloride using:
    (1) HBF4 / ∆ Set of reagents for above conversion is
    (1) NaBF4/∆
    (2) HBF4 / NaNO 2 ,Cu, ∆
    (2) NaNO 2 (298K) followed by NaBF4//∆
    (3) CuF/HF
    (3) NaNO2 (273K) followed by NaBF4//∆
    (4) Cu/HF
    (4) NaNO2 + HBF4 (273K)
    2

    10. 11.

    X is-
    Above reaction is known as-
    (1) Swarts Reaction
    (2) Sandmeyer’s Reaction
    (1) (2)
    (3) Hunsdiecker Reaction
    (4) Kolbe’s Reaction
    (3) (4) None of these
    3

    Answer Key
    1. (4)
    2. (3)
    3. (1)
    4. (1)
    5. (4)
    6. (4)
    7. (1)
    8. (4)
    9. (3)
    10. (2)
    11. (2)

    For more questions, kindly visit the library section: Link for app: https://links.physicswallah.live/vyJw

    For more questions, kindly visit the library section: Link for web: https://physicswallah.live/tabs/tabs/library-tab

    PW Mobile APP: https://physicswala.page.link/?type=contact-us&data=open


    For PW Website: https://www.physicswallah.live/contact-us

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