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Chemistry: A Molecular Approach, 3e (Tro)
Chapter 10 Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and Molecular
Orbital Theory
1) Give the approximate bond angle for a molecule with an octahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
Diff: 2 Page Ref: 10.2
3) Determine the electron geometry (eg) and molecular geometry (mg) of CO32⁻.
A) eg=tetrahedral, mg=tetrahedral
B) eg=tetrahedral, mg=trigonal pyramidal
C) eg=trigonal planar, mg=bent
D) eg=trigonal planar, mg=trigonal planar
E) eg=tetrahedral, mg=trigonal planar
Answer: D
Diff: 2 Page Ref: 10.2
4) Determine the electron geometry (eg) and molecular geometry (mg) of CH3+1.
A) eg=tetrahedral, mg=tetrahedral
B) eg=tetrahedral, mg=trigonal pyramidal
C) eg=trigonal planar, mg=bent
D) eg=trigonal planar, mg=trigonal planar
E) eg=tetrahedral, mg=trigonal planar
Answer: D
Diff: 2 Page Ref: 10.2
1
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5) Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.
A) eg=tetrahedral, mg=trigonal pyramidal
B) eg=octahedral, mg=square planar
C) eg=trigonal bipyramidal, mg=trigonal pyramidal
D) eg=tetrahedral, mg=bent
E) eg=tetrahedral, mg=tetrahedral
Answer: E
Diff: 2 Page Ref: 10.2
6) Determine the electron geometry (eg) and molecular geometry (mg) of PF5.
A) eg=trigonal bipyramidal, mg=trigonal bipyramidal
B) eg=octahedral, mg=octahedral
C) eg=trigonal bipyramidal, mg=tetrahedral
D) eg=tetrahedral, mg=trigonal pyramidal
E) eg=trigonal planar, mg=octahedral
Answer: A
Diff: 2 Page Ref: 10.2
7) Determine the electron geometry (eg) and molecular geometry (mg) of CO2.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, mg=trigonal planar
C) eg=trigonal planar, mg=bent
D) eg=linear, mg=linear
E) eg=trigonal planar, mg=trigonal planar
Answer: D
Diff: 2 Page Ref: 10.2
2
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10) Determine the electron geometry (eg) and molecular geometry (mg) of NCl3.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, mg=trigonal planar
C) eg=trigonal planar, mg=bent
D) eg=linear, mg=linear
E) eg=tetrahedral, mg=trigonal pyramidal
Answer: E
Diff: 2 Page Ref: 10.4
11) Determine the electron geometry (eg) and molecular geometry (mg) of ICl3.
A) eg=trigonal planar, mg=trigonal planar
B) eg=trigonal bipyramidal, mg= T-shape
C) eg=trigonal planar, mg=bent
D) eg=trigonal bipyramidal, mg=see-saw
E) eg=tetrahedral, mg=trigonal pyramidal
Answer: B
Diff: 3 Page Ref: 10.4
12) Determine the electron geometry (eg) and molecular geometry (mg) of ICl2⁻.
A) eg=tetrahedral, mg=bent
B) eg=tetrahedral, mg=trigonal pyramidal
C) eg=trigonal bipyramidal, mg=linear
D) eg=trigonal bipyramidal, mg=trigonal planar
E) eg=octahedral, mg=linear
Answer: C
Diff: 3 Page Ref: 10.4
13) Determine the electron geometry (eg) and molecular geometry (mg) of XeF2.
A) eg=trigonal bipyramidal, mg=bent
B) eg=linear, mg=linear
C) eg=tetrahedral, mg=linear
D) eg=trigonal bipyramidal, mg=linear
E) eg=tetrahedral, mg=bent
Answer: D
Diff: 3 Page Ref: 10.4
14) Determine the electron geometry (eg) and molecular geometry (mg) of XeF4.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, eg=linear
C) eg=tetrahedral, mg=bent
D) eg=trigonal bipyramidal, mg=tetrahedral
E) eg=octahedral, mg=square planar
Answer: E
Diff: 3 Page Ref: 10.4
3
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15) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, eg=linear
C) eg=tetrahedral, mg=bent
D) eg=trigonal bipyramidal, mg=tetrahedral
E) eg=octahedral, mg=square planar
Answer: A
Diff: 3 Page Ref: 10.4
16) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, eg=linear
C) eg=tetrahedral, mg=bent
D) eg=trigonal bipyramidal, mg=tetrahedral
E) eg=octahedral, mg=square planar
Answer: C
Diff: 3 Page Ref: 10.4
17) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom H2CO.
A) eg=tetrahedral, mg=tetrahedral
B) eg=trigonal planar, eg=trigonal planar
C) eg=tetrahedral, mg=bent
D) eg=trigonal bipyramidal, mg=tetrahedral
E) eg=octahedral, mg=square planar
Answer: B
Diff: 3 Page Ref: 10.4
18) Consider the molecule below. Determine the molecular geometry at each of the 2 labeled carbons.
A) C1 = tetrahedral, C2 = linear
B) C1 = trigonal planar, C2= bent
C) C1 = bent, C2 = trigonal planar
D) C1 = trigonal planar, C2 = tetrahedral
E) C1 = trigonal pyramidal, C2 = see-saw
Answer: D
Diff: 3 Page Ref: 10.4
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19) Consider the molecule below. Determine the molecular geometry at each of the 3 labeled atoms.
20) Place the following in order of increasing X-Se-X bond angle, where X represents the outer atoms
in each molecule.
21) Place the following in order of increasing F-A-F bond angle, where A represents the central atom in
each molecule.
5
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22) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom
and X represents the outer atoms in each molecule.
23) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom
and X represents the outer atoms in each molecule.
24) Place the following in order of increasing X-A-X bond angle, where A represents the central atom
and X represents the outer atoms in each molecule.
6
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25) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO3.
A) eg=tetrahedral, mg=trigonal pyramidal, polar
B) eg=tetrahedral, mg=tetrahedral, nonpolar
C) eg=trigonal planar, mg=trigonal planar, nonpolar
D) eg= trigonal bipyramidal, mg=trigonal planar, polar
E) eg=trigonal pyramidal, mg=bent, nonpolar
Answer: C
Diff: 2 Page Ref: 10.5
A) 1
B) 2
C) 3
D) 4
E) 0
Answer: A
Diff: 3 Page Ref: 10.5
A) 2
B) 0
C) 1
D) 3
E) 4
Answer: D
Diff: 3 Page Ref: 10.5
28) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2.
A) eg=tetrahedral, mg=bent, polar
B) eg=trigonal planar, mg=bent, polar
C) eg=linear, mg=linear, nonpolar
D) eg=tetrahedral, mg=tetrahedral, nonpolar
E) eg=trigonal pyramidal, mg=trigonal pyramidal, polar
Answer: B
Diff: 3 Page Ref: 10.5
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29) Determine the electron geometry (eg), molecular geometry (mg), and polarity of PCl3.
A) eg=tetrahedral, mg=bent, polar
B) eg=trigonal planar, mg=trigonal planar, nonpolar
C) eg=linear, mg=linear, nonpolar
D) eg=tetrahedral, mg=trigonal pyramidal, polar
E) eg=trigonal pyramidal, mg=trigonal pyramidal, polar
Answer: D
Diff: 3 Page Ref: 10.5
30) Determine the electron geometry, molecular geometry and polarity of SF6.
A) eg=trigonal bipyramidal, mg=trigonal bipyramidal, nonpolar
B) eg=tetrahedral, mg=tetrahedral, polar
C) eg=trigonal bipyramidal, mg=see-saw, polar
D) eg=octahedral, mg=trigonal bipyramidal, nonpolar
E) eg=octahedral, mg=octahedral, nonpolar
Answer: E
Diff: 3 Page Ref: 10.5
31) Determine the electron geometry (eg), molecular geometry(mg) and polarity of XeO3.
A) eg=trigonal planar, mg=trigonal planar, nonpolar
B) eg=tetrahedral, mg=trigonal pyramidal, polar
C) eg=trigonal planar, mg=trigonal pyramidal, polar
D) eg=trigonal bipyramidal, mg=trigonal planar, nonpolar
E) eg=octahedral, mg=tetrahedral, nonpolar
Answer: B
Diff: 3 Page Ref: 10.5
32) Determine the electron geometry, molecular geometry and polarity of HBrO2.
A) eg=trigonal bipyramidal, mg=trigonal planar, nonpolar
B) eg=octahedral, mg=square planar, nonpolar
C) eg=tetrahedral, mg=trigonal pyramidal, polar
D) eg=tetrahedral, mg=linear, nonpolar
E) eg=linear, mg=linear, polar
Answer: C
Diff: 3 Page Ref: 10.5
A) I < II = III
B) II < III < I
C) I < II < III
D) II < I < III
E) I < III < II
Answer: E
Diff: 3 Page Ref: 10.5
8
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34) Place the following in order of decreasing dipole moment.
35) Identify the number of electron groups around a molecule with sp hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: B
Diff: 1 Page Ref: 10.7
36) Identify the number of electron groups around a molecule with sp2 hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: C
Diff: 1 Page Ref: 10.7
37) Identify the number of electron groups around a molecule with a tetrahedral shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: D
Diff: 1 Page Ref: 10.7
38) Identify the number of electron groups around a molecule with a trigonal bipyramidal shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: E
Diff: 1 Page Ref: 10.7
9
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39) Identify the number of electron groups around a molecule with an octahedral shape.
A) 6
B) 2
C) 3
D) 4
E) 5
Answer: A
Diff: 1 Page Ref: 10.7
40) Give the electron geometry (eg), molecular geometry (mg), and hybridization for NH3.
A) eg=tetrahedral, mg=trigonal planar, sp2
B) eg=trigonal pyramidal, mg=trigonal pyramidal, sp3
C) eg=tetrahedral, mg=trigonal pyramidal, sp3
D) eg=trigonal pyramidal, mg=tetrahedral, sp3
E) eg=trigonal planar, mg=trigonal planar, sp2
Answer: C
Diff: 1 Page Ref: 10.7
41) Give the electron geometry (eg), molecular geometry (mg), and hybridization for H2O.
A) eg=tetrahedral, mg=bent, sp3
B) eg=trigonal pyramidal, mg=trigonal pyramidal, sp3
C) eg=tetrahedral, mg=trigonal pyramidal, sp3
D) eg=bent, mg=bent, sp2
E) eg=trigonal planar, mg=trigonal planar, sp2
Answer: A
Diff: 1 Page Ref: 10.7
42) Give the electron geometry (eg), molecular geometry (mg), and hybridization for XeF4.
A) eg=tetrahedral, mg=tetrahedral, sp3
B) eg=trigonal pyramidal, mg=trigonal pyramidal, sp3
C) eg=octahedral, mg=square planar, sp3d2
D) eg=octahedral, mg=octahedral, sp3d2
E) eg=trigonal bipyramidal, mg=seesaw, sp3d
Answer: C
Diff: 1 Page Ref: 10.7
10
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44) Give the hybridization for the O in H3O+.
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
Diff: 3 Page Ref: 10.7
11
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49) Give the hybridization for the Br in BrCl3.
A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: B
Diff: 3 Page Ref: 10.7
52) How many of the following molecules have sp2 hybridization on the central atom?
A) 4
B) 3
C) 2
D) 1
E) 0
Answer: D
Diff: 5 Page Ref: 10.7
12
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53) Which of the following statements is TRUE?
A) The total number of molecular orbitals formed doesn't always equal the number of atomic orbitals in
the set.
B) A bond order of 0 represents a stable chemical bond.
C) When two atomic orbitals come together to form two molecular orbitals, one molecular orbital will
be lower in energy than the two separate atomic orbitals and one molecular orbital will be higher in
energy than the separate atomic orbitals.
D) Electrons placed in antibonding orbitals stabilize the ion/molecule.
E) All of the above are true.
Answer: C
Diff: 3 Page Ref: 10.8
54) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D
Diff: 4 Page Ref: 10.8
13
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55) Use the molecular orbital diagram shown to determine which of the following are paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above are paramagnetic.
Answer: D
Diff: 4 Page Ref: 10.8
14
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56) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D
Diff: 4 Page Ref: 10.8
15
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57) Use the molecular orbital diagram shown to determine which of the following are paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
Diff: 4 Page Ref: 10.8
58) Draw the molecular orbital diagram shown to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D
Diff: 5 Page Ref: 10.8
16
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59) Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above are paramagnetic.
Answer: D
Diff: 5 Page Ref: 10.8
60) Draw the molecular orbital diagram shown to determine which of the following is most stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D
Diff: 5 Page Ref: 10.8
61) Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
Diff: 5 Page Ref: 10.8
Algorithmic Questions
1) What geometric arrangement of charge clouds is expected for an atom that has four charge clouds?
A) trigonal bipyramidal
B) octahedral
C) tetrahedral
D) square planar
Answer: C
Diff: 1 Page Ref: 10.2
2) Give the approximate bond angle for a molecule with a trigonal planar shape.
A) 109.5°
B) 180°
C) 120°
D) 107°
E) 90°
Answer: C
Diff: 2 Page Ref: 10.2
17
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3) Give the approximate bond angle for a molecule with a tetrahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: A
Diff: 2 Page Ref: 10.2
4) Give the approximate bond angle for a molecule with a linear shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: B
Diff: 2 Page Ref: 10.2
5) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3F.
A) eg=tetrahedral, mg=tetrahedral
B) eg=linear, mg=trigonal planar
C) eg=trigonal planar, mg=tetrahedral
D) eg=linear, mg=linear
E) eg=trigonal planar, mg=trigonal planar
Answer: A
Diff: 2 Page Ref: 10.4
18
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8) What is the molecular geometry of SF5-?
A) octahedral
B) seesaw
C) square pyramidal
D) trigonal bipyramidal
Answer: C
Diff: 3 Page Ref: 10.4
9) Which of the following best describes ClF2-? It has a molecular geometry that is
A) linear with no lone pairs on the Cl atom.
B) linear with lone pairs on the Cl atom.
C) nonlinear with no lone pairs on the Cl atom.
D) nonlinear with lone pairs on the Cl atom.
Answer: B
Diff: 3 Page Ref: 10.4
11) Using the VSEPR model, the electron-domain geometry of the central atom in BrF4- is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) trigonal bipyramidal
E) octahedral
Answer: E
Diff: 3 Page Ref: 10.4
12) Using the VSEPR model, the molecular geometry of the central atom in XeF2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: A
Diff: 3 Page Ref: 10.4
19
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13) Using the VSEPR model, the molecular geometry of the central atom in BF3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: B
Diff: 3 Page Ref: 10.4
14) Using the VSEPR model, the molecular geometry of the central atom in CF4 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: C
Diff: 3 Page Ref: 10.4
15) Using the VSEPR model, the molecular geometry of the central atom in SO2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: D
Diff: 3 Page Ref: 10.4
16) Using the VSEPR model, the molecular geometry of the central atom in NCl3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: E
Diff: 3 Page Ref: 10.4
17) Using the VSEPR model, the molecular geometry of the central atom in XeF4 is ________.
A) tetrahedral
B) seesaw
C) square planar
D) trigonal bipyramidal
E) square pyramidal
Answer: C
Diff: 3 Page Ref: 10.4
20
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