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Chemistry: A Molecular Approach, 3e (Tro)
Chapter 10 Chemical Bonding II: Molecular Shapes, Valence Bond Theory, and Molecular
Orbital Theory
Multiple Choice Questions
1) Give the approximate bond angle for a molecule with an octahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: E
Diff: 2 Page Ref: 10.2
2) Determine the electron geometry (eg) and molecular geometry(mg) of BCl3.

A) eg=trigonal planar, mg=trigonal planar
B) eg=tetrahedral, mg=trigonal planar
C) eg=tetrahedral, mg=trigonal pyramidal
D) eg=trigonal planar, mg=bent
E) eg=trigonal bipyramidal, mg= trigonal bipyramidal
Answer: A
3) Determine the electron geometry (eg) and molecular geometry (mg) of CO32⁻.
A) eg=tetrahedral, mg=tetrahedral
B) eg=tetrahedral, mg=trigonal pyramidal
C) eg=trigonal planar, mg=bent
D) eg=trigonal planar, mg=trigonal planar
E) eg=tetrahedral, mg=trigonal planar
Answer: D
4) Determine the electron geometry (eg) and molecular geometry (mg) of CH3+1.
D) eg=trigonal planar, mg=trigonal planar
E) eg=tetrahedral, mg=trigonal planar
Answer: D
1
Copyright © 2014 Pearson Education, Inc.
5) Determine the electron geometry (eg) and molecular geometry (mg) of SiF4.
A) eg=tetrahedral, mg=trigonal pyramidal
B) eg=octahedral, mg=square planar
C) eg=trigonal bipyramidal, mg=trigonal pyramidal
D) eg=tetrahedral, mg=bent
E) eg=tetrahedral, mg=tetrahedral
Answer: E
6) Determine the electron geometry (eg) and molecular geometry (mg) of PF5.
A) eg=trigonal bipyramidal, mg=trigonal bipyramidal
B) eg=octahedral, mg=octahedral
C) eg=trigonal bipyramidal, mg=tetrahedral
D) eg=tetrahedral, mg=trigonal pyramidal
E) eg=trigonal planar, mg=octahedral
Answer: A
7) Determine the electron geometry (eg) and molecular geometry (mg) of CO2.
B) eg=linear, mg=trigonal planar
D) eg=linear, mg=linear
E) eg=trigonal planar, mg=trigonal planar
Answer: D
8) The bond angle in NH3 is

A) 107°
B) 104.5°
C) 120°
D) 109.5°
E) 95°
Answer: A
9) The bond angle in H2O is

A) 107°
B) 104.5°
C) 120°
D) 109.5°
E) 95°
Answer: B
2
10) Determine the electron geometry (eg) and molecular geometry (mg) of NCl3.
E) eg=tetrahedral, mg=trigonal pyramidal
Answer: E
11) Determine the electron geometry (eg) and molecular geometry (mg) of ICl3.
A) eg=trigonal planar, mg=trigonal planar
B) eg=trigonal bipyramidal, mg= T-shape
D) eg=trigonal bipyramidal, mg=see-saw
E) eg=tetrahedral, mg=trigonal pyramidal
Answer: B
12) Determine the electron geometry (eg) and molecular geometry (mg) of ICl2⁻.
A) eg=tetrahedral, mg=bent
C) eg=trigonal bipyramidal, mg=linear
D) eg=trigonal bipyramidal, mg=trigonal planar
E) eg=octahedral, mg=linear
Answer: C
13) Determine the electron geometry (eg) and molecular geometry (mg) of XeF2.
A) eg=trigonal bipyramidal, mg=bent
B) eg=linear, mg=linear
C) eg=tetrahedral, mg=linear
D) eg=trigonal bipyramidal, mg=linear
E) eg=tetrahedral, mg=bent
Answer: D
14) Determine the electron geometry (eg) and molecular geometry (mg) of XeF4.
B) eg=linear, eg=linear
C) eg=tetrahedral, mg=bent
D) eg=trigonal bipyramidal, mg=tetrahedral
E) eg=octahedral, mg=square planar
Answer: E
3
15) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
Answer: A
16) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom
CH3OCH3.
Answer: C
17) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined atom H2CO.
B) eg=trigonal planar, eg=trigonal planar
Answer: B
18) Consider the molecule below. Determine the molecular geometry at each of the 2 labeled carbons.
A) C1 = tetrahedral, C2 = linear
B) C1 = trigonal planar, C2= bent
C) C1 = bent, C2 = trigonal planar
D) C1 = trigonal planar, C2 = tetrahedral
E) C1 = trigonal pyramidal, C2 = see-saw
Answer: D
4
19) Consider the molecule below. Determine the molecular geometry at each of the 3 labeled atoms.
A) 1=trigonal planar, 2=tetrahedral, 3=trigonal pyramidal

B) 1=tetrahedral, 2=tetrahedral, 3=tetrahedral
C) 1=trigonal planar, 2=tetrahedral, 3=tetrahedral
D) 1=tetrahedral, 2=tetrahedral, 3=trigonal planar
E) 1=trigonal planar, 2=trigonal pyramidal, 3=trigonal pyramidal
Answer: A
20) Place the following in order of increasing X-Se-X bond angle, where X represents the outer atoms
in each molecule.
SeO2 SeCl6 SeF2
A) SeCl6 < SeF2 < SeO2

B) SeF2 < SeO2 < SeCl6
C) SeF2 < SeCl6 < SeO2
D) SeO2 < SeF2 < SeCl6
E) SeCl6 < SeO2 < SeF2
Answer: A
21) Place the following in order of increasing F-A-F bond angle, where A represents the central atom in
each molecule.
PF3 OF2 PF4⁺
A) PF3 < OF2 < PF4⁺

B) OF2 < PF3 < PF4⁺
C) OF2 < PF4⁺ < PF3
D) PF4⁺ < OF2 < PF3
E) PF4⁺ < PF3 < OF2
Answer: B
5
22) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom
and X represents the outer atoms in each molecule.
N2O NCl3 NO2⁻
A) NCl3 > NO2⁻ > N2O

B) NO2⁻ > N2O > NCl3
C) N2O > NO2⁻ > NCl3
D) NCl3 > N2O > NO2⁻
E) N2O > NCl3 > NO2⁻
Answer: C
23) Place the following in order of decreasing X-A-X bond angle, where A represents the central atom
CS2 CF4 SCl2
A) CS2 = SCl2 > CF4

B) SCl2 > CF4 > CS2
C) CF4 > CS2 > SCl2
D) CS2 > CF4 > SCl2
E) CF4 > CS2 > SCl2
Answer: D
24) Place the following in order of increasing X-A-X bond angle, where A represents the central atom
HCN H2O H3O⁺
A) H2O < H3O⁺ < HCN

B) H3O⁺ < H2O < HCN
C) HCN < H3O⁺ < H2O
D) H2O < HCN < H3O⁺
E) H2O < H3O⁺ < HCN
Answer: E
6
25) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO3.
A) eg=tetrahedral, mg=trigonal pyramidal, polar
B) eg=tetrahedral, mg=tetrahedral, nonpolar
C) eg=trigonal planar, mg=trigonal planar, nonpolar
D) eg= trigonal bipyramidal, mg=trigonal planar, polar
E) eg=trigonal pyramidal, mg=bent, nonpolar
Answer: C
26) How many of the following molecules are polar?
BrCl3 CS2 SiF4 SO3
A) 1
B) 2
C) 3
D) 4
E) 0
Answer: A
27) How many of the following molecules are polar?
PCl5 COS XeO3 SeBr2
A) 2
B) 0
C) 1
D) 3
E) 4
Answer: D
28) Determine the electron geometry (eg), molecular geometry (mg), and polarity of SO2.
A) eg=tetrahedral, mg=bent, polar
B) eg=trigonal planar, mg=bent, polar
C) eg=linear, mg=linear, nonpolar
D) eg=tetrahedral, mg=tetrahedral, nonpolar
E) eg=trigonal pyramidal, mg=trigonal pyramidal, polar
Answer: B
7
29) Determine the electron geometry (eg), molecular geometry (mg), and polarity of PCl3.
A) eg=tetrahedral, mg=bent, polar
B) eg=trigonal planar, mg=trigonal planar, nonpolar
C) eg=linear, mg=linear, nonpolar
D) eg=tetrahedral, mg=trigonal pyramidal, polar
E) eg=trigonal pyramidal, mg=trigonal pyramidal, polar
Answer: D
30) Determine the electron geometry, molecular geometry and polarity of SF6.
A) eg=trigonal bipyramidal, mg=trigonal bipyramidal, nonpolar
B) eg=tetrahedral, mg=tetrahedral, polar
C) eg=trigonal bipyramidal, mg=see-saw, polar
D) eg=octahedral, mg=trigonal bipyramidal, nonpolar
E) eg=octahedral, mg=octahedral, nonpolar
Answer: E
31) Determine the electron geometry (eg), molecular geometry(mg) and polarity of XeO3.
A) eg=trigonal planar, mg=trigonal planar, nonpolar
B) eg=tetrahedral, mg=trigonal pyramidal, polar
C) eg=trigonal planar, mg=trigonal pyramidal, polar
D) eg=trigonal bipyramidal, mg=trigonal planar, nonpolar
E) eg=octahedral, mg=tetrahedral, nonpolar
Answer: B
32) Determine the electron geometry, molecular geometry and polarity of HBrO2.
A) eg=trigonal bipyramidal, mg=trigonal planar, nonpolar
B) eg=octahedral, mg=square planar, nonpolar
C) eg=tetrahedral, mg=trigonal pyramidal, polar
D) eg=tetrahedral, mg=linear, nonpolar
E) eg=linear, mg=linear, polar
Answer: C
33) Place the following in order of increasing dipole moment.
I. BCl3 II. BIF2 III. BClF2
A) I < II = III
B) II < III < I
C) I < II < III
D) II < I < III
E) I < III < II
Answer: E
8
34) Place the following in order of decreasing dipole moment.
I. cis-CHCl=CHCl II. trans-CHCl=CHCI III. cis-CHF=CHF
A) III > I > II

B) II > I > III
C) I > III > II
D) II > III > I
E) I = III > II
Answer: A
35) Identify the number of electron groups around a molecule with sp hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: B
36) Identify the number of electron groups around a molecule with sp2 hybridization.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: C
37) Identify the number of electron groups around a molecule with a tetrahedral shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: D
38) Identify the number of electron groups around a molecule with a trigonal bipyramidal shape.
A) 1
B) 2
C) 3
D) 4
E) 5
Answer: E
9
39) Identify the number of electron groups around a molecule with an octahedral shape.
A) 6
B) 2
C) 3
D) 4
E) 5
Answer: A
40) Give the electron geometry (eg), molecular geometry (mg), and hybridization for NH3.
A) eg=tetrahedral, mg=trigonal planar, sp2
B) eg=trigonal pyramidal, mg=trigonal pyramidal, sp3
C) eg=tetrahedral, mg=trigonal pyramidal, sp3
D) eg=trigonal pyramidal, mg=tetrahedral, sp3
E) eg=trigonal planar, mg=trigonal planar, sp2
Answer: C
41) Give the electron geometry (eg), molecular geometry (mg), and hybridization for H2O.
A) eg=tetrahedral, mg=bent, sp3
C) eg=tetrahedral, mg=trigonal pyramidal, sp3
D) eg=bent, mg=bent, sp2
E) eg=trigonal planar, mg=trigonal planar, sp2
Answer: A
42) Give the electron geometry (eg), molecular geometry (mg), and hybridization for XeF4.
A) eg=tetrahedral, mg=tetrahedral, sp3
C) eg=octahedral, mg=square planar, sp3d2
D) eg=octahedral, mg=octahedral, sp3d2
E) eg=trigonal bipyramidal, mg=seesaw, sp3d
Answer: C
43) Give the hybridization for the O in OF2.

A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
10
44) Give the hybridization for the O in H3O+.
A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: B
45) Give the hybridization for the S in SO3.

A) sp
B) sp3
C) sp2
D) sp3d
E) sp3d2
Answer: C
46) Give the hybridization for the Br in BrO4⁻.

A) sp
B) sp3d2
C) sp3d
D) sp3
E) sp2
Answer: D
47) Give the hybridization for the S in SF6.

A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2
Answer: E
48) Give the hybridization for the Br in BrF5.

A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: A
11
49) Give the hybridization for the Br in BrCl3.
A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: B
50) Give the hybridization for the C in HCN.

A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: E
51) Give the hybridization for the C in HCCH.

A) sp3d2
B) sp3d
C) sp3
D) sp2
E) sp
Answer: E
52) How many of the following molecules have sp2 hybridization on the central atom?
HCN SO2 OCl2 XeCl2
A) 4
B) 3
C) 2
D) 1
E) 0
Answer: D
12
53) Which of the following statements is TRUE?
A) The total number of molecular orbitals formed doesn't always equal the number of atomic orbitals in
the set.
B) A bond order of 0 represents a stable chemical bond.
C) When two atomic orbitals come together to form two molecular orbitals, one molecular orbital will
be lower in energy than the two separate atomic orbitals and one molecular orbital will be higher in
energy than the separate atomic orbitals.
D) Electrons placed in antibonding orbitals stabilize the ion/molecule.
E) All of the above are true.
Answer: C
54) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D
13
55) Use the molecular orbital diagram shown to determine which of the following are paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above are paramagnetic.
Answer: D
14
56) Use the molecular orbital diagram shown to determine which of the following is most stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D
15
57) Use the molecular orbital diagram shown to determine which of the following are paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
58) Draw the molecular orbital diagram shown to determine which of the following is most stable.
A) F2
B) F22⁺
C) Ne22⁺
D) O22⁺
E) F22⁻
Answer: D
16
59) Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) O22⁻
B) Ne22⁺
C) O22⁺
D) F22⁺
E) None of the above are paramagnetic.
Answer: D
60) Draw the molecular orbital diagram shown to determine which of the following is most stable.
A) C22⁺
B) N22⁺
C) B2
D) C22⁻
E) B22⁺
Answer: D
61) Draw the molecular orbital diagram shown to determine which of the following is paramagnetic.
A) B22⁺
B) B22⁻
C) N22⁺
D) C22⁻
E) B2
Answer: E
Algorithmic Questions
1) What geometric arrangement of charge clouds is expected for an atom that has four charge clouds?
A) trigonal bipyramidal
B) octahedral
C) tetrahedral
D) square planar
Answer: C
2) Give the approximate bond angle for a molecule with a trigonal planar shape.
A) 109.5°
B) 180°
C) 120°
D) 107°
E) 90°
Answer: C
17
3) Give the approximate bond angle for a molecule with a tetrahedral shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: A
4) Give the approximate bond angle for a molecule with a linear shape.
A) 109.5°
B) 180°
C) 120°
D) 105°
E) 90°
Answer: B
5) Determine the electron geometry (eg) and molecular geometry (mg) of the underlined carbon in
CH3F.
C) eg=trigonal planar, mg=tetrahedral
E) eg=trigonal planar, mg=trigonal planar
Answer: A
6) What is the molecular geometry of ClF4 -?

A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral
Answer: B
7) What is the molecular geometry of SbCl3?

A) T-shaped
B) tetrahedral
C) trigonal planar
D) trigonal pyramidal
Answer: D
18
8) What is the molecular geometry of SF5-?
A) octahedral
B) seesaw
C) square pyramidal
D) trigonal bipyramidal
Answer: C
9) Which of the following best describes ClF2-? It has a molecular geometry that is
A) linear with no lone pairs on the Cl atom.
B) linear with lone pairs on the Cl atom.
C) nonlinear with no lone pairs on the Cl atom.
D) nonlinear with lone pairs on the Cl atom.
Answer: B
10) What is the molecular geometry of SBr4?

A) seesaw
B) square planar
C) square pyramidal
D) tetrahedral
Answer: A
11) Using the VSEPR model, the electron-domain geometry of the central atom in BrF4- is ________.
A) linear
B) trigonal planar
C) tetrahedral
E) octahedral
Answer: E
12) Using the VSEPR model, the molecular geometry of the central atom in XeF2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
E) trigonal pyramidal
Answer: A
19
13) Using the VSEPR model, the molecular geometry of the central atom in BF3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: B
14) Using the VSEPR model, the molecular geometry of the central atom in CF4 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: C
15) Using the VSEPR model, the molecular geometry of the central atom in SO2 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: D
16) Using the VSEPR model, the molecular geometry of the central atom in NCl3 is ________.
A) linear
B) trigonal planar
C) tetrahedral
D) bent
Answer: E
17) Using the VSEPR model, the molecular geometry of the central atom in XeF4 is ________.
A) tetrahedral
B) seesaw
C) square planar
E) square pyramidal
Answer: C
20
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Multiple Choice Questions

2) Determine the electron geometry (eg) and molecular geometry(mg) of BCl3.

8) The bond angle in NH3 is

9) The bond angle in H2O is

A) 1=trigonal planar, 2=tetrahedral, 3=trigonal pyramidal

SeO2 SeCl6 SeF2

A) SeCl6 < SeF2 < SeO2

PF3 OF2 PF4⁺

A) PF3 < OF2 < PF4⁺

N2O NCl3 NO2⁻

A) NCl3 > NO2⁻ > N2O

CS2 CF4 SCl2

A) CS2 = SCl2 > CF4

HCN H2O H3O⁺

A) H2O < H3O⁺ < HCN

26) How many of the following molecules are polar?

BrCl3 CS2 SiF4 SO3

27) How many of the following molecules are polar?

PCl5 COS XeO3 SeBr2

33) Place the following in order of increasing dipole moment.

I. BCl3 II. BIF2 III. BClF2

I. cis-CHCl=CHCl II. trans-CHCl=CHCI III. cis-CHF=CHF

A) III > I > II

43) Give the hybridization for the O in OF2.

45) Give the hybridization for the S in SO3.

46) Give the hybridization for the Br in BrO4⁻.

47) Give the hybridization for the S in SF6.

48) Give the hybridization for the Br in BrF5.

50) Give the hybridization for the C in HCN.

51) Give the hybridization for the C in HCCH.

HCN SO2 OCl2 XeCl2

6) What is the molecular geometry of ClF4 -?

7) What is the molecular geometry of SbCl3?

10) What is the molecular geometry of SBr4?

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