Product Name: EXXSOL™ D80 FLUID

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SAFETY DATA SHEET

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

PRODUCT
Product Name: EXXSOL™ D80 FLUID
Product Description: Dearomatised Hydrocarbons

Intended Use: Solvent

COMPANY IDENTIFICATION
Supplier: ExxonMobil Chemical Asia Pacific (Regn. No. 52893724C)
(A Division Of ExxonMobil Asia Pacific Pte Ltd - Regn. No. 196800312N)
INTERMEDIATES
1 HarbourFront Place
#06-00 HarbourFront Tower One 098633 Singapore

24 Hour Emergency Telephone 800-101-2201

Supplier General Contact +65 6885 8000

Local Contact:
Country Emergency Telephone Number
CHEMTREC International +1-703-741-5970
Australia 0800-293-702
China +86-4001-204-937
Hong Kong 800-968-793
India 000-800-100-7141
Indonesia 001-803-017-9114
Japan +81-3-4520-9637
Malaysia 1-800-815-308
New Zealand 0800-425-459
Philippines 1-800-1-116-1020
Taiwan 00801-14-8954
Thailand 001-800-13-203-9987

This (M)SDS is a generic document with no country specific information included.

SECTION 2 HAZARDS IDENTIFICATION

This material is hazardous according to UN GHS Criteria. Classification includes all GHS hazard classes. For hazard
categories with two cut-off/concentration limits, classification was based on the higher limit.

GHS CLASSIFICATION:

Flammable liquid: Category 4.

Aspiration toxicant: Category 1.

GHS Label Elements:

Pictogram:
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Signal Word: Danger

Hazard Statements:

Physical: H227: Combustible liquid.

Health: H304: May be fatal if swallowed and enters airways.

Precautionary Statements:

Prevention: P210: Keep away from flames and hot surfaces. No smoking. P280: Wear protective gloves and
eye / face protection.
Response: P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do
NOT induce vomiting. P370 + P378: In case of fire: Use water fog, foam, dry chemical or carbon dioxide (CO2)
to extinguish.
Storage: P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.
Disposal: P501: Dispose of contents and container in accordance with local regulations.

Contains: DISTILLATES (PETROLEUM), HYDROTREATED LIGHT

Other hazard information:

PHYSICAL / CHEMICAL HAZARDS

Material can accumulate static charges which may cause an ignition. Material can release vapours that
readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Combustible.

HEALTH HAZARDS
May be irritating to the eyes, nose, throat, and lungs. Repeated exposure may cause skin dryness or
cracking.

ENVIRONMENTAL HAZARDS
No significant hazards.

NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert
advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary
from person to person.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

This material is defined as a complex substance.

Hazardous Substance(s) or Complex Substance(s) required for disclosure

Name CAS# Concentration* GHS Hazard Codes
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 100 % H227, H304
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* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
Concentration values may vary.
SECTION 4 FIRST AID MEASURES

INHALATION
Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use
adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Wash contact areas with soap and water. Remove contaminated clothing. Launder contaminated clothing
before reuse.

EYE CONTACT
Flush thoroughly with water. If irritation occurs, get medical assistance.

INGESTION
Seek immediate medical attention. Do not induce vomiting.

ACUTE AND DELAYED SYMPTOMS/EFFECTS

See Toxicological Section

NOTE TO PHYSICIAN
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA
Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish
flames.

Inappropriate Extinguishing Media: Straight streams of water

FIRE FIGHTING
Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering
streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in
enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces
and to protect personnel.

Unusual Fire Hazards: FLAMMABLE.

Hazardous Combustion Products: Incomplete combustion products, Oxides of carbon, Smoke, Fume

FLAMMABILITY PROPERTIES
Flash Point [Method]: 81°C (178°F) [ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 6.0
Autoignition Temperature: 227°C (441°F) [Extrapolated]

SECTION 6 ACCIDENTAL RELEASE MEASURES

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NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable
regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas if
required, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See the
Hazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 for
advice on the minimum requirements for personal protective equipment. Additional protective measures may be
necessary, depending on the specific circumstances and/or the expert judgment of the emergency responders.

For emergency responders: Respiratory protection: half-face or full-face respirator with filter(s) for organic
vapor and, when applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used depending on
the size of spill and potential level of exposure. If the exposure cannot be completely characterized or an
oxygen deficient atmosphere is possible or anticipated, SCBA is recommended. Work gloves that are resistant
to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl acetate (PVA) are not water-
resistant and are not suitable for emergency use. Chemical goggles are recommended if splashes or contact
with eyes is possible. Small spills: normal antistatic work clothes are usually adequate. Large spills: full body
suit of chemical resistant, antistatic material is recommended.

SPILL MANAGEMENT
Land Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak
if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch
or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A
vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed
material. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Recover by
pumping or with suitable absorbent.

Water Spill: Stop leak if you can do so without risk. Warn other shipping. Remove from the surface by
skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants.

Water spill and land spill recommendations are based on the most likely spill scenario for this material;
however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction
and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be
consulted. Note: Local regulations may prescribe or limit action to be taken.

ENVIRONMENTAL PRECAUTIONS
Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,
sewers, basements or confined areas.

SECTION 7 HANDLING AND STORAGE

HANDLING
Avoid contact with skin. Small metal particles from machining may cause abrasion of the skin and may
predispose to dermatitis. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static
charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an
electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during
switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing
may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance.
Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of
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Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static
Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to
static electricity).

Loading/Unloading Temperature: [Ambient]

Transport Temperature: [Ambient]

Transport Pressure: [Ambient]

Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive,
static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a
semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive
or semiconductive, the precautions are the same. A number of factors, for example liquid temperature,
presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.

STORAGE
The type of container used to store the material may affect static accumulation and dissipation. Keep
container closed. Handle containers with care. Open slowly in order to control possible pressure release.
Store in a cool, well-ventilated area. Storage containers should be earthed and bonded. Fixed storage
containers, transfer containers and associated equipment should be earthed and bonded to prevent
accumulation of static charge.
Storage Temperature: [Ambient]
Storage Pressure: [Ambient]

Suitable Containers/Packing: Tank Trucks; Drums; Barges; Tank Cars

Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Stainless Steel; Teflon;
Polyethylene; Polypropylene
Unsuitable Materials and Coatings: Butyl Rubber; Natural Rubber; Ethylene-proplyene-diene monomer
(EPDM); Polystyrene

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters/Exposure limits:

Exposure limits/standards (Note: Exposure limits are not additive)

Substance Name Form Limit/Standard Note Source Year

DISTILLATES (PETROLEUM), Vapour. RCP - 1200 165 ppm ExxonMobil 2009
HYDROTREATED LIGHT [Total TWA mg/m3
Hydrocarbons]

Biological limits

No biological limits allocated.

NOTE: Limits/standards shown for guidance only. Follow applicable regulations.

ENGINEERING CONTROLS
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The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider:
Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-
proof ventilation equipment.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use
with this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a

level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator
selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of
respirators to be considered for this material include:
No protection is ordinarily required under normal conditions of use and with adequate ventilation.
Half-face filter respirator Type A filter material.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,
gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove
manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.
Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use
conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material
include:
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with
forearms is likely, wear gauntlet-style gloves. Nitrile

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. The types of clothing to be considered for this material include:
If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be
cleaned. Practice good housekeeping.

ENVIRONMENTAL CONTROLS
Comply with applicable environmental regulations limiting discharge to air, water and
soil. Protect the environment by applying appropriate control measures to prevent or limit
emissions.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Note: Physical and chemical properties are provided for safety, health and environmental considerations only
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and may not fully represent product specifications. Contact the Supplier for additional information.

GENERAL INFORMATION
Physical State: Liquid
Form: Clear
Colour: Colourless
Odour: Slight
Odour Threshold: N/D

IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15.6 °C): 0.79 [With respect to water] [Calculated]
Density: 794 kg/m³ (6.63 lbs/gal, 0.79 kg/dm³) [ASTM D4052]
Flammability (Solid, Gas): N/A
Flash Point [Method]: 81°C (178°F) [ASTM D-93]
Flammable Limits (Approximate volume % in air): LEL: 0.6 UEL: 6.0
Autoignition Temperature: 227°C (441°F) [Extrapolated]
Boiling Point / Range: 200°C (392°F) - 250°C (482°F) [ASTM D86]
Decomposition Temperature: N/D
Vapour Density (Air = 1): 6.1 at 101 kPa [Calculated]
Vapour Pressure: 0.01 kPa (0.08 mm Hg) at 20 °C [Calculated]
Evaporation Rate (n-butyl acetate = 1): 0.01 [Calculated]
pH: N/A
Log Pow (n-Octanol/Water Partition Coefficient): > 4 [Estimated]
Solubility in Water: Negligible
Viscosity: 1.6 cSt (1.6 mm2/sec) at 40ºC | 2.3 cSt (2.3 mm2/sec) at 20°C [Calculated]
Oxidizing Properties: See Hazards Identification Section.

OTHER INFORMATION
Freezing Point: N/D
Melting Point: N/A
Pour Point: -48°C (-54°F) [ASTM D5950]
Molecular Weight: 178 g/mol [Calculated]
Hygroscopic: No
Coefficient of Thermal Expansion: 0.00092 per Deg C [Calculated]

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Material is stable under normal conditions.

CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.

MATERIALS TO AVOID: Strong oxidisers

HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

POSSIBILITY OF HAZARDOUS REACTIONS: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

INFORMATION ON TOXICOLOGICAL EFFECTS

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Hazard Class Conclusion / Remarks
Inhalation
Acute Toxicity: (Rat) 4 hour(s) LC50 > Minimally Toxic. Based on test data for structurally similar
5000 mg/m3 (Vapour) materials. Test(s) equivalent or similar to OECD Guideline 403
Irritation: No end point data for material. Negligible hazard at ambient/normal handling temperatures.
Ingestion
Acute Toxicity (Rat): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials. Test(s) equivalent or similar to OECD Guideline 401
Skin
Acute Toxicity (Rabbit): LD50 > 5000 mg/kg Minimally Toxic. Based on test data for structurally similar
materials. Test(s) equivalent or similar to OECD Guideline 402
Skin Corrosion/Irritation: Data available. May dry the skin leading to discomfort and dermatitis. Based on
test data for structurally similar materials. Test(s) equivalent or
similar to OECD Guideline 404
Eye
Serious Eye Damage/Irritation: Data May cause mild, short-lasting discomfort to eyes. Based on test
available. data for structurally similar materials. Test(s) equivalent or similar
to OECD Guideline 405
Sensitisation
Respiratory Sensitization: No end point data Not expected to be a respiratory sensitizer.
for material.
Skin Sensitization: Data available. Not expected to be a skin sensitizer. Based on test data for
structurally similar materials. Test(s) equivalent or similar to OECD
Guideline 406
Aspiration: Data available. May be fatal if swallowed and enters airways. Based on physico-
chemical properties of the material.
Germ Cell Mutagenicity: Data available. Not expected to be a germ cell mutagen. Based on test data for
structurally similar materials. Test(s) equivalent or similar to OECD
Guideline 471 473 474 476 478 479
Carcinogenicity: Data available. Not expected to cause cancer. Based on test data for structurally
similar materials. Test(s) equivalent or similar to OECD Guideline
453
Reproductive Toxicity: Data available. Not expected to be a reproductive toxicant. Based on test data for
structurally similar materials. Test(s) equivalent or similar to OECD
Guideline 413 414 415
Lactation: No end point data for material. Not expected to cause harm to breast-fed children.
Specific Target Organ Toxicity (STOT)
Single Exposure: No end point data for Not expected to cause organ damage from a single exposure.
material.
Repeated Exposure: Data available. Not expected to cause organ damage from prolonged or repeated
exposure. Based on test data for structurally similar materials.
Test(s) equivalent or similar to OECD Guideline 408 413 422

OTHER INFORMATION
For the product itself:

Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may
cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects
including death. Prolonged and/or repeated skin contact with low viscosity materials may defat the skin resulting in
possible irritation and dermatitis. Small amounts of liquid aspirated into the lungs during ingestion or from vomiting
may cause chemical pneumonitis or pulmonary edema.
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IARC Classification:
The following ingredients are cited on the lists below: None.

--REGULATORY LISTS SEARCHED--

1 = IARC 1 2 = IARC 2A 3 = IARC 2B

SECTION 12 ECOLOGICAL INFORMATION

The information given is based on data for the material, components of the material, or for similar materials, through the
application of bridging principals.

ECOTOXICITY
Material -- Not expected to be harmful to aquatic organisms.
Material -- Not expected to demonstrate chronic toxicity to aquatic organisms

PERSISTENCE AND DEGRADABILITY

Biodegradation:
Material -- Expected to be readily biodegradable.
Hydrolysis:
Material -- Transformation due to hydrolysis not expected to be significant.
Photolysis:
Material -- Transformation due to photolysis not expected to be significant.
Atmospheric Oxidation:
Material -- Expected to degrade rapidly in air

SECTION 13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable
laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS
Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should
be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be
taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with
governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION.
THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

SECTION 14 TRANSPORT INFORMATION

LAND (ADR/RID) : Not Regulated for Land Transport

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SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code

Marine Pollutant: No

AIR (IATA): Not Regulated for Air Transport

SECTION 15 REGULATORY INFORMATION

Material is hazardous according to UN GHS Criteria.

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS

Listed or exempt from listing/notification on the following chemical inventories : AIIC, DSL, ENCS,
IECSC, KECI, PICCS, TCSI, TSCA

SECTION 16 OTHER INFORMATION

N/D = Not determined, N/A = Not applicable

KEY TO THE H-CODES CONTAINED IN SECTION 3 OF THIS DOCUMENT (for information only):
H227: Combustible liquid; Flammable Liquid, Cat 4
H304: May be fatal if swallowed and enters airways; Aspiration, Cat 1

THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Section 08: Exposure Limits Table information was modified.
Section 14: IMO ANNEX II Product Name - Header information was deleted.
Section 14: Pollution Category (pulled from EMS_NUMBER column) information was deleted.
Section 14: Proper Shipping Name information was deleted.
Section 14: Ship Type (pulled from ER_GUIDE_PAGE column) information was deleted.
Revision Date: 01 Dec 2021

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The information and recommendations contained herein are, to the best of ExxonMobil's knowledge and belief,
accurate and reliable as of the date issued. You can contact ExxonMobil to insure that this document is the most
current available from ExxonMobil. The information and recommendations are offered for the user's consideration and
examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer
repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is
included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to
handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, re-
publication or retransmission of this document, in whole or in part, is not permitted. The term, "ExxonMobil" is used for
convenience, and may include any one or more of ExxonMobil Chemical Company, Exxon Mobil Corporation, or any
affiliates in which they directly of indirectly hold any interest.

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DGN: 4406091HAP (1015587)
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