Alcohols, Phenols and Ethers - JEE Advanced Practice Sheet - Lakshya JEE 2025

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Exercise-2 ozonolysis gives a molecule (C6H10O3) which gives

Only One Option Correct Type Question (1-5) positive iodoform test. Find out structure of ‘A’.

H /H 2O
1. Product (A) (B)

The main product is: (C) (D)

(A) (B) 4.

‘X’ will be:

(C) (D) (A)

(B)
Br2 H 2O NaOH NH3
2. Product
or(HOBr)
(C)
The product is:
(D) All of these

(A)
HI (excess)
5. ; which of the following

is major product?

(B) (A)

(B)

(C) (C)
(D) None of these

(D)

3. An organic compound A (Molecular formula


C6H12O) does not change the colour of acidic
dichromate solution. Compound A on treatment with
H2SO4 produces alkene, which on oxidative

6
One Or More Than One Correct Type Question (6-10)
6. CH3CH2 — OH can be converted to CH3CH2CN by (A)
the following reactions
(A) CH3CH2OH + KCN
(B)
(B) CH3CH2OH + HCN
TsCl KCN
(C) CH3CH2OH
SOCl2 KCN
(D) CH3CH2OH (C)

7. (D)

1.Mg Br2
10. H2C = CH – CH2Br 2.HCHO
A B
3.H3 O

(A) D is CH3 – CH = CH2 KOH


C alc.KOH

(B) E is CH3 – CH2 – CH2 –OH


(C) F is CH3 – CH – CH3 (A) A is H2C = CH – CH2CH2OH
|
OH Br
|
(D) B is CH3CH2Cl (B) B is CH 2 CH CH 2 CH 2 OH
|
Br
8. Compound A is an optically active alcohol.
Treatment with oxidising agent converts it to a (C) C is
ketone B. In a separate reaction A is treated with
PBr3, converting it into C. C on reaction with Mg is
added to B to yield . Identify the correct (D) C is

options.
(A) A is 2-butanol Integer Type Question (11-15)
(B) A is 1-butanol ?
11. R – CH2 – OH R – CH2 – Cl
(C) C is 2-bromobutane Find out number of reagents that can be used for
(D) C is 1-bromobutane
above conversion, from following.
HCl, ZnCl2, PCl3, POCl3, SOCl2, NaCl, TsCl, PCl5
9. A 3º optically active alcohol C9H18O ‘A’ on
dehydration with conc. H2SO4 produces B(C9H16)
12. Identify numbers of alcohol those will show
which exists in two stereoisomeric forms. For
ozonolysis of B followed by work up with Zn-H2O rearrangement during dehydration with concentrate
produces CH3 – C – H and C (C7H12O). C on H2SO4.
||
O
treatment with LiAlH4 produces D (C7H14O). D on

dehydration produced .

Identify the correct answer.

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