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CH4 Test on lesson One Chapter 4

First Choose the correct answer for the questions 1: 10

1. CuSO4 solution is not preserved in aluminum containers, because …..

a. Cu atoms are oxidized.

b. Cu atoms are reduced.

c. Cu2+ ions are reduced.

d. CuSO4 solution is dissociated.

2. The following equation represents the reaction of the metal (M) with the strong acids :

M(s) + 2H+(aq) 2+ →M²+(aq) + H2(g)

Each of the following can be represented by this ionic equation, except…..

a. zinc + dil. hydrochloric acid.

b. copper + dil. hydrochloric acid.

c. iron + dil. sulphuric acid.

d. calcium + dil. nitric acid.

3. In the reaction: Mg(s) + Cl2(g)→ MgCl2(aq)

The correct oxidation half reaction is ….

a. Mg0(s) + 2e- →Mg2+(aq)

b. Cl20(g) +2e-→2Cl-(aq)

c.Mg0(s) →Mg2+ (aq) + 2e-

d. Cl20(g)→2Cl-(aq) + 2e-

4. KCI is used as an electrolyte in the salt bridge used in the galvanic cell which is represented by the
cell diagram ……

a. Zn0(s)/Zn2+(aq)//2Ag+(aq)/2Ag0(s)

b. Pb0(s)/Pb2+(aq) // Cu2+(aq)/Cu0(s)

c. 3Cu0(s)/3Cu2+(aq) // 2A3+(aq)/2Au0(s)

d. Fes0(s)/Fe2+(aq) // Pb2+(aq)/Pb0(s)

5. A redox reaction is represented by the equation:

2PF2I(l) + 2Hg(l) →P2F4(g) + Hg2I2(s)

What is the number of the transferred electrons, and what is the substance which was oxidized?
Choices Number of the transferred electrons The oxidized substance
a. 2e- P
b. 1 e- Hg
c. 1 e- P
d. 2 e- Hg
6. By knowing the following electrodes potentials:

• Mg2+ + 2e- →Mg E° = -2.37 V

• V2+ +2e-→V E° = -1.19 V

• Cu2+ + e-→ Cu+ E° = +0.16 V

Which of the following equations represents a spontaneous reaction ?

a. Mg2+ + V →V2++ Mg

b. Mg2+ +2Cu+→2Cu2++ Mg

c. V2+ + 2Cu+ →V + 2Cu2+

d. V+ 2Cu2+→V2+ + 2Cu+

7. The opposite figures represent three different reactions, so if the metal:

• (Z) replaces (W) in beaker (1).

• (W) replaces (X) in beaker (2).

• (X) replaces (Y) in beaker (3).

What is the correct graduation in activity in these metals ?

a. W>X>Z>Y

b. X>Y>W>Z

c. Z>W>Y>X

d. Z>W>X>Y

8. The electrolyte used in the salt bridge of Daniel cell can be….

a. Pb(NO3)2

b. BaCl2

s. KNO3

d. CaCl2

9. In the opposite figure : Which of the following shows the


electrode towards which Co2+ ions move, and the change which
occurs in the mass of zinc electrode over time ?
Choices The electrode to which Co2+ ions move The change in the mass of zinc electrode
a. Co Increases
b. Co Decreases
c. Zn Increases
d. Zn Decreases

10. A galvanic cell, its cell diagram is: Pt(s) + H2(g)/2H+ (aq) // 2M+ (aq)/2M(s) , and emf of this cell equals 0.8
V. What is the standard oxidation potential of the electrode (M) ?

a. -0.8 V

b. +0.8 V

c. +0.4 V

d. -0.4 V

Second: Answer the following essay questions 11, 12:

11. The ionic equation below represents the reaction of a galvanic cell:

Pb2+(aq) + Mg(s) ► Pb(s) + Mg2+(aq)

(1) Write the cell diagram.

(2) Calculate emf of the cell.

12. One of the reactions below is spontaneous and the other is nonspontaneous (without order):

1. Cu(s) + Ni2+(aq)→Cu2+(aq)+ Ni(s)

2. 2Cr(s) + 3Fe2+ (aq)→2Cr3+ (aq) + 3Fe(s)

(1) Which of these reactions is nonspontaneous ? Explain.

(2) Is there any colour change that takes place in the solution of the spontaneous reaction after its
completion? Explain.
Test ? on lesson Two Chapter 4

First Choose the correct answer for the questions 1:10

1. What happens during charging the lead-acid battery ?

a. Sulphuric acid is consumed.

b. Sulphuric acid is formed.

c. Lead is consumed.

d. Lead (II) sulphate is formed.

2. Fuel cell is similar to mercury cell in

a. storing chemical energy which is converted into electric energy when needed.

b. being not consumed, as they are supplied with fuel from an external source.

c. the value of the electromotive force.

d. the used electrolyte.

3.The figure shows a lithium ion battery. is this figure illustrating


the charging or the discharging process ? What is the role of the
electrode (X) ?

Choices State of battery Role of electrode (X)


a. Charging Anode
b. Discharging Cathode
c. Discharging Anode
d. Charging Cathode

4. What does happen when H₂ and O₂ gases are used in fuel cell ?...

a. Electric energy is used in water production.

b. Electric energy is generated directly.

c. Hydrocarbon fuel is formed.

d. H₂ is reduced forming water vapour.

5. On comparing lithium ion battery with lead-acid battery, it is found that….

a. lead-acid battery has lower electromotive force.

b. lead-acid battery has higher ability to store energy.

c. lithium ion battery is more widely used.

d. lithium ion battery is larger in size.


6. What happens during charging the lead accumulator ?

a. pH of the solution in the battery doesn't change.

b. PbSO4 produced from the discharging process is converted into Pb and PbO2

c. The lead plates dissolve in the battery forming Pb2+

d. All Pb2+ ions are oxidized into Pb4+ ions.

7. By operating mercury cell, …..

a. mercury is formed on the anode.

b. the electrons move from mercury (II) oxide to zinc.

c. zinc atoms are reduced.

d. Hg2+ ions act as the oxidizing agent.

8. What is the number of moles of the electrons produced from the consumption of 0.347 g of lithium
[Li = 6.94] in lithium ion battery?

a. 3.47 mol of e-

b. 1 mol of e-

c. 0.5 mol of e-

d. 0.05 mol of e-

9. The following figure shows the processes occurring in mercury


cell:

Which of the following represents (1), (2), (3) and (4) ?

Choices (1) (2) (3) (4)


a. HgO Hg ZnO Zn
b. HgO Hg Zn ZnO
c. Hg HgO ZnO Zn
d. Hg HgO Zn ZnO

10. Each of the following expresses the fuel cell, except

a. the fuel used in it is the same fuel used in launching rockets.

b. the electrolyte used in it is KOH solution.

c. anode oxidation potential = cathode reduction potential.

d. it works at high temperature.


Second Answer the following essay questions 11, 12

11. The positive electrode in a battery is the oxide of a transition metal:

(1) Write the chemical formula of this oxide.

(2) What is the salt which composes the electrolyte of this battery ?

Is it dissolved in water or in an organic solvent ?

12 The diagram below represents a reaction that takes place in lead accumulator :

(1) Write the ionic equation of this reaction.

(2) Is this reaction spontaneous or nonspontaneous ? Explain.


Test ? on lesson Three Chapter 4

First Choose the correct answer for the questions 1: 10

1. The opposite figure represents an experiment which was performed in a laboratory, it was
observed after one month that water has risen to
the highest level in tube…

a. (W)

b. (X)

c. (Y)

d. (Z)

2. Which of the following metals has the fastest corrosion reaction when being connected to a
platinum electrode ? …

a. Ag

b. Au

c. Zn

d. Fe

3. The following equations represent the mechanism of iron rusting, in no particular order, except ….

a. O2(g)+2H2O(l)+4e-→4OH-(aq)

b. Fe(s)→Fe2+(aq)+2e- (aq)

c. Fe2O3.H2O(s)+6H+ (aq) →2Fe3+(aq)+4H2O (l)

d. 4F2+(aq)+O2(g)+4H+(aq)→4Fe3+(aq)+2H2O(l)

4. The following figures illustrate 4 test tubes, each tube contains an iron plate preserved in certain
circumstances:

After short time, rusting occurs


to iron plate(s) found in…..

a. tube (1) only.

b. tube (2) only.

c. tubes (1) and (2).

d. tubes (2) and (4).

5. Connecting zinc to iron protects iron from rusting, as zinc ...................

a. is less active than iron, and iron ability to lose electrons is lower than that of zinc.
b. is less active than iron, and iron ability to lose electrons is higher than that of zinc.

c. is more active than iron, and iron ability to lose electrons is lower than that of zinc.

d. is more active than iron, and iron ability to lose electrons is higher than that of zinc.

6. All the following are correct about metal corrosion, except…

a. chromium in stainless steel alloy forms a layer of oxide on the surface of the alloy.

b. galvanized steel is covered with zinc to form a nonporous layer of zinc oxide.

c. anodic protection is used to protect the pipes buried under the surface of the earth.

d. both chromium and tin are used to protect steel from rusting.

7. The rate of nail rusting is the slowest in the tube …..

8. A bike is left outdoor for months, then rust marks were noticed on some of its parts, all the
following can decrease the rate of rusting reaction, except ….

a. removing rust and painting its position with primer.

b. removing rust and moving the bike to a dry place.

c. removing rust and wiping its position with a clean cloth wet with water.

d. removing rust and wiping its position with a clean cloth wet with oil.

9. Protecting steel from rusting by being electroplated with chromium is attributed to ….

a. the anodic protection.

b. the porosity of the layer of chromium.

c. the cathodic protection.

d. the chemical combination between chromium and oxygen.

10 Connecting iron to each of the following metals protects it from rusting, except….

a. manganese.

b. magnesium.

c. tin.
d. zinc.

Second Answer the following essay questions 11, 12

11. A shiny iron nail is wrapped with a wire of copper, and another nail is wrapped with a strip of zinc.

Describe the difference between these two nails after being dipped for 2 days in:

(1) Distilled water.

(2) Salty water.

12. The shown diagram represents the mechanism of iron rusting:

(1) is the area (X) the anode or the cathode ?

Write the reaction equation.

(2) How does the presence of a copper rivet nail in the area (X) affect the rate of iron rusting? Explain.
Test 2 on lesson Four Chapter 44

First Choose the correct answer for the questions 1: 10

1. 0.1 mol of chlorine gas evolves when 3 A current is passed in sodium chloride melt for

a. 55 min

b. 107.22 min

c. 220 min

d. 319.7 min

2. Quantity of electricity required for the evolution of 0.5 g of hydrogen gas, causes also the
deposition of a mass of copper in CuSO4 solution equals…[H=1, Cu=63.5]

a. 12.7 g

b. 31.8 g

d. 15.9 g

d. 63.5 g

3. On passing 965 A electric current in an electrolyte for 100s, (m) g were deposited at one of the
electrodes. The gram equivalent mass of this deposited substance is estimated by the quantity

mxc
a.
t
b. m

1
c. .
m
t
d.
mxc
4. The opposite figure shows the connection of a galvanic
cell to an electrolytic cell in series. What are the letters
which indicate the anode and the cathode in each cell ?

Choices (A) (B) (C) (D)


a. Cathode Anode Anode Cathode
b. Cathode Anode Cathode Anode
c. Anode Cathode Anode Cathode
d. Anode Cathode Cathode Anode
5. Converting 1 mol of Fe2O3 into FeO requires a quantity of electricity equals…

a. 1F

b. 2F
c. 3F

d. 4F

6. Chromium electroplating is carried out according to the equation:

CrO3+6H++6e- →Cr+ 3H2O

What is the mass of chromium [Cr = 52] which can be deposited on the metal to be plated, when an
electric current with intensity equals 0.1 A is used for 3 h?

a. 0.097 g

b. 10.8 g

d. 5.2 g

d. 0.52 g

7. The opposite figure illustrates the electrolytic cell of zinc chloride melt. What happens in this cell ?

Choices Occurring process Occurring reaction equation

a. Oxidation at the electrode (X) 2Cl-(l) →Cl2(g) +2e-


b. Oxidation at the electrode (Y) Zn2+(l) +2e→Zn(s)
c. Reduction at the electrode (X) Zn2+(l) +2e→Zn(s)
d. Reduction at the electrode (Y) 2Cl-(l) →Cl2(g) +2e-
8. What is the number of moles of the electrons produced from passing an electric current whose
intensity is 14.4 A in an electrolyte for 3.2 h ?

a. 46.1 mol of e-

b. 3.35 mol of e-

c. 1.72 mol of e-

d. 9.33 x 103 mol of e-

9. A quantity of electricity equals 3 F was passed in three different electrolytes connected in series,
which are Al2O3 melt, CuSO4 solution and NaCl melt. Which of the following represents the ratio
between the number of moles of the deposited metals ? …
Choices Al Cu Na
a. 3 4 6
b. 2 1 6
c. 3 2 1
d. 2 3 6
10. On passing a quantity of electricity equals 10800 C in an electrolyte, 2.977 g of the metal (X) whose
gram atomic mass (g atom) is 106.4 g/mol are deposited on the cathode of the cell.

What is the oxidation number of the metal (X) ?

a. 4

b. 3

c. 2

d. 1

Second Answer the following essay questions 11, 12

11. The electrolysis of a concentrated solution of copper (II) sulphate can be represented by the
equation:

2Cu2+(aq)+4OH-(aq) →2Cu(s)+2H2O(l)+O2(g)

(1) Deduce the change in the colour of the used electrolyte after the consumption of all Cu 2+ ions
through the process.

(2) Guess the change in the colour of litmus indicator when it is added to the remaining solution after
electrolysis.

12. This graph represents the relation between the mass of


metal (M) deposited on the cathode, and the quantity of
electricity passed in the solution of its ions :

(1) Calculate the number of (M) moles deposited on the cathode


after passing 600 C in the solution, knowing that the gram
equivalent mass of (M) is 63.5 g

(2) How much electricity is required to deposit 1 g of metal (M) ?

Deposited mass of metal (M) (g)


Test ? on lesson Five Chapter 4

First Choose the correct answer for the questions 1:10

1.These opposite figures illustrate two experiments for the electrolysis of CuSO 4 solution.

What are the two electrodes on which copper will deposit ?

a. (1) and (2).

b. (1) and (3).

c. (2) and (4).

d. (3) and (4).

2. Which of the following shows the results of the electrolysis of copper (II) sulphate solution by using
copper electrodes ?

Choices Positive electrode Negative electrode Intensity of the colour of the electrolyte
a. Its mass decreases Its mass increases Remains constant
b. Its mass decreases A gas evolves at it Decreases
c. A gas evolves at it Its mass increases Decreases
d. A gas evolves at it A gas evolves at it Remains constant
3. The opposite figure illustrates the electrochemical cell used in an attempt to plate an iron key with
a layer of copper, this attempt was unsuccessful. What is the change which must be done for this
attempt to be successful?

a. Increasing the concentration of the used electrolyte.

b. Increasing the potential difference of the electrical source.

c. Replacing copper (II) sulphate solution with dilute sulphuric acid.

d. Switching the two electrodes of the battery.

4. An electrolysis process was carried out to silver nitrate solution by using


two silver electrodes and an electric current with constant strength. Which graph does represent the

5. The opposite figure shows an experiment for plating a gear in a car engine with a metal. What is the
letter which indicates the gear, and what is the used electrolyte ?
Choices The gear Electrolyte
a. (X) CrCl3
b. (X) CuCl2
c. (Y) CrCl3
d. (Y) CuCl2

(X)

-(Y)

(X)

(Y)

(Y)

6. Which of the following occurs at the positive electrode of

the cell of aluminum extraction?

Choices Al3+ + 3e-→Al 2O2-→O₂+4e- C+O2 →CO2


a. ✓ X X
b. X ✓ X
c. ✓ X ✓
d. X ✓ ✓

7. An electrolytic cell its two electrodes are of copper, and its electrolyte is CuCl 2(aq), after a period of
operation, the mass of the cathode increased by 3.175 g What happens at the anode ?

a. 0.01 mol of Cu2+ is transferred from it to the electrolyte. [Cu=63.5]

b. 0.05 mol of Cu2+ is transferred from it to the electrolyte.

c. 11.2 L of Cl2(g) are evolved at it (at STP).

d. 11.2 L of O2(g) are evolved at it (at STP).

8. Which of the following represents the cell used in extracting aluminum from bauxite ?

Choices E0 Type of the redox Electron movement


reaction direction

Positive Spontaneous From anode to cathode


a.
Positive Spontaneous From cathode to anode
b.
Negative Nonspontaneous From anode to cathode
c.
Negative Nonspontaneous From cathode to anode
d.
9. The following metals are used in electroplating other metals, except………

a. chromium.
b. copper.
c. silver.
d. sodium.

10. During metal purification (electrorefining) processes, the oxidation process occur at…….

a. the anode.
b. the cathode.
c. the electrolyte.
d. the salt bridge.

Second Answer the following essay questions 11, 12

11. Calculate the concentration of silver ions Ag+ [Ag = 108] in 0.25 L solution of it, if they are
completely consumed in electroplating a spoon using 2 A electric current for 2.3 minutes.

12 The given diagram represents the process of purifying copper metal:

(1) What happens to the electrode (A) ?

Write the equation of the reaction occurring at it.

(2) What happens to the silver found in the impure copper electrode ? Explain.

Examination model

on Chapter

Answered

Interactive test

First

Choose the correct answer for the questions 1:27

Which of the following is true for the cell diagram of any galvanic cell ?

The electrode written on the left side represents the cathode.

The electrode written on the right side represents the anode.

◉ The electrode written on the left side represents the positive electrode.

The electrode written on the right side represents the positive electrode.
2 The following table shows the ability of three metals X, Y and Z to react with the salt solutions of other
cations :

Metal

W2+

x2+

v3+

(X)

Aqueous solutions of the cations



(Y)

(Z)

Which of the following indicates the order of the oxidation potentials of these metals ?

Y>W>Z>X

X>W>Z>Y

Y>Z>W> X

X>Z>W>Y

3 A galvanic cell is composed of the two half cells (X) and (Y), the reduction potential of (x) is -1.19 V, and
that of (Y) equals -0.14 V

All the following statements about this cell are correct, except that

the electrode of the half cell (X) undergoes an oxidation process.

the anions of the salt bridge transfer to the half cell of the electrode (Y).

the electrons flowing in the external circuit come from the electrode of the half cell (x).
the electrode of the half cell (Y) undergoes a reduction process.

4 Which of the following equations represents a reduction process ?

Fe2+ + e
Fe2+

Fe3+

Fe3+ + e

Fe3+ + Fe2+

Fe3+ Fe6++3e

5 In terms of the following ionic reactions:

(1) Z+X2+22+ + X

(2) Z+2W+Z2+ + 2W

(3) X + 2W+X2+ + 2W

(4) Y+Z2+Y2+ + Z

What is the correct order of the activities of these metals ?

Choices

The most active

The least active

X
Y

The following processes are spontaneous, except

Zn(s) + 2H(aq) Znaq) + H2(g)

Cu(s) + Fe 2+ 2+ Cu) + Fe(s)

Fe(s) + 2Ag(aq) -Feq) + 2Ag(s) (aq)

Zn(s) + Pba) (aq)

Zn2+ n(aq) + Pb(s)

7 Which of the following statements about the cells of energy production is more accurate ?

All fuel cells are galvanic.

All galvanic cells are primary.

Some secondary cells do not store energy.

Some fuel cells give emf higher than other galvanic cells.
8 In the opposite figure: A charged car battery (X) is connected to an uncharged battery (Y).

What is the role of the positive


pole of the battery (Y) ?

A cathode and its oxidation potential is -1.69 V

◉ An anode and its oxidation potential is +1.69 V

◎ A cathode and its oxidation potential is +1.69 V

④ An anode and its oxidation potential is -1.69 V

BATTERY

Battery (X)

BATTERY

Battery (Y)

Which of the following figures represents lithium ion battery during discharging?

Anode

Li

Cathode

CoO2

CoO2

Cathode

e-

Anode

Li

Li in graphite

Li in graphite

Anode

Li in graphite

Li

Cathode

CoO2

Anode

Li
Cathode

CoO2

Li in graphite

10 Regarding these statements:

(1): Equal volumes of H, and O, gases are consumed in it.

(2): It is environment friendly.

(3): Hydrogen gas is being reduced in it.

(4): The reactants used in it are gases (at STP).

Which of these statements describe a fuel cell ?

(1) and (2).

(1) and (3).

(2) and (4).

(3) and (4).


11 The following figures show an experiment to investigate the rate of iron rusting at different
conditions:

Oxygen

Water + Table salt

(1)

Boiled distilled water

Air

(2)

Oxygen

Water

Water

(3)

(4)

Which of the following arrangements represents the descending graduation in the rate of the nail
rusting ?

4
1

12 To convert 1 mol of each of lead and lead dioxide into lead (II) sulphate in lead accumulator, it
requires an amount of dil. sulphuric acid equals

1 mol

2 mol

3 mol

4 mol

13 A steel reservoir was connected to a piece of copper, and another steel reservoir was connected to a
piece of magnesium, and they were both buried under soil:

Piece of copper

Steel reservoir (X)

Steel reservoir (Y)

Piece of magnesium

Which of the following represents the reactions occurring at these two reservoirs ?

Choices

Reservoir (X)

Reservoir (Y)

Cu Cu2+ + 2e

Fe Fe2+ + 2e

Fe Fe2+ + 2e

Fe →Fe2+ + 2e

Fe Fe2+ + 2e

Mg Mg2+ + 2e

Cu Cu2+ +2e

MgMg2+ + 2e
14 The experiment illustrated in the opposite figure was conducted and left for 10 days.

(X)

(Y)
Galvanized iron

Pure iron

Water

Air

What happens to the level of water surface in each of the two tubes (X) and (Y) ?

Choices

Tube (X)

Goes down

Does not change

Rises up

Rises up

Tube (Y)

Rises up

Does not change

Goes down

Does not change

15 Calcium can be extracted through

the reduction of CaCl, by using Cu

the oxidation of CaCl, by air.

the electrolysis of CaCl, melt.

the electrolysis of CaCO3 solution.

16 Which of the following figures shows the suitable conditions for iron rusting, as well as the sacrifying
electrode connected to it?

02(g) Copper Iron

O2(g)+H2O(l) Copper Iron

O2(g)+H2O(v)

-Magnesium Iron

-O2(g)+H2O(l)
Magnesium

Iron
✔ During the electrolysis of a dilute solution of H2SO4, the following reactions occur at the two
electrodes:

4OH(aq)

-O2(g) + 2H2O(0+4e

4H(aq) +4e-

2H2(g)

What is the ratio between the mass of the evolving gas at the cathode and that of the evolving gas at
the anode ?

[H=1,016]

16

1 16

18 Which of the following statements represents the movement of the anions in the electrolytic solution
?

◉ They move towards the cathode in the electrolytic cell, and towards the anode in the galvanic cell.

They move towards the cathode in the galvanic cell, and towards the anode in the electrolytic cell.

They move towards the cathode in both the electrolytic and the galvanic cells.

They move towards the anode in both the electrolytic and the galvanic cells.

19 Two electrolytic cells connected in series, the electrolyte of the first cell is iron (III) chloride solution,
and that of the second cell is iron (II) chloride solution. What is the ratio between the two masses of iron
deposited at the two cathodes ?

[Fe=55.86]

23

20 What is the quantity of electricity required to deposit 1 mol of the metal (M) in a solution containing
M2+ ions ?

0.5 F

1F

2F

96500 F
21 On passing an electric current with 2 A intensity for 5 h in metal (M) salt melt, 22 g of metal (M) [M =
177] were deposited. What is the oxidation number of the ion of (M) in this salt ?

+1

+2

+3

+4
22 In the experiment shown in the opposite figure: Drops of sodium hydroxide solution are added in
excess to aluminum sulphate solution. Which of the following graphical figures represents the relation
between the ammeter reading and the added volume of sodium hydroxide

Burette-

during the experiment ?

Ammeter reading (A)

Ammeter reading (A)

NaOH volume (mL)

NaOH volume (mL)

NaOH solution

Two graphite electrodes

Aluminum sulphate solution

Ammeter reading (A)

Ammeter reading (A)

NaOH volume (mL)

NaOH volume (mL)

24 If the reduction potentials of (Ag+, Cu2+, Pb2+ and Zn2+) are (+0.80 V, +0.34 V, -0.126 V and -0.76 V)
respectively, so when the metal (A) is immersed in solution (C), it is covered with a layer of the metal (B).
Which of the following represents each of (A), (B) and (C)?

Choices

(A)

Ag

Cu

Pb

Pb

(B)

(C)

Pb

Zn

Pb(NO3)2
ZnSO4

Zn

ZnSO4

Cu

CuCl2

24 What is the quantity of electricity required to convert 1 mol of MnO into 1 mol of Mn2+?

96500 C

5 x 96500 C

3 x 96500 C

7 x 96500 C
25 The shown figure illustrates the electrolytic cell of the extraction of aluminum from bauxite ore.
Which of the following identifies each of (X), (Y) and (Z) ?

(x)

(Y)

Choices

(X)

(Y)

(z)

(Z)

Negative electrode

Aluminum oxide + Cryolite

Aluminum

Negative electrode

Cryolite

Aluminum oxide

Positive electrode

Aluminum oxide

Cryolite

Positive electrode

Aluminum oxide + Cryolite

Aluminum

26 What are the metals which can be deposited by electrolysis in a solution containing Na+, Cu2+, Mg2+
and Ag+ ions ?

Na, Cu, Mg and Ag

Cu and Mg

Na and Cu

Cu and Ag

27 The following figures illustrate two electrolytic cells containing copper (II) chloride solution as an
electrolyte :

Graphite anode
Graphite cathode

Impure copper anode

Pure copper cathode

Copper (II) chloride solution

Cell (1)

Cell (2)

Copper (II) chloride solution

What is the change in the mass of the anode of each cell ?

Choices

Cell (1)

Cell (2)

Decreases

Decreases

Does not change

Does not change

Increases

Does not change

Does not change

Decreases
Second Answer the following essay questions 28: 30

28 From the shown figure and the given

metals:

• Silver.
• Zinc.

• Iron.

Lead.

Select the metals of the electrodes and which give together the brightest light for the lamp, with
explanation.

Electrode (1)

2Na SO

Bulb

Electrode (2)

Salt bridge

29 This reaction is nonspontaneous :

Cu(aq) + 2Cl(aq) → Cu(s) + Cl2(g)

Ecell = -1.02 V

(1) Why is this reaction nonspontaneous ?

(2) Use the substances of this reaction to write an equation representing a spontaneous reaction.

30 Iron can be galvanized by two methods, one of them is the electrolysis as shown in the figure:

(1) Specify the substance of:

(i) Electrode (X).

Electrode (X)

Electrode (Y)

(ii) Electrode (Y).

Zinc chloride melt

(2) What is the other method which can be used in iron galvanization ?

====== ****
Questions of the experimental tests and the exams of the previous years until 1st session 2023

?
on Chapter

Answered

First Multiple choice questions (MCQ)

On dipping a magnesium strip in silver nitrate solution, the following reaction is occurred:

Mg(s) + 2AgNO3(aq)

Mg(NO3)2(aq) + 2Ag(s)

Which of the following properly expresses what happens?

Oxidation of magnesium and reduction of silver ions.

(Exp./ June 21)

⑥ Oxidation of magnesium and oxidation of silver.

◉ Reduction of magnesium and oxidation of silver.

Reduction of magnesium and reduction of silver ions.

2 On adding potassium dichromate solution acidified by sulphuric acid to iron (II) sulphate solution, so
the correct equation that expresses

the oxidation reduction reaction is

2+ Fe(aq) + Cr2O3(aq) + 14H(aq)

3+ 3+ Feaq) + 2Craq) +7H2O(l)

6Feaq) + Cr2O7(aq) + 14H(aq)

6Fe (aq) + 2Cr(aq) +7H2O(l) 3+

Feaq) + Cr2O7(aq) +14H(aq)

3+ Fe(aq) + 2Cr(aq) + 7H2O(l)

2+ 6Fe2aq) + Cr2O3(aq) + 14H H(aq)

6Fe(aq) + 2Cr(aq) + 7H2O (l)

3 In the cell in front of you:

(B)

(2nd session 22)

Solution (B)

Solution (A)
(A)

Which of the following is correct?

(1st session 21)

The cell is a galvanic cell, the concentration of solution (A) increases.

The cell is a galvanic cell, the concentration of solution (B) increases.

The cell is an electrolytic cell, the concentration of solution (A) decreases.

The cell is an electrolytic cell, the concentration of solution (B) decreases.


If the following reaction occurs in an electrochemical cell :

Sn(s) + 2Ag(aq) Snaq) + 2Ag(s)

This reaction represents


(2nd session 22)

galvanic cell, the electrons transfer from Ag to Sn

electrolytic cell, the electrons transfer from Sn2+ to Ag

electrolytic cell, the electrons transfer from Ag+ to Sn

① galvanic cell, the electrons transfer from Sn to Ag+

5 Galvanic cell which represented by the following cell diagram:

Ni(s)/Nizaq) // 2Ag(aq)/2Ag(s)

Choose the correct answer to increase time of working this cell

increasing the concentration of silver ions in half cell of cathode.

decreasing the concentration of nickel ions in half cell of anode.

decreasing the mass of anode.

increasing the mass of cathode.

(Exp./ March 23)

6 In the galvanic cell which illustrated by the following diagram :

2+ Zn(s)/Zn2(aq) // Pbaq)/Pb(s)

On adding drops from HCl(aq) to both half cells. Which of the following choices is correct?

(1st session 23)

Increasing conc. of Pb2a) ions. (aq)

emf value for the cell increase.

Time for consuming battery decrease.

✔ Decrease conc of Znaq) ions.

7 On putting a metal (X) in the salt solution YCI₂, the concentration of cations Y2+ is changed from 0.1 M
to 0.01 M Which of the following exist in the solution ?

(15t session 22)

Ions of X2+, Y2+ and Cl

Ions of X2+, Cl only.

Ions of Y2+ and CI, X is precipitated at the bottom of the vessel.

Ions of CI, X and Y are precipitated at the bottom of the vessel.


• Three rods of different elements (A, B and C) are put in HCl(aq), (A) and (B) react,

while (C) doesn't react, when a rod of element (A) is put in a solution contains ions
of element (B), it is corroded. So the arrangement of these elements according to their oxidation
potential is

(Exp./June 21)

A>B>C

B>A>C

C>B>A

A>C>B

⑨ On a rod of an element (A) is placed in a solution of ions of an element (B) If you know that (A) is
divalent, (B) is monovalent. Which of the following is true ?

(15t session 21)

Number of dissolved moles of (A) is double the number of precipitated moles of (B).

⑥ Number of dissolved moles of (A) is half the number of precipitated moles of (B).

Number of dissolved moles of (A) equals the number of precipitated moles of (B).

Number of dissolved moles of (A) is three times the number of precipitated moles of (B).

10 When a piece of zinc is added to diluted sulphuric acid then the evolved gas is passed in four
solutions at the suitable conditions. Which one of the following processes occurs ?

(Exp./ March 23)

YSO4Y2(SO4)3

WCIWC12

X2(SO4)3 XSO4

ZC12ZC13

11 In the following reaction:

MnO2(s) + 4HCl(aq)

MnCl2(aq) + 2H2O(l) + Cl2(g)

(2nd session 21)

The changes that occur are

Mn+/Mn2+, Cl₂/2СГ

Mn++/Mn2+, 2CI/Cl₂

Mn2+/Mn+, 2CI/Cl₂

Mn2+/Mn+ CL/2CI
12 If you know that the element (X) is a divalent element, and it precedes the monovalent element (Y) in
the electromotive series. So the cell diagram which represents the formed cell is

X²+/X // 2Y/2Y

X/X2+ // 2Y/2Y

2Y/2Y+ // x2+/X

2Y/2Y+ // x/x2+

(1st session 22)


13 An electrolytic cell its electrodes made of chromium and platinum, if the standard reduction
potentials as follows:

3+ Cr+3e- (aq) Cr(s) E°=-0.727 V

Pta)+2ePt(s) E° = +1.2 V

The diagram which represents this cell is

(Exp./May 21)

3P)/3Pt(s) // 2Cr(aq)/2Cr(s)

Pt)/Pt) // 2Cr(s)/2Cra)

Cr/Cra) // Pt)/Pt(s)

2Cr(s)/2Cr(aq) // 3Pt(aq)/3Pt(s)

14 If you know that:

K+K

E° = -2.92 V

Cu2+ Cu

E° = 0.34 V

Then the cell diagram which represents the cell formed from the two electrodes

is

(Exp./ June 21)

2K/2K+ // Cu2+/Cu

Cu/Cu2+ // 2K/2K+

Cu2+/Cu° // 2K+/2K°

K+/K° // Cu°/Cu2+

15 If you know that:

-Al Al3+ + 3e E = 1.67 V

Cu2+ + 2e- Cu E = 0.34 V

The diagram of the cell composed of these two electrodes is

A10/Al3+ // Cu2+ / Cu

(2nd session 21)

3Cu/3Cu2+ //2A13+ /2A10


2A1/2A13+ // 3Cu2+/3Cu

Cu2+/Cu// A13+/A10
16 The following two figures are represented two galvanic cells:
1.5 V

(A)

(B)

(C)

2V

(B)

If both (A), (B) divalent, (C) trivalent so the cell diagram for galvanic cell formed from elements (A), (C) is

(1st session 23)

3+ 2+ 2C(s)/2Caq) // 3A2aq)/3A(s)

3A(s)/3A2) //2C3)/2C(s)

2A(s)/2Aaq) // 3C(aq)/3C(s)

2C(s)/2C2aq) // 2Aaq)/2A(s)

17 Cell potential formed from element (X) and standard hydrogen electrode = 0.280 V

cell potential formed from element (X) and element (Y) = 2.095 V

When putting element (Y) in solution of element (X), no reaction takes place. Then the potential of the
cell formed from element (Y) and standard hydrogen electrode equals

(1st session 23)

-2.375 V

2.375 V

1.815 V

-1.815 V

18 A galvanic cell is expressed by the following cell diagram: Fe/Fe2+ // Ni2+ / Niº if:

- Fe(s) Fe2+ Feaq) + 2e-

E +0.409 V

Nizaq) + 2e- Ni (s)

E°=-0.23 V

Then the e.m.f of the cell is

(1st session 21)

1.639 V
0.936 V

0.396 V

0.179 V

19 In the cell whose electrodes are nickel and cadmium, if you know that :

2+

Cd(s) -Cdaq) + 2e

E = +0.402 V

Ni(aq) + 2eNi(s)

E°=-0.23 V

(Exp./ June 21)

Then the value of e.m.f is

-0.632 V

0.632 V

-0.172 V

0.172 V
20 A cell consists of two elements (X) and (Y), the e.m.f of the cell equals 0.94 V and standard oxidation
potential of the element (X) is + 0.136 V, electrons transfer from (X) to (Y) across the wire.
So the oxidation potential of the element (Y) equals

(1st session 22)

+0.8 V

+1.076 V

-0.8 V

-1.076 V

reduction potential of tin = -0.136 V and that of silver = + 0.8 V 21 A galvanic cell its two poles are tin and
silver, if you know that the standard Which of the following represents the spontaneous reduction
reaction in the cell ?

2Ag(aq) + 2e2Ag(s)

E° = + 0.8 V

(1st session 22)

2Ags) 2Ag(aq) + 2e

E° = -1.6 V

2Ag(aq) +2e2Ag(s)

E°=-0.8 V

2Ag 2Ag(aq) + 2e

E = + 1.6 V

22 If you know that:

A A2+ +2e-

B →B++e

E° = 0.409 V

E°=-0.800 V

If a galvanic cell composed of the two elements (A) and (B). Which of the following represents the cell
diagram and the value of e.m.f?

A/A2+ // 2B+/2B

e.m.f 1.209 V

(1st session 21)

2B+/2B // A/A2+

e.m.f = 1.4 V
B+/B// 2A/2A2+

e.m.f0.896 V

2A/2A2+ // B+/B

e.m.f0.879 V

23

Element

(A)

(B)

(C)

(D)

Standard oxidation potential (Volt)

+2.711

+0.28

-1.2

-2.87

The previous table represents the standard oxidation potential of four elements (A), (B), (C) and (D). The
galvanic cell produces the highest e.m.f

is

(Exp./ May 21)

(B) as an anode, (D) as a cathode.

(A) as an anode,

(D) as a cathode.

(D) as an anode, (C) as a cathode.

(D) as an anode, (A) as a cathode.


24 A galvanic cell its electrodes are chromium (Cr) and gold (Au), the oxidation potentials of chromium is
(+0.41 V) and the reduction potential of gold is (+1.42 V) So, the emf value and the cell diagram are

(2nd session 22)


1.83 V, Cr/Cra) // Aug)/Aus)

1.01 V, Au)/Aus) // Cr(s)/Cra

1.83 V, Cray)/Cr) // Aus)/Au)

1.01 V, Au/Au) // Craq)/Cr(s)

PbO2(s) + SO4(aq) + 4H+(aq) + 2Hg() + 2Cl(aq) →Hg2Cl2(s) + PbSO4(s) + 2H2O(l)

If you know: Pb2+/Pb+= -1.69 V Hg/Hg+= -0.59 V

So this reaction is considered

(Exp./ March 23)

non spontaneous and emf = -1.1 V

spontaneous and emf = 1.1 V

non spontaneous and emf = -2.28 V

spontaneous and emf = 2.28 V

20 The following reactions occur in galvanic cells at standard conditions:

X+Y2+ X2+ + Y emf0.351 V

Y+Z2+ Y2+ + Z emf 0.749 V

From the above reactions the value of emf of the following cell equals

Z+X2+ Z2+ + X

-1.1 V

1.1 V

0.398 V

-0.398 V

(Exp./ March 23)

27 In Daniell cell zinc half-cell is replaced by silver half-cell. Which of the following is correct?

En) = 0.76 V, E=-0.8 V (2nd session 22) (Zn) A

The value of e.m.f decreases, the current direction does not change.

The value of e.m.f increases, the current direction changes.

The value of e.m.f decreases, the current direction changes.

The value of e.m.f increases, the current direction does not change.
28 The reaction that occurs at the anode of primary galvanic cell is

Ag2O(s) + Zn(s) ZnO (s) + 2Ag(s)


Zn(s) + 2OH(aq) ZnO (s) + H2O (l) +2e

Ag2O (s) + H2O (l) +2e 2Ag(s) + 2OH(aq)

ZnO (s) + H2O (l) + 2e- → Zn(s) + 2OH(aq)

(2nd session 22)

(1st session 21)

29 The cell diagram for the fuel cell expresses by one of the following

H₂/2H+ // 02/202-

2H₂/4H+ // 02/202-

202/O2 // 2H+/H₂

02/202// 2H₂/4H+

30 The oxidation reduction reactions in the fuel cell lead to

(Exp./ June 21)

transferring of hydroxide ions towards anode.

transferring of hydroxide ions towards cathode.

ⓒ oxygen is converting to hydroxide ion by oxidation.

hydrogen is converting to water molecules by reduction.

1 In the fuel cell, the hydrogen of hydroxide group during the operation of the cell

(2nd session 21)

oxidation takes place for it and it loses 4 electrons.

oxidation takes place for it and it loses 2 electrons.

no oxidation, no reduction takes place for it.

reduction takes place for it and it gains 4 electrons.

32 During operation of fuel cell.

Which one of the following choices is correct?

④ Concentration of electrolyte remains constant.

Decreasing the concentration of electrolyte.

Decreasing the value of pH of electrolyte.

④ Increasing the value of pH of electrolyte.

(Exp./ March 23)


During the discharge process of the lead acid battery.
Which of the following is correct?

(2nd session 21)

The concentration of the acid increases and its density decreases.

The concentration of the acid decreases and its density increases.

The oxidation number of cathode material changes from (+4 to +2).

The oxidation number of anode material changes from (0 to +4).

34 On charging the lead acid accumulator.

All the following occur, except

the concentration of the acid increases.

(1st session 21)

the mass of water decreases.

POH value decreases.

pH decreases.

35 During charging the car battery,

(2nd session 22)

the value of e.m.f of the car battery decreases and the concentration of the acid increases.

the value of e.m.f of the car battery increases and the concentration of the acid decreases.

◉ the negative pole of electrical source is connected to the lead electrode.

the positive pole of electrical source is connected to the lead electrode.

30 On connecting lead accumulator to an external source of electricity its emf = 14 V Which one of the
following choices is correct?

Decreasing the pOH value of electrolyte.

(Exp./ March 23)

Decreasing the pH value of electrolyte.

ⓒ Increasing oxidation number of lead at anode.

Increasing the quantity of water in battery.

In lead acid battery during discharging process the following data are recorded :

The potential of the anode = +0.36 V

The potential of the cathode = +1.69 V


The hydrometer reading = 1 g/cm³

So this battery

(1st session 23)

completely charged and the battery produces 12 volt.

⑥ required to be recharged, and the battery produces 2.05 volt after recharging.

☑ completely charged and the cell produces 12 volt.

required to be recharged, and the cell produces 2.05 volt after recharging.
38 In lithium ion battery, lithium ions transfers through (LiPF) as follow

from the negative anode to the positive cathode during discharging.


(Exp./ June 21)

from the negative anode to the positive cathode during charging.

from the cathode to the anode during discharging.

from the cathode to the anode during charging.

39 In mercury cell and fuel cell. Which of the following is correct?

(15t session 22)

Oxidation for oxygen ions takes place in mercury cell.

Reduction for oxygen ions takes place in fuel cell.

Nither oxidation nor reduction take place for oxygen ions in mercury cell.

Oxidation for oxygen ions takes place in fuel cell.

40 If you know that the electrodes potentials in secondary galvanic battery are:

NiO2 + 2H2O + 2eNi(OH)2 + 2OH

E° = + 0.49 V

Fe(OH)2 + 2e-Fe + 2OH To complete charging of this battery, it must be connect to external source of
electric current its electromotive force equals

E°=-0.88 V

(1st session 22)

2V

1.37 V

220 V

1.3 V

41 The electrolyte which leads to the corrosion of metals with a high rate is

H₂SO₄ (0.5 M).

HCI (0.5 M).

HNO2 (1 M).

H2SO3 (1 M).

(Exp./June 21)

42 From the following table:

Element
Fe

Reduction potential

-0.409 V

-2.375 V

-1.67 V

-0.23 V

You have four pieces from iron, three of them partially plated first by X, second by Y, third by Z and the
fourth one is not plated. Which piece will rust faster ?

First.

Third.

Fourth.

Second.

(Exp./ March 23)


you know that, the oxidation potential of the element (X) = + 0.409 V

If The element that can be used as a cathodic protection for the element (X) is
(1st session 22)

◉ element with standard reduction potential = -0.76 V

element with standard oxidation potential = + 1.03 V

element with standard reduction potential = -0.136 V

④ element with standard oxidation potential = +0.74 V

44 A piece of element (X) is covered by a layer of element (Y), If you know that :

• The standard reduction potential of the element (X = -0.409 V).

• The standard reduction potential of the element (Y = -2.375 V).

Which one of the following expresses this process correctly?

(2nd session 22)

Anodic protection and reduction occurs for the ions of element (X).

Anodic protection and reduction occurs for oxygen of humid air.

◎ Cathodic protection and reduction occurs for oxygen of humid air.

Cathodic protection and reduction occurs for the ions of element (X).

The following table illustrates the standard reduction potentials of the elements W, X, Y and Z:

The element

(W)

(X)

(Y)

(Z)

Reduction potential

-2.37 V

-0.25 V

-0.74 V

-1.66 V

(2nd session 21)

One of the following choices expresses anodic protection,................

① the element (Y) is plated by element (Z).

the element (Y) is plated by element (X).


the element (W) is plated by element (Z).

the element (W) is plated by element (X).

46

Element

Reduction potential

-1.66

-2.37

+0.799

-1.26

The previous table represents reduction potential for four elements (A, B, C and D). Which of the
previous metals can be used as a sacrifying electrode for another element ?

(Exp./ May 21)

C for A

C for D

B for A

A for B
47 The standard reduction potential for elements (X), (Y) and (Z) as shown in the following table:

Element

(X)
(Y)

(Z)

Standard reduction potential

-0.28 V

+1.2 V

-1.029 V

Which of the following coatings is the most corrosive for coated metal when scratching ?

(1st session 23)

Plating element (X) by element (Z).

Plating element (Z) by element (Y).

Plating element (Y) by element (X).

Plating element (X) by element (Y).

48 To protect the element (A) form corrosion by using element (B). Which of the following occurs ?

(1st session 21)

Withdrawing of electrons from (A) to (B) and it represents anodic protection.

Withdrawing of electrons from (B) to (A) and it represents anodic protection.

Transferring of electrons to the element (A) and it represents cathodic protection.

Transferring of electrons between the elements (A), (B) and (A) represents sacrifying electrode.

If the amount of electricity required to precipitate the equivalent mass of a metal equals the amount of
electricity needed to precipitate one mole of it. Which of the following correctly represents this
process ?

(1st session 21)

A mole of metal ion gains a mole of electrons.

A mole of metal ion loses a mole of electrons.

A mole of metal ion gains 2 moles of electrons.

A mole of metal ion loses 2 moles of electrons.

50 To precipitate 10 g of element (A) according to the equation:

A2+ +2e-

A
The quantity of electricity =

[A=63.5) (Exp./ June 21)

0.315 F

0.675 C

15196 C

30393 F

The quantity of electricity that required to evolve 1.204 × 1023 molecules of oxygen gas on electrolysis
of acidified water is

0.8 F

0.4 F

9650 C

19300 C

(1st session 22)


The amount of electricity in faraday required to precipitate 0.5 g of gold on a metallic medal by
electrolysis according to the equation Au³+ + 3e equals Au [Au=196.98) (2nd session 21)

2.53 x 10m³ F
7.61 F

7.61 x 103 F

2.53 F

On passing a quantity of electricity 5000 C in aqueous solution of (X) chloride, 3.4 g of the element (X) is
deposited.

The equivalent mass of the element (X) equals

(2nd session 22)

32.8 g

65.6 g

98.4 g

196.9 g

On passing a quantity of electricity through molten magnesium nitride, 48 g from magnesium is ppt. at
cathode. So the volume of nitrogen gas evolve (at STP) at anode is

14.93 L

[N=14. Mg=24) (1st session 23)

22.4 L

44.8 L

33.6 L

The opposite figure represents an analytical cell for molten iron (III) oxide when 10 amperes passed for
two hours through the molten iron (III) oxide, the volume of evolved gas at anode (at STP) is

Pr

Pr

8.34 L

(Exp/May 21)

16.68 L

Molten iron (III) oxide

12.51 L

4.17 L
55.The quantity of electricity that required to evolve 1.204 × 1023 molecules of oxygen gas on
electrolysis of acidified water is…..(1st session 22)

a. 0.8 F

b. 0.4 F

c. 9650 C

d. 19300 C

56. The following reaction occurs in an electric cell :

Ni0(s) + 2Ag+(aq)→Ni2+(aq) + 2Ag0(s)

If you know that:

• Ni0(s)→ Ni2+(aq) + 2e- E = +0.23 V

• 2Ag+(aq) + 2e- →2Ag0(s) E° = + 0.8 V

Which of the following is correct? …….(2nd session 21)

a. The cell is electrolytic, e.m.f = -1.03 V

b. The cell is galvanic, e.m.f = 1.03 V

c. The cell is galvanic, e.m.f = 0.564 V

d. The cell is electrolytic, e.m.f = -0.564 V

57. In the cell whose electrodes are iron and tin, if you know that:

• Fe(s)→ Fe2+(aq)+2e-, E = 0.409 V

• Sn2+(aq) + 2e-→Sn(s), E = 0.150 V

Which of the following is correct? ….(2nd session 21)

a. Iron is the anode, and the value of e.m.f of the cell is positive.

b. Iron is the cathode, and the value of e.m.f of the cell is negative.

c. Tin is the anode, and the value of e.m.f of the cell is positive.

d. Tin is the cathode, and the value of e.m.f of the cell is negative.

58. In the opposite diagram:

Cell (1): Contains molten sodium chloride.

Cell (2): Contains aqueous solution of sodium chloride.

An electrolysis process is made for both of them, the substances formed at the electrodes (X, Y, Z and
L) are …..(Exp./ May 21)
Choices (X) (Y) (Z) (L)
a. H2 Cl2 Na Cl2
b. Cl2 Na H2 O2
c. Cl2 Na Cl2 H2
d. Cl2 Na Na Cl2
59. The following equations represents the reactions of two half electric cells :

• 2Ni³+ + 2e- →2Ni2+ E° = +0.898 V

• Cd2+ +2e- →Cd0 E° = -0.402 V

Then the nonspontaneous oxidation reaction which occurred in the cell is …..(1 st session 23)

Cd0 →Cd2+ + 2e- E° = + 0.402 V

2Ni2+→2Ni³+ + 2e- E°=-0.898 V

Cd2+ +2e- →Cd0 E°=--0.402 V

2Ni³+ + 2e- →2Ni2+ E° = + 0.898 V

60. In plating a metallic object by using a pure gold rode immersed in a solution of gold (III) chloride
AuCl3. Which of the following represents what occurs to mass of anode and the reaction at
cathode ?.... (Exp./ May 21)

Choices Mass of anode Reaction at cathode


a. Does not change 3Cl₂+6e-→6Cl-
b. Increases 2Au0→2Au³++6e+
c. Decreases 6Cl-→3Cl₂+6e-
d. Decreases 2Au³++6e+→2Au0
61. By using electrode potential from the following table:

Element A C B
Oxidation potential +0.52 V +0.12 V -0.34 V
To purify metal its reduction potential 0.8 V, the electrolytic cell is connected to galvanic cell consists
of…..(Exp./ March 23)

a. A and C and impure metal connected by A

b. B and C and pure metal connected by C

c. B and A and pure metal connected by B

d. A and C and impure metal connected by C

.62In the purification cell of chromium contains impurities (X) and (Y) we notice that precipitations of
(X), (Y) in the bottom if beacker after complete purification, and the colour of (X) salt solution is
changed on adding element (Y) to it. The right arrangement of oxidation potential (Cr), (Y) and (X) is....
(1st session 23)

a. Y<Cr <X
b. Y<X<Cr

c. X<Cr<Y

d. X<Y<Cr

Second: Essay question

.63When amount of electricity passing through two cells connected in series.

The first cell contains Pb(NO3)2, then 8.28 g of lead precipitated, while in the second cell the reaction
X4+ + 3e- →X+ takes place.

Calculate the number of moles which formed from X+ . [Pb=207] (Exp./ March 23)

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