DPP

For
Chemical Kinetics
12th JEE
1 If the concentration of H2O2 changes from 0.5 M to
0.05 M in 15 sec, then calculate
(i) Rate of reaction (ii) Rate of appearance of O2
H 2O 2 → H 2O + ½ O 2
2 For the following reaction, a curve for conc. v/s
time is given below. 2NH3 → N2 + 3H2.
Calculate the rate of reaction in the interval of 5-15
sec.
3 For the following reaction, some parameters are
given.
-d[N2O5]/dt = K1[N2O5]
+d[NO2]/dt = K2[N2O5]
+d[O2]/dt = K3[N2O5]
Find the relation between K1, K2 and K3
N2O5(g) → 2NO2(g) + ½O2(g)
4 The molar conductivities at infinite dilution of KCl,
HCl and CH3COOK are 130.1, 379.4, 95 mho
cm2/mol respectively. Calculate molar conductivity
at infinite dilution of CH3COOH.

A 154.3

B 604.5

C 344.3

D 414.5
5
K
For a chemical reaction A → B, it is found that the
rate doubles when the conc. of A is increased 4
times. Find the order of the reaction.
6 Calculate order of the following reaction.
2NO(g) + 2H2(g) → N2(g) + 2H2O(g)
7
A zero order reaction is 20% completed in 10 min.
At what time, it will be 80% completed ?
8
A first order reaction is 75% completed in 100 min.
Calculate the time taken for 87.5% completion.
9
For an elementary reaction, X → Y + Z, t1/2 = 10
min. In what period of time, would the conc. of X be
reduced to 10% of original value ?
10 An organic compound undergoes first order
decomposition. The time taken for its
decomposition to 1/8 and 1/10 of its initial
concentration are t1/ 8 and t1/10 respectively. What is
the value of (t1/8/t1/10)x10 ? (log102 = 0.3)
11 For a first order reaction, choose the correct value
of half-life (t1/2).
(a) 0.3 min (b) 0.6 min
(c) 0.8 min (d) NOTA
12 A FOR reaction has a half life of 1 min. The time
required for 99.9% completion of the reaction is X
min. Determine X (Round off to the nearest
integer) [ln 2 = 0.69, ln 10 = 2.3]
13
What amount of reactant for first order reaction will
be left after 3.5 min ? Take ln 2 = 0.7.
14 In what time will the molar ratio of ethylene to
cyclobutane be 1.
C4H8 → 2C2H4 K = 2.3 × 10-4 s-1
15
Calculate the activation energy of reaction in
(i) kJ/mol (ii) kcal/mol
16
The rate constant of a reaction at 227oC and 427oC
are 0.02 s-1 and 0.2 s-1. Calculate the activation
energy of reaction.
17
The standard reduction electrode potential values
of elements A, B, C are +0.68, -2.50, and -0.50 V
respectively. The order of their reducing power is

A A>B>C

B A>C>B

C C>B>A

D B>C>A
18 In an electrochemical reaction of lead, at standard
temperature, if E0(Pb2+/Pb) = m Volt and
E0(Pb4+/Pb) = n Volt, then the value of
E0(Pb2+/Pb4+) is given by m - xn. The value of x is_.
19
Which one of the following statements is correct for
electrolysis of brine solution?

A O2 is formed at cathode

B H2 is formed at anode

C Cl2 is formed at cathode

D OH- is formed at cathode

20
The resistivity of a 0.8 M solution of an electrolyte
is 5 × 10-3𝛺cm. Its molar conductivity is _____×
104𝛺-1 cm2 mol-1
Answer Key Ques. No. Answer Ques. No. Answer
1 0.015 11 0.3 min
mol/L/Sec

2 0.02 12 10
mol/L/sec

3 4 K3 13

4 C 14 1700 s

5 1/2 15 2.303

6 2 16 700 J

7 40 min 17 D

8 150 min 18 2

9 33 min 19 D

10 9 20 25
1
Solution:

Part (i)
1
Solution:

Part (ii)
2
Solution:
3
Solution:
4
Solution:
5
Solution:
6
Solution:
7
Solution:
8
Solution:
9
Solution:
10
Solution:
11
Solution:

Slope = -k / 2.303
tan 135O = -k / 2.303
-1 = -k / 2.303
k = 2.303 min-1
12
Solution:
13
Solution:

Slope = -k
tan 135O = -k
-1 = -k
k =1 min-1
14
Solution:
15
Solution:

Slope = -Ea / 2.303 R

-3 = -Ea / 2.303 R
16
Solution:
17
Solution:

More is the reduction potential, more is the power to get

itself reduced or lesser is reducing power or greater is
oxidising power.
18
Solution:
19
Solution:
20
Solution: