EE857 - Lecture3 - Surface Plasmons at Metal-Dielectric Interface
EE857 - Lecture3 - Surface Plasmons at Metal-Dielectric Interface
EE857 - Lecture3 - Surface Plasmons at Metal-Dielectric Interface
Lecture 3
Wave?
• From Introduction to Electrodynamics by Griffiths:
“A wave is a disturbance of a continuous medium that
propagates with a fixed shape at constant velocity.”
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Wave Equation
• Wave equation:
𝜕2𝑓 1 𝜕2𝑓
2
= 2 2
𝜕𝑥 𝑣 𝜕𝑡
• General solution:
𝑓 𝑥, 𝑡 = 𝑔 𝑥 − 𝑣𝑡 + ℎ 𝑥 + 𝑣𝑡
• 3D wave equation:
2
2
1 𝜕 𝑓
𝛻 𝑓= 2 2
𝑣 𝜕𝑡
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Example: Sinusoidal Waves
𝜔
𝑓 𝑥, 𝑡 = 𝐴0 sin(𝑘𝑥 − 𝜔𝑡) = 𝐴0 sin 𝑘 𝑥 − 𝑡
𝑘
• Amplitude: 𝐴0
2𝜋
• Wavenumber: 𝑘 = 𝑓
𝜆
𝐴0
2𝜋
• Frequency: 𝜔 =
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𝑘𝑥, 𝜔𝑡
𝜔
• Phase velocity: 𝑣 =
𝑘
4
Phase Velocity vs Group Velocity
• Two sinusoidal waves with different 𝑘 and 𝜔:
𝑓1 𝑥, 𝑡 = 𝐴0 sin 𝑘1 𝑥 − 𝜔1 𝑡
𝑓2 (𝑥, 𝑡) = 𝐴0 sin(𝑘2 𝑥 − 𝜔2 𝑡)
2 2
𝑘1 + 𝑘2 𝜔1 + 𝜔2
× sin 𝑥− 𝑡
2 2
Δ𝑘 Δ𝜔
= 2𝐴0 cos 𝑥− 𝑡 sin 𝑘ത 𝑥 − 𝜔𝑡
ഥ
2 2
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Phase Velocity vs Group Velocity
Δ𝑘 Δ𝜔
𝑓1 𝑥, 𝑡 + 𝑓2 𝑥, 𝑡 = 2𝐴0 cos 𝑥− 𝑡 sin 𝑘ത 𝑥 − 𝜔𝑡
ഥ
2 2
Oscillation
Envelope
• Fixed phase point moves with speed 𝑣ph = 𝜔/ ത
ഥ 𝑘.
• By taking the limit Δ𝑘 → 0, the phase velocity and the group velocity
at a specific frequency are defined as
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𝜔 𝜕𝜔
𝑣ph = , 𝑣𝑔 =
𝑘 𝜕𝑘
• Examples:
𝑣ph = 2𝑣𝑔 ↓ 𝑣ph < 0, 𝑣𝑔 > 0 →
Wikipedia
6
Dispersion Relation
• Dispersion relation relates the wavenumber(𝑘) of a wave to its
frequency (𝜔).
• Linear dispersion (ex. electromagnetic waves in vacuum):
𝜔 = 𝑐𝑘
𝑣𝑔 = 𝑐 = 𝑣ph
Velocity does not depend on 𝜔
• Quadratic dispersion (ex. nonrelativistic De Broglie waves):
𝜔 = 𝑐𝑘 2
𝜕𝜔
𝑣𝑔 = = 2𝑐𝑘 = 2 𝑐𝜔 = 2𝑣ph
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𝜕𝑘
• Square-root dispersion (ex. deep water waves):
𝜔=𝑐 𝑘
𝜕𝜔 𝑐 𝑐2 𝑣ph
𝑣𝑔 = = = =
𝜕𝑘 2 𝑘 2𝜔 2
7
Dispersion Relation
• Negative group velocity is also possible. For example,
𝑐 𝑐 𝜔2 𝑐
if 𝜔 = , then 𝑣𝑝ℎ = = > 0 and 𝑣𝑔 = − = −𝑣ph < 0.
𝑘 𝑘2 𝑐 𝑘2
𝑘2 𝑘
𝑘 −1
𝑘
𝜔
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𝑘
8
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Intro: Radio Wave Frequencies (RF)
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Intro: Microwaves
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Intro: Infrareds
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Intro: Visible Light
𝛻 ⋅ 𝜖𝐄 = 𝐄 ⋅ 𝛻𝜖 + 𝜖𝛻 ⋅ 𝐄 = 0
2
𝐄 2
𝜕 𝐄
𝛻 − ⋅ 𝛻𝜖 − 𝛻 𝐄 = −𝜇0 𝜖0 𝜖 2
𝜖 𝜕𝑡
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Electromagnetic Wave Equation
• For slowly varying 𝜖(𝐫) (i.e., 𝜖(𝐫) is nearly constant over
distances on the order of optical wavelength),
2
2
𝜖 𝜕 𝐄
𝛻 𝐄= 2 2
𝑐 𝜕𝑡
• Similarly,
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2𝐇
𝜖 𝜕
𝛻2𝐇 = 2 2
𝑐 𝜕𝑡
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Monochromatic Plane Waves
• Monochromatic plane waves propagating along 𝐤:
𝐄 = 𝐄0 𝑒 𝑖(𝐤⋅𝐫−𝜔𝑡)
𝐇 = 𝐇0 𝑒 𝑖(𝐤⋅𝐫−𝜔𝑡)
𝜔 2 𝑛
𝐤 2 =𝜖 →𝑘= 𝜔
𝑐 𝑐
𝑘 = 𝐤 = 2𝜋/𝜆: wavenumber
𝑛 = 𝜖: refractive index
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Properties of Plane Waves
• From Maxwell’s equations (for isotropic and homogeneous 𝜖),
𝛻⋅𝐃=0↔𝐤⋅𝐄=0
𝛻⋅𝐁=0↔𝐤⋅𝐇=0
𝜕𝐁
𝛻×𝐄=− ↔ 𝐤 × 𝐄 = 𝜔𝜇0 𝐇
𝜕𝑡
𝜕𝐃
𝛻×𝐇= ↔ 𝐤 × 𝐇 = −𝜔𝜖0 𝜖𝐄
𝜕𝑡
• Direction of 𝐄 and 𝐇 fields are perpendicular to 𝐤
• 𝐄 and 𝐇 fields are perpendicular to each other
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Properties of Plane Waves
• Poynting’s theorem:
𝜕𝑢
− =𝛻⋅𝓢+𝐉⋅𝐄
𝜕𝑡
Energy Rate of work done
Rate of
flux (0 for lossless media)
energy
transfer
• Energy density (lossless and non-dispersive media)*:
1 1 2
1
𝑢 = 𝐄⋅𝐃+𝐁⋅𝐇 = 𝜖𝜖0 𝐄 + (𝐤 × 𝐄) ⋅ 𝐇
2 2 𝜔
1 1
= 𝜖𝜖0 𝐄 − (𝐤 × 𝐇) ⋅ 𝐄 = 𝜖𝜖0 𝐄 2
2
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2 𝜔
• Poynting vector:
𝐄 × (𝐤 × 𝐄) 𝐄 𝟐𝐤 − 𝐄 ⋅ 𝐤 𝐄 𝐄 𝟐𝐤 𝑐
𝓢 =𝐄×𝐇= = = = መ
𝑢𝐤
𝜔𝜇0 𝜔𝜇0 𝜔𝜇0 𝑛
* For dissipative and dispersive media, the expression for 𝑢 should be modified.
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Electromagnetic Power Flow
• Time derivative of electromagnetic energy density 𝑤
𝜕𝑢 1 𝜕 𝜕𝐃 𝜕𝐁 𝐃 = 𝜖𝐄
= 𝐄⋅𝐃+𝐇⋅𝐁 =𝐄⋅ +𝐇⋅ 𝑩 = 𝜇𝐇
𝜕𝑡 2 𝜕𝑡 𝜕𝑡 𝜕𝑡
= 𝐄 ⋅ (𝛻 × 𝐇 − 𝜎𝐄) + 𝐇 ⋅ (−𝛻 × 𝐄) Ampere’s law and Faraday’s law
= −𝜎𝐸 2 + 𝐄 ⋅ 𝛻 × 𝐇 − 𝐇 ⋅ (𝛻 × 𝐄)
= −𝜎𝐸 2 − 𝛻 ⋅ (𝐄 × 𝐇)
Poynting vector:
= −𝜎𝐸 2 − 𝛻 ⋅ 𝓢 𝓢=𝐄×𝐇
• Poynting’s theorem:
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𝜕𝑢 Divergence
− = 𝜎𝐸 2 + 𝛻 ⋅ 𝓢
𝜕𝑡 theorem
𝜕
− න 𝑢 𝑑𝑣 = න 𝜎𝐸 2 𝑑𝑣 + ර 𝓢 ⋅ 𝑑𝐒
𝜕𝑡 𝑣 𝑣 𝑆
Rate of decrease Ohmic power Net outward
in stored energy dissipated power flux
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Electromagnetic Power Flow
• Time-average Poynting vector:
1 𝑇 1 2𝜋
𝓢 = න 𝓢𝑑𝑡 = Re 𝐄 𝐫 × 𝐇 ∗ 𝐫 𝑇=
𝑇 0 2 𝜔
Proof:
𝓢 𝐫, 𝑡 = 𝐄 𝐫, 𝑡 × 𝐇 𝐫, 𝑡 = Re{𝐄 𝐫 𝑒 −𝑖𝜔𝑡 } × Re{𝐇 𝐫 𝑒 −𝑖𝜔𝑡 }
1 1
= 𝐄 𝐫 𝑒 −𝑖𝜔𝑡 + 𝐄 ∗ 𝐫 𝑒 𝑖𝜔𝑡 × 𝐇 𝐫 𝑒 −𝑖𝜔𝑡 + 𝐇 ∗ 𝐫 𝑒 𝑖𝜔𝑡
2 2
1
= 𝐄 𝐫 × 𝐇∗ 𝐫 + 𝐄 ∗ 𝐫 × 𝐇 𝐫 + 𝐄 𝐫 × 𝐇 𝐫 𝑒 −2𝑖𝜔𝑡 + 𝐄 ∗ 𝐫 × 𝐇 ∗ 𝐫 𝑒 2𝑖𝜔𝑡
4
1 1
= Re 𝐄 𝐫 × 𝐇 ∗ 𝐫 + Re 𝐄 𝐫 × 𝐇 𝐫 𝑒 −2𝑖𝜔𝑡
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2 2
1 𝑇1 1 1
𝓢 = න Re 𝐄 𝐫 × 𝐇 ∗ 𝐫 + Re 𝐄 𝐫 × 𝐇 𝐫 𝑒 −2𝑖𝜔𝑡 𝑑𝑡 = Re 𝐄 𝐫 × 𝐇 ∗ 𝐫
𝑇 0 2 2 2
• Total time-average power crossing a surface 𝑆:
𝓢 : time averaged Poynting vector
𝑃 = න 𝓢 ⋅ 𝑑𝐒
𝑆 𝑑𝐒: difference surface element
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Dispersion Relations
• Free space (𝜖 = 1):
𝜖
𝑘= 𝜔 → 𝜔 = 𝑐𝑘
𝑐
• Silica (𝜖 ≈ 2):
𝜖
𝑘= 𝜔 → 𝜔 ≈ 0.7𝑐𝑘
𝑐
2
𝜔𝑝
• Metal (𝜖(𝜔) ≈ 1 − ):
𝜔2
𝜔 𝜔𝑝2
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𝑘= 1 − 2 → 𝜔2 = 𝜔𝑝2 + 𝑐 2 𝑘 2
𝑐 𝜔
- Slow group velocity 𝑣𝑔 < 𝑐
- Long wavelength 𝑘 > 𝑘0
- Asymptotically approaches to light line as 𝜔 → ∞
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Dispersion Relations
Metal
𝜔2 ≈ 𝜔𝑝2 + 𝑐𝑘 2
Air
𝜔 = 𝑐𝑘
𝜔
𝜔𝑝 SiO2
𝜔 ≈ 0.7𝑐𝑘
*the dielectric function
of silica is assumed to
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be non-dispersive.
𝑐
𝑘
𝜔𝑝
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Bound Waves at Metal-Dielectric Interface
𝜖𝑑 > 0
𝜔𝑝2
𝜖𝑚 =1− 2
𝜔
• Wave solution:
𝐄 𝐄0 𝑖(𝑘 𝑥+𝑘 𝑦+𝑘 𝑧−𝜔𝑡) 2 𝜔 2
= 𝑒 𝑥 𝑦 𝑧 , 𝑘𝑥 + 𝑘𝑦2 + 𝑘𝑧2 = 𝜖
𝐇 𝐇0 𝑐
• Propagation along 𝑥 direction with propagation constant 𝑘𝑥 = 𝛽
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𝑥 𝑦 𝑧
• Bound waves have longer wavevector (shorter wavelength)
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𝜕𝐸𝑦 𝜕𝐻𝑦
= −𝑖𝜔𝜇0 𝐻𝑥 = 𝑖𝜔𝜖0 𝜖𝐸𝑥
𝜕𝑧 𝜕𝑧
𝜕𝐸𝑥 𝜕𝐻𝑥
− 𝑖𝛽𝐸𝑧 = 𝑖𝜔𝜇0 𝐻𝑦 − 𝑖𝛽𝐻𝑧 = −𝑖𝜔𝜖0 𝜖𝐸𝑦
𝜕𝑧 𝜕𝑧
𝑖𝛽𝐸𝑦 = 𝑖𝜔𝜇0 𝐻𝑧 𝑖𝛽𝐻𝑦 = −𝑖𝜔𝜖0 𝜖𝐸𝑧
27
TE Modes?
• Transverse electric (TE) polarization (𝐸𝑥 = 0):
1 𝜕𝐸𝑦
𝐻𝑥 = 𝑖
𝜔𝜇0 𝜕𝑧
𝛽
𝐻𝑧 = 𝐸𝑦
𝜔𝜇0
• Ansatz:
𝐴1 𝑒 𝛾1𝑧 𝑒 𝑖(𝛽𝑥−𝜔𝑡) (𝑧 < 0)
𝐸𝑦 = ൝
𝐴2 𝑒 −𝛾2 𝑧 𝑒 𝑖(𝛽𝑥−𝜔𝑡) (𝑧 > 0)
• Boundary conditions (𝑧 = 0):
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(𝐸1 )𝑦 = 𝐸2 𝑦 and 𝐵1 𝑥 = 𝐵2 𝑥
→ 𝐴1 = 𝐴2 and 𝛾1 = −𝛾2
• No surface wave, since confinement to the surface requires
Re 𝛾1 > 0 and Re 𝛾2 > 0.
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Surface Plasmons at a Single Interface
• Transverse magnetic (TM) polarization (𝐻𝑥 = 0):
1 𝜕𝐻𝑦
𝐸𝑥 = −𝑖
𝜔𝜖0 𝜖 𝜕𝑧
𝛽
𝐸𝑧 = − 𝐻𝑦
𝜔𝜖0 𝜖
• Ansatz:
𝐴1 𝑒 𝛾1𝑧 𝑒 𝑖(𝛽𝑥−𝜔𝑡) (𝑧 < 0)
𝐻𝑦 = ൝
𝐴2 𝑒 −𝛾2 𝑧 𝑒 𝑖(𝛽𝑥−𝜔𝑡) (𝑧 > 0)
• Boundary conditions (𝑧 = 0):
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(𝐻1 )𝑦 = 𝐻2 𝑦 and 𝐸1 𝑥 = 𝐸2 𝑥
• Therefore,
𝛾2 𝜖𝑑
𝐴1 = 𝐴2 and =−
𝛾1 𝜖𝑚
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Surface Plasmons at a Single Interface
𝛾2 𝜖𝑑
=−
𝛾1 𝜖𝑚
• Surface waves exist only at interfaces between materials with
opposite signs of the real part of their dielectric permittivities.
𝜔 2
• From wave equations, 𝑘𝑥2 + 𝑘𝑦2 + 𝑘𝑧2 =𝜖
𝑐
𝜔2
𝛾𝑖2 = 𝛽2 − 𝜖𝑖 (𝑖 = 1, 2)
𝑐2
• Combining all, we get the dispersion relation of surface
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30
Dispersion Relation
Air
𝜔 = 𝑐𝑘
𝜔 Im 𝑘 𝜔𝑝
𝜔𝑠𝑝 =
𝜔𝑝 1 + 𝜖𝑑
Re 𝑘
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𝑘(𝑐/𝜔𝑝 )
• SPPs are smaller than free space light (has shorter wavelength)
• SPPs are slower than free space light.
• At low frequencies, SPP dispersion approaches to light line.
• At 𝜔𝑠𝑝 , SPP has zero group velocity and infinite wavenumber.
31
Why Slow?
Wikipedia
𝐇 = (0, 𝐻𝑦 , 0)
𝑐2 𝑐
Weakly bound: metal strongly repels electromagnetic field and
the wave extend over many wavelengths into the dielectric
space.
→ SPPs behave like free waves.
33
Properties of Surface Plasmons
𝜔𝑝
• For 𝜔 → 𝜔sp = :
1+𝜖𝑑
𝜖𝑚 𝜔 → −𝜖𝑑
𝛽
S1𝑥 = 𝐻𝑦2 → − S2𝑥
𝜔𝜖0 𝜖𝑚
Energy flow in each medium cancels out each other.
→ Zero energy velocity. For lossless medium, group velocity and
energy velocity are equal.*
𝜔 𝜖𝑑 𝜖𝑚 𝜔 2
→ ∞, 𝛾𝑖2 = 𝛽2 − 𝜖𝑖 2 → ∞
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𝛽=
𝑐 𝜖𝑑 + 𝜖𝑚 𝑐
*For more details, see M. A. Biot, Phys. Rev. 105, 1129 (1957). 34
Bulk vs Surface Plasmons
Bulk Plasmon Surface Plasmon
• Condition: • Condition:
𝜖𝑚 𝜔 = 0 𝜖𝑚 𝜔 + 𝜖𝑑 = 0
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Metal with Damping
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Metal with Damping
Lossless Lossy
Air (𝛾 = 0) (𝛾/𝜔𝑝 = 0.05)
𝜔 = 𝑐𝑘
Im 𝑘
𝜔
𝜔𝑝 Re 𝑘
𝜔𝑝2
𝜖𝑚 𝜔 =1− 2
𝜔 + 𝑖𝛾𝜔
𝑘(𝑐/𝜔𝑝 ) 𝑘(𝑐/𝜔𝑝 )
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• Gold
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• Copper