Solution

MEGA TEST - KE20243009

Class 11 - Chemistry
Section A
1.
(b) 2.0
Explanation:
Δn =2=n
gas gas ( Product) - n gas (reactant)

2. (a) reverse direction

Explanation:
reverse direction
Section B
3. i. n = 4
Total number of electrons = 2n2 = 2 × 16 = 32
Half out of these will have ms = -1/2
∴ Total electrons with ms (-1/2) = 16
ii. For n = 3
l = 0 m1 = 0, ms = + 1/2, - 1/2 (two e-)

4. Applying Rydberg's Formula for the Balmer transition, n2 = 4, to n1 = 2 in a He+ ion, We have,
ad
Ac
1

λ
= Z
2
RH (
1

2
−
1

2
)= Z
2
RH (
1

2
−
1

2
)=
3

4
RH ..........(i)
n n 2 4
1 2

Now, By applying Rydberg's Formula for a hydrogen atom, We have.

ow

λ
= RH (
1

2
−
1

2
) ........(ii)
n n
1 2

On equating equations (ii) and (i), we get.

1 1 3
− =
2 2 4
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n n
1 2

This equation gives n1 = 1 and n2 = 2. Thus the transition n = 2 to n = 1 in hydrogen (1H)atom will have same wavelength as

transition, n = 4 to n = 2 in He+.
5. T he molecular orbital configuration of Br2 is given
2 1 1
B2: [σ1s] 2 ∗ 2
[σ 1s] [σ2s] [σ ∗ 2s] [π2px ] [π ∗ 2py ]
2

Since B2 has two unpaired electrons, so it is paramagnetic.

6. The equilibrium constant of a reaction depends on
i. Temperature i.e. the constant depends on the sign of ΔH
ii. Stoichiometry of the reaction i.e. how the reaction is represented.

7. The acid is BF3 and the base is NH3. The Lewis theory of acids and bases explains it. The hybridization of B in BF3 is sp2 and the

hybridization of N in NH3 is sp3.

8. According to Balmer formula, v̄ = ¯

¯
1

λ
= RH [
1

2
−
1

2
]
n n
1 2

In order that the wavelength (λ )may be the maximum, wave number (v)must be the least. This is possible in case n2 - n1 is
minimum. Now, for Balmer series, n1= 2 and n2 must be 3. Substituting these values in the Balmer formula,
7 −1 1 1
¯¯
v̄ = (1.097 × 10 m )( − )
2 2
2 3

7 −1 5 6 −1
= 1.097 × 10 m ( ) = 1.523 × 10 m
36

9. S.No. Orbit Orbital

1. An orbit is a well-defined circular path around An orbital is a three-dimensional space around the nucleus within which

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 the nucleus in which the electrons revolve. the probability of finding an electron is maximum (up to 90%)

It represents the planar motion of an electron It represents the three-dimensional motion of an electron around the
2.
around the nucleus. nucleus.

Different orbitals have different shapes, i.e. s-orbitals are spherically

3. All orbits are circular and disc-like.
symmetrical, p-orbitals are dumb-bell shaped and so on.

It is not according to Heisenberg's uncertainty

4. It is according to Heisenberg's uncertainty principle.
principle.

Maximum number of electrons in an orbit is

5. Maximum number of electrons in an orbital is 2.
2n2. Where n= number of orbit.
10. Electron gain enthalpy generally becomes more negative across a period as we move from left to right. Within a group, electron
gain enthalpy becomes less negative down a group. However, adding an electron to the 2p-orbital leads to greater repulsion than
adding an electron to the larger 3p-orbital. Hence the element with most negative electron gain enthalpy is chlorine; the one with
the least negative electron gain enthalpy is phosphorus.
11. i. BeF2 ; F - Be - F:
ii. BCI3:

iii. SiCI4:
ad
Ac
ow

iv. PF5:
Kn

v. SF6:

12. i. In predicting the nature of the molecules: Molecules with specific dipole moments are polar in nature and those of zero dipole
moments are non-polar in nature.
ii. In the determination of shapes of molecules.
iii. In calculating the percentage ionic character.
13. Kp and Kc are related to each other as, Kp = Kc(RT)△n g

The value of Kc can be calculated as follows:

a. 2N OC l(g) ⇌ 2N O(g) + C l ; Kp = 1.8 × 10
2
−2
at 500K.
△ng = np -nr = 3-2 = 1

R = 0.0821 litre atm K-1mol-1

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 Kp −2

Kc = △ng
=
1.8 × 10

0.0821×500
(RT )

= 4.4 × 10 mol L −4 −1

The value of Kc = 4.4 × 10 −4

mol L
−1

b. C aC O (s) ⇌ C aO(s) + C O
3 2 (g)

Kp = 167 atm, △n = 1 g

R = 0.0821 litre atm K-1 mol-1; T = 1073 K

Kp 167
Kc = = = 1.89
△ng 0.0821×1073
(RT )

The value of Kc = 1.9 mol-1 L

14. At a given time, the reaction quotient Q for the given reaction will be
[ H2 ][ I2 ]
Q =
2
[HI]

−5 −5
1× 10 ×1× 10 1
= =
−5 2 4
(2× 10 )

= 0.25
Given Kc = 1 x 10-4.
Hence Kc < Q
So, the reaction will proceed in the backward direction i.e.in the direction of reactants.
(760torr)×(0.15 atm)
15. (a) K p =
(1 atm)

ad
= 1.14 × 10 torr

(b) K p = Kc (RT )
Δn

Kp
Kc =
Δn
(RT )
Ac
(0.15atm)
=
−1 −1 2−1
(0.0821 L atm k mo l ×298k)

−3 −1
= 6.13 × 10 mol L

16. Limitations of Bohr's model of an atom:

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i. It could not explain spectrum of multi-electron atoms.

ii. It could not explain Zeeman and Stark effects.
iii. It could not explain shape of molecules.
iv. It was not in accordance with Heisenberg's uncertainty principle.
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Quantum Mechanical Model: It was developed on the basis of Heisenberg's uncertainty principal and dual behaviour of matter.
Main features of this model are given below:
i. The energy of electrons in an atoms is quantized i.e. can only have certain values.
ii. The existence of quantized electronic energy levels is a direct result of the wave like properties of electrons.
iii. Both the exact position and velocity of an electron in an atom cannot be determined simultaneously.
iv. The orbitals are filled in increasing order of energy. All the information about the electron in an atom is stored in orbital wave
function Ψ .
v. From the value of ψ at different points within atom, it is possible to predict the region around the nucleus where electron
2

most probably will be found.

17. 2H (g) + C O(g) ⇌ C H OH
2 3

According to Le-Chatelier's principle:

When any system at equilibrium for a long period of time is subjected to a change in concentration, temperature, volume, or
pressure, the system changes to a new equilibrium. This change partly counteracts the applied change.
i. On addition of H2 (increase in the concentration of reactants), equilibrium will be shifted in the forward direction (more
products are formed).
ii. On addition of CH3OH (increase in concentration or product), equilibrium will be shifted in the backward direction.
iii. On removal of CO , equilibrium will be shifted in the backward direction.
iv. On removal of CH3OH, Equilibrium will be shifted in the forward direction.
Section C

18. i. The increasing order of negative stabilities of CN, CN+ and CN- is CN+ > CN > CN-.

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 ii. The molecular orbital theory is preferred over valence bond theory because molecular orbital theory explains the magnetic
nature of the molecule.
iii. Lower than O2 and equal to H2.
iv. Option (b) B2, O2, NO is correct where all the species are paramagnetic.
v. The given statement is false because the bonding molecular orbital is lowered by a lesser amount of energy than the amount
by which antibonding molecular orbital is raised.

d
A ca
ow
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