Chemistry - Toppers - Test - 2 - Electro Chemistry - Q + Soln

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Class II PreUni Plus 2020-21 (Toppers) Solution to Test 2 Topics Electrochemistry Max. Marks 30 Duration 30 Minutes Date 22-10-2020
Instructions
1.
 
This test paper contains 30 multiple choice questions. 2.
 
For each question there are four options of which one option is correct. Choose the correct option and darken the appropriate circle in the response sheet. 3.
 
Each question carries 1 mark for correct answer and 0 mark for wrong answer. 4.
 
Rough work can be done on the question paper itself. 5.
 
Calculator / Log table is not allowed.
1.
 
Among the following expressions, the correct expression for K
a
 is (A)
mamm
CK()
°°
=
 (B)
2mammm
CK()
° °
=∧ −
 (C)
2mam
CK
 =
 (D)
2mamm
CK()
°
=
 
Ans
(B) 2.
 
m
 of M32 solution of weak acid is 8 S cm
2
 mol
1
 and
m
°
 is 400 S cm
2
 mol
–1
. Ka for acid is (A) 1.25
×
 10
–6
 (B) 6.25
×
 10
–4
 (C) 1.25
×
 10
–4
 (D) 1.25
×
 10
–5
Ans
(D)
mm
8140050
°
= = =
 
2
CKa(11)1
=
 
2
111KaC325050
= ∝ = × ×
 
2
111Ka322510
= × ×
118104
= ×
 = 0.125
×
 10
–4
3.
 
m2
HO
°
 is equal to (A)
m(HCl)m(NaOH)m(NaCl)
° ° °
+
 (B)
33
m(HNO)m(NaNO)m(NaOH)
° ° °
+
 (C)
33
m(HNO)m(NaOH)m(NaNO)
° ° °
++
 (D)
44
m(NHOH)m(HCl)m(NHCl)
° ° °
+∧ −
 
Ans
(A)
2
mHHClNaOHNaCl
+ − + − +
° ° ° ° ° ° °
=λ +λ +λ +λ λ λ
 4.
 
Match the terms given is column I with the items given in column II.
Column I Column II
(a)
m
Λ
 (i) Intensive property (b)
cell
E
°
 (ii) Depends on number of ions / volume (c) K (iii) Extensive property (d)
r
G
cell
(iv) Increases with dilution (A) a
 (iv); b
 (ii); c
 (i); d
 (iii) (B) a
 (iv); b
 (i); c
 (ii); d
 (iii) (C) a
 (i); b
 (ii); c
 (iii); d
 (iv) (D) a
 (ii); b
 (iii); c
 (iv); d
 (ii)
 
2P2021CT2S(SKN)
 
2
 
Ans
(A) 5.
 
The same amount of electricity is passed through CuSO
4
 solution and acidulated water, the volume of H
2
 liberated at STP, if 0.16 g Cu is deposited, is (A) 63 cc (B) 56 cc (C) 69 cc (D) 70 cc
Ans
(B)
22
CuCuHH
mE32mE1
= =
 
2
H
0.1632m1
=
 
2
H
0.16m0.005g32
= =
 Vol. of H
2
 liberated massdeposited22,400molarmass
= ×
 0.00522,4002
=
 = 56 ml 6.
 
The cathodic reaction of electrolysis of aluminium oxide is
3
Al3eAl
+
+ 
. The amount of electricity required to furnish 4.12 kg of aluminium metal (at mass Al = 27) is (A) 4.42
×
 10
7
 C (B) 1.83
×
 10
7
 C (C) 5.49
×
 10
4
 C (D) 5.49
×
 10
10
 C
Ans
(A)
3
Al3eAl
+
+ 
 W = ZQ W= 4.12 kg = 4.12
×
 10
3
 g EZ96500
=
996500
=
 
3
965004.1210Q9
× ×=
 = 4.42
×
 10
7
 C 7.
 
Consider the reaction of electroplating of chromium
32
CrO6H6eCr3HO
+
+ + → +
 If 0.1 A of current is passed for 3 hrs, then the amount of Cr deposited is (at wt of Cr = 52 g) (A) 0.096 g (B) 10.8 g (C) 5.2 g (D) 0.52 g
Ans
(A) 52Z696500
=×
 520.133600m69500
× × ×=×
 = 0.096 g 8.
 
Among the following statements regarding dilution of an electrolytic solution, the correct one is (A) Both conductivity and molar conductivity increase (B) Both conductivity and molar conductivity decrease (C) Conductivity decreases and molar conductivity increases (D) Conductivity increases and molar conductivity decreases
Ans
(C)
5
 
2P2021CT2S(SKN)
 
3
 
9.
 
The time taken for reducing 3 mol of Fe
3+
 to Fe
2+
 with 2.0 A current is (A) 39.15 hours (B) 40.21 hours (C) 50.21 hours (D) 49.15 hours
Ans
(B)
32
FeeFe
+ +
+ 
 charge396500tcurrent2
×= =
 = 1, 44, 750 s = 40.2 hrs 10.
 
AgCl
Λ
 is obtained (A) by extrapolation of the graph of
Λ
m
 Vs. C to zero concentration (B) by known values of
Λ
 of AgNO
3
, HCl and HNO
3
 (C) both (A) and (B) (D) by known values of
Λ
 of AgNO
3
, HCl and NaNO
3
Ans
 (B) 11.
 
The number of coulombs provided by a current of 0.010 mA in the calculator battery that can operate for 1000 hours is (A) 1.0 (B) 10 (C) 0.010 (D) 36
Ans
 (D) Q = It = 0.01
×
 10
–3
 
×
 1000
×
 60
×
 60 = 36 C 12.
 
The correct statement with respect to conductivity cell is (A) same conductivity cell is used for the determination of conductivity of both strong and weak electrolytes (B) cell constant is a constant for any conductivity cell (C) cell constant is a constant for a given conductivity cell (D) cell constant is given by the relation
aG
=
l
 where a = area of cross section of electrodes and
l
 = distance between the electrodes
Ans
 (C) 13.
 
Electrolytic conduction differs from metallic conduction with respect to (A) resistance decreases with decrease of temperature (B) resistance decreases with increase of temperature (C) the flow of current does not generate heat (D) resistance is independent of the length of the conductor
 
Ans
 (B) As temperature increases, conductance decreases in metallic conductors. 14.
 
When an electrolyte solution is progressively diluted, the dilution reaches a stage known as infinite dilution. The degree of dissociation at the stage (A) exceeds 1.0 (B) is equal to 1.0 (C) is exactly 0.5 (D) is zero
 
Ans
 (B)
5
 
2P2021CT2S(SKN)
 
4
 
15.
 
The number of coulombs required for oxidation of 1 mol of H
2
O to O
2
 is (A) 9.65
×
 10
4
 (B) 1.93
×
 10
5
 (C) 1.93
×
 10
4
 (D) 1.93
×
 10
2
Ans
 (B)
222
1HOHO2
+
 i.e.,
22
1OO2e2
+
 i.e., 1 mol of H
2
O require = 2
×
 96500 C = 1.93
×
 10
5
 C 16.
 
When
4
KMnO
 acts as an oxidizing agent and ultimately forms
24223
MnO,MnO,MnO
 and
2
Mn,
+
 then the number of electrons transferred in each case is respectively (A) 4, 3, 1 and 5 (B) 1, 5, 3 and 7 (C) 1, 3, 4 and 5 (D) 3, 5, 7 and 1
Ans
 (C) O.N. of Mn in KMnO
4
 is + 7 In
24
MnO,
 O.N. of Mn is + 6; Number of electrons transferred 7
 6 = 1 In
2
MnO,
 O.N. of Mn is + 4; Number of electrons transferred 7
 4 = 3 In
23
MnO,
 O.N. of Mn is + 3; Number of electrons transferred 7
 3 = 4 In
2
Mn,
+
 O.N. of Mn is + 2; Number of electrons transferred 7
 2 = 5 17.
 
In a given reaction,
3
NO
 is reduced to
4
NH
+
. The mass of
3
NO
 ion gaining one mole of electrons is (A) 31.0 g (B) 15.5 g (C) 7.75 g (D) 62.0 g
Ans
 (C)
5334
NONH
+ +
 Change in oxidation state = 8
3
MolarmassEquivalentmassofNOChangeinoxidationstate
=
627.758
= =
 1 gram equivalent gains 1 mol of electrons for reduction, i.e., 7.75 g absorbs 1 mol of electrons. In other words, mass of
3
NO
 ions that gains 1 mol of electrons is 7.75 g. 18.
 
A certain current liberates 0.504 g of hydrogen in 2 h. The mass of copper (in g) liberated by the same current flowing for the same time through CuSO
4
 solution is (A) 12.7 (B) 16 (C) 31.8 (D) 63.5
Ans
 (B) Number of equivalents of H
2
 = No. of equivalents of Cu Eq. of H
2
 = Eq. of Cu
Cu
w0.50463.512
=
 w
Cu
 = 16 g 19.
 
The approximate time duration in hours to electroplate 30 g of calcium from molten calcium chloride using a current of 5 A is (A) 16 (B) 8 (C) 80 (D) 10
Ans
 (B)
5
5
5

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