NUCLEI
NUCLEI
NUCLEI
2. Atomic Structure
# Constituents of an Atom: Electrons, Protons, Neutrons
1. Electrons:
o Negatively charged subatomic particles orbiting the nucleus.
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o Mass is approximately 9.109×10 kg (about 1/1836 the mass of a
proton).
o Responsible for chemical properties and bonding due to their
interactions in atomic orbital’s.
2. Protons:
o Positively charged particles located in the nucleus.
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o Mass is approximately1.672×10 kg.
o The number of protons defines the atomic number (Z), which
identifies the element.
3. Neutrons:
o Electrically neutral particles found in the nucleus.
o Mass is slightly greater than that of protons,
approximately1.675×10−27 kg.
o Neutrons provide nuclear stability by reducing electrostatic
repulsion between protons.
4. Nucleus:
o The dense core at the center of an atom composed of protons and
neutrons (collectively called nucleons).
o The nuclear force binds protons and neutrons, overcoming the
repulsion between positively charged protons.
3. Isotopes:
o Atoms of the same element that have the same number of protons but
a different number of neutrons.
o Isotopes of an element have the same chemical properties but different
nuclear properties.
o Example:
Carbon-12 : 6 protons and 6 neutrons.
Carbon-14 : 6 protons and 8 neutrons (radioactive isotope).
4. Isotopic Notation:
Z
o Isotopes are represented as AX where A is the mass number, Z is the
atomic number, and X is the chemical symbol.
235
o Example: 92235U represents Uranium-235.
1. Nuclear Radius:
o The radius of a nucleus is related to the mass number AAA of the atom
and can be approximated by the empirical formula: R=R0A1/3 where R0 is
a constant approximately 1.2×10−15 (1.2 femimeters).
2. Size of the Nucleus:
o The nucleus is incredibly small compared to the overall size of the
atom.
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o A typical atomic radius is on the order of 10 meters (0.1 nanometers),
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while the nuclear radius is about 10 meters, making the atom mostly
empty space.
3. Nuclear Density:
o The density of the nucleus is extremely high.
o Despite its small size, the nucleus contains nearly all the mass of the
atom.
Energy Levels:
o Electrons occupy specific energy levels (or shells) around the nucleus,
defined by the principal quantum number nnn.
o The energy of an electron in a hydrogen-like atom is given by
o En=−n213.6eV where n is the principal quantum number.
Electron Orbitals:
o Each energy level contains subshells labeled by the azimuthal quantum
number l, which defines the shape of the orbital (s, p, d, f orbitals).
o The number of orbitals and their shapes determine how electrons are
distributed around the nucleus.
Quantum States:
o The state of an electron in an atom is described by a set of quantum
numbers:
Principal Quantum Number (n): Defines the energy level and
distance from the nucleus.
Azimuthal Quantum Number (l): Defines the orbital shape.
Magnetic Quantum Number (ml): Defines the orientation of the
orbital in space.
Spin Quantum Number (ms): Describes the electron’s intrinsic
spin.
Pauli Exclusion Principle:
o No two electrons in an atom can have the same set of four quantum
numbers, meaning each orbital can hold a maximum of two electrons
with opposite spins.
Energy Transitions:
o Electrons can move between energy levels by absorbing or emitting
photons with energy equal to the difference between the levels
Atomic Spectra:
When electrons transition between energy levels, they emit or absorb light at
specific wavelengths, resulting in an atomic spectrum that is unique to each
element.
Strong Nuclear Force: Two positive charges repel each other because
of the electromagnetic force, so the strong nuclear force lives up to its
name by overcoming the intense repulsion between similarly charged
particles that coexist in the nucleus of atoms. When the strong nuclear
force that binds protons and neutrons in an atom is broken, extreme high-
energy photons are released in the process.
Weak Nuclear Force: The weak nuclear force can change a neutron
into a proton in a process called nuclear decay. When the weak nuclear
force converts a neutrally charged neutron into a positively charged
proton, sub-atomic particles are released near the speed of light.
Nuclear Models
Nuclear models are theoretical frameworks used to describe the structure and
behavior of atomic nuclei. Due to the complexity of the forces at play within the
nucleus, several models have been developed, each offering insights into different
aspects of nuclear behavior. The main models are the liquid Drop Model, the Shell
Model, and the Collective Model.
# Liquid Drop Model
The Liquid Drop Model treats the nucleus as if it were a drop of incompressible
fluid. It provides a good approximation of nuclear properties such as binding
energy and fission behavior, particularly for heavy nuclei.
Key Features:
- The protons and neutrons (nucleons) behave similarly to molecules in a liquid,
held together by a strong nuclear force, analogous to surface tension.
- The model accounts for the nuclear binding energy through terms such as
volume energy, surface energy, Coulomb energy (repulsive force between
protons), and asymmetry energy (related to the neutron-to-proton ratio).
Applications:
- Explains nuclear fission, where the nucleus can "split" like a droplet.
Limitations:
- It does not explain the existence of magic numbers (specific numbers of protons
or neutrons that lead to particularly stable nuclei).
# Shell Model
The Shell Model views the nucleus as a system of nucleons (protons and neutrons)
moving in distinct energy levels or "shells," much like electrons in an atom.
Key Features:
- Nucleons fill energy levels in a manner similar to electrons in atomic orbitals.
There are specific shells for both protons and neutrons.
- The Shell Model successfully predicts nuclear spin and magnetic moments.
Applications:
- Accurately predicts the structure of light and medium-mass nuclei.
- Explains nuclear phenomena such as nuclear spins, magnetic moments, and the
existence of magic numbers.
Limitations:
- It becomes less effective for describing the structure of heavy nuclei.
- The model assumes that nucleons move independently, which may not always
capture the collective behaviors observed in large nuclei.
# Collective Model
The Collective Model (also known as the Unified Model) combines features of both
the Liquid Drop and Shell models. It is particularly useful for describing the
collective motions of nucleons, such as rotational and vibrational states, within
medium and heavy nuclei.
Key Features:
- Nuclei are considered to have collective excitations, where groups of nucleons
act together in coordinated motion.
- This model helps describe phenomena like nuclear quadrupole moments, where
the shape of the nucleus is not perfectly spherical, and rotational bands observed
in deformed nuclei.
Applications:
- Describes deformed, non-spherical nuclei and rotational bands.
Limitations:
- While effective for describing collective behavior, it does not delve deeply into
individual nucleon interactions.
- It is less suited for light nuclei, where individual particle behavior is more
pronounced.
4.RADIOACTIVITY:
Radioactivity is the spontaneous decay of an unstable atom through the emission,
from the atomic nucleus, of a particle of ionising radiation.
The different types of radiation can be identified by their ability to pass through
matter. In 1899 Ernest Rutherford named alpha (α), beta (β), and gamma (γ)
radiation, after the first three letters of the Greek alphabet.
α-decay
When an atomic nucleus transforms into a different element by emitting an α-
particle. An α-particle is the nucleus of a helium atom, helium-4, which consists of
two protons and two neutrons. The atomic number of an α-particle is Z=2, so the
atomic number of the decaying nucleus is decreased by two during an α-decay and
a different element is created. α-radiation can be stopped by a sheet of paper
Involves the emission of an alpha particle (2 protons, 2 neutrons, equivalent to a
Helium nucleus).
U238→Th234+α
β-decay
When a nucleus decays spontaneously by emitting an electron or a positron (the
electron’s positive antimatter partner). An electron is emitted when a neutron is
converted to a proton inside the decaying nucleus. This tends to occur in proton-
deficient nuclei, where the neutron number is much greater than the proton
number. A positron is emitted when a proton is converted into a neutron. During a
β-decay, a proton is either created or lost, so the atomic number of the decaying
nucleus is changed by one. Most β-particles can be stopped by six millimeters of
aluminium.
C14→N14+β− + νe
Beta-plus (β⁺) Decay (Positron Emission): A proton decays into a neutron,
emitting a positron and a neutrino:
F18→O18+β + + νe
γ-decay
When a nucleus emits electromagnetic radiation in the form of a high-energy
photon or γ-ray. It can be caused by the redistribution of protons and neutrons in
a nucleus, or by the de-excitation of an energetic nucleus. The atomic number is
not changed during a γ-decay, so the chemical element of the decaying nucleus
does not change. γ-rays can be stopped by several millimeters of lead.
Gamma rays are highly penetrating and can pass through several centimeters
of lead or meters of concrete, making shielding essential when working with
gamma-emitting substances.
Example: Cobalt-60 undergoes beta decay to form Nickel-60, which then emits gamma
rays as it reaches a stable state:
Ni60*→Ni60+γ
5.NUCLEAR REACTIONS:
Conservation Laws
In nuclear reactions, several conservation laws apply:
Conservation of Mass-Energy: The total mass and energy before and after a
reaction remain constant.
-Conservation of Momentum: The total momentum of the system is
conserved.
Conservation of Charge: The total electric charge before and after the
reaction remains the same.
Conservation of Nucleon Number: The total number of protons and
neutrons (nucleons) is conserved.
# Types of Nuclear Reactions
There are several types of nuclear reactions, with the most significant being fission,
fusion, and capture reactions.
Fission: In fission, a heavy nucleus splits into two or more smaller nuclei,
along with the release of neutrons and a large amount of energy. The most
common isotopes involved in fission reactions are Uranium-235 and
Plutonium-239. For example:
U235+n→Ba141+Kr92+3n+Energy
Fission is the process used in nuclear reactors and atomic bombs.
D+T→He4+n+Energy
Fusion has the potential to be a clean energy source, but it requires extremely
high temperatures and pressures to sustain.
U238+n→U239
This reaction is important in nuclear reactors, as it can lead to the formation of
Plutonium-239, which is also fissionable.
# Reaction Cross-Sections
Nuclear reaction kinetics refers to the rate at which nuclear reactions occur,
depending on factors such as the number of reactants, their energy, and the reaction
cross-section.
The energy released in nuclear reactions comes from the binding energy of the
nucleus, which is the energy that holds the protons and neutrons together.
In fission, the total binding energy of the resulting smaller nuclei is greater
than that of the original heavy nucleus, and the difference in energy is
released as heat and radiation.
In fusion, the binding energy per nucleon increases as smaller nuclei
combine to form a more stable, larger nucleus. This increase in binding
energy is released in the form of high-energy particles and radiation.
6. Nuclear Fission
# Theory of Fission:
The theory of fission explains how and why a heavy nucleus can break apart when
it becomes unstable. The process can be understood through the following steps:
- Neutron Emission: During fission, additional neutrons (usually two or three) are
emitted. These neutrons can then trigger further fission events, leading to a chain
reaction.
- Energy Release: The mass of the resulting fragments and neutrons is less than the
original mass of the Uranium-236 nucleus. This mass difference is converted into
energy according to Einstein’s mass-energy equivalence formula, \( E = mc^2 \).
The energy released per fission event is around 200 MeV (million electron volts).
The energy comes from the strong nuclear force that binds protons and neutrons
together in the nucleus. When the nucleus splits, some of this binding energy is
released as kinetic energy of the fission fragments, gamma radiation, and energy
of the emitted neutrons.
# Chain Reactions:
A chain reaction occurs when the neutrons produced by fission events cause
further fission in other fissile nuclei, such as Uranium-235 or Plutonium-239.
- Sustained Chain Reaction: In a sustained chain reaction, each fission event causes
one or more subsequent fission events, maintaining a constant rate of reaction.
This requires careful control of the neutron population, as not all neutrons will
successfully cause additional fission.
- How It Works:
- Fission reactions in the reactor core produce heat.
- The heat converts water into steam.
- The steam drives a turbine, which generates electricity.
- The reactor is kept in a critical state, ensuring a controlled rate of energy
production.
7. Nuclear Fusion:
Nuclear fusion is the process where two light atomic nuclei combine to form a
heavier nucleus, releasing a tremendous amount of energy. Fusion powers the
stars, including our Sun, and is considered a potential source of virtually limitless
and clean energy on Earth.
# Fusion Reactions:
In fusion reactions, two light nuclei, such as isotopes of hydrogen (deuterium and
tritium), combine to form a heavier nucleus, releasing energy due to the mass
difference between the reactants and the products.
D+T→He4+n+Energy
In this reaction, deuterium and tritium fuse to form helium-4 and a neutron,
releasing around 17.6 MeV of energy.
- Tokamaks: Tokamaks are devices that use powerful magnetic fields to confine hot
plasma in a toroidal (doughnut-shaped) chamber. The plasma is heated to
temperatures sufficient for fusion to occur.
- ITER (International Thermonuclear Experimental Reactor) is a large-scale fusion
experiment based on the tokamak design, currently under construction in France.
It aims to demonstrate the feasibility of fusion as a large-scale and carbon-free
energy source.
- Inertial Confinement Fusion (ICF): In ICF, lasers or other forms of energy are used
to compress small fuel pellets to the point where fusion occurs. Research facilities
such as the National Ignition Facility (NIF) focus on this approach.
Neutrons play a critical role in nuclear reactors, where controlled fission reactions
produce heat used to generate electricity. Neutron physics is essential for
understanding how reactors work, how to control them, and how to ensure safety.
# Neutron Physics:
Neutrons are neutral particles with no electric charge, making them ideal for
interacting with atomic nuclei without being repelled by the positive charge of the
protons. In fission reactors, neutrons are key to sustaining the chain reaction.
- Fast Neutrons: Produced directly from fission, these high-energy neutrons move
rapidly and can induce further fission in fissile materials.
- Thermal Neutrons: Slower neutrons that are more likely to cause fission in
uranium-235 and plutonium-239 nuclei. Neutrons must often be slowed
(moderated) for efficient reactor operation.
# Neutron Capture Reactions:
In addition to causing fission, neutrons can be captured by nuclei, resulting in the
formation of a heavier isotope.
# Neutron Moderation:
Neutron moderation is the process of slowing down fast neutrons to increase the
likelihood of fission. Moderators are materials that reduce neutron speed through
collisions without capturing them.
- Common Moderators:
- Water (H2O): Often used as a coolant and moderator in reactors.
- Heavy Water (D2O): Used in heavy-water reactors such as CANDU reactors.
- Graphite: Used in some reactors, such as the first-generation nuclear reactors.
- CANDU Reactors: Use heavy water as a moderator and coolant, allowing for the
use of natural uranium as fuel.
- Fast Breeder Reactors (FBR): Use fast neutrons to create more fissile material
than they consume, often from U-238 or Th-232.
Nuclear forces and binding energy are fundamental concepts in nuclear physics,
explaining how nuclei stay together and how much energy is associated with
nuclear processes.
# Mass Defect
The mass defect is the difference between the total mass of a nucleus's individual
protons and neutrons and the actual mass of the nucleus.
- Mass-Energy Equivalence: According to Einstein's famous equation ( E = mc 2 ),
this mass defect corresponds to the binding energy that holds the nucleus
together.
- For example, the mass of a helium nucleus is slightly less than the sum of its
constituent protons and neutrons, and the missing mass is converted into the
energy that binds the nucleus.
# Stability of Nuclei
The stability of nuclei depends on the balance between the attractive strong
nuclear force and the repulsive electromagnetic force.
- Stable Nuclei: Typically, stable nuclei have a balanced number of protons and
neutrons, especially for lighter elements. For heavier elements, more neutrons are
needed to maintain stability.
- Unstable Nuclei: If the ratio of neutrons to protons is too high or too low, the
nucleus becomes unstable, leading to radioactive decay.
Nuclear physics has numerous applications across various fields, from medicine to
energy production and defense.
# Nuclear Weapons
Nuclear weapons harness the energy released from fission or fusion reactions for
massive destructive power.
- Atomic Bombs: Use nuclear fission (usually of Uranium-235 or Plutonium-239) to
release large amounts of energy in an explosion. The bombs dropped on Hiroshima
and Nagasaki were based on this principle.
- Hydrogen Bombs: Also called thermonuclear weapons, these use a fission
reaction to trigger a fusion reaction, resulting in an even more powerful explosion.
- Nuclear Proliferation: The spread of nuclear weapons and the technology to
produce them is a major international security concern, leading to treaties and
agreements aimed at controlling the development and deployment of nuclear
weapons.
# nucleosynthesis of stars
Stellar nucleosynthesis is the process by which elements are created within
stars through nuclear fusion. In terms of nuclear physics:
3. Energy and Stability: Each fusion reaction releases energy (in the form of
photons) due to the mass-to-energy conversion (as per Einstein’s (E = mc2), which
sustains the star against gravitational collapse. However, elements heavier than
iron require energy input to fuse, rather than releasing it.
Neutron stars and black holes are the dense remnants left after massive
stars exhaust their fuel and undergo supernova explosions:
Neutron Stars: These are incredibly dense objects, formed when a
star’s core collapses and protons and electrons combine to form
neutrons. They are only about 10-20 km across but have more mass
than the Sun. The density and magnetic fields of neutron stars are
extreme, making them valuable for studying nuclear matter under
intense conditions.
Black Holes: If a star's remnant is even more massive, gravity will
continue to collapse it into a black hole, a point of infinite density (a
singularity) where not even light can escape its gravitational pull.
Black holes warp spacetime around them, providing a natural testbed
for general relativity.
14. Recent Developments in Nuclear Physics
- Generation IV Reactor: These reactors are designed to be safer and more efficient
than current reactors, with improved sustainability and reduced waste. Key types
include:
- Molten Salt Reactors (MSRs): Use molten salt as both coolant and fuel, offering
high-temperature operation and passive safety features.
- Sodium-cooled Fast Reactors (SFRs): These reactors can recycle fuel, use fast
neutrons, and reduce long-term nuclear waste by transmuting isotopes.
- Small Modular Reactors (SMRs): SMRs are compact nuclear reactors designed for
flexibility, safety, and quicker deployment. They can be used in smaller grids or for
remote areas, offering lower upfront capital costs compared to large nuclear
power plants.
# Energy Solutions
As global energy demand increases, nuclear energy is viewed as a potential
solution for reducing carbon emissions while meeting electricity needs.
- Nuclear Power: Fission-based nuclear power plants remain a key low-carbon
energy source, but concerns over safety, waste, and cost limit their expansion.
Developing safer and more efficient reactor technologies (e.g., Generation IV and
SMRs) is critical for future growth.
- Fusion Energy: If achieved, fusion power offers an almost limitless, safe, and
environmentally friendly energy source. While significant technical hurdles remain,
projects like ITER and advances in plasma physics hold promise for bringing fusion
energy to the grid in the coming decades.
- Timeline: Although fusion power has been in development for decades, the first
commercial fusion plants could come online within the next 20 to 30 years, with
projects like ITERand SPARC leading the way.
Conclusion
The study of nuclear science is essential for understanding matter’s fundamental
forces and offers wide-ranging applications. By exploring nuclear structures,
reactions, and detection methods, we gain insights that impact fields such as
medicine, with advances in diagnostic imaging and cancer treatments, and energy
production through nuclear power. Nuclear fusion research also holds the promise
of cleaner, sustainable energy.As we unlock the potential of nuclear science,
prioritizing safety and ethical considerations is vital. Overall, nuclear science
enriches our knowledge of the universe and provides critical solutions for health,
energy, and a sustainable future.
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