06-10-2024

9610WJA801013240017 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Apparent frequency detected by an observer is

When observer is stationary and source travels toward the observer

(A)

When observer is moving away from source and source is moving away from observer
(B)

When observer is stationary and source is stationary

(C)

When observer is moving towards the source and source is moving away from observer
(D)

2) Y (x, t) = 0.05/[(4x+2t)2 +5] represents a moving wave pulse, where x and y are in meters and t is
in seconds. Then which statement (s) are correct

(A) pulse is moving in –x direction

(B) wave speed is 0.5 m/s
(C) max. particle displacement is 1 cm
(D) it is a symmetric pulse

3) A uniform rope of mass M length L hangs vertically from the ceiling, with its lower and free. A
disturbance on the rope travelling upwards starting from the lower end has a velocity v at a point P
at distance x from the lower end

(A) Tension at point P is Mg

(B)
(C)

(D)
Tension at a point P is

4) A convex spherical surface of radius 10 cm is used to form the image of a point object as shown.
What should be the object distance x so that the distance between object and the image is 1 m ?
(A) 40 cm
(B) 50 cm
(C) 60 cm
(D) 70 cm

5) AB is the principal axis of a spherical mirror. I is the point image corresponding to a point object

O. Choose the correct options.

(A) Mirror is lying to the right hand side of O

(B) Focus of mirror is lying to the right hand side of O
(C) Centre of curvature of mirror is lying to the right hand side of O
(D) Centre of curvature of mirror is lying between I and O

6)

In L-C oscillations,

Time period of oscillation is

(A)

(B)
Maximum current in circuit is

(C)
Maximum rate of change of current in circuit is

(D) Maximum potential difference across the inductor is .

Here, q0 is maximum charge on capacitor

7) A very long straight conductor and a square conducting frame is in a plane and are separated
from each other as shown in the figure a = 10 cm. If current in the square frame is increasing a rate

of 2 A/s in clockwise direction :-

Mutual inductance of the two loops is

(A)

(B) The current induced in the wire upwards.

(C) The current induced in the wire is downwards.
(D) The current induced in the wire is zero.

8)

A cylindrical region has a uniform magnetic field as shown, which varies linearly with time. A
conducting loop in the shape of equilateral triangle is placed in the region as shown. A current flows
in the loop due to changing flux. Then :-

(A) in wire OP only conservative electric field drives the current.

(B) in wire PQ both conservative and non-conservative electric field drive the current.
(C) in wire QO only non-conservative electric field drives the current.
(D) in all the wires only non-conservative electric field drives the current.

9)

Three concentric conducting spherical shells have radii r, 2r and 3r respectively. In the state shown
charges are q1, q2 and q3 are present on innermost, middle and outermost shells respectively. Then
select correct alternative(s).

(A) q1 + q3 = – q2

(B)

(C)

(D)

10) A block of mass 1 kg is pushed towards another block of mass 2 kg from 6 m distance as shown
in figure. Just after collision velocity of 2 kg block becomes 4 m/s :-

(A) coefficient of restitution between two blocks is 1

(B) coefficient of restitution between two blocks is 1/2
(C) velocity of centre of mass after 2 s is 2 m/s
(D) velocity of centre of mass after 2 s is 1 m/s

SECTION-I (ii)

1) Three resistors of resistance 6MΩ, 3MΩ and 3MΩ, one capacitor of capacitance µF, two cells of
potential difference 5V and 10V and two switches are connected in the circuit as shown in the
figure. Both switches is closed simultaneously at t = 0. (e–1 = 0.37)

List-I describe the charges and currents in the

circuit at a particular time and List-II gives possible values of charges and current.

List-I List-II

(I) The maximum charge on the capacitor in µC (P) 0.63

(II) Charge on capacitor at t = 1 sec in µC (Q) 1.54

(III) Current in the branch of capacitor at t = 1 sec in µA (R) 2.06

Current passing through battery of 5V at t = 1 sec in

(IV) (S) 1.00
µA

(T) 0.37
Which one of the following options is correct ?
(A) I → P;II → T;III → R;IV → S
(B) I → T;II → P;III → Q;IV → R
(C) I → P;II → R;III → T;IV → Q
(D) I → S;II → P;III → T;IV → Q

2) List–I shows four systems, each of the same length L, for producing standing waves. The lowest
possible natural frequency of a system is called its fundamental frequency, whose wavelength is
denoted as lf. Match each system with statements given in List–II describing the nature and
wavelength of the standing waves.
 List–I List–II
(P) Pipe closed at one end (1) Longitudinal waves

(Q) Pipe open at both ends (2) Transverse Waves

(R) Stretched wire clamped at both ends (3) λf=L

(S) Stretched wire clamped at both ends (4) λf = 2L

and at mid-point (5) λf = 4L

(A) P → 2,3;Q → 2,4;R → 1,4;S → 1,5

(B) P → 2.4;Q → 2,3;R → 1,4;S → 1,5
(C) P → 1,5;Q → 1,4;R → 2,4;S → 2,3
(D) P → 1,5;Q → 2,4;R → 2,3;S → 1,4

SECTION-III

1) In a wave, travelling in +X direction with speed of 2cm/s, the particles displacement at x = 0 is

given by . Find the displacement of particle (in mm) at x = 4 cm at t = 5

sec.

2) Solenoid 2 has twice the radius and six times the number of turns per unit length as solenoid 1.
Find the ratio of the magnetic field in the interior of 2 to that in the interior of 1. Assume thin and
long ideal solenoid.

3) The density of a solid spherical planet of radius R is given as ρ = ρ0r, where ρ0 = constant and r is
distance measured from centre of planet. The acceleration due to gravity of this planet is half of
maximum value at distance x from centre and also at a distance y from the centre. The value of x + y

is . Here α and β are single digit integer. Find the value of α-β? (Where the fraction is in lowest
form)

4) Numerical value of maximum power (in watt) delivered to Rext is

5) In the following circuit, the current through the resistor R is I Amperes. The value of I is

6) Determine potential difference across capacitor at sec. [Emf of AC source is in volts and ‘t’
is in seconds]

7) A ball of mass 2.5 kg is dropped on a fixed smooth inclined plane having e = 0.5 from height of
3.2 m as shown in figure. The impulse (in N-sec) exerted by the inclined plane on the ball during 1st

collision is given by 3α. Fill the value of α in OMR sheet. (g = 10 m/s2)

8)

Equivalent capacitance between A and B is nC. The value of n is :

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following is/are correct option?

(A) Tetrapeptide represents, 4 peptide bond in a molecule of polypeptide.

(B) Glucose & Fructose can be differentiated by Tollen’s reagent & Fehling’s solution.
(C) One mole of glucose reacts with maximum of 3 mole of phenylhydrazine.
(D) Sucrose is a disaccharide which is non-reducing in nature.

2) Which of the following statement(s) is/are false?

(A) All adiabatic processes are isoentroic(or isentropic) process

(B) When (ΔGsystem)T, P < 0 the reaction must be exothermic
(C) dG = VdP – SdT is applicable for closed system, both PV and non-PV work
The heat of vaporization of water at 100oC is 40.6 kJ.mol. When 9 g of water vapour condenses
(D)
to liquid at 100oC and 1 atm, then system DSsystem = 54.42 J/K

3) In which of the following compounds, there will be either loss of optical activity or change of
optical rotation, while keeping in very dilute acidic or basic aqueous solution?

(A)

(B)

(C)

(D)

4)

In water, the enthalpy of a protein in its folded state (Hf) is lower than that in its unfolded state(Huf).
The entropies of the folded and unfolded states are Sf and Suf respectively. The condition(s) under
which this protein spontaneously folds in water at a temperature T is(are)

(A) Suf < Sf

(B) Suf = 0
(C) Suf = Sf
(D) (Sf – Suf) > Hf – Huf/T

5) The transition metal complex(es) with zero magnetic moment, zero dipole moment and CFSE of
-2.4Δ0 is(are)

(A) [Mn(CO)5 (CH3)]

(B) [Trans-Ni(ethylenediamine)2Cl2]
–
(C) [trans-Co(CN)4(H2O)2]
4–
(D) [Trans-Fe(CN)4Cl2]
6) Which of the following compound(s) is/are more reactive than chlorobenzene towards
electrophilic attack?

(A)

(B)

(C)

(D)

7) For a reaction A → B, Ea for the forward reaction (Ea)f and backward reaction (Ea)b is 19 kJ/mole
and 9 kJ/mole respectively. Potential energy of A is 12 kJ/mole
Find out which of the following options are correct?

(A) Heat of reaction is 10 kJ/mol

(B) It is an exothermic reaction
(C) The threshold energy of reaction is 31 kJ/mol
(D) The potential energy of product is 22 kJ/mol

8) For an ideal gas, consider only P−V work in going from an initial state X to the final state Z. The
final state Z can be reached by either of the two paths shown in the figure. Which of the following
choice(s) is (are) correct? [Take ΔS as change in entropy and w as work done]

(A)
(B)
(C)
(D)

9) 1 mole benzene ( = 42mm of Hg) and 2 mole toluene ( = 36mm of Hg) will have

(A) total vapour pressure 38 mm of Hg

(B) mole fraction of vapours of benzene above liquid mixture is 7/19
(C) positive deviation from Raoult’s law
(D) negative deviation from Raoult’s law

10) Correct acidity order of the following substrate in H2O solvent.

(A) b < c < a

(B) b >a
(C) b >c >a
(D) c >b

SECTION-I (ii)

1) Match the following

Column – I (Using Pt electrode) Column – II

(A) Aqueous solution of HCl (p) O2 evolved at anode

(B) Aqueous solution of NaCl (q) H2 evolved at cathode

(C) Molten NaCl (r) Cl2 evolved at anode

(D) Aqueous solution of AgNO3 (s) Na deposited at cathode

(t) Ag deposited at cathode

(A) A → pq;B → rs;C → st;D → pr
(B) A → pr;B → qr;C → st;D → pq
(C) A → qr;B → qr;C → rs;D → pt
(D) A → qr;B → pq;C → st;D → rs

2) Match the following

List – I (Thermodynamics process) List – II (ΔS System)

(P) Isothermal reversible (1)

 (Q) Adiabatic irreversible (2)

(R) Isochoric reversible (3)

(S) Isobaric reversible (4)

(A) P → 3;Q → 4;R → 1;S → 2

(B) P → 2;Q → 1;R → 3;S → 4
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 4;Q → 3;R → 1;S → 2

SECTION-III

1)

A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0 % to the total weight of the hydrolyzed products. The
number of glycine units present in the decapeptide is (nearest integer)

2)

Number of monohalogen derivative (excluding stereo isomers) for the following is

3) Number of co-ordination isomerism for the complex is (including itself)

4) Number of stereo isomers in the complex [Ma2b2c2] [where a, b, c are monodentate ligand]

5)
If x moles of HI can be completely consumed by one mole of the above compound, what is the value
of x?
6)
How many maximum moles of HI is needed for complete reaction of one mole of the above
compound ?

7) PhCO2H+NaHCO3 →A(gas)
PhOH+NaNH2 → B (gas)
CH3OH+NaH → C(gas)
CH3SH+ EtLi→D (gas)
PhSO3H+Na → E (gas)
If the molecular weight of A, B, C, D, E is x, y, z, w, v. then find the value of (y + z + w + v) – x.

8) In 2nd order reaction: 2A → A2, the rate of formation of A2 is 10–5 M sec-1 and the rate of
disappearance of A is x × 10–5 M sec-1 find out the value of x ?

PART-3 : MATHEMATICS

SECTION-I (i)

1) If g(x) = x2 – x + 1 and ƒ(x) = , then -

(A) Domain of ƒ(g(x)) is [0,1]

(B)
If f(g(x)) exists then range of g(x) is
(C) ƒ(g(x)) is many-one function
(D) ƒ(g(x)) is unbounded function

2) Given three vectors ; ; . Which of the following

hold good for the vectors ?

(A) are linearly dependent

(B)
(C) form a triplet of mutually perpendicular vectors
(D)

3) Let ƒ : and g : be two non-constant differentiable functions. If ƒ'(x) = (e(ƒ(x) –

g(x)))
g'(x) for all , and ƒ(1) = g(2) = 1, then which of the following statement(s) is (are) TRUE ?

(A) ƒ(2) < 1 – loge2

(B) ƒ(2) > 1 – loge2
(C) g(1) > 1 – loge2
(D) g(1) < 1 – loge2

4) Let R1 = then.
R2 =
R3 =

(A)
Area formed by R1 is sq units

(B)
Area formed by R2 is sq units

(C)
Area formed by R1 R2 is units

(D)
Area formed by R1 R2 R3 is sq units

5) Let . If and , then which of the

following holds good?

(A)
(B)
(C)
(D) If , then a + b + c = –13

6) If = y2 + 4y + 5, then y can be equal to-

(A) 1
(B)
(C)
(D)

7) If (where c ≠ 0), then has the............ equal to :

(A)

(B)

(C)

(D)
8)

A square matrix A with elements from the set of real numbers is said to be orthogonal if If
A is an orthogonal matrix, then :

(A) is orthogonal
(B) is orthogonal
Adj. A =
(C)

(D) |A-1| = 1

9) If and then-

(A) I3 > I4
(B) I3 < I4
(C) I1 > I2
(D) I2 > I1

10) If f(x) = Then,

(A) f(1+) + f(1–) = 0

(B) f(1+) + f(1–) + f(1) = 3/2
(C) f(–1+) + f(–1–) = –1
(D) f(1+) + f(–1–) = 0

SECTION-I (ii)

1)

Column-I Column-II

(P) The value of cot20° cot40°+ cot40°cot80° – cot20°cot80° is (1) 11

Let if the maximum value

(Q) (2) 3
of sinα+ sinβ is (p and q are co-prime numbers) then
(p + q) equals

(R) (3) 4
If cosA , then value of

(S) (4) 7

is
 (5) 2
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 2;Q → 4;R → 1;S → 5
(C) P → 2;Q → 4;R → 3;S → 5
(D) P → 3;Q → 1;R → 4;S → 2

2)

Column-I Column-II

(P) (1) 0
If , then k is greater than

(Q) (2) 1
If , then ak is less than

(R) (3) 3
If , then k is less than

(S) (4) 4
If , then is greater than

(5) 2

(where C is constant of integration)

(A) P → 1,2;Q → 4,5;R → 2,3,4;S → 1,5
(B) P → 2,4;Q → 3,5;R → 1,2;S → 4,5
(C) P → 1,2;Q → 3,4,5;R → 3,4;S → 1,2
(D) P → 2,3;Q → 4,5;R → 2,3,4;S → 1,5

SECTION-III

1) is equal to

2) The number of solutions of sin3xcosx + sin2x cos2x + sinxcos3x = 1 in [0, 2π] is

3) is :-

4) If ƒ(x) = and ƒ(1) = 0, then the value of |3ƒ (e2)| is equal to

5)
Consider a 3 × 3 matrix where ∀ i,j ∈ {1,2,3}. If matrix of order 3 × 3

exists such that A–1=3B, then the value of is (where |X| denotes determinant value of matrix
X)

6)

The number of x in (0, 2π) satisfying the equation 1 + sin 2x = sin x + sin2x is

7)

The solution of is where c is constant then, find the value

of p + q ?

8)

If and then λ = ?
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6 7 8 9 10
A. A,B A,B,C,D B,D A,B A,B,D B,C A,C A,B A,B,C A,C

SECTION-I (ii)

Q. 11 12
A. D C

SECTION-III

Q. 13 14 15 16 17 18 19 20
A. 3 6 7 6 1 5 8 4

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 21 22 23 24 25 26 27 28 29 30
A. C,D A,B,C,D A,B,D A,B,C,D C,D B,C,D A,C,D A,C A,B B,C

SECTION-I (ii)

Q. 31 32
A. C D

SECTION-III

Q. 33 34 35 36 37 38 39 40
A. 6 4 2 6 7 6 7 2

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 41 42 43 44 45 46 47 48 49 50
A. A,B,C B,C,D B,C A,D A,B,D B,D A,B,C A,B B,C B,C,D

SECTION-I (ii)

Q. 51 52
A. B C
 SECTION-III

Q. 53 54 55 56 57 58 59 60
A. 3 0 1 8 5 2 4 8
 SOLUTIONS

PART-1 : PHYSICS

1)

Conceptual

2)

Given:

Y(x, t) =
The general equation for a wave is given by f(ωt – kx) = Y(x, t);
Comparing with the given equation we get ω = 2rads–1
and k = – 4m–1

v=
v = –0.5 ms–1 (negative sign indicates travel in negative x direction)
The function obtains maximum displacement when (4x + 2t) vanishes (= 0)

At this point the displacement is = 0.01 m = 1 cm

We can also see that

What this implies is that the function Y(x, t) is symmetric about x =

Hence, the pulse is symmetric.

3)

Let M be the total mass of the rope and L be its length.

Tension at distance x from the bottom is given by

T=

Velocity of wave at distance x, v =

4)

=
x = 0.4, 0.5 m
x = 40, 50 cm

5)

Real, inverted, enlarged image

object ⇒ F to C
Image ⇒ beyond C

6)

Theory

7)

8)

Conceptual

9)

…(i)

…(ii)
Solving (i) and (ii)
10)

From conservation of linear momentum,

velocity of 1 kg block just after the collision is 2m/sec.

After the collision relative velocity of

approach = 6 m/sec,
Relative velocity of separation = 6 m/sec

11) For τ:

⇒ For qmax at steady state

Current passing through 10 V battery =

VA – VB = 5V
qmax = 1 µC
⇒ At time t = 1 sec
q = 1 (1–e–t) = 0.63 µC
From KVL

i1 = 1.54 µA

12)

Conceptual

13) Time taken by wave to travel from x = 0 to x = 4cm

Displacement at x = 4 at t = 5 is same as displacement at

x = 0 at t = 3
At t = 3 y at x = 0
y = 6 – 3 = 3mm

14) B = µ0ni

15)

dm = ρ0r4πr2dr

Inside

g1 = Gρ0πx2
Outside-

Given
gsurface = Gρ0πR2

α=9
β=2
16) (P)

vab = IR =

Rab =

ρmax = = 6 watt

17) It forms wheatstone bridge

Req = 3.5 + 4.5 = 8Ω

i= = 1A

18)

at ; vC = 5 V

19)

Velocity perpendicular to the wedge before collision =

∴ after collision velocity of ball =

 ∴
(velocity along the incline will not change)

20)

C and D are same potetial.

PART-2 : CHEMISTRY

21) (A) 4 amino acids

(B) Both shows positive
(C) Osazone
(D) No free hemiacetal

22) Theoretical
ΔSsystem should be negative.

23) Enolisation & hemiacetal

24)

uf → f
ΔG = ΔH - TΔS
For spontaneous ΔG = –ve

25) ‘VBT’ with SFL pairing occur.

26) Fluorine is more activating than chlorine due to greater +R effect.

27) Heat of reaction = 19 – 9 = 10(It is not a exothermic reaction)

28) [entropy(S) is a state function, hence additive]

[work done in Y → Z is zero as it is an isochoric process]

29)

30) a b→ pKa = 4.76

a c → pKa = 9.95
a a → pKa 16 −17

31)

Theory Based

32)

Theory Based

33)

Molar mass of decapeptide = 796 g mol-1

Decapeptide contains nine peptide linkages. So one mole of decapeptide absorbs 9 moles of
H2O for hydrolysis.
∴Mass of all amino acids obtained after hydrolysis = 796 + 18(9) = 958 g mol-1
Glycine contribute = 47%

∴ Mass of glycine = ×958 = 450.26 g

Molar mass of glycine = 75 g mol-1

∴ Number of glycine molecules =

34)

35) [Pt(NH3)4] [PtCl4] and [Pt(NH3)3 Cl] [PtCl3NH3]

36) Number of stereo isomers for the complex is 6.

 37)

38)

39) A → CO2
B → NH3
C → H2
D → CH3 – CH3
E → H2
(y + z + w + v) – x ⇒ (17 + 2 + 30 + 2) – 44
=7

40)

PART-3 : MATHEMATICS

41)

ƒ(g(x)) =

(A) Domain of ƒ(g(x)) : x – x2 ≥ 0 ⇒ x∈[0, 1]

(B) Range of ƒ(g(x)) : g(x) = x2 – x + 1, x∈[0, 1]
⇒
(D) Hence ƒ(g(x)) is bounded.
(C) ∵ g(x) is many one in [0, 1]
∴ ƒ(g(x)) is many one.

42)

Thus are non-coplannar therefore

are linearly independent

=0–0=0

forms triplet of mutually perpendicular

similarly
Thus B, C, D are correct.

43)

f′(x) = ef(x)–g(x) g′(x) given f(1) = g(2) = 1

e–f(x) = e–g(x) + C

put x = 1 ⇒ C =

x = 2 ⇒ ef(2) =
⇒ g(1) > 1 – loge 2 & f(2) > – loge 2

44)
45)

46)

y2 + 4y + 5 =

47) ..........(1)

................(2)
from 1 + 2
On putting value of C, other form of can be arrived.

48)

49)

I3 < I4 and I1 > I2

50)

∴ f(1+) = f(–1–) = 0
f(1–) = 1, f(–1+) = –1
f(1) = 1/2

51) (P) cot20°cot40° + cot40°cot80° – cot20°cot80°

⇒ (cot20°cot40° – 1) + (cot40°cot80° – 1)
– (cot20°cot80° + 1) + 3
⇒ cot60°(cot20° + cot40°) + cot120°(cot40° + cot80°) – cot60°(cot20° – cot80°) + 3 = 3

(Q) sinα + sinβ =

⇒ max(sinα + sinβ) =

(R) ,
16(cos2A – cos3A)
⇒ 16((2cos2A – 1) – (4cos3A – 3cosA))
16(2cos2A – 1 – 4cos3A + 3cosA)

⇒ =11
(S) ⇒x=2
⇒ y = 18

52) (P)
let 2x = t

(Q)

(R)

k=2

(S)
53)

54) sin3xcosx + sin2xcos2x + sinx cos3x = 1

sinx cosx + (sinx cosx)2 = 1
Let sinx cosx = t
t2 + t – 1 = 0

not possible

55)

0
ℓ1 = e = 0

⇒
ℓ1 + ℓ2 = 1

56) Put ℓnx = t ⇒ dx = etdt

⇒ ƒ(x) =
∴ ƒ(1) = 0 + C
⇒C=0
∴ ƒ(x) =

ƒ(e2) =
⇒ 3ƒ(e2) = –8

57)

58)

y = 1 + sin2x and y = sin2x + sinx will intersect twice in (0, 2π).

59)

or

⇒
⇒

60)