Chemstry Paper II
Chemstry Paper II
Chemstry Paper II
Note:
1. 2. 3. 4.
All questions are compulsory All question carry equal marks Give balanced equations and draw diagrams, wherever necessary Figures to the right hand side indicate marks.
Q.1. Select and write the most appropriate answer from the given alternatives for each sub-questions:
[08 M] 1. Which of the following is used as an antiseptic a. Bleaching power b. Thymol c. Tincture iodine d. Chloroform 2. In esterification reaction, conc.H2SO4 act as a. Dehydrating agent b. Hydrating agent c. Catalyst d. Sulphonating agent 3. Which of the following amines give yellow oily liquid with nitrous acid a. Ethyl amine b. Methyl amine c. Diethyl amine d. Triethyl amine 4. Ethanol and phenol are distinguished from each other , by the action of a. Neutral ferrous chloride b. Neutral ferric chloride c. Ferric hydroxide d. Ferrous hydroxide 5. Which of the following statements is correct about SN2 mechanism? a. Two step reaction b. Complete inversion of configuration c. Formation by polar solvent d. Favoured by polar solvent 6. A + B Dryether Complex H2O/H+ Ethyl methyl ketone. In above reaction , A and B are a. Formonitril, Propyl magnesium bromide b. Ethyl cyanide, Ethyl magnesium bromide c. Hydrogen cyanide, Ethyl magnesium bromide
d. Acetonitrile, Ethyl magnesium bromide. 7. Colour of tripositive ion of lanthanides series elements are due to a. Lanthanide contraction b. Their catalytic properties c. Number of unpaired electrons in 4f orbitals. d. Uniform +3 oxidation state 8. Which of the following is NOT true about Glucose? a. It is monosaccharide b. It is polyhydroxide aldehyde c. It is polyhydroxy ketone d. It contains six carbon atoms.
[ 02 M]
2. What are antibiotics ? What is the difference between bactericidal and bacteriostatic antibiotics?
1. Why does the basicity of hydroxides of lanthanide series elements decrease with increase in atomic number? 2. State and explain Markownikoff,s Rule with a suitable example.
[02 M]
1. From methyl magnesium iodide , how are the ethanol and propan-2-ol are prepared?
[04 M]
1. What are synthetic fibres/ How is terylene prepared? 2. Define asymmetric carbon atom and explain optical activity of 2-chlorobutane
[ 03 M]
[03 M]
[02 M] [04 M]
[04 M]
2. What are amine ? What is the action of acetyl chloride on ethanamine, N-ethyl ethanamine and N,N-Dimethyl ethanamine?
1. What are ethers/ Classify proteins on the basis of hydrolysis products and give examples. 2. How will you prepare trichloromethane (Chloroform) from ethanol?
[04 M]
[04 M]