Term II reexam chemistry qp class 11 (1)

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D.A.V. SR SECONDARY SCHOOL CHENNAI -37

REEXAMINATION 2021-2022
CHEMISTRY THEORY (043)
CLASS: XI TERM-II MAX. MARKS: 35
DATE: 19/03/2022 TIME: 2.00Hrs
GENERAL INSTRUCTIONS:
Read the following instructions carefully.
1. There are 12 questions in this question paper with internal choice.
2. SECTION A- Q. No 1 to 3 are very short answer questions carrying 2 marks each.
3. SECTION B- Q. No 4 to 11 are short answer questions carrying 3 marks each.
4. SECTION C- Q. No 12 is case based question carrying 5 marks.
5. All questions are compulsory.
6. Use of log tables and calculators is not allowed.
SECTION-A
1. The following concentrations were obtained for the formation of NH3 from N2 and H2 at
equilibrium at 500 K. [N2]= 1.5×10-2 M, [H2]=3.0×10-2 M and [NH3]=1.2×10-2 M, calculate
the equilibrium constant. (2)
2. Answer any two from the following : (1x2=2)
(a) Why are alkali metals soft and have low melting points?
(b) What makes Be to show anomalous properties as compared to rest of the

alkaline earth metals?
(c) Name the three types of oxides formed by potassium when it reacts in air.
3. (a) Write reactions to justify amphoteric nature of aluminum (1)
(b) Define common ion effect? (1)
SECTION-B
4. (a). Write the structural formula of the following: (1)
(i) 2,5 - Dimethyloctane (ii) 4-Methylhex-3-ene
(b) The boiling point 2,2-dimethylpropane is less than pentane. Give reason. (1)
(c) Draw the structure of the staggered newman conformer of ethane. (1)
(OR)
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4. Complete the following reaction. (1+1+1)

𝑅𝑒𝑑 ℎ𝑜𝑡 𝑖𝑟𝑜𝑛 𝑡𝑢𝑏𝑒
(i) CH≡CH → ?
873𝐾
Na/NH3
(ii) CH3−C≡CH + H2 →−−→ ?
(iii) 2CH3Cl + Na (dry ether) → ?
5. (a) (i) Why real gases deviate from ideal behavior? (½)
(ii) What is compressibility factor? (½)
(b) At 25°C and 760 mm of Hg pressure a gas occupies 600 mL volume. What will
be its pressure at a height where temperature is 10°C and volume of the gas is
640 mL. (2)
(OR)
5. (a) State Boyle’s law. (1)
(b) What will be the total pressure exerted by a mixture of 3.2g methane and 4.4g
carbon dioxide in a 9dm3 flask at 27oC. (R= 0.082 L atm K-1mol-1) (2)
6. (a) Explain Isomerisation reaction with an equation? (1)
(b). Explain the mechanism of HBr addition on propene. (2)
7. (a) The ionization constant of HCOOH at 298K is 1.8 × 10–4 , Calculate

the ionization constant of the corresponding conjugate base. (1)
(b) State Le-Chatelier’s principle. (1)
(c) Predict in each of the following cases whether appreciable concentration of

reactants or products will prevail at equilibrium. (1)
(i) N2(g) + 3H2 ⮀ 2NH3(g) Kc = 5x10-30
(ii) Cl2(g) + H2O(g) ⮀ HOCl(g) +HCl(g) Kc = 108

(OR)
7. (a) Write the conjugate acid and base for H2O (1)
(b) Identify the Lewis acid and bases from the following
NH3, BF3, C2H5OH , BeCl2 (2)

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8. (a) Why does boron not form B3+ ions? (1)
(b). Explain why PbI4 does not exist (1)
(c). Identify the amphoteric and neutral oxides among the following: (1)
CO, CO2, SnO2, GeO2, PbO2, SiO2
(OR)
8. (a)Differentiate the various allotropes formed by Carbon? (2)
(b) [SiF6]2- is known whereas [SiCl6]2- is not. Give reason to justify the statement. (1)
(c) Standard electrode potential values, E° for Al3+/Al is –1.66 V and that of Tl3+/Tl is
+1.26 V. Predict about the formation of M3+ ion in solution and compare the
electropositive character of the two metals (1)
9. Illustrate the following reactions by giving equations. (1x3=3)
(a) Friedel-Crafts acylation reaction
(b) Nitration of Benzene
(c) Kolbe electrolytic method.
10. (a). Beryllium and Magnesium do not impart colour to the flame. Give reason (1)
(b). Write the products obtained on decomposition of LiNO3 and NaNO3 when
heated? (1)
(c). Chlorides of Mg & Ca exist as hydrates Givereason. (1)
SECTION C
11. Read the passage given and answer the questions that follow.
Thermodynamics deals with energy changes of macroscopic systems.

Systems are classified into three types and the properties of the system are the bulk
behaviour of matter called macroscopic properties which are divided into extensive and
intensive properties.
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Every system has definite energy in the form of heat (q) or work (w), which can be
exchanged between system and surroundings. This exchange of energies can be
represented by sign conventions. During physical or chemical change, the energy may
be converted from one form to another but the total energy remains constant. So, the
first law of thermodynamics is mathematically represented as ∆U = q + w.
Heat absorbed or evolved in a reaction at constant volume is internal energy

change, ∆U and at constant pressure is enthalpy change, ∆H and their relationship is
more significant in reaction involving gaseous reactants and products.
The enthalpy changes of a reaction can be measured as the difference between

the sum of the enthalpies of the products and sum of the enthalpies of reactants. The
enthalpy changes are expressed in different ways depending upon the nature of the
reaction. The various types of enthalpies are, enthalpy of formation, enthalpy of
combustion, enthalpy of solution, enthalpy of atomisation, enthalpy of hydration and also
lattice enthalpy using Hess’s law. Applications of Hess’s law is used to measure lattice
enthalpy using Born Haber cycle and enthalpy of formation or hydration of substances
where direct measurement is not possible.
(a) What are extensive properties? Give an example. (1)
(b) Find the internal energy change when 62J of work is done by the system and 128J
of heat is transferred to the surroundings? (1)
(c) How are ∆G and ∆H related to a thermodynamic reaction? (½)
Find the value of ∆ng for the reaction (½)
C2H5OH (l) + O2 (g) → CO2 (g) + H2O (l)
(d) Enthalpy of formation of CO (g) , CO2 (g) , N2O (g) and N2O4 (g) are −110, −393, 81,
and 9.7 KJ mol-1 respectively. Calculate enthalpy change for the reaction,
N2O4 (g) + 3CO (g) → N2O (g) + 3CO2 (g) (2)
(OR)
a) For oxidation of iron
4Fe (s) +3O2 → 2Fe2O3(s)

entropy change is – 549.4 JK–1mol–1at 298 K. Inspite of negative entropy change of
this reaction, why is the reaction spontaneous? (∆rH0 for this reaction is –1648
kJ mol –1)
(2)
****************************************

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D.A.V. SR SECONDARY SCHOOL CHENNAI -37

equilibrium at 500 K. [N2]= 1.5×10-2 M, [H2]=3.0×10-2 M and [NH3]=1.2×10-2 M, calculate

the equilibrium constant. (2)

2. Answer any two from the following : (1x2=2)

(b) What makes Be to show anomalous properties as compared to rest of the

3. (a) Write reactions to justify amphoteric nature of aluminum (1)

(b) Define common ion effect? (1)

4. (a). Write the structural formula of the following: (1)

(i) 2,5 - Dimethyloctane (ii) 4-Methylhex-3-ene

4. Complete the following reaction. (1+1+1)

(iii) 2CH3Cl + Na (dry ether) → ?

(ii) What is compressibility factor? (½)

640 mL. (2)

5. (a) State Boyle’s law. (1)

6. (a) Explain Isomerisation reaction with an equation? (1)

(b). Explain the mechanism of HBr addition on propene. (2)

7. (a) The ionization constant of HCOOH at 298K is 1.8 × 10–4 , Calculate

(b) State Le-Chatelier’s principle. (1)

(c) Predict in each of the following cases whether appreciable concentration of

(i) N2(g) + 3H2 ⮀ 2NH3(g) Kc = 5x10-30

(ii) Cl2(g) + H2O(g) ⮀ HOCl(g) +HCl(g) Kc = 108

NH3, BF3, C2H5OH , BeCl2 (2)

8. (a) Why does boron not form B3+ ions? (1)

(b). Explain why PbI4 does not exist (1)

CO, CO2, SnO2, GeO2, PbO2, SiO2

8. (a)Differentiate the various allotropes formed by Carbon? (2)

electropositive character of the two metals (1)

9. Illustrate the following reactions by giving equations. (1x3=3)

(a) Friedel-Crafts acylation reaction

(b) Nitration of Benzene

(c) Kolbe electrolytic method.

(c). Chlorides of Mg & Ca exist as hydrates Givereason. (1)

Thermodynamics deals with energy changes of macroscopic systems.

Heat absorbed or evolved in a reaction at constant volume is internal energy

The enthalpy changes of a reaction can be measured as the difference between

(a) What are extensive properties? Give an example. (1)

of heat is transferred to the surroundings? (1)

(c) How are ∆G and ∆H related to a thermodynamic reaction? (½)

Find the value of ∆ng for the reaction (½)

C2H5OH (l) + O2 (g) → CO2 (g) + H2O (l)

N2O4 (g) + 3CO (g) → N2O (g) + 3CO2 (g) (2)

a) For oxidation of iron

4Fe (s) +3O2 → 2Fe2O3(s)

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