Called ASPA - Alumino Silicate Poly Acrylate Cements
Called ASPA - Alumino Silicate Poly Acrylate Cements
Powder :-
Liquid :-
Polyacrylic Acid
Itaconic Acid - 40-55%
Maleic Acid
Tartaric Acid - 5-15%
Water - 30%
Indication :-
Restoration of deciduous teeth.
Long-term temporary restorations.
Liner/base application.
ART technique.
RESIN MODIFIED COMPOMER
GLASS IONOMER
Application CEMENT,RESTORATIV RESTORATIVE
E
Acid-base setting reaction YES NO
Polymerization setting YES YES
reaction
VLC depth of cure (mm) 2.7 4.7
Radiopacity (mm of Al) 1.8 3
Water 174 26
absorption(ụg/mm3)
Fluoride release(ụg/cm2) 21.2 7.8
Stage 1 Dissolution :-
The surface of glass particles is attacked by the polyacid results
in dissolution of the surface of the glass particles releasing calcium
and aluminium ions to the formation of a cement sol.
Stage 2 Precipitation of salts; gelation and hardening :-
Calcium and aluminium ions bind to the polycarboxylate groups.
Initial set : Due to cross-binding of the more readily available
calcium ions, complete within 4-5min after mixing.
Final set : Occurs over next 24hrs when the aluminium ions get
bound within the cement matrix to form a more rigid cross-linking
between the polyacid chains.
Sodium and fluoride ions do not take part in the cross-linking of
cement.
Unreacted portions of the glass particles are sheathed by a silica
gel which develops during removal of cations from the surface of the
particles.
Stage 3 Hydration of salts :-
Progressive hydration of matrix salts which leads to a sharp
improvement in the physical properties of the cement.
Structure of the set Conventional Glass Ionomer Cement :-
1) Hand Mixing :-
Great care is required to ensure proper powder-liquid ratio.
Mixing may be done in a cool, dry glass slab or a paper pad using a thin-bladed plastic spatula.
Main objective of mixing is to wet the Surface of each glass particle with the liquid.
The powder is divided into two halves.
The first half is rapidly incorporated into the liquid within 10 seconds by gently but rapidly rolling the
powder into the liquid.
The second half is then incorporated and mixed within 15
seconds.
Mixing should be completed within 25-30 seconds.
The finished mix should be ‘glossy wet’ on the surface.
The working time for the mixed cement is 1-2 minutes.
2) Mechanical Mixing :-
Pre-proportioned capsules provide consistent powder-liquid
ratio, mechanical mixing in an amalgamator ensures standardized
mixing and setting times.
The material can also be syringed into the cavity and
exhibits optimum physical properties.
The loss of gloss/slump test helps in checking the efficiency
of the mechanical mixer.
Properties of Glass Ionomer Cements :-
5.Radiopacity :-
- Conventional glass ionomer cements are radiolucent.
- Resin-modified and luting glass ionomer cements are
radiopaque due to the presence of lanthanum, barium or strontium in
the powder.
- Metal modified glass ionomer are more radiopaque due to
presence of silver particles.
6.Strength and Fracture resistance :-
- The compressive strength is similar to that of zinc phosphate
cement.
Type I 70-150MPa
Type II 140-220MPa
- The tensile strength is slightly higher than that of zinc
phosphate cement.
- The modulus of elasticity ranges from 7GPa to 13GPa.
- Weak and lack fracture resistance when compared to composite
resins and amalgams.
7.Abrasion resistance :-
- Less resistance to abrasion than composite resins but improves
as the cement matures.
- Cermet ionomers have improved abrasion resistance due to the
presence of silver particles.
8.Solubility and disintegration :-
- Exhibits low solubility in the oral environment.
- Resin modified glass ionomer cements are more resistance to
solubility and disintegration than conventional glass ionomer
cements because of initial setting by polymerization.
2.Anticariogenic effect :-
- Released fluoride which prevents development of recurrent caries
and also plaque accumulation on the surface of glass ionomer
restoration.
3.Acceptable esthetics :-
- Available in various shades which exhibit good colour matching &
translucency.
4.Low solubility :-
Less soluble than other restoration.
5.Biocompatibility :-
Pulpal response to glass ionomer cement is favourable.
Freshly mixed cement is acidic in nature.
3.Colour :-
Autocured glass ionomer cements are not as esthetic as composite resins.
2.Class I restorations :-
- Indicated for restoration of buccal and lingual pits in molars and
lingual pits in anterior teeth.
3.Tunnel restorations :-
For restoring initial proximal caries in posterior teeth as tunnel
restoration.
5.Class V restorations :-
- Preferred materials for carious and non-carious Class V cavities.
6.Root caries :-
- Due to adhesive potential and fluoride releasing capacity, used for
caries involving root surfaces.
7.As a liner/base :-
- Preferred as a liner/base beneath composite resins, amalgam and cast restorations
because of its adhesive nature and biocompatibility known as “Sandwich Technique”.
10.Luting cement :-
- Employed for luting inlays, onlays, crowns, orthodontic bands, pots and fixed
partial dentures.
13.In endodontics :-
- As an endodontic access filling material, root canal sealer, repair material for
root perforations and as a retrograde filling material.
Contraindications of Glass Ionomer Cements :-
2) Labial buildup :-
- When large areas of labial enamel in anterior teeth has to be
replaced as in case of discolouration, abrasion or fractures because of
its esthetic is not as composite.
3) Cuspal coverage :-
- Not suited for cuspal replacement due to their lack of strength,
rigidity and fracture toughness.
4) In mouth-breathers :-
The restoration becomes opaque, brittle and disintegrate over a short
period of time.
General Clinical Steps For Glass Ionomer Restorations :-
Isolation :-
Highly sensitive to moisture contamination during placement so care
should be taken to isolate the tooth surface properly using rubber dam,
cotton rolls, retraction cords and saliva ejectors.
Tooth preparation :-
a) Cavity preparation :-
Required while restoring Class III or Class V carious lesions.
Cavity preparation should be dictated only by the extent of caries.
No mechanical retentive features are necessary.
For abrasion and erosion defects there is no need for cavity preparation.
Prophylaxis followed by surface conditioning is mandatory.
a) Prophylaxis :-
Done using pumice slurry carried in a bristle brush.
This will remove any plaque or salivary pellicle from the tooth surface.
b) Surface conditioning :-
This is an important step in promoting good adhesion of glass ionomers.
Various agents have been tried for conditioning the tooth surface, such as :
10% Citric Acid.
3% Hydrogen Peroxide.
10% EDTA.
25% Tannic Acid.
10% Polyacrylic Acid.
Of these agents, 10% polyacrylic acid applied for 10 to 25 seconds
is most widely accepted.
Advantages of conditioning with polyacrylic acid:-
- It lowers the surface energy of the tooth thus increasing the
wettability by glass ionomer cement.
- It removes the smear layer while retaining the smear plugs.
- Being part of the glass ionomer system any residues left over will
not interfere with the setting reaction of the cement.
Clinical Procedure :-
a) Fissure widening :-
- Done by using fine tapered diamond bur in a high speed
handpiece under air/water spray open the fissure slightly which
ensure better flow and retention of the glass ionomer cement.
b) Conditioning :-
- After isolation, the tooth surface should be conditioned using 10%
polyacrylic acid for 10 to 15 seconds, washed thoroughly and
gently dried.
c) Cement Placement :-
- A type III conventional glass ionomer cement or a restorative type
resin-modified cement is mixed in the recommended powder-liquid
ratio and syringed into the pit and fissures.
- After setting, the excess material can be trimmed with a sharp
spoon excavator.
- Protected by light cured bonding agents.
Advantages :-
Adhesion to enamel by an ion-exchange mechanism.
Fluoride release.
Disadvantages :-
Cement will not flow into pits and fissures that are not patent.
Retention rates are flow.
2.Tunnel restoration
First described by Jinks in 1963 as a conservative alternative
for Class II cavity preparation in primary molars.
Indications :-
- Patients with high esthetic demand and low caries rate who exhibit
involvement of the marginal ridge.
Contraindications :-
Large proximal caries involving marginal ridges.
Difficulty in access.
Marginal rides subjected to excess occlusal loads.
Clinical technique :-
- Following rubber dam isolation, access is gained to the proximal
caries through the occlusal aspect 2mm away from the marginal
ridge on the involved side.
- A “tunnel” is prepared diagonally under the marginal ridge into
the proximal carious dentin.
- Proximal enamel may be preserved or removed depending upon
its status.
- During restoration, a sectional matrix band is adapted and secured
by a wooden wedge.
- Cermet ionomer were originally used to restore cavities.
- After one to two weeks, the occlusal 1.5 to 2mm of the preparation
can be filled with composite resins as they are more wear resistant.
Advantages :-
- Marginal ridge is preserved.
- The perimeter of the restoration is reduced minimizing
microleakage.
- The adjacent tooth is protected.
- If the need arises in future a conventional approach can be adopted
and a regular Class II cavity prepared.
Disadvantages :-
- Poor visibility and lack of control over caries removal.
- Marginal ridge may be undermined.
- Preparation may extend closer to the pulp than desired.
3.The Atraumatic Restorative Technique (ART) technique
Modern restorative dentistry requires electrically powered
equipment to perform various procedures.
So, restoration of carious tooth are not possible in the
developing countries especially in remote areas due to lack of water,
electricity and equipment.
Hand instruments are used to excavate the soft caries followed
by restoring the cavities with a highly viscous version of autocure
glass ionomer cement.
Indications :-
- Occlusal pit and fissure cavities of small to moderate size with
adequate tooth structure to surround the restoration.
- Less industrialized countries.
- Physically or mentally handicapped patients, refugees, children,
patients receiving home care services, etc.
Clinical procedure :-
- Teeth are isolated with cotton rolls.
- Undermined enamel is broken away using hand instruments
such as hatchets.
- Caries is excavated using spoon excavators.
- A highly viscous glass ionomer cement is placed into the
cavity and pressed by means of a gloved finger to fill the adjacent
pits and fissure also.
- Occlusion is checked and excess material is removed before
it hardens.
- The restoration is finally coated with Vaseline or petroleum
jelly.
Advantages :-
- Maximum preservation of the tooth structure.
- Minimal intervention procedure.
- Benefits of glass ionomer cement – adhesion, fluoride release,
biocompatibility.
- No need of sophisticated equipment or electricity.
- Minimal discomfort to patient.
- Low cost of the treatment.
Disadvantages :-
- Hand fatigue during instrumentation.
- Lack of proper access and visibility especially in extreme
posterior region.
4.Glass ionomer cement as liners and bases
Type III glass ionomer cements are used as liners and bases
under various restorations.
Lining cements :-
- Used in a low powder-liquid ratio (1.5:1).
- Employed under any restoration when the cavity is deep.
- Used in thin section and should not be exposed to the oral
environment.
- Flow easily and fill deeper portions of the cavity.
- Seal the dentinal tubules.
- Prevent thermal insult to the pulp.
Base cements :-
- Used in a high powder-liquid ratio (3:1).
- Employed as bases beneath restorations, has to be placed in bulk.
- Considered as dentin substitutes and form an integral part of final
restoration.
“Sandwich” technique :-
Clinical steps :-
- After cavity preparation, condition the cavity to develop good
adhesion with the glass ionomer.
- A fast setting type III glass ionomer cement is used to replace the
lost dentin in sufficient bulk.
- Once it has set, cut back to expose the enamel margins and to allow
enough bulk for composite resins.
- Etch the enamel and autocured glass ionomer cements for 15
seconds using phosphoric acid which improve the micromechanical
bond to composite resins.
- Wash and gently dry.
- Apply a thin coat of a low viscosity enamel bonding agent on the
enamel and glass ionomer base and light cure for 20 seconds.
- Proceed with composite resin buildup.
Advantages :-
- Favourable pulpal response due to biocompability of glass ionomer
cement.
- Ion-exchange adhesion of glass ionomer to dentin prevents
microleakage.
- Fluoride release from glass ionomers minimizes recurrent caries.
- Excellent subgingival response.
- By minimizing the bulk of the composite resin, polymerization
shrinkage of the resin is reduced.
- Better strength, finish and esthetics of the overlying composite.
Disadvantages :-
Time consuming procedure.
Technique sensitive.
5.Class III glass ionomer restorations
Indication :-
Patient with high caries incidence.
When the labial enamel is intact.
Low occlusal stress and margins are not in areas of occlusal
contact.
Clinical Procedure :-
a. Local anaesthesia : To increase patient comfort and co-operation.
e. Surface conditioning :
- Done using 10% polyacrylic acid applied for 10 to 15 seconds.
- The surface is then rinsed copiously with water and dried gently to
avoid dessication.
g. Finishing :
- Gross excess is trimmed by BP blade and surface is protected with
a resin bonding gent.
- Final finishing is done after 24hrs using finishing diamonds,
tungsten carbide finishing burs and Sof-Lex discs.
6.Class V glass ionomer restorations :-
Indications :-
- Patients with high caries intake.
- Several abrasion and erosion lesions.
- Where esthetics is not of prime concern.
- Root surface lesions as subginvival margins are suitable for glass
ionomer cements.
- Preferred materials for Class V lesions because of their adhesion
and also due to their flexibility-the low modulus of elasticity.
Clinical Preparation :-
a. Local anaesthesia : done to improve patient comfort and co-
operation.
g. Surface conditioning :
h. Manipulation : Same as Class III glass ionomer restorations.
I. Finishing :
7.Long-term temporary restorations using glass ionomer cements
Recommendation :
- As part of a caries control programme in acute carious lesions that
are raidly advancing towards the pulp.
- While awaiting the outcome of a pulp capping procedure.
8.Core buildup
Cermet ionomers are useful as core buildup materials especially
in posterior teeth.
Clinical steps :
- After tooth preparation, isolate using cotton rolls.
- Condition the dentin surfaces using 10% polyacrylic acid for 10
seconds, wash and gently dry.
- Mix cermet ioomers according to manufacturer’s instructions and
place using a syringe or plastic instrument.
- Matrix may or may not be used.
- Coat the cement surface with varnish to protect from moisture while
setting.
- The material sets fast.
- Following setting complete crown preparation and proceed with the
impressions.
Advantages :
- Adhesive properties.
- Caries resistance.
- Low thermal conductivity.
- Cohesive nature which makes placement easy without the need for
a matrix.
- Fast setting time which allow quick crown reparation.
9.Luting with glass ionomer cements :-
Useful for luting indirect restoration like inlays, onlays, crowns,
bridges as well as orthodontic appliances.
Manipulation :-
- The powder-liquid ratio : 1.5:1.0
- The setting time is 5 to 7 minutes.
- The freshly mixed cement has good thixotropic flow. So no need
for application of pressure after the restoration is fully seated.
Advantages :-
- Good flow characteristics.
- Low film thickness.
- Biocompatibility with the pulp and gingival tissues.
- Low solubility.
- Anticariogenic property due to fluoride release.
- Adhesive property.
- Tensile strength and abrasion resistance similar to zinc phosphate
cement.